• Bulletin of the Korean Chemical Society
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• 제2권2호
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• pp.60-66
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• 1981

The hypothesis that three classes of water exist in hydrogels, namely X water (free water-like), Z-water (bound water-like), and Y water (interfacial water-like), has been verified and generally accepted. To further check the validity of this hypothesis and to study the nature of X, Y, and Z water as conformation changes, several experiments have been done using Tactic Poly(2-hydroxyethyl methacrylate) (P-HEMA) gels. Thermal expansively data for tactic P-HEMA gel was obtained. In each case of isotactic and syndiotactic P-HEMA, the higher water content gels showed an extremely sharp volume change at $0^{\circ}C$, indicating the presence of normal free water-like. Lower water content gels showed no anomalous change in thermal expansion, indicating that the water is bound water-like. The medium water content gels exhibited intermediate behavior. These results were also confirmed by bulk gel conductivity measurments. The differential scanning calorimeter(DSC) experiment was simply introduced to further verify the bound water-like quantities which was obtained by the method of dilatometry and specific conductivity. Observing the amounts of X, Y, and Z water with the change of tacticity, the similar content of bound water-like may be due to the same primary structure of isotactic and syndiotactic polymer and the difference in free and interfacial water-like content may be due to the difference in secondary and tertiary structure of tactic polymer. Therefore, as the polymer conformation varies, the free and interfacial water-like content will be varied. In order to demonstrate these concepts, Russel et al.'s CPK space-filling molecular models of isotactic and syndiotactic P-HEMA was utilized.

• 대한화학회지
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• 제15권4호
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• pp.171-175
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• 1971

Significant structure theory has been applied to the viscosities of supercooled liquids with success. In the supercooled region, the effect of free volume decrease is so significant that the thermal effects on the solid-like volume must be considered properly. In addition, the two state theories proposed by Jhon and Eyring for water and Litovitz et al. for boron trioxide have been successfully applied to the structure change in the liquid state. Considered liquids are benzene, carbon tetrachloride, p-xylene, water and boron trioxide.

• Journal of the Korean Wood Science and Technology
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• 제44권2호
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• pp.231-240
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• 2016

The change in chemical compositions of leachate and medium density fiberboard (MDF) from a laboratory-scale simulated landfill which constructed in a plastic container containing alternating layers of soil and MDF was investigated to evaluate decomposing of MDF in soil. Four treatments were conducted: 1) MDF in soil, 2) MDF only, 3) cured UF resin in soil, and 4) soil only. Molecular weight (MW) distribution of compounds in leachate from soil only treatment did not change over time. In UF resin in soil treatment, the MW distribution shifted to a lower MW distribution over time, while the peak shifted to the left indicated changing to higher MW distribution in leachate from treatment 1 and 2 contained MDF. Higher percent nitrogen in leachate was observed in MDF containing treatments due to the UF resin in the MDF. The percent carbon slightly increased in MDF only while that greatly decreased in MDF in soil treatment maybe due to bacterial activity. The percent of extractable materials from the MDF decreased greatly on day 35 compare to day 0, and subsequently did not change much on day 77. In contrast, percent holocellulose and lignin did not change much over time. No structural change of the wood fiber in MDF occurs during the study. Water-soluble materials from MDF in soil contributed the change in chemical composition of leachate.

• 콘크리트학회논문집
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• 제26권4호
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• pp.457-463
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• 2014

이 연구는 화학혼화제 인수검사 기준으로 활용할 수 있는 고형분량 변동이 콘크리트 품질에 미치는 영향에 대해 살펴보는데 그 목적을 두었다. 현재 한국도로공사의 잠정기준으로 운용 중인 ASTM C 494 기반의 고형분량 변동범위 ${\pm}12%$는 혼화제의 종류 및 고형분량의 특성을 반영하지 못해 혼화제 종류에 따라 상이하게 나타났다. 고형분량 변동에 따른 콘크리트의 품질 변동을 평가한 결과 리그닌은 감수율이 낮은 관계로 고형분량의 변동범위가 큰 반면 나프탈렌계 및 폴리칼본산계 고성능감수제는 높은 감수율로 인하여 인수검사 기준으로 활용 중인 고형분량의 차이에 대한 허용범위 재조정이 요구되었다.

• 상하수도학회지
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• 제33권6호
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• pp.457-467
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• 2019

Because non-point source pollution is very closely related to hydrological characteristics, its importance is highly emphasized nowadays along with accelerating climate change. Especially for Korea, the non-point source pollution and its control are entirely depending on runoff, precipitation, drainage, land use or development, based on geographical and topographical reasons of Korea. Many studies reported the physical (e.g., apparatus- and natural-type facilities, etc.) and chemical methods (e.g., organic and inorganic coagulants, etc.) of controling non-point pollutant source pollution, however, those are needed to be reconsidered along with climate change causing the unexpected patterns and amounts of precipitation and strengthen complexity of social community. The objectives of this study are to assess recent situations of non-point source pollution in Korea and its control means and to introduce possible effective ways of non-point source pollution against climate change in near future.

• Bulletin of the Korean Chemical Society
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• 제4권3호
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• pp.133-139
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• 1983

To understand the importance of Y-base adjacent to the anticodon stabilizing codon-anticodon interaction, a study has been undertaken for the model compound involving the interaction between Y-base and anticodon as well as the participation of water molecule by calculating the conformational free energy using an empirical potential function. We restrict our analysis to sites directly associated with Y-base by varying only the backbone torsion angles of Y-base. The hydration and $Mg^{+2}$ binding effects on the conformational stability of Y-base are calculated and discussed. The free Y-base is proved to be less stable than the hydrated one. The free energy change due to the hydration of Y-base amounts to -119.5 kcal/mole, in which the conformational energy change is -142.4 kcal/mole and the configurational entropy change is -76.9 e. u. It is found that the water molecules bound to Y-base and $Mg^{+2}$ contribute to the conformation of Y-base dominantly.

• 한국환경보건학회:학술대회논문집
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• 한국환경보건학회 2002년도 춘계 국제 학술대회
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• pp.54-64
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• 2002

This study evaluated advanced water treatment (AWT) system in Korea. There are currently 16 plants operating with AWT. However, no attempt has been made to evaluate AWT system. This study selected one water treatment plant with AWT (pre-ozonation ＋ BAC). Using the operation data from 1995 to 2001 and pilot study results, the post-evaluation of the AWT system has been conducted. The study found that AWT improved water qualities of organic, ammonia, and turbidity, as expected. However, the extent of the improvement was generally short of the pilot study expectations. Pre-ozonation failed to decrease coagulant consumption. The dosage increased rather than decreased. AWT was, however, successful to decrease chlorine consumption. The chlorine reduction was related to the change in raw water characteristics and AWT introduction. Pre-ozonation failed to decrease coagulant consumption. The dosage increased rather than decreased. AWT was, however, successful to decrease chlorine consumption. The chlorine reduction was related to the change in raw water characteristics and AWT introduction, Both operation of pre-ozonation and reduced ammonia loading were responsible for the reduction. AWT increased the operation cost. Maintenance, raw water, and power cost increased, while labor and chemical cost decreased. Manpower reduction resulting form automation caused the decrease of labor cost. The reduction of chlorine consumption caused the decrease of chemical cost.

• Bulletin of the Korean Chemical Society
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• 제8권1호
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• pp.31-39
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• 1987

By using a complete rate constant($k_e$) which treats a solvent (water) as a reactant, and a conventional rate constant($k_c$), which ignores the solvent in describing the rate, the parameters ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were introduced. These quantities represent the volume change, the enthalpy change, and the entropy change accompanying the electrostriction which occurs when solvent molecules condense on the activated complex. The authors measured the rates of the solvolysis of benzoyl chloride in water-acetone mixtures at $15^{\circ}$ to $30^{\circ}C$ and 1 bar to 2500 bars. Applying the authors' theory to the experimental results, the parameters, ${\Delta}V^{\neq}_s,\;{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ were evaluated, and it was found that they are all negative, indicating that water dipoles condense on the activated complex. They also proposed the following equations: ${\Delta}H^{\neq}_c\;=\;{\Delta}H^{\neq}_e\;+\;{\Delta}H^{\neq}_s\;and\; {\Delta}S^{\neq}_c\;=\;{\Delta}S^{\neq}_e\;+{\Delta}S^{\neq}_s\;,\;where\;{\Delta}H^{\neq}_c\;and\;{\Delta}H^{\neq}_c\;and\;{\Delta}S^{\neq}_s $are the activation enthalpy change and the activation entropy change for the conventional reaction rate, respectively, and ${\Delta}H^{\neq}_e$ and ${\Delta}S^{\neq}_e$ are the corresponding quantities for the complete reaction rate. The authors proposed that for the $SN_1$ type, all the quantities, ${\Delta}V^{\neq}_s,\;{\Delta}S^{\neq}_s\;,{\Delta}H^{\neq}_s\;and\;{\Delta}S^{\neq}_s$ are comparatively large, and for the $SN_2$ type, these quantities are smaller than for the $SN_1$ type, and occasionally the case ${\Delta}S^{\neq}_e$ < 0 occurs. Using these criteria, the authors concluded that at high temperature, high pressure and for a high water content solvent, the SN_1$ type mechanism predominates whereas in the reversed case the $SN_2$M type predominates.

• 한국환경과학회지
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• 제14권10호
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• pp.937-944
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• 2005

Presently, aquatic plants are used for the water purification in inland water. This study was carried out to investigate the water purification effect of aquatic plants, Oenanthe javanica and Typha angustata, The experiment was conducted in outdoor flowing water was conducted for ten days, Water quality was measured in terms of water temperature, COD(chemical oxygen demand), SS(suspended solids), Total N, Total P. The results of field experimentation showed that hydraulic retention time was the earliest in July and August 2003, and there were not any particular changes of monthly water temperature in inflow water and outflow water. As we look at the changes taken place in inflow water and outflow water throughout the whole experiment period, the change of water quality in summer was salient, especially SS removal ratio showed distinguished change as $25\%$, when the pebble filter and aquatic were attached to it. The removal rate of COD, total N total P were $14,7\%,\;8\%\;and\;9\%$, respectively. In relating the length of water extension to the change in water quality, the water quality tended to get lower generally in proportion to hydraulic retention time.

• Korean Chemical Engineering Research
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• 제46권3호
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• pp.516-520
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• 2008

우리나라는 상수도시설의 노후화와 그 동안의 상수원 수질변화에 대응한 정수처리공정의 개량과 개선이 요구되어지고 있는 상황에 있어서, 기존의 정수처리공정에 어떠한 시설개량이나 설비의 보완 없이 DAF 공정을 추가하여 점토와 조류입자를 효과적으로 제거할 수 있는 DAF hybrid 공정의 적용성을 살펴보고자 일련의 실험을 실시하였다. DAF 공정의 설치위치는 조류입자의 제거에는 응집지나 침전지 전단을 이용하는 DAF-CGS 공정조합보다는 침전지 후단 또는 여과지 전단을 이용하는 DAF-CSF 방식이 더 효과적인 것으로 나타났다. 또한, DAF-CSF hybrid 공정을 도입함으로써 기존의 상수처리조건과 동일한 처리속도(수리학적 부하량)에서 처리효율이 향상될 것이며, 높은 수리학적 부하에서도 재래식 상수도시설에 적용하여 안정된 처리효율을 얻을 수 있을 것으로 판단되었다.