• Korean Journal of Agricultural Science
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• v.14 no.2
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• pp.358-372
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• 1987

This study was performed to obtain data which can be applied to use of water-proof mortars. The data was based on the properties of water-proof mortars depending upon various mixing ratios to compare those of cement mortar. The water-proof agents used were retard and accelerate type which are being used as mortar structures. The water-proof agents, mixing ratios of cement to fine aggregate were 1:1, 1:2, 1:3 and 1:4. The results obtained were summarised as follows; 1. The results of flow test, water-cement ratio was increased with the increasing of mixing ratio. 2. The permeability were increased in poorer mixing ratio and higher water pressure. 3. The bulk density was decreased with the increasing of mixing ratio, and compressive and tensile strength were increased with increasing of the bulk density. 4. At 1:1 mixing ratio, the highest strengths were showed and strengths were decreased with the increasing of mixing ratio. 5. The absorption rates were increased in- poorer mixing ratio 6. The correlation between W/C, permeability, bulk density, compressive strength and absorption rate were highly significant as a straight line, respectively.

• Magazine of the Korean Society of Agricultural Engineers
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• v.26 no.1
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• pp.52-72
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• 1984

This study was performed to obtain the basic data which can be applied to the use of epoxy resin mortars. The data was based on the properties of epoxy resin mortars depending upon various mixing ratios to compare those of cement mortar. The resin which was used at this experiment was Epi-Bis type epoxy resin which is extensively being used as concrete structures. In the case of epoxy resin mortar, mixing ratios of resin to fine aggregate were 1: 2, 1: 4, 1: 6, 1: 8, 1:10, 1 :12 and 1:14, but the ratio of cement to fine aggregate in cement mortar was 1 : 2.5. The results obtained are summarized as follows; 1.When the mixing ratio was 1: 6, the highest density was 2.01 g/cm$^3$, being lower than 2.13 g/cm$^3$ of that of cement mortar. 2.According to the water absorption and water permeability test, the watertightness was shown very high at the mixing ratios of 1: 2, 1: 4 and 1: 6. But then the mixing ratio was less than 1 : 6, the watertightness considerably decreased. By this result, it was regarded that optimum mixing ratio of epoxy resin mortar for watertight structures should be richer mixing ratio than 1: 6. 3.The hardening shrinkage was large as the mixing ratio became leaner, but the values were remarkably small as compared with cement mortar. And the influence of dryness and moisture was exerted little at richer mixing ratio than 1: 6, but its effect was obvious at the lean mixing ratio, 1: 8, 1:10,1:12 and 1:14. It was confirmed that the optimum mixing ratio for concrete structures which would be influenced by the repeated dryness and moisture should be rich mixing ratio higher than 1: 6. 4.The compressive, bending and splitting tensile strenghs were observed very high, even the value at the mixing ratio of 1:14 was higher than that of cement mortar. It showed that epoxy resin mortar especially was to have high strength in bending and splitting tensile strength. Also, the initial strength within 24 hours gave rise to high value. Thus it was clear that epoxy resin was rapid hardening material. The multiple regression equations of strength were computed depending on a function of mixing ratios and curing times. 5.The elastic moduli derived from the compressive stress-strain curve were slightly smaller than the value of cement mortar, and the toughness of epoxy resin mortar was larger than that of cement mortar. 6.The impact resistance was strong compared with cement mortar at all mixing ratios. Especially, bending impact strength by the square pillar specimens was higher than the impact resistance of flat specimens or cylinderic specimens. 7.The Brinell hardness was relatively larger than that of cement mortar, but it gradually decreased with the decline of mixing ratio, and Brinell hardness at mixing ratio of 1 :14 was much the same as cement mortar. 8.The abrasion rate of epoxy resin mortar at all mixing ratio, when Losangeles abation testing machine revolved 500 times, was very low. Even mixing ratio of 1 :14 was no more than 31.41%, which was less than critical abrasion rate 40% of coarse aggregate for cement concrete. Consequently, the abrasion rate of epoxy resin mortar was superior to cement mortar, and the relation between abrasion rate and Brinell hardness was highly significant as exponential curve. 9.The highest bond strength of epoxy resin mortar was 12.9 kg/cm$^2$ at the mixing ratio of 1:2. The failure of bonded flat steel specimens occurred on the part of epoxy resin mortar at the mixing ratio of 1: 2 and 1: 4, and that of bonded cement concrete specimens was fond on the part of combained concrete at the mixing ratio of 1 : 2 ,1: 4 and 1: 6. It was confirmed that the optimum mixing ratio for bonding of steel plate, and of cement concrete should be rich mixing ratio above 1 : 4 and 1 : 6 respectively. 10.The variations of color tone by heating began to take place at about 60˚C, and the ultimate change occurred at 120˚C. The compressive, bending and splitting tensile strengths increased with rising temperature up to 80˚ C, but these rapidly decreased when temperature was above 800 C. Accordingly, it was evident that the resistance temperature of epoxy resin mortar was about 80˚C which was generally considered lower than that of the other concrete materials. But it is likely that there is no problem in epoxy resin mortar when used for unnecessary materials of high temperature resistance. The multiple regression equations of strength were computed depending on a function of mixing ratios and heating temperatures. 11.The susceptibility to chemical attack of cement mortar was easily affected by inorganic and organic acid. and that of epoxy resin mortar with mixing ratio of 1: 4 was of great resistance. On the other hand, when mixing ratio was lower than 1 : 8 epoxy resin mortar had very poor resistance, especially being poor resistant to organicacid. Therefore, for the structures requiring chemical resistance optimum mixing of epoxy resin mortar should be rich mixing ratio higher than 1: 4.

• Proceedings of the Korean Society of Near Infrared Spectroscopy Conference
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• 2001.06a
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• pp.1182-1182
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• 2001

In this study, the newly constructed optical measurement system, which was mainly composed of a parametric tunable laser and a near infrared photoelectric multiplier, was introduced to clarify the optical characteristics of wood as discontinuous body with anisotropic cellular structure from the viewpoint of the time-of-flight near infrared spectroscopy (TOF-NIRS). The combined effects of the cellular structure of wood sample, the wavelength of the laser beam λ, and the detection position of transmitted light on the time resolved profiles were investigated in detail. The variation of the attenuance of peak maxima At, the time delay of peak maxima Δt and the variation of full width at half maximum Δw were strongly dependent on the feature of cellular structure of a sample and the wavelength of the laser beam. The substantial optical path length became about 30 to 35 times as long as sample thickness except the absorption band of water. Δt ${\times}$ Δw representing the light scattering condition increased exponentially with the sample thickness or the distance between the irradiation point and the end of sample. Around the λ=900-950 nm, there may be considerable light scattering in the lumen of tracheid, which is multiple specular reflection and easy to propagate along the length of wood fiber. Such tendency was remarkable for soft wood with the aggregate of thin layers of cell walls. When we apply TOF-NIRS to the cellular structural materials like wood, it is very important to give attention to the difference in the light scattering within cell wall and the multiple specular-like reflections between cell walls. We tried to express the characteristics of the time resolved profile on the basis of the optical parameters for light propagation determined by the previous studies, which were absorption coefficient K and scattering coefficient S from Kubelka-Munk theory and n from nth power cosine model of radiant intensity. The wavelength dependency of the product of K/S and n, which expressed the light-absorbing and -scattering condition and the degree of anisotropy, respectively, was similar to that of the time delay of peak maxima Δt. The variation of the time resolved profile is governed by the combination of these parameters. So, we can easily find the set of parameters for light propagation synthetically from Δt.

• Journal of Pharmaceutical Investigation
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• v.38 no.2
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• pp.127-134
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• 2008

Peroral administration is the most convenient one for the administration of pharmaceutically active compounds. Most of poorly water-soluble drugs administered via the oral route, however, remain poorly available due to their precipitation in the gastrointestinal (GI) tract and low permeability through intestinal mucosa. In this study, one of drug delivery carriers, lipid nanoparticles (LNPs) were designed in order to reduce side effects and improve solubility and stability in GI tract of the poorly water soluble drugs. However, plain LNPs are generally unstable in the GI tract and susceptible to the action of acids, bile salts and enzymes. Accordingly, the surface of LNPs was modified with polyethylene glycol (PEG) for the purpose of improving solubility and GI stability of paclitaxel (PTX) in vitro. PEG-modified LNPs containing PTX was prepared by spontaneous emulsification and solvent evaporation (SESE) method and characterized for mean particle diameter, entrapping efficiency, zeta potential value and in vitro GI stability. Mean particle diameter and zeta potential value of PEG-modified LNP containing PTX showed approximately 86.9 nm and -22.9 mV, respectively. PTX entrapping efficiency was about 70.5% determined by UV/VIS spectrophotometer. Futhermore, change of particle diameter of PTX-loaded PEG-LNPs in simulated GI fluids and bile fluid was evaluated as a criteria of GI stability. Particle diameter of PTX-loaded PEG-LNPs were preserved under 200 nm for 6 hrs in simulated GI fluids and bile fluid at $37^{\circ}C$ when DSPE-mPEG2000 was added to formulation of LNPs above 4 mole ratio. As a result, PEG-modified LNPs improved stability of plain LNPs that would aggregate in simulated GI fluids and bile solution. These results indicate that LNPs modified with biocompatible and nontoxic polymer such as PEG might be useful for enhancement of GI stability of poorly water-soluble drugs and they might affect PTX absorption affirmatively in gastrointestinal mucosa.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.330-337
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• 2021

3D printing is not only at the fundamental study and small-scale level, but has recently been producing buildings that can be inhabited by people. Buildings require a lot of cost and labor to work on the form work, but if 3D printing is applied to the building, the construction industry is received attention from technologies using 3D printing as it can reduce the construction period and cost. 3D printing technology for buildings can be divided into structural and non-structural materials, of which 3D printing is applied to non-structural materials. Because 3D printing needs to be additive manufacturing, control such as curing speed and workability is needed. Since cement mortar has a large shrinkage due to evaporation of water, cement polymer dispersion is used to improve the hardening speed, workability, and adhesion strength. The addition of polymer dispersion to cement mortar improves the tensile strength and brittleness between the cement hydrate and the polymer film. Cement mortar using polymer materials can be additive manufacturing but it has limited height that can be additive manufacturing due to its high density. When light-weight materials are mixed with polymer cement mortar, the density of polymer cement mortar is lowered and the height of additive manufacturing, so it is essential to use light-weight materials. However, the use of EVA redispersible polymer powder and light-weight materials, additional damage such as cracks in cement mortar can occur at high temperatures such as fires. This study produced a test specimen incorporating light-weight materials and EVA redispersible polymer powder to produce exterior building materials using 3D printing, and examined flame resistance performance through water absorption rate, length change rate, and cone calorimeter test and non-flammable test. From the test result, the test specimen using silica sand and light-weight aggregate showed good flame resistance performance, and if the EVA redispersible polymer powder is applied below 5%, it shows good flame resistance performance.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.1
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• pp.47-53
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• 2011

The artificial aggregates (AAs) were manufactured from the parent batch powders consisting of bottom ash containing excess unburned carbon and dredged soil, 7 : 3 weight ratio by direct sintering method and those physical properties were evaluated. Especially, the effects of waste glass or frit (NWG) which was made by addition of 5 wt% $Na_2O$ to the waste glass upon the bloating phenomenon of AAs were analyzed. The AAs manufactured from the parent batch powders showed a lower specific gravity than that of specimens containing waste glass or NWG due to excess u$Na_2O$nburned carbon which usually obstructs a sintering process. But, the waste glass added on parent batch powders promoted the sintering and densification thus increased the specific gravity of AAs. Also the specific gravity of AAs added with 5 wt% NWG, was lowered compared to that of AAs added with as-received waste glass. This is because of bloating of shell which captures gases owing to the lowered viscosity of liquid formed at the specimen surface caused by $Na_2O$ addition. In conclusion, the AAs sintered at above $1100^{\circ}C$ in this study showed characters of lightweight aggregate of specific gravity 1.15~1.34 and water absorption 11~19 %, and the bloating phenomenon of AAs was occurred at the shell rather black core part.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.4
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• pp.404-417
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• 2016

The purpose of this study is to examine the extent to which the deterioration in strength of high strength concrete of 60MPa replaced by a large amount of recycled coarse aggregates (more than 60% to 100% of replacement ratio) could be recovered with steel fiber reinforcement through material compressive strength test and shear failure test on short and middle beams and then to offer useful data for aggregate supply system of a sustainable resource circulation type. This study first examined the results of previous related tests. The results of the material compressive strength tests confirmed that when using a combination of steel fiber reinforcements of volumn ratio 0.75% and high quality recycled coarse aggregates with an water absorption rate within 2.0%, the strength characteristics of high strength concrete of 60MPa level were not only restored to the strength level of concrete made with natural aggregates, but also showed superior ductility. And the shear failure tests on short and middle beams using recycled coarse aggregates more than 60% with shear span to depth ratio (a/d) of 2 and 4 controlled by shear forces mainly confirmed that effects of superior shear strength increase and ductile behavior characteristics were showed by steel fiber reinforcements.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.18 no.5
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• pp.211-216
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• 2008

The artificial lightweight aggregate (ALA) was manufactured in a rotary kiln at $1125^{\circ}C$ using green body formed by pelletizing the batch powder composing of coal bottom ash (CBA) produced from power plant, clay and dredged soil (DS). The TCLP (Toxicity characteristic leaching procedure) results showed that the dissolution concentration of heavy metal ions of ALA fabricated in this study was below the limitation defined by the enforcement regulations of wastes management law in Korea. The ALA containing 60$\sim$70 wt% CBA had a bulk density of 1.45$\sim$1.49 and a water absorption of 17.2$\sim$18.5 %. The impact values for oven-dry state and saturated-surface dry state of ALA were 27.4$\pm$1.3 and 23.4$\pm$2.6 % respectively. The 28-days compressive strength of concrete made with various ALA was $22.7\sim27.8 N/mm^2$. The slump of concrete with ALA containing CBA 60 and 70 wt% were 7.9 and 14.3 cm respectively. The unit weight of concrete made with any ALA fabricated in this study was satisfied with the standard specifications of lightweight concrete for the civil engineering and construction presented by Korea as below $1.84 ton/m^3$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.21 no.1
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• pp.41-46
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• 2011

The artificial aggregates (AAs) composing of 2 wastes, coal bottom ash and dredged soil (7 : 3, weight ratio) were fabricated as a function of red mud contents,0~30 wt% using direct sintering method at $1050{\sim}1250^{\circ}C$ for 10 min, and those physical properties were evaluated. Especially, in order to analyze the red mud addition effect on the bloating phenomenon of AAs manufactured, the specific gravity and water absorption were measured and studied linked with the microstructural observation results. The lightening of AAs was enhanced due to increased bloating with increasing temperature and red mud contents. The AAS sintered at $1050{\sim}1150^{\circ}C$ showed well-developed black-coring structure, but for the specimens containing red mud sintered over $1200^{\circ}C$ generated excessive liquid and gas caused by reduction of $Fe_2O_3$, thus the black-coring part was gradually burst open out of shell of AAs. Particularly, all specimens containing 30 wt% red mud was burst up when sintered over $1100^{\circ}C$. The AAs containing no red mud sintered at $1200^{\circ}C$ had a specific gravity of about 1.2 and those containing 20 wt% had below 1.0 which are characters of lightweight aggregate.