• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.640-647
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• 2023

Material corrosion in nuclear power plant (NPP) is not controlled only by amine injection but also by ion exchange (IX) which is the best option to remove trace Na⁺. This study was conducted to understand the Na⁺ leakage characteristics of IX beds packed with ethanolamine-form (ETAH-form) and hydrogen-form (H-form) resins in the simulated water-steam cycle in terms of intrinsic behaviors of four kinds of cation-exchange resins through ASTM test and Vanselow mass action modeling. Na⁺ was inappreciably escaped throughout the channel created in resin layer. Na⁺ leakage from IX bed was non-linearly raised because of its decreasing selectivity with increasing Na⁺ capture and with increasing the fraction of ETAH-form resin. Na⁺ did not reach the breakthrough earlier than ETAH⁺ and NH₄⁺ due to the increased selectivity of Na⁺ to the cation-exchange resin (H⁺ < ETAH⁺ < NH₄⁺ ≪ Na⁺) at the feed composition. Na⁺ leakage from the resin bed filled with small particles was decreased due to the enhanced dynamic IX processes, regardless of its low selectivity. Thus, the particle size is a predominant factor among intrinsic properties of IX resin to reduce Na⁺ leakage from the condensate polishing plant (CPP) in NPPs.

• Journal of the Korean Wood Science and Technology
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• v.52 no.3
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• pp.243-261
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• 2024

In this study, samples were collected from various ancient wooden shipwrecks, including the Shinan shipwreck and Jindo shipwreck that used iron nails, the Yeongheungdo shipwreck carrying iron artifacts, as well as the Sibidongpado shipwreck and Wando shipwreck where degradation products were not observed, all of which were salvaged by the National Research Institute of Maritime Heritage. The aim was to analyze the characteristics of degradation products generated by iron (Fe) within the salvaged wooden shipwreck materials and establish fundamental data on degradation products in waterlogged archaeological wood. The analysis revealed that sulfur (S) is generally accumulated in wood obtained from marine environments. It was observed that the content of inorganic substances such as iron and sulfur was significantly higher in the Shinan shipwreck, Jindo shipwreck, and Yeongheungdo shipwreck compared to Sibidongpado shipwreck and Wando shipwreck, which used wooden nails. This indicates that the presence of iron affects the accumulation of degradation products and suggests that iron is a factor in the corrosion of wood. Furthermore, crystallin compounds were observed within the cell walls, and higher concentrations of iron and sulfur were found in the resin ducts, rays, and radial tissues. This suggests that during desalination and consolidation treatments, warm water or polyethylene glycol (PEG) may move degradation factors into resincanals, rays, radial tissues, etc.

• Tribology and Lubricants
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• v.40 no.3
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• pp.71-77
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• 2024

Hydrogen has emerged as an eco-friendly and sustainable alternative to fossil fuels. However, the utilization of hydrogen requires high-pressure compression, storage, and transportation, which poses challenges to the durability of compressor components, particularly the diaphragm. This study aims to improve the durability of 304 stainless steel diaphragms in hydrogen compressors by optimizing their surface roughness and corrosion resistance through wet etching. The specimens were prepared by immersing 304 stainless steel in a mixture of sulfuric acid and hydrogen peroxide, followed by etching in hydrochloric acid for various durations. The surface morphology, roughness, and wettability of the etched specimens were characterized using optical microscopy, surface profilometry, and water contact angle measurements. The friction and wear characteristics were evaluated using reciprocating sliding tests. The results showed that increasing the etching time led to the development of micro/nanostructures on the surface, thereby increasing surface roughness and hydrophilicity. The friction coefficient initially decreased with increasing surface roughness owing to the reduced contact area but increased during long-term wear owing to the destruction and delamination of surface protrusions. HCl-30M exhibited the lowest average friction coefficient and a balance between the surface roughness and oxide film formation, resulting in improved wear resistance. These findings highlight the importance of controlling the surface roughness and oxide film formation through etching optimization to obtain a uniform and wear-resistant surface for the enhanced durability of 304 stainless steel diaphragms in hydrogen compressors.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.14 no.4
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• pp.515-523
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• 2001

In this paper results of a linear structural analysis for design and dimensioning of disposal containers for spent pressurized water reactor nuclear fuel and spent Canadian deuterium and uranium reactor nuclear fuel are presented. The container structure studied here is a solid structure with a cast insert and a corrosion resistant outer shell, which is designed for the spent nuclear fuel disposal in a deep repository. An evenly distributed load of hydrostatic pressure from the groundwater and large swelling pressure from the bentonite buffer are applied on the container. Hence, the container must be designed to endure these large pressure loads. In this study, the array type of inner baskets and thicknesses of outer shell and lid/bottom are attempted to be determined through a linear static structural analysis.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.29 no.10
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• pp.530-537
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• 2017

Scales generated inside pipes cause negative effects on heat transfer performance, pressure loss and flow rate due to increased thermal resistance and reduced flow cross-sectional area. If these scales are not prevented or eliminated, thermal-fluid performance of the facilities can be deteriorated, or in extreme cases, accidents such as explosion due to overheating can occur. There are two ways to remove the scales, physically and chemically. Removing the scales physically needs specific machines which are expensive, and removing them chemically may provoke corrosion or shorten the age of the facilities. In this study, an eco-friendly pipe scale cleaner using natural organic acid is developed by applying the concept of a limestone cave generation. The manufactured scale cleaner is applied to remove the scales in industrial, water heating and urinal pipes. The results show that this cleaner removes scales more effectively and safely compared to existing scale treatments. Scale removal efficiencies of this work is 1.2~10.7 times for industrial pipes and 1.8~15.5 times for boiler water heating pipes higher than those of conventional cleaners.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.3 no.2
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• pp.142-151
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• 1991

In the present investigation, it has been proposed to utilize a direct contact heat exchanger as an evaporator to solve the difficulties such as scaling, corrosion and law thermal efficiencies, associated with the conventional evaporator. Liquified nitrozen was utilized as a working fluid to investigate basic natures of bubble dynamics in the evaporator, and spray nozzles were adopted to inject liquified nitrozen into the spray column with varying flow rates of dispersed phase fluids. Experimentations were carried out in the range of $6.54{\times}10^{-4}kg/s$ - 0.030 kg/s for dispersed phase flow rates with one, three and five nozzle holes. Observing the bubble dynamics for the evaporator the feasibility of utilizing a direct contact heat exchanger as a LNG evaporator has been evaluated. The results show that no eruption phenomena was observed in the present investigation with $LN_2$ and the interface between $N_2$ bubbles and water was fully turbulent. It is believed that the high injection velocity of $LN_2$ through the spray nozzles provide good mixing effects for both heat and mass transfers between water and $N_2$ bubbles. Ice was formed on the surface of the spray nozzle for higher $LN_2$ flow rates. However, even in this case, it is observed that the ice was detached as soon as it was formed. Under the present experimental conditions, the shapes of $LN_2$ bubbles were in the spherical-cap region according to the Clift, Grace and Weber Graphs. The height of foam region caused by the breakup of larger bubbles keeps increasing with high injection velocities until it reaches it's maximum height.

• Journal of the Korea Institute of Building Construction
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• v.2 no.2
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• pp.165-172
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• 2002

A reinforced concrete building neighboring in Pusan or Ulsan where is directly exposed to salt water contrasting with other in land areas contains much salt content percolated from the outside that the high salt content percolates and diffuses through the inside of reinforced concrete; therefore, an immovable tunic surrounding it begins to be destroyed and eroded with high speed. At the time, the cross-sectional area and volume expansion of re-bar reinforcing result in being cracks make a rapid progress gradually until they appear in the surface of the one, the phenomenon such as being a thin layer or falling off the part of it causes a lowering of its durability and might collapse the concrete construction. So far, we've investigated into salt content of reinforced concrete constructions neighboring in a seaside district and damage by carbonation, and we came to a conclusion as follows: $\circled1$ Under the oceanic circumstance a concrete construction is influenced by sea water directly that contains much amount of salt content contrasting with other constructions on inland areas. $\circled2$ Because of chloride penetration the carbonation of reinforced concrete made a rapid progress until more than the covering thickness of re-bar. $\circled3$ An old reinforced concrete building which has been piled up salt injury and proceeding the carbonation of its cross-sectional area. $\circled4$ According to rapidly cracking from the inside to surface of reiforced concrete, the phenomenon of being a thin layer or falling off the part of reinforced concrete results in a lowering of durability and shortening the life-time of concrete construction itself.

• Applied Chemistry for Engineering
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• v.9 no.1
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• pp.58-65
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• 1998

Substituted dicyandiamide(Sub-DICY), Accelerated dicyandiamide(Acc-DICY), Trimellitic anhydride(TMA), Pyromellitic dianhydride(PMDA) and Phenolic curing agent(Ph.C.A.) are mainly used for epoxy powder coating curing agent. Various characteristics of epoxy films fully cured by optimum condition such as mechanical properties like $T_g$, tensile strength, elongation at break hardness, abrasion resistance and chemical properties like water absorption, acid resistance, alkali resistance and electrical properties, corrosion resistance are determined by various measuring devices and analyses devices. In conclusion, phenolic curing agent was shown excellent thoughness but severe color change as temperature increased. Acid anhydride has excellent insulation properties and color stability at elevated temperature but lower thoughness and adhesion to substrate. DICY curing agent was shown high water absorption and severe color chance as temperature increased.

• Tribology and Lubricants
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• v.23 no.3
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• pp.130-133
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• 2007

Fuel cladding tubes in nuclear fuel assembly are held up by supporting grids because the tubes are long and slender. Fluid flows of high-pressure and high-temperature in the tubes cause oscillating motions between tubes and supports. This is called as FIV (flow induced vibration), which causes fretting wear in contact parts of tube and support. The fretting wear of tube and support can threaten the safety of nuclear power plant. Therefore, a research about the fretting wear characteristics of tube-support is required. The fretting wear tests were performed with supporting grids and cladding tubes, especially after corrosion treatment on tubes, in water. The tests were done using various applied loads with fixed amplitude. From the results of fretting tests, the wear amounts of tube materials can be predictable by obtaining the wear coefficient using the work rate model. Due to stick phenomena the wear depth was changed as increasing load and temperature. The maximum wear depth was decreased as increasing the water temperatures. At high temperatures there are the regions of some severe adhesion due to stick phenomena.

• Tribology and Lubricants
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• v.24 no.3
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• pp.129-132
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• 2008

Fuel cladding tubes in nuclear fuel assembly are held up by supporting grids because the tubes are long and slender. Fluid flows of high-pressure and high-temperature in the tubes cause oscillating motions between tubes and supports. This is called as FIV (flow induced vibration), which causes fretting wear in contact parts of tube and support. The fretting wear of tube and support can threaten the safety of nuclear power plant. Therefore, a research about the fretting wear characteristics of tube-support is required. The fretting wear tests were performed with supporting grids and cladding tubes, especially after corrosion treatment on tubes, in water. The tests were done using various applied loads with fixed amplitude. From the results of fretting tests, the wear amounts of tube materials can be predictable by obtaining the wear coefficient using the work rate model. Due to stick phenomena the wear depth was changed as increasing load and temperature. The maximum wear depth was decreased as increasing the water temperatures. At high temperatures there are the regions of some severe adhesion due to stick phenomena.