• 멤브레인
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• 제34권1호
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• pp.10-19
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• 2024

바이폴라막은 양이온교환층과 음이온교환층 및 양극접합층으로 이루어진 이온교환막으로 물 분해 특성을 기반으로 하여 프로톤과 수산화 이온을 생성시키는 막이다. 이러한 특성을 이용하여 화학 산업, 식품 가공, 환경 보호, 에너지 변환 및 저장과 같은 다양한 응용 분야에서 연구가 되고 있다. 본 논문에서는 바이폴라막 기술에 대한 종합적인 이해를 제공하기 위해 바이폴라막의 개념 및 물 분해 메커니즘과 물 분해 촉매에 대한 조사하였다. 마지막으로 최근 에너지 기술에 적용되고 있는 바이폴라막 프로세스를 조사하였다.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2010년도 추계학술대회 초록집
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• pp.115.2-115.2
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• 2010

Autothermal reforming(ATR) processes of hydrocarbon liquids such as diesel fuels are spotlighted as methods to produce hydrogen for Fuel cell. However, the use of heavy hydrocarbons as feedstocks for hydrogen production causes some problems which increase the catalyst deactivation by the carbon deposition. Coking can be inhibited by increasing the water dissociation on the catalyst surface. This results in catastrophic failure of whole system. Performance degradation of diesel autothermal reforming leads to increase of undesirable hydrocarbons at reformed gases and subsequently decrease the performance. In this study, perovskite-based catalysts were investigated as alternatives to substitute the noble metal catalyst for the ATR of diesel. The investigated perovskite structure was based on LaCrO3. and metals were added at the A-site to enhance oxygen ion mobility, transition metals were doped on the B-site to enhance the reformation. Substituted Lanthanum chromium perovskite were made by aqueous combustion synthesis, which can produce high surface area. And for the homogeneous fuel supply, we made ultrasonic injection system for reforming. We compared durability of evaporation system and ultrasonic system for fuel injection.