• Corrosion Science and Technology
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• v.10 no.3
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• pp.95-100
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• 2011

Protective coatings play an important role in the protection of metallic structures against corrosive environment. The main function of anticorrosive coating is to prevent the materials from corrosive agents, such as water, oxygen and ions. In the study, the corrosion protection properties of urethane and epoxy coating systems were evaluated using EIS methods exposed to the corrosion acceleration test such as Norsok M501, Prohesion and hygrothermal cyclic test. AFM analysis of the coating systems was carried out to monitor the change of roughness of coatings. Urethane coating system was more stable than the epoxy coating under given cyclic conditions. Water uptake into the urethane coatings was less than that into the epoxy coating. The urethane coating system showed better corrosion protection than epoxy coating system based on the changes of the impedance modulus at low frequency region with exposure time. Consequently, the corrosion protection properties of the epoxy and urethane coatings was well correspond with their surface roughness changes and water uptakes.

• Corrosion Science and Technology
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• v.7 no.1
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• pp.27-34
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• 2008

In industrial and fluid handling systems, frequently the protective film forming materials suffer from severe corrosion due to microbial effects. As an example, various micro-organisms, including bacteria, exist in seawater normally fed to power and desalination plants. Unless seawater intakes are properly disinfected to control these microbial organisms, biological fouling and microbial induced corrosion (MIC) will be developed. This problem could destroy metallic alloys used for plant construction. Seawater intakes of cogeneration plants are usually disinfected by chlorine gas or sodium hypochlorite solution. The dose of disinfectant is designed according to the level of contamination of the open seawater in the vicinity of the plant intake. Higher temperature levels, lower pH, reduced flow velocity and oxidation potential play an important role in the enhancement of microbial induced corrosion and bio-fouling. This paper describes, in brief, the different types of bacteria, mechanisms of microbiological induced corrosion, susceptibility of different metal alloys to MIC and possible solutions for mitigating this problem in industry. A case study is presented for the power plant steam condenser at Al-Taweelah B-station in Abu Dhabi. The study demonstrates resistance of Titanium tubes to MIC.

• Corrosion Science and Technology
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• v.16 no.5
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• pp.265-272
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• 2017

Inhibition of pitting corrosion of the copper sprinkler tubes by removing dissolved oxygen in water with sodium sulfite was studied on the wet sprinkler systems operated in 258 household sites. First, air in the sprinkler tubing was removed by vacuum pumping. The tube was then filled with sodium sulfite dissolved in water. Sodium sulfite was very effective in maintaining a very low dissolved oxygen concentration in water in the sprinkler tube for the observation period of six months. Water leakage from the copper sprinkler tube was reduced significantly by using sodium sulfite. Both pitting corrosion process and pitting corrosion inhibition mechanism were investigated by examining microscopical and structural aspects of corrosion pits formed in failed copper sprinkler tube. Pitting corrosion was caused by pressurized air as well as sediments such as sand particles in copper tubes through oxygen concentration cells. It was confirmed microscopically that growth of corrosion pits was stopped by reducing dissolved oxygen concentration to a very level by using sodium sulfite.

• Corrosion Science and Technology
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• v.4 no.5
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• pp.178-190
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• 2005

In order to develop a new corrosion sensor for detecting and monitoring the external and internal corrosion damage of buried pipeline, the electrochemical property of sensors and the correlation of its output to corrosion rate of steel pipe, were evaluated by electrochemical methods in two soils of varying resistivity (5,000 ohm-cm, 10,000 ohm-cm) and synthetic tap water environments. In this paper, two types of galvanic probes were manufactured: copper-pipeline steel (Cu-CS) and stainless steel-pipeline steel (SS-CS). The corrosion behavior in synthetic groundwater and synthetic tap water for the different electrodes was investigated by potentiodynamic test. The comparison of the sensor output and corrosion rates revealed that a linear relationship was found between the probe current and the corrosion rates. In the soil resistivity of $5,000{\Omega}-cm$ and tap water environments, only the Cu-CS probe had a good linear quantitative relationship between the sensor output current and the corrosion rate of pipeline steel. In the case of $10,000{\Omega}-cm$, although the SS-CS probe showed a better linear correlation than that of Cu-CS probe, the Cu-CS probe is more suitable than SS-CS probe due to the high current output.

• Corrosion Science and Technology
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• v.4 no.3
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• pp.95-99
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• 2005

Wheel test and potentiodynamic polarization methods were used to evaluate the relative effectiveness of some hydrogen sulfide corrosion inhibitors for the wet gas pipeline API 5L grade X 65 steel. Five commercially corrosion inhibitors have been studied in the deoxygenated produced water solutions containing 10 ppm and 100 ppm of hydrogen sulfide. Based on the experiment results the steel corrosion inhibition mechanism in discussed and two most effective corrosion inhibitors are selected.

• Corrosion Science and Technology
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• v.11 no.5
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• pp.184-190
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• 2012

Cu alloy is widely used for marine applications due to its excellent ductility and high resistance for corrosion as wells as cavitation. However, long term exposure of the material to marine environments may result in damages caused by cavitation and corrosion. Water cavitation peening has been introduced in order to improve resistance of Cu alloy to corrosion and cavitation. The technology induces compressive residual stress onto the surface, and thus enhances the fatigue strength and life. In this study, the characteristics of the material were investigated by using water cavitaiton peening technique, and results showed that 2 minutes of water cavitation peening indicated the considerable improvement in hardness. On the other hand, over 10 minutes of water cavitation peening accelerated damages to the surface. In the case of ALBC3, water cavitation peening in the range of 2 to 10 minutes has shown the excellent durability and corrosion resistance while minimizing surface damages.

• Proceedings of the KIEE Conference
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• 2004.11a
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• pp.227-229
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• 2004

The corrosion rate of buried steel pipes for water works was investigated under soil environment. Steel pipe shows various characteristics caused by complicated environment condition of underground and especially the corrosion rate of it depends on the resistivity of soil controlled by content of water. In this paper, the corrosion behavior of steel pipe was observed by polarization test under soil and the silica sand in the water content range of 0-50%. Generally it is well known that the resistivity of soil decreased rapidly over 15% water content. In fact the corrosion rate, corrosion potential, and corrosion consumption (MPY) of steel pipe were shown very different aspects within 20% water content.

• Journal of Korean Society on Water Environment
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• v.28 no.4
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• pp.615-623
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• 2012

In this study, we evaluate the corrosion indexes (CI) such as Langelier Index (LI), Larson ratio (LR), Ryznar saturation index (RSI), Aggressiveness index (AI) of water quality for raw water, treated water and water in distribution reservoir at major eight drinking water treatment plants (DWTPs) in Korea. By analyzing secondary contamination of tap water, the variation of secondary contaminants was investigated with regard to pipe materials, aging and corrosion index (CI). In addition, we suggested an appropriate CI applicable water quality and the management plan for CI monitoriing. All CI showed corrosive water quality, and they did not change significantly in the distribution network. However, Copper (Cu), iron (Fe) and zinc (Zn) concentrations as secondary contaminants increased through the distribution network. Among CI, LI was most sensitive to changes in raw water quality and drinking water treatment. Also, it has high correlations with other indexes such as RSI, AI. Therefore, LI is considered as an appropriate CI to the domestic water quality. Based on these result, we propose LI as a drinking water quality standard to control the pipe corrosion from DWTPs.

• Corrosion Science and Technology
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• v.8 no.3
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• pp.103-109
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• 2009

An epoxy coating was designed to give a hydrophobic property on its surface by modifying it with three types of Amino Terminated Polydimethylsiloxane (ATP), and then effects of the modification on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protectiveness of the modified epoxy coating were examined using FT-IR spectroscopy, hydrothermal cyclic test, and impedance test. The surface of epoxy coating was changed from hydrophilic to hydrophobic property due primarily to a phase separation tendency between epoxy and modifier by the modification. The phase separation tendency is more appreciable when modified by ATP with higher molecular weight ATP at higher content. Water transport behavior of the modified epoxy coating decreased more in that with higher hydrophobic surface property. The resistance to localized corrosion of the modified epoxy coated carbon steel was well agreed with its water transport behavior and hydrophobic tendency.

• Corrosion Science and Technology
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• v.10 no.4
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• pp.151-155
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• 2011

The iron oxide particles could be resulted from the corrosion of the circulating water system of a power plant. Because it may be one of the trouble materials which affect the power generation efficiency due to the deposition on steam generator tube and turbine blade, the continuous observation of its concentration is very important. The laser induced break-down detection (LIBD) technology was applied to monitor continuously the concentration of corrosion products with the detection limit of ppb level. The measurement system consists of a Nd:YAG pulsed laser, a polarizing beam splitter, a flow-type sample cell, an acoustic emission sensor, a high speed data acquisition board, a personal computer, etc.. The performance test results confirmed that this technology can be effective to monitor the corrosion product concentration of the circulating water system of a power plant.