• Title/Summary/Keyword: water content in dispersion medium

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The Preparation of NiCuZn Ferrite Slurry Using the Water Mixed Binder System (수계 바인더를 이용한 NiCuZn Ferrite의 슬러리 제조)

  • 류병환;이정민;고재천
    • Resources Recycling
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    • v.7 no.4
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    • pp.35-42
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    • 1998
  • Surface mount technology is the biggest theme in the area of deιIronic component. To miniatunze an electronic component, s such as ferrite chip inductor, the cer뼈lic wet process for green-sheet lamination and/or screen printing method through a s solvent medium system is widely used. The preparation and characterization of NiCuZn Ferrite (NCZF) shurry and the green s sheet using the water mixed binder system has been studied. The 21 vol% of NCZF slurry was prepared by a ball milling. The p polyacrylic vinyl copolymer (Mw; 60,000) was used as a binder. Th$\xi$ mixture of distilled water, isopropyl alcohol (IPA) and 2l butoxy ethanol was used as a dispersion medium. The water content of medium varied from about 40% to 80%. As the results. Thc disp$\xi$rston stability of the NCZF slurry was attributed to the free polymer rather than the electrostatic force of the particle. T The viscosity of the NCZF slurry was greatly depended on the ratio of water content in the medium.

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Environmental Effects on the Hydrologic and Ecologic System around the Wasted Ore Dump of the Moak Gold-Silver Mine (모악 금·은광산에 방치된 폐석이 주변 수계 및 생태계에 미치는 환경적 영향)

  • Na, Choon-Ki;Jeon, Seo-Ryeong
    • Economic and Environmental Geology
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    • v.28 no.3
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    • pp.221-229
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    • 1995
  • The heavy metal contents and their dispersion patterns in stream water, stream sediments, land plants and aquatic larvae collected from the hydrologic system flowing via the wasted ore dump of the Moak Au-Ag mine were investigated systematically in order to evaluate the environmental impacts of the abandoned metal mine. The heavy metal content increases abruptly in the vicinity of the wasted ore dump, then attenuated with increasing distance from the mine area. Attenuating rates were stream water > stream sediments > land plants > aquatic larvae. On the other hand, the cumulative content of heavy metals was stream sediments >aquatic larvae > land plants > stream water. Each element tends to be enriched selectively according to media; Zn > Cu > Cd > Pb in stream water, Zn > Pb > Cu > Cd in stream sediments and land plants, and Zn > Cu > Pb > Cd in aquatic larvae. These results show that the degree of enrichment and dispersion of pollutant extruded from the wasted ore dump are different according to elements and media, and that the circulation system of materials of each medium is different. The heavy metals, especially Cu, Pb and Zn, of polluted downstream sediments occur in high proportions of Fe-Mn oxides and organic bounded forms, which show high potential of a secondary pollution source. The content of heavy metals and their dispersion patterns in stream sediments are different from those of ten years ago; pollution levels of heavy metals were degraded in various ranges. The Zn and Cu-polluted areas were widened whereas Fe and Pb-polluted areas were reduced. In crops collected from the farm lands in downstream area, the pepper was more concentrated in all heavy metal than rice. The pepper showed some contaminated level in Cu(9.7ppm) and Zn(149ppm), and the rice in Zn(90ppm). However, both crops showed no significant level in Cd(<0.2ppm) and Pb(<0.5ppm).

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Dispersion Polymerization of Acrylamide in the Media of t-Butyl Alcohol/$H_2O$ Mixtures (t-Butyl Alcohol/$H_2O$ 혼합 용매에서 아크릴아미드의 분산중합)

  • 이기창;이성은;송봉근;이동주
    • Polymer(Korea)
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    • v.24 no.5
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    • pp.629-637
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    • 2000
  • Dispersion polymerization of acrylamide in the media of t-butyl alcoho1/$H_2O$ mixtures at 30~5$0^{\circ}C$ in the presence of hydroxypropyl cellulose and ammonium persulfate as steric stabilizer and initiator, respectively, was carried out. It was studied the effects of concentrations of initiator and steric stabilizer, amount of monomer, polymerization temperature, t-butyl alcohol/$H_2O$ ratio, concentration of crosslinker, purification of monomer and nitrogen purge on the particle size of the resulting acrylamide latices and molecular weight of the latex-poly(acrylamide). In this study, poly(acrylamide) latices of 0.1~0.5 ${\mu}{\textrm}{m}$ with 470000~2080000 in (equation omitted) were prepared and the resulting PAM latices were all dissolved in water in stantly.

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Silica/polymer Nanocomposite Containing High Silica Nanoparticle Content : Change in Proton Conduction and Water Swelling with Surface Property of Silica Nanoparticles (고농도의 Silica Nanoparticle을 함유한 Silica/polymer 나노복합체 : 실리카 표면 특성에 따른 수소이온 전도성 및 수팽윤도 변화)

  • Kim, Ju-Young;Kim, Seung-Jin;Na, Jae-Sik
    • Applied Chemistry for Engineering
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    • v.21 no.5
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    • pp.514-521
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    • 2010
  • A new one-shot process was employed to fabricate proton exchange membranes (PEMs) over conventional solvent-casting process. Here, PEMs containing nano-dispersed silica nanoparticles were fabricated using one-shot process similar to the bulk-molding compounds (BMC). Different components such as reactive dispersant, urethane acrylate nonionmer (UAN), styrene, styrene sulfuric acid and silica nano particles were dissolved in a single solvent dimethyl sulfoxide (DMSO) followed by copolymerization within a mold in the presence of radical initiator. We have successfully studied the water-swelling and proton conductivity of obtained nanocomposite membranes which are strongly depended on the surface property of dispersed silica nano particles. In case of dispersion of hydrophilic silica nanoparticles, the nanocomposite membranes exhibited an increase in water-swelling and a decrease in methanol permeability with almost unchanged proton conductivity compared to neat polymeric membrane. The reverse observations were achieved for hydrophobic silica nanoparticles. Hence, hydrophilic and hydrophobic silica nanoparticles were effectively dispersed in hydrophilic and hydrophobic medium respectively. Hydrophobic silica nanoparticles dispersed in hydrophobic domains of PEMs largely suppressed swelling of hydrophilic domains by absorbing water without interrupting proton conduction occurred in hydrophilic membrane. Consequently, proton conductivity and water-swelling could be freely controlled by simply dispersing silica nanopartilces within the membrane.