• Title/Summary/Keyword: water chemical characteristics

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Spatial distribution and temporal variation of hydrogeochemistry in coastal lagoons and groundwater on the eastern area of korea

  • Chanyoung Jeong;Soo Min Song;Woo-Hyun Jeon;Hee Sun Moon
    • Proceedings of the Korea Water Resources Association Conference
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    • 2023.05a
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    • pp.247-247
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    • 2023
  • Coastal lagoons play a crucial role in water exchange, water quality, and biodiversity. It is essential to monitor and understand the dynamics of hydrogeochemistry in lagoon water and its groundwater to preserve and sustainably manage the groundwater-dependent ecosystems like coastal lagoons. This study investigated the spatial and temporal hydrogeochemical characteristics of coastal lagoon (Songjiho) and groundwater on the east coast of Korea. The concentrations of major ions, water isotopes, and nutrients (nitrogen and dissolved organic carbon) in lagoon water and groundwater were periodically monitored for one year. The study revealed that major ions and total dissolved solids (TDS) concentration were higher at deeper depths of aquifers and closer to the coastal area. The hydrogeochemical characteristics of coastal lagoon and groundwater chemistry were classified into two types, Ca-Mg-HCO3 and Na-Cl, based on their spatial location from inland to coastal area. Moreover, the hydrogeochemical characteristics of coastal lagoons and groundwater varied significantly depending on the season. During the wet season, the increased precipitation and evaporation lead to changes in water chemistry. As a result, the total organic carbon (TOC) of coastal lagoons increases during this season, likely due to increased runoff by rainfall whereas the variation of chemical compositions in the lagoon and groundwater were not significant because there is reduced precipitation, resulting in stable water levels and during the dry season. The study emphasizes the impact of spatial distribution and seasonal changes in precipitation, evaporation, and river discharge on the hydrogeochemical characteristics of the coastal aquifer and lagoon system. Understanding these impacts is crucial for managing and protecting coastal lagoons and groundwater resources.

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A Study on Characteristics of Urethane Polymer as Injection Material for Ground Improvement

  • Chun, Byung-Sik;Park, Heung-Kyu;Ryu, Dong-Sung
    • Geotechnical Engineering
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    • v.12 no.3
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    • pp.99-108
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    • 1996
  • The physical and chemical properties of polyurethane-yieding twofomponent liquid injection mixture and those of the resulting polyurethane solid foam for chemical grouting are investigated. The chemical experiments on the factors influencing the properties of polyurethane show that the behaviors of polyurethane-yielding liquid material and those of the produced polyurethane solid foam are greatly affected by the ground conditions such as temperature, water content and density of soil. The ground reinforcing and water -blocking effects of polyurethane grouting are examined through field case history of tunnel ericavati on of the subway under construction.

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Stability of hydrophobic properties of plasma polymerized tetrakis(trimethylsilyloxy)silane film surface

  • Jang, Jinsub;Woo, Sungmin;Ban, Wonjin;Nam, Jaehyun;Lee, Yeji;Choi, Woo Seok;Jung, Donggeun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.147.1-147.1
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    • 2016
  • Hydrophobic thin films are variously applicable for encapsulation of organic devices and water repulsive glass, etc. In this work, the stability of hydrophobic characteristics of plasma polymerized tetrakis (trimethylsilyloxy) silane (ppTTMSS) thin films were investigated. The films were deposited with plasma enhanced chemical vapor deposition (PECVD) on the glass. The deposition plasma power and deposition pressure was 70 W and 600 mTorr, respectively. Thereafter, deposited films were treated by 248nm KrF excimer laser. Stability of hydrophobic properties of plasma polymerized tetrakis(trimethylsilyloxy)silane film surface was tested by excimer laser irradiation, which is thought to simulate severe outdoor conditions. Excimer laser irradiation cycles changed from 10 to 200 cycles. The chemical structure and hydrophobicity of ppTTMSS films were analyzed by using Fourier transform infrared (FTIR) spectroscopy and water contact angle (WCA) measurement, respectively. Absorption spectra peaks and WCA of excimer laser treated ppTTMSS films did not change notably. These results show that our ppTTMSS films possess stable hydrophobic properties.

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MORPHOLOGICAL CHARACTERISTICS OF NONLINEAR OPTICAL MOLECULES AT THE AIR/WATER INTERFACE

  • Lim, Sung-Taek;Park, Mi-Kyung;Shin, Dong-Myung;Kwon, Ohoak
    • Journal of Photoscience
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    • v.5 no.1
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    • pp.11-15
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    • 1998
  • The texture change of non-linear optical molecules at the air/water interface was investigated as a function of surface pressure with Brewster angle microscopy. The texture change resulted from the aggregation of dye molecules is important to understand the film uniformity and grain formation process. The 4-Octadecylhydroxy-4'-nitrostilbene (OHNS) generated the small spots of size around 1$\mu$m. The spots exhibit high contrast with other film area and do not show angle dependent reflectivity change. It is interesting to observe that the size of the domain stays the same as the film pressure increases. At high surface pressure, the contrast ratio of domains becomes high, which means dense packing of OHNS. And, the size of domain grows. In the middle of domain, highly contrasted domains are formed. The first and the second order transitions of OHNS observed from surface pressure-area isotherm result from the two types of grains. The N,N-Dihexadecylcyanoaniline (DHCA) formed highly contrasted gains over entire region, and the grains are the double layers. The difference in Langmuir film of OHNS and DHCA at the air/water interface is consistent with the small tilt angle from the surface normal for OHNS and the large tilt angle for DHCA in the Langmuir-Blodgett films.

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Study on the Abrasive Capsulation Pad in Interlayer Dielectric Chemical Mechanical Polishing (층간절연막 화학기계연마에서 입자코팅패드에 관한 연구)

  • Kim, Ho-Yun;Park, Jae-Hong;Jeong, Hae-Do;Seo, Hyeon-Deok;Nam, Cheol-U;Lee, Sang-Ik
    • Journal of the Korean Society for Precision Engineering
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    • v.18 no.11
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    • pp.168-173
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    • 2001
  • The chemical mechanical polishing (CMP) is generally consisted of pad, slurry including abrasives and so on. However, there are some problems in a general CMP: defects, a high Cost of Consumable (CoC), an environmental problem. The slurry including abrasives especially gives rise to not only increase a CoC, but also prohibition from achieving an eco-process. This paper introduces an abrasive capsulation pad to achieve an eco-process decreasing abrasives used is CMP. The binder wth a water a water swelling and a water soluble characteristic is used for an auto-conditioning, and the $CeO_2$abrasive is selected for an abrasive capsulation pad. Comparing with a conventional CMP, an abrasive capsulation pad appears good characteristics in ILD CMP and is able to achieve an eco-process decreasing wasted slurry.

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Settling Characteristics of Saemankeum fine-Cohesiv Sediments : Effects of Physico-Chemical Properties (새만금 미세점착성 퇴적물의 침강특성 : 퇴적물의 물리.화학적 특성의 영향)

  • Hwang, Gyu-Nam;Jo, Yong-Sik
    • Journal of Korea Water Resources Association
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    • v.35 no.5
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    • pp.475-484
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    • 2002
  • A series of settling tests and physico-chemical property tests on Saemankeum fine-cohesive sediments has been conducted in order to investigate the correlation between settling properties and their physico-chemical properties which are represented as grain size distribution, mineralogical composition, and percentage of organic contents. Experimental results of physico-chemical property tests show that Saemankeum sediments are relatively large in average grain size(52${\mu}{\textrm}{m}$), and contain very small organic materials(2%), and are dominantly composed of Quarts in mineralogical aspect which has relatively low cohesion. Thus, Saemankeum sediments might be specified as the sediments whose settling properties are more influenced by the gravity than the cohesion. This characteristics of Saemankeum sediments are found to lead to relatively small settling velocity in flocculated settling region in which increasing cohesion results in increasing settling velocity, while relatively large settling velocity in hindered settling region in which settling velocity decreases with increasing cohesion.

Water Quality and Pollutions of River waters in Gwangju City (광주광역시 하천수의 수질 및 오염)

  • 오강호;고영구
    • Journal of Environmental Science International
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    • v.12 no.3
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    • pp.287-297
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    • 2003
  • To investigate water quality and pollution states of rivers in Gwangju city, total of 30 water samples were taken from the main stream of Yeongsan river, Hwangryong river and Gwangju stream in dry and flood seasons. Physico-chemical characteristics of above streams according to pH-Eh and Piper's diagrams we, typically, assigned to natural river water. In the streams, BOD, COD, T-N and T-P indicating water quality mostly increase toward downstream. Notably, water qualities in area near connection between the Gwangju stream and the main stream of Yeongsan river are polluted over V level in rivers and lakes water quality standard. The pollutions are influenced by lift and agricultural foul waters from Gwangju City and farming areas around upstream branches of the Yeongsan river, reasonably. Besides, heavy metals are below the standard in those streams. So, it is considered that the streams are polluted by not industrial but life/agricultural foul waters.

Investigation of Demixing Phenomena of a Polymer Solution During the Phase Inversion Process

  • Han, Myeong-Jin;D. Bhattacharyya
    • Proceedings of the Membrane Society of Korea Conference
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    • 1995.04a
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    • pp.11-15
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    • 1995
  • Polysulfone (PS) membranes were prepared by the phase inversion process using water or isopropanol as nonsolvent. The Flory-Huggins theory for a ternary system nonsolvent/solvent/polymer is applied to describe the thermodynamic equilibria of the components. The calculated ternary phase equilibria show that demixing of a PS binary solution with n-methylpyrrolidone (NMP) will be fast in a water coagulation bath and will be delayed in an isopropanol bath. The prepared membranes were characterized by SEM, gas adsorption-desorption measurement, and permeability test. The membrane, which is precipitated by fast demixing in a water bath, has nodular structures in the skin region and includes finger-like cavities in the sublayer. The membrane coagulated by isopropanol has a very dense and thick skin structure, which is formed by delayed demixing. The membrane coagulated by isopropanol showed considerably lower pore volume and surface area compared to that observed with water coagulation method. With dimethylformamide (DMF) as solvent and 2-3 wt% of water, the solution can show the liquid-liquid phase separation due to agglomation of the polymer-lean phase from the homogeneous solution. The membranes, which were coagulated near an equilibrium state, show the large (micron size) round pores in the whole membranes. The pores do not contribute the permeation characteristics.

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Heat transfer characteristics of Triple-Tube Type Latent Heat Storage Tank (3중관 튜브형 잠열 축열조에서의 열전달 특성 연구)

  • Lee, W.K.;Han, G.Y.;Kang, Y.H.
    • Journal of the Korean Solar Energy Society
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    • v.21 no.1
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    • pp.71-82
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    • 2001
  • The heat transfer experiment in a latent heat storage tank as a solar energy storage system for the hot water supply was carried out. The latent heat storage tank was consisted of triple - tube type ; Outer shell for hot water from solar collector, PCM storage vessel in the middle of the tank and inside tube for hot water recovery. The heat storage tank has the dimension of 60 cm long and 34 cm outside diameter. Paraffin wax(m.p = 55.4C) and sodium acetate trihydrate(m.p = 58 C) were employed as the PCM this study. Experimental variables were inlet temperature and flow rate of the hot water for heat storage stage and cold water for heat recovery stage. Temperature profiles, heat transfer coefficient and the efficiency of heat storage$(Q/Q_{max})$ and heat recovery $(Q/Q_{max})$ were determined for the paraffin wax and inorganic salt respectively.

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Heat transfer characteristics of Immersed Coil Type Latent Heat Storage Tank (내부코일형 잠열 축열조에서의 열전달 특성 연구)

  • Lee, W.K.;Han, G.Y.;Kang, Y.H.
    • Journal of the Korean Solar Energy Society
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    • v.21 no.1
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    • pp.83-91
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    • 2001
  • The heat transfer experiment in a pilot scale latent heat storage tank as a solar energy storage system for the hot water supply was carried out. The latent heat storage tank was consisted of three parts; Outer shell for hot water from solar collector, PCM storage vessel in the middle of the tank and immersed coil in the PCM vessel for hot water recovery. The heat storage tank has the dimension of 115 cm in height and 32 cm outside diameter. Paraffin wax (m.p = 55.4C) and sodium acetate trihydrate (m.p = 58 C) were employed as the PCM this study. Experimental variables were inlet temperature and flow rate of the hot water for heat storage stage and cold water for heat recovery stage. Temperature profiles, heat transfer coefficient and the efficiency of heat storage $(Q/Q_{max})$ and heat recovery $(Q/Q_{max})$ were determined for the paraffin wax and inorganic salt respectively.

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