• Title/Summary/Keyword: water corrosion

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The examination of application possibility and development of new welding joint shape for aluminum alloy (Al어선 선체용접부의 신형상 개발 및 적용 가능성 검토)

  • Jong-Myung Kim;Chong-In Oh;Han-Sur Bang
    • Journal of the Society of Naval Architects of Korea
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    • v.38 no.1
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    • pp.99-107
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    • 2001
  • Manufacture of fishing vessel is needed the effective material for light, strength, fire and corrosion of water in order to improve durability by high-speed and fishing. These fishing vessel can be divided into FRP and AI alloys fishing vessel. FRP fishing vessel is light and effective for strength but highly ignited and susceptible to heat during the manufacturing ship by-produce noxious component for human. In the case of a scrapped ship, it cause environmental pollution. On the other hand, aluminum is a material in return for FRP and has merit of high-strength and lightness. It's more heat proof and durable than FRP and superior to prevent from corrosion. Al alloys fishing vessel development is rising as an urgent matter. But, al alloy has some defect of bad weldability, welding transformation, cracks and overcost of construction. Therefore this study is to develop the new welding joint shape solving aluminum defects and mechanical behavior. First of all, strength was compared and reviewed by analysis of plate, stiffen plate, new model simplified by using plate theory. On the base of this result, plate and new model of temperature distribution, weld residual stress and strength of tensile, compressive force were compared and reviewed by finite element computer program has been developed to deal with heat conduction and thermal elasto plastic problem. Also, new model is proved application possibility and excellent mechanic by strength comparison is established to tensile testing result.

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Study on Stress Recovery Length of 7-Wire Strand due to Local Damage (강연선의 국부적 손상에 따른 응력 회복길이 분석 연구)

  • Seo, Dong-Woo;Kim, Byung-Chul;Jung, Kyu-San;Na, Wongi;Park, Ki-Tae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.12
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    • pp.150-156
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    • 2017
  • This study examined the stress recovery length due to the local damage of a 7-wire strand, which is applied widely to PSC (Post Tensioned Concrete) bridges and cable-stayed bridges. The 7-wire strand is a multiple stranded steel of PC prestressing strand. Owing to the nature of the material, it is damaged continuously after completion with corrosion being the main cause of damage. On the other hand, due to its structural characteristics, it is difficult to grasp the degree of damage inside the cable and the pattern of stress variation. In the case of cables applied to bridges, the parts that are susceptible to corrosion are generated depending on the water supply and installation shape, which may cause local damage. This study analyzed the tendency of performance degradation and stress recovery length according to local damage of a 7-wire strand, which is applied mainly to bridge post-tensioning or stay cables. This study developed a computer-based simulation model that was validated with experimental results. The model developed in this study can be used to evaluate the safety level and estimate the remaining life span of P SC bridges or cable-stayed bridges.

Sensitivity Analysis of Nozzle Geometry Variables for Estimating Residual Stress in RPV CRDM Penetration Nozzle (원자로 상부헤드 관통노즐의 잔류응력 예측을 위한 노즐 형상 변수 민감도 연구)

  • Bae, Hong Yeol;Oh, Chang Young;Kim, Yun Jae;Kim, Kwon Hee;Chae, Soo Won;Kim, Ju Hee
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.3
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    • pp.387-395
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    • 2013
  • Recently, several circumferential cracks were found in the control rod drive mechanism (CRDM) nozzles of U.S. nuclear power plants. According to the accident analyses, coolant leaks were caused by primary water stress corrosion cracking (PWSCC). The tensile residual stresses caused by welding, corrosion sensitive materials, and boric acid solution cause PWSCC. Therefore, an exact estimation of the residual stress is important for reliable operation. In this study, finite element simulations were conducted to investigate the effects of the tube geometry (thickness and radius) on the residual stresses in a J-groove weld for different CRDM tube locations. Two different tube locations were considered (center-hole and steepest side hill tube), and the tube radius and thickness variables ($r_o/t$=2, 3, 4) included two different reference values ($r_o$=51.6, t=16.9mm).

Development of Dry Process Caisson Method for Maintenance of Submerged Harbor Structure (수중 항만구조물의 유지보수를 위한 건식 케이슨 공법 개발)

  • Lee Joong-Woo;Oh Dong-Hoon;Kwak Seung-Kyu;Kim Sung-Tae
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2006.06b
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    • pp.163-170
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    • 2006
  • Together with the trend of enhancement in domestic industrial development and economic progress due to import and export, the demand for construction of the roads, bridges, especially port facilities, and several coastal protection and ocean structures is increasing rapidly. MOMAF of Korean Government is driving construction of 9 new ports and renovation of the existing fishery ports. Among these structures most of bridge base, wharves, dolphins, quays, and jetties are being newly built of steel or concrete pile. As the base, supporting bulkheads, and piles are underwater after construction, it is difficult to figure out the status of structures and not enough to get maintenance and strengthen the structures. Every year, moreover, these works suck the government budget due to higher incomplete maintenance expense for protection from corrosions of structures and increased underwater construction period. For the purpose of cutting down the expense of government budget, it is necessary to extend the life cycle of the existing structures. Therefore, we developed a new method for maintenance of submerged structures near the waterline by allowing dry work environment with the floating caisson. The method shows easy to move around the working area and handle. It also showed not only a significant reduction maintenance expenses and time for anti-corrosion work but also better protection. This will be a milestone to reduce the maintenance and construction expenses for the shore and water structures.

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Galvanic Anode Charactristics of Grounding Cell Design for Corrosion Protection of Pipings (배관 방식용 접지전지 설계를 위한 유전양극의 특성에 관한 연구)

  • 임우조
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.19 no.1
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    • pp.57-62
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    • 1983
  • The galvanic anodes have three kinds of Zn alloy anode, Al alloy anode and Mg alloy anode, which are widely used in cathodic protection for all metal structures in water or under ground. This paper to be used for designing of the grounding cell has reached the following conclusion as the results of an experimental study on the characteristics of such galvanic anodes for corrosion protection of pipings: 1) Zn alloy anode was the best when the specific resistance of the environment was bellow 1000 $\Omega$.cm, and when above 1000 $\Omega$.cm, Mg alloy anode to be used for designing of the grounding cell was the best. 2) Al alloy anode was better than Mg alloy anode for grounding cell when the specific resistance was bellow 500 $\Omega$.cm, but the Al alloy anode in all the environments reduced the characteristics of galvanic anode to the lower grade than those of Zn alloy anode. 3) Each impressed voltage (E) of the anodes at which drainage current density ($\rho$) begins rapidly increasing is quantitatively presented as follows: \circled1 E sub(Zn)=log (4.9465/$\rho$super(0.0639))+11$\times$10 super(-6)$\rho$super(0.8923i) \circled2 E sub(Al)=log (4.9306/$\rho$super(0.0525))+13$\times$10 super(-6)$\rho$super(0.9314i) \circled3 E sub(Mg)= log (3.7086/$\rho$super(0.0988))+181$\times$10 super(-6)$\rho$super(0.5406i) 4) The empirical equations between the drainage current density (i) and impressed environment are modeled as the following type. logi=g+root(n.E+r)(g,n,r; constants)

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Review of Research on Chloride-Induced Stress Corrosion Cracking of Dry Storage Canisters in the United States (미국의 건식저장 캐니스터에서의 CISCC 연구에 대한 검토)

  • Park, Hyoung-Gyu;Park, Kwang-Heon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.4
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    • pp.455-472
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    • 2018
  • It is important to study how to manage dry storage casks of spent nuclear fuels (SNF), because wet storage spaces for SNF will shortly be at full capacity in the Republic of Korea. The US has operated a dry storage cask system for several decades, and has carried out significant studies into how to successfully manage dry storage cask for SNF. This type of expertise and experience is currently lacking in the Republic of Korea. The degradation of dry casks is an important issue that must be considered. In particular, chloride-induced stress corrosion cracking (CISCC) is known to lead to the release of radioisotopes from canisters. The U.S. Department of Energy, U.S. Nuclear Regulatory Commission, and the Electric Power Research Institute have undertaken research into the CISCC mechanism. In addition, Sandia National Laboratories (SNL) has extensively researched CISCC and how to manage it in dry storage canisters. In this review paper, the probabilistic model proposed by the SNL is analyzed and, based on this model, US-based CISCC research is reviewed in detail. This paper will inform the management of dry cask storage of SNF from light water reactors in austenite stainless steel canisters in the Republic of Korea.

Properties analysis of environment friendly calcareous deposit films electrodeposited at various temperature conditions in natural seawater (천연해수 중 온도 변화에 따라 전착한 환경친화적인 석회질 피막의 특성 분석)

  • Lee, Chan-Sik;Kang, Jun;Lee, Myeong-Hoon
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.7
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    • pp.779-785
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    • 2015
  • Cathodic protection is recognized as the most cost-effective and technically appropriate corrosion prevention method for the submerged zone of offshore structures, ships, and deep-sea facilities. When cathodic protection is applied, the cathodic currents cause dissolved oxygen reduction, generating hydroxyl ions near the polarized surface that increase the interfacial pH and result in enhanced carbonate ion concentration and precipitation of an inorganic layer whose principal component is calcium carbonate. Depending on the potential, magnesium hydroxide can also precipitate. This mixed deposit is generally called "calcareous deposit." This layer functions as a barrier against the corrosive environment, leading to a decrease in current demand. Hence, the importance of calcareous deposits for the effective, efficient operation of marine cathodic protection systems is recognized by engineers and scientists concerned with cathodic protection in submerged marine environments. Calcareous deposit formation on a marine structure depends on the potential, current, pH, temperature, pressure, sea-water chemistry, flow, and time; deposit quality is significantly influenced by these factors. This study determines how calcareous deposits form in sea water, and assesses the interrelationship of formation conditions (such as the sea water temperature and surface condition of steel), deposited structure, and properties and the effectiveness of the cathodic protection.

Conservation of Iron Dagger & Scabbard Excavated in Daho-ri, Changwon (다호리 출토 칠초철검(漆鞘鐵劍)의 보존)

  • Sim, Myungbo;Lim, Jihyun;Ma, Daewan;Kim, Midori
    • Conservation Science in Museum
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    • v.12
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    • pp.19-24
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    • 2011
  • This study presents an investigation into the conservation process of an iron dagger and scabbard, which are a lacquered scabbard and a dagger inserted in it, excavated in the Daho-ri relic of Changwon by Gimhae National Museum. The bronze dagger whose condition was poor due to corrosion was coated with Incralac, an intensifier, to reveal the surface patterns through a microscope. The lacquered scabbard was removed of foreign substances on the surface and coated with HPC 2%(in water) to protect the film. Applied onto the surface from which foreign substances were removed was Caparol Binder 5%(in water) two to three times to form a protective film and then faced with Korean paper. Once it was fixed in a polyurethane foam in a stable manner, it was turned over to receive the same process on the back. Three layers of Korean paper were attached to the back of the scabbard to support the thin artifact. HPC 2%(in water), which was applied to the scabbard, was also applied to the iron dagger inside for cementing effect. After all the processes were completed, the artifact was put in a transparent acrylic box for future display.

Chemical Effects on Head Loss across Containment Sump Strainer under Post-LOCA Environment (LOCA이후 환경에서 원자로건물집수조 여과기의 수두손실에 대한 화학적 영향)

  • Ku, Hee-Kwon;Jung, Bum-Young;Hong, Kwang;Jeong, Eun-Sun;Jung, Hyun-Jun;Park, Byung-Gi;Rhee, In-Hyoung;Park, Jong-Woon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.11
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    • pp.3260-3268
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    • 2009
  • A test apparatus has been fabricated to simulate chemical effect on head loss through a strainer in a pressurized water reactor (PWR) containment water pool after a loss of coolant accident (LOCA). Tests were conducted under condition of same ratio of strainer surface area to water volume between the test appratus and the containment sump. A series of tests have been performed to investigate the effects of spray, existence of calcium-silicate with tri-sodium phosphate (TSP), and composition of materials. The results showed that head loss across the chemical bed with even a small amount of calcium-silicate insulation instantaneously increased as soon as TSP was added to the test solution. Also, the head loss across the test screen is strongly affected by spray duration and is increased rapidly at the early stage, because of high dissolution and precipitation of aluminum and zinc. After passivation of aluminum and zinc by corrosion, the head loss increase is much slowed down and is mainly induced by materials such as calcium, silicon, and magnesium leached from NUKONTM and concrete. Furthermore, it is newly found that the spay buffer agent, tri-sodium phosphate, to form protective coating on the aluminum surface and reduce aluminum leaching is not effective for a large amount of aluminum and a long spray.

The XPS and SEM Evaluation of Various Technique for Cleansing and Decontamination of The Rough Surface Titanium Implants (수종의 방법으로 임프란트 표면 처치후 표면의 형태 및 성분 변화 분석에 관한 연구)

  • Kim, Sun-bong;Yim, Sung-Bin;Chung, Chin-Hyung
    • Journal of Periodontal and Implant Science
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    • v.31 no.4
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    • pp.749-763
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    • 2001
  • Osseointegrated titanium implants have become an integral therapy for the replacement of teeth lost. For dental implant materials, titanium, hydroxyapatite and alumina oxide have been used, which of them, titanium implants are in wide use today. Titanium is known for its high corrosion resistance and biocompatability, because of the high stability of oxide layer mainly consists of $TiO_2$. With the development of peri-implantitis, the implant surface is changed in surface topography and element composition. None of the treatments for cleaning and detoxification of implant surface is efficient to remove surface contamination from contaminated titanium implants to such extent that the original surface elemental composition. In this sights, the purpose of this study was to evaluate rough surface titanium implants by means of scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS) with respect to surface appearance and surface elemental composition. Moreover, it was also the aim to get the base for treatments of peri-implantitis. For the SEM and XPS study, rough surface titanium models were fabricated for control group. Six experimental groups were evaluated: 1) long-time room exposure, 2 ) air-powder abrasive cleaning for 1min, 3) burnishing in citric acid(pH1) for 1min, 4) burnishing in citric acid for 3min, 5) burnishing in tetracycline for 1min, 6) burnishing in tetracycline for 3min. All experimental treatments were followed by 1min of rinsing with distilled water. The results were as follows: 1. SEM observations of all experimental groups showed that any changes in surface topography were not detected when compared with control group. (750 X magnification) 2. XPS analysis showed that in all experimental groups, titanium and oxygen were increased and carbon was decreased, when compared with control group. 3. XPS analysis showed that the level of titanium, oxygen and carbon in the experimental group 3(citric acid treatment for 1min, followed by 1min of distilled water irrigation) reached to the level of control group. 4. XPS analysis showed that significant differences were not detected between the experimental group 1 and the other experimental groups except of experimental group 3. The Ti. level of experimental group 2, airpowder abrasive treatment for lmin followed by 1min of saline irrigation, was lower than the Ti. level of tetracycline treated groups, experimental group 5 and 6. From the result of this study, it may be concluded that the 1min of citric acid treatment followed by same time of rinsing with distilled water gave the best results from elemental points of view, and can be used safely to treat peri-implantitis.

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