• Title/Summary/Keyword: water contact angle

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Influence of Artificial Tear Containing Carboxymethyl Cellulose Component on Physical Properties of Hydrogel Contact lens (카르복시메칠 셀룰로오스 성분이 포함된 인공누액이 하이드로젤 콘택트렌즈의 물성에 미치는 영향)

  • Cho, Seon-Ahr;Sung, A-Young
    • Journal of Korean Ophthalmic Optics Society
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    • v.18 no.4
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    • pp.457-463
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    • 2013
  • To determine the impact of artificial tears which include carboxymethyl cellulose on a hydrogel contact lenses. Methods: A contact lenses made of the cross-linking agent, EGDMA (ethylene glycol dimethacrylate) and HEMA (2-hydroxyethyl methacrylate) and with added NVP (n-vinyl-2-pyrrolidone) and MMA (methyl methacrylate) was evaluated for water content, refractive index, spectral transmittance and contact angle of produced contact lens. Results: The physical properties of the sampled copolymerized polymers showed that water content, refractive index, visible ray transmittance and contact angle were in the range of 26.61%~48.58%, 1.422~1.455, 80.8%~91.4% and $33.93^{\circ}{\sim}65.70^{\circ}$, respectively. In addition, after soaking with artificial tears, the water content, refractive index and contact angle were in the range of 24.46%~48.25%, 1.422~1.457, 77.0%~91.0% and $37.25^{\circ}{\sim}77.33^{\circ}$, respectively. The changes of the physical property depending on hydration time and showed an increase of refractive index and contact angle, decrease of water content and visible ray transmittance. Conclusions: Artificial tears which include carboxymethyl cellulose sodium which is used as a wetting agent influenced water content, refractive index, contact angle and spectral transmittance of a hydrogel contact lenses.

Effects of Surface Roughness on Contact Angle of Nanofluid Droplet (표면조도가 나노유체 액적의 접촉각에 미치는 영향)

  • Kim, Yeung Chan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.6
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    • pp.559-566
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    • 2013
  • The effects of solid surface roughness on the contact angle of a nanofluid droplet were experimentally investigated. The experiments were conducted using the solid surface of a 10 mm cubic copper block and the nanofluid of water mixed with CuO nanoparticles. The experimental results showed that the contact angles of nanofluid droplets were lower than those of water droplets and that the contact angle of the nanofluid droplet increased with the solid surface roughness. Furthermore, it was found that the contact angles of water droplets on the solid surface quenched by both water and the nanofluid were lower than those of water droplets on the pure solid surface. However, significant differences were not observed between the contact angles on the solid surfaces quenched by water and the nanofluid.

A Study on the Super-hydrophobicity of Poly(ethylene terephthalate) Fabric by TiO2 Nano-particles Coating (TiO2 나노입자 코팅에 의한 PET섬유의 초발수성에 관한 연구)

  • Park, Sung-Min;Kwon, Il-Jun;Kim, Ji-Yeon;Kim, Chang-Nam;Yeum, Jeong-Hyun;Yoon, Nam-Sik
    • Textile Coloration and Finishing
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    • v.21 no.1
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    • pp.30-37
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    • 2009
  • Studies on plants such as lotus leaf suggested that dual-scale structure could contribute to super-hydrophobicity. We introduced super-hydrophobicity onto poly(ethylene terephthalate)(PET) fabric with dual-scale structure by assembling $TiO_2$ nano sol. PET fabric was treated with $TiO_2$ sol, water-repellent agent using various parameters such as particle size, concentration. Morphological changes by particle size were observed using field emmission scanning electron microscopy(FE-SEM) and AFM measurement, contact angle measurement equipment. The contact angle of water was about 138.5$^{\circ}$, 125.8$^{\circ}$, 125.5$^{\circ}$ and 108.9$^{\circ}$ for PET fabric coated with 60.2nm, 120.1nm, 200nm and 410.5nm $TiO_2$ particles, compared with about 111.5$^{\circ}$ for PET fabric coated with water repellent. When we mixed particle sizes of 60.2nm and 120.1nm by 7:3 volume ratio, the contact angle of water was about 132.5$^{\circ}$. And we mixed particle sizes of 60.2nm and 200nm by 7:3 volume ratio, the contact angle of water was about 141.8$^{\circ}$. Also we mixed particle sizes of 60.2nm and 410.5nm by 7:3 volume ratio, the best super-hydrophobicity was obtained. In this paper, we fabricated various surface structures to the water-repellent surfaces by using four types of $TiO_2$ nano-particles, and we found that the nanoscale structure was very important for the super-hydrophobicity.

Effect of Native Oxide Layer on the Water Contact Angle to Determine the Surface Polarity of SiC Single Crystals (접촉각 측정방법을 이용한 SiC 단결정의 극성표면 판별에 있어 자연산화막의 영향)

  • Park, Jin Yong;Kim, Jung Gon;Kim, Dae Sung;Yoo, Woo Sik;Lee, Won Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.3
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    • pp.245-248
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    • 2020
  • The wettability of silicon carbide (SiC) crystal, which has 6H-SiC and 4H-SiC regions prepared using the physical vapor transport (PVT) method, is quantitatively analyzed using dispensed deionized (DI) water droplets. Regardless of the polytypes in SiC, the average of five contact angle measurements showed a difference of about 6° between the Si-face and C-face. The contact angle on the Si-face (C-face) is measured after the removal of the native oxide using BOE (6:1), and revealed a significant decrease of the contact angle from 74.9° (68.4°) to 47.7° (49.3°) and from 75.8° (70.2°) to 51.6° (49.5°) for the 4H-SiC and 6H-SiC regions, respectively. The contact angle of the Si-face recovered over time during room temperature oxidation in air; in contrast, that of the C-face did not recover to the initial value. This study shows that the contact angle is very sensitive to SiC surface polarity, specific surface conditions, and process time. Contact angle measurements are expected to be a rapid way of determining the surface polarity and wettability of SiC crystals.

Study on Wetting Characteristics of Laser Cladding Surfaces (레이저 클래딩 표면에 대한 젖음 특성에 관한 연구)

  • Jang, Mu-Yeon;Park, Young-Whan;Kim, Tae-Wan
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.11
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    • pp.35-40
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    • 2019
  • Laser processing has been used in various fields. In this study, the feasibility of a hydrophobic surface was investigated through the laser cladding technique. A diode laser was used, and the output was set to 600-800 W. Seven different specimens were prepared with different cladding widths and spacings, and the contact angles for water droplets were evaluated. As a result, the contact angle of water droplets measured in the direction parallel to the cladding line was higher than that in the vertical direction. The wider the cladding width and the cladding space, the higher the contact angle in the parallel direction. It is thought that when a higher contact angle is formed in the parallel direction, more air can be placed in the valley between the cladding lines. In addition, for the hydrophobic coating effect, the contact angle of the coated cladding surface was increased by about $5-15^{\circ}$ as a whole compared to the coated smooth surface. It was confirmed that the wetting characteristics were improved through the cladding.

NUMERICAL STUDY OF MULTIPLE DROPLET DYNAMICS IN A PEMFC AIR FLOW CHANNEL (고분자전해질막 연료전지의 공기유로 내에서의 다중 액적 거동에 대한 수치적 연구)

  • Choi, J.Y.;Son, G.
    • 한국전산유체공학회:학술대회논문집
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    • 2009.04a
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    • pp.159-164
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    • 2009
  • The water droplet motion and the interaction between the droplets in a PEMFC air flow channel with multiple pores, through which water emerges, is studied numerically by solving the equations governing the conservation of mass and momentum. The liquid-gas interface is tracked by a level set method which is based on a sharp-interface representation for accurately imposing the matching conditions at the interface. The method is modified to implement the contact angle conditions on the walls and pores. The dynamic interaction between the droplets growing on multiple pores while keeping the total water flow rate through pores constant is investigated by conducting the computations until the droplet motion exhibits a periodic pattern. The numerical results show that the droplet merging caused by increasing the number of pores is not effective for water removal and that the contact angle of channel wall strongly affects water management in the PEMFC air flow channel.

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Application of poly(vinyl acetate) and poly(1,4-butylene adipate) hydrophobic surface coatings on cementitious mortar specimens

  • Sanal, Irem;Yalcin, Bestenur;Yalcin, Ibrahim Ertugrul;Arda, Lutfi
    • Advances in concrete construction
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    • v.11 no.4
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    • pp.323-333
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    • 2021
  • The main objective of this study is to characterize and evaluate the hydrophobic performance of polymer-based water-repellent coatings on cementitious mortar surfaces. Different concentrations of poly(vinyl acetate) (PVAc) and poly(1,4-butylene adipate) (PBA) were prepared in the laboratory and their applicability and performance was tested experimentally by water absorption test and analysis of surface contact angles of cementitious mortar specimens. According to the results of this study, it can be stated that incorporation of nano polymer particles on the surface of cementitious mortar specimens can enhance contact angles and reduce water absorption by increasing hydrophobicity. However, a dosage limit exists for polymer materials in coating, and observed hydrophobic improvements decreases when polymer dosage reached beyond the limit. Additionally, it is observed that water absorption of polymer coated cementitious mortars is closely related with the results of surface contact angle.

Effects of Static Contact Angle and Roughness on Rolling Resistance of Droplet (액적의 구름저항에 대한 정접촉각 및 거칠기의 영향)

  • Cho, Won Kyoung;Cho, Sang Uk;Kim, Doo-In;Kim, Dae-Up;Jeong, Myung Yung
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.1
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    • pp.23-28
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    • 2016
  • In this study, the effects of the contact angle (CA) and contact angle hyteresis (CAH) of planar and nano-patterned surfaces on rolling resistance of water droplet were studied. Based on the investigation on the CAH of water droplet on surfaces with various static wettability, it was found that the rolling resistance coefficient of water droplet is highly influenced by the surface pattern as well as CAH. The observed results suggest that the optimal surface patterns should be designed in order to minimize the rolling resistance of water droplet for the practical applications where superhydrophocitiy is required.

Failure Analysis of Commercial Water-Repellent Coatings for High Temperature Plant (플랜트 부품용 상용 발수코팅의 고온 환경 고장 특성 비교 분석)

  • Lee, Byung-Ho;Kim, Hye-young;Hyeon, Chang-young;Byeon, Jai-Won
    • Journal of Applied Reliability
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    • v.17 no.1
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    • pp.78-82
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    • 2017
  • Purpose: The purpose of this study is to evaluate failure characteristic and mechanism of four commercial water-repellent coatings for elevated temperature machinery applications. Method: Thermal degradation was performed for up to 64 thermal cycles. 1 cycle consists of 15 minute holding at 523K under 300rpm revolution and 15 minute-natural cooling. Contact angle was measured and microstructure of the coating layer was observed by using a scanning electron microscope. Results: Four kinds of commercial repellent coating showed hydrophobic or super-hydrophobic property implying that all coatings are suitable for room temperature application. Contact angle of three kinds of commercial coatings decreased rapidly after thermal exposure, while only one specimen having hydrophobic surface showed extremely slow degradation. Conclusion: Observed decrease in contact angle of the coatings were attributed to formation of macro-sized pores and disappearance of micro-protrusion during thermal exposure. Optimum water-repellent coating needs to be selected under the consideration of initial contact angle as sell as service temperature.

Properties of Microemulsion Containing Quaternary Ammonium Salt as Polishing Wax (광택용 왁스로서 4차 암모늄염을 함유한 마이크로에멀젼의 특성)

  • Lee, Jang-Weon;Kim, Myung-Soo;Jeong, Noh-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.21 no.4
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    • pp.335-344
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    • 2004
  • In this work, the properties as polishing wax for automobile of O/W type microemulsion containing wax, liquid paraffine and quaternaryammonium salt was investigated. The microemulsions were prepared at $96{\sim}97^{\circ}C$ by the phase inversion method, and polyoxyethylene(20) sorbitan monooleate (POE(20)SMO) and distearyl dimethyl ammonium chloride(D.D.A.C) as the emulsifiers were used. The mean particle size of the rnicroemulsions was about 7${\pm}$0.5nm and as the properties of polishing wax, gloss increased degree, water resistant gloss degree, initial and final contact angle after water resistance were tested. The result was that the value of water resistantance and contact angle were decreased with increasing amount of POE(20)SMO and D.D.A.C., while the gloss degree values did not affected. And the rnicroemulsion blended with mono ethylene glycol(MEG) of 5${\sim}$15wt% showed smaller particle size and more stable particle size distribution than without MEG. Finally, this microemulsion showed more excellent values of gloss degree, the water resistant gloss degree and contact angle, than two kinds of commercial polishing wax for automobile.