• 제목/요약/키워드: water absorption coefficients

검색결과 94건 처리시간 0.024초

환경수의 수온과 암모니아 농도 변화에 따른 쥐노래미(Hexagrammos otakii Jordan et Starks) 육성어의 산소소비와 암모니아 배설 (Effects of Water Temperature and Ambient Ammonia Concentration on Oxygen Consumption and Ammonia Excretion of Greenling Hexagrammos otakii Jordan et Stalks)

  • 김유희;김병기;김현주;조재윤;한원민;박정환
    • 한국수산과학회지
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    • 제42권4호
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    • pp.373-379
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    • 2009
  • This study investigated oxygen consumption rate (OCR), $Q_{10}$ coefficient and ammonia excretion rate of the greenling, Hexagrammos otakii Jordan et Starks with the average body weight of 250 g in a semi-recirculated respiratory measuring system. The experiment was done under three different water temperatures (10, 15, $20^{\circ}C$) and five different ambient ammonia concentrations (0, 2.5, 5, 10, 20 mg/L). As the water temperature and ambient ammonia concentration increased the OCR has significantly increased (P<0.05). Given experimental conditions, the OCR of greenling were $50.8{\sim}159.4\;mg\;O_2\;kg^{-1}\;hr^{-1}$ and the relationship of water temperature (T) and ambient ammonia concentration (C) on the OCR were following: OCR = 41.3 - 1.87T - 7.38C + $0.463T^2$ + $0.66lC^2$ + 0.642TC - $0.011T^3$ - $0.010C^2$ - $0.031TC^2$ - $0.001T^2$C ($r^2$= 0.9226). $Q_{10}$ coefficients were $1.88{\sim}3.50$ for $10^{\circ}C$ to $15^{\circ}C$, $1.03{\sim}2.73$ for $15^{\circ}C$ to $20^{\circ}C$ and $1.40{\sim}1.90$ for $10^{\circ}C$ to $20^{\circ}C$, respectively. In general, the ammonia excretion rate tended to increase with increasing of the water temperature within normal ambient ammonia concentration. However, interestingly, it was observed that ammonia was absorbed rather than excreted above the ambient ammonia concentration of $2.5\;mg\;L^{-1}$, regardless of the water temperature. Thus, the largest ammonia absorption rate (AAR) was obserbed at the level of $98.4\;mg\;TAN\;kg^{-1}\;hr^{-1}$. The relationship ambient ammonia concentration (C) on AAR was following: Y = 1.61 + $10.9X^{0.7}$ ($r^2$ = 0.889).

강섬유 보강 콘크리트의 수송계수 및 부식저항효과 (Transport Coefficients and Effect of Corrosion Resistance for SFRC)

  • 김병일
    • 콘크리트학회논문집
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    • 제22권6호
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    • pp.867-873
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    • 2010
  • 이 연구에서는 강섬유로 보강된 철근콘크리트에서의 부식 특성에 관한 실험적 연구를 수행하였다. 먼저 강섬유의 보강콘크리트의 수송특성, 즉 공극률, 흡수성, 투과성 및 염소이온 확산성에 관한 실험을 수행하여 철근부식과 의 관계를 비교 평가 하였다. 강섬유의 보강으로 인해 약간의 압축강도 증가와 함께, 흡수성, 투과성 및 확산성에 관한 실험 결과에서도 콘크리트 내부로의 유해물질의 침투저항성이 크게 증가하는 것으로 나타났다. 철근부식과의 관계에서는 예상된 결과와는 다르게 강섬유의 혼입이 철근부식을 가속화 시키는 경향이 나타났다. 염화나트륨 용액이 침투하는 노출면에서는 강섬유의 부식팽창으로 인한 표면박리현상이 관찰되었으며, 철근부위 절단면에서는 철근 주변에 강섬유의 부식이 국부적으로 관찰 되었다. 고온 및 고농도의 염화물 환경에서의 건습 싸이클링이 노출표면에 가까운 공극에서 지속적으로 염분결정체의 증가와 더불어 내부공극에서의 강섬유의 부식으로 증가된 압력이 표면 박리를 일으킨 것으로 보인다. 결과적으로는 노출면 부근에서의 미세균열을 증가가 물, 염화이온 및 산소의 침투를 보강근으로의 가속화를 진행 시킨 것으로 판단이 된다. 이 연구에서는 강섬유로 보강된 철근콘크리트에서 철근부식에 영향을 주는 명확한 메커니즘은 충분히 규명이 되지 않았으며, 보다 명확한 관계를 이해하기 위해서는 부식과정에서 강섬유의 잠재적인 부식팽창에 관한 보다 상세한 실험적 연구가 필요할 것으로 판단되어 진다.

붕산처리(硼酸處理) 합판(合板)의 열판건조(熱板乾燥) 및 동적(動的) 탄성율(彈性率)에 관(關)한 연구(硏究) (Studies on Press Drying and Dynamic Elastic Modulus of Plywood Treated with Boric Acid)

  • 김종만
    • Journal of the Korean Wood Science and Technology
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    • 제15권3호
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    • pp.56-67
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    • 1987
  • Plywoods used for construction as a decorative interior material are inflammable and can make fire accidents, causing destruction of human life and property. Therefore, it is indeed required to make fire-retardant treated plywood. In this study, 3.7mm yellow meranti plywoods were soaked in 18% boric acid solutions and tap water by hot-cold bath for 1/2, 2/2, 4/2, 6/2 hours and redrying of treated plywoods was carried out by press drying at the platen temperature of 110, 130, 160, $180^{\circ}C$ and then it was conducted to investigate solution absorption, drying rates, dynamic young's modulus. specific gravity and fire-retardant factors such as burning point, flame spread length. flame exhausted time, back side carbonized area and weight loss by treating time, treating solutions and platen temperature. The results are as follows; 1. When plywood was impregnated with the hot bath temperature of $70^{\circ}C$ for 1. 2, 4, 6 hours and the cold bath temperature of $15^{\circ}C$ for 2 hours respectively, retentions of boric acid were 1.565, l.597, 1.643, 1.709kg/$(30cm)^3$ and all of them exceeded the minimum retention [1.125kg/$(30cm)^3$] even in the shortest treatment. 2. In hot-cold bath method for 1/2 hours, the drying rates of treated plywood remarkably increased with the extension of platen temperature of 110, 130, 160, $180^{\circ}C$ and the values of boric acid treated plywood were 5.900, 10.196, 45.42, 54.958m.c%/min and the values of water treated plywood were 6.014, 12.373, 46.520, 55.730m.c%/min and drying rates of water treated plywood were faster than those of boric acid treated plywood. 3. The values of boric acid treated plywoods in dynamic young's modulus were widely higher than those of water treated plywoods. And it can be observed that there were highly significant differences for treating time between dynamic young's modulus, and the values of boric acid plywoods increased with the extension of treating time but on the contrary water treated plywoods were decreased values with prolonged time 4. It was observed that there were highly significant differences for platen temperature between dynamic young's modulus. When the values of water treated plywoods in dyna nic young's modulus were abruptly decreased according to the rise of platen temperature. boric acid treated plywoods showed rather increased values at $160^{\circ}C$ of platen temperature. And in 2- way interactions, there were also highly significant for dynamic young's modulus between treating time x treating solutions and platen temperature x treating solutions. 5. Correlation coefficients of fire-retardant factors were shown in table 5. It could be recognized that there were close correlations between the treating solutions and burning point, flame spread length, back side carbonized area, flame exhausted time and weight loss, but there was no correlation between fire-retardant factors and treating time and platen temperature. 6. From table 6, it can be observed that there were highly significant differences for burning point, flame spread length, flame exhausted time, back side carbonized area, weight loss between treating solutions. And in 2-way interactions, there were highly significant for burning point, flame spread length, weight loss between treating time $\times$ treating solutions.

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MODIS 적외 자료를 이용한 동아시아 지역의 총가강수량 산출 (Estimation of Total Precipitable Water from MODIS Infrared Measurements over East Asia)

  • 박호순;손병주;정의석
    • 대한원격탐사학회지
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    • 제24권4호
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    • pp.309-324
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    • 2008
  • Terra/Aqua MODIS의 적외관측 자료를 이용하여 동아시아 지역에서 물리적 방법과 split-window 방법으로 총가강수량을 산출하는 알고리즘을 개발하였다. 물리적 방법에서는 동아시아 지역에 대한 분석 예측 자료를 생산하는 RDAPS 자료를 알고리즘의 초기 추정치로 사용하였다. 이 과정에서 복사전달계산을 위해 빠르고 정확도가 높은 RTTOV-7 모델을 이용하였다. Split-window를 이용한 총가강수량 산출에서는 동아시아 지역의 라디오존데 관측자료를 훈련자료로 사용하여 밝기온도를 계산하였고, 이로부터 관측된 밝기온도로부터 총가강수량을 산출할 수 있는 회귀식을 도출하였다. 위의 두 알고리즘을 2004년 8월과 12월의 MODIS 적외 자료에 적용하여 산출한 결과를 해양에서는 DMSP SSM/I 결과와 육지에서는 라디오존데 관측 결과와 비교하여 검증하였고, 이를 바탕으로 총가강수량의 정확성에 영향을 미치는 요인과 산출과정에 중요한 물리과정을 분석하였다. 비교결과 RDAPS, MODIS, split-window 방법에 비해 물리적 방법을 이용한 총가강수량의 산출 정확성이 높은 것으로 나타났다. 그러나 물리적 방법은 초기 추정치에 따라 산출결과가 상이하게 나타나는 단점을 가지고 있는 것으로 파악되었다. 따라서 TIGR 자료와 같은 기후 평균값을 초기치로 적용함에 있어 주의가 요구된다. 이러한 원인으로 지표 부근의 수증기에 대한 정보 부족 등을 들 수 있다. 이러한 단점에도 불구하고 지표와 지형의 변화가 큰 한반도를 포함한 동아시아 지역에서는 물리적 방법에 의한 총가강수량 산출의 효율성이 큰 것으로 사료된다.

적조 해수의 광학 및 수질변수 관측자료 분석 (Analysis on Optical and Water Quality Measurements for Red Tide Waters)

  • 고수윤;백승일;임태홍;전기성;정유진;김필립;이민영;손문호;김예진;김원국
    • 대한원격탐사학회지
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    • 제38권6_1호
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    • pp.1541-1555
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    • 2022
  • 적조는 식물성 플랑크톤의 번성현상으로써, 해양생태 및 양식업에 유해한 영향을 끼칠 수 있는 현상이다. 다양한 광학원격센서를 이용한 적조탐지 연구가 수행되어왔지만, 기개발된 적조 탐지 알고리즘들은 수심이 얕고, 부유퇴적물이 많은 연안해역에 적용하기에는 한계가 있다. 적조 해수의 광학적특성에 대한 이해를 높이기 위해서 원격탐사반사도 및 수중구성성분에 대한 분석의 중요성이 높아지고 있다. 본 연구는 선박현장조사를 통하여 적조해수의 광학변수(원격탐사반사도)와 수질변수(Chl-a(Spec), 총부유물농도, aph, ad, 종 동정, Chl-a(HPLC))를 취득하고 광학변수와 수질변수간의 관계를 분석하였다. 메조디니움과 코클로디니움 두가지 적조 종 및 엽록소농도에 따른 원격탐사반사도와 식물성플랑크톤 흡광계수에 대한 분석을 수행하였고, 원격탐사반사도의 특정 파장대를 이용한 적조 엽록소농도의 추정 가능성을 제시하였다. 분석 결과, 적조의 엽록소농도와 식물성플랑크톤 흡광계수는 결정계수 0.9의 상관도를 나타냈으며, REdiff를 이용한 기법이 B-G ratio를 이용한 기법보다 적조농도를 더욱 정확하게 추정하는 것으로 나타났다.

보은지역 흑색셰일 분포지역에서의 암석-토양-식물계내 잠재적 독성원소들의 분산과 이동 (Dispersion and Migration of Potentially Toxic Elements in the Rock-Soil-Plant System from the Boeun Area Underlain by Black Shales, Korea)

  • 이진수;전효택;김경웅
    • 자원환경지질
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    • 제30권6호
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    • pp.587-601
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    • 1997
  • This study had three purposes: (1) to investigate the enrichment levels and dispersion patterns of potentially toxic elements in the rock-soil-plant system; (2) to evaluate the uptake ratios of heavy metals from soils into plants and (3) to assess the chemical speciation of heavy metals in soils. Rock, surface soil and plant samples were collected in the Boeun area underlain by black shales of the Okchon Zone. These samples were analyzed for multi-elements using INAA, ICP-AES and AAS. The maximum abundance of U in black shales is 16 mg/kg and radioactivity counts up to 300 cpm. In particular, Mo, V, Ba, Cd, Pb and U are enriched in black shales. Most of soils derived from black shales show high concentrations of U, As, Mo, Ba, Cu, Cd, Pb, Zn and mean concentrations of As and Mo in soils (20 mg/kg of As and 6.6 mg/kg of Mo) are higher than the permissible level suggested by Kloke (1979). Enrichment index values of soils are calculated and higher than 1.0 in the black shale area with the highest value of 6.4. Mean concentration of Cd in plants is higher than those of Cu, Pb and Zn. The concentration of Cd in plant species decreases in the order of Chinese cabbage > red pepper > soybean=sesame > rice stalk > com > rice grain. The biological absorption coefficients (BAC) in plants are in the order of Cd > Zn=Cu > Pb, which suggests that Cd is more bioavailable to plants than Cu, Pb and Zn. From the results of sequential extraction analysis of soils, relatively high proportion of Cu, Pb and Zn are present as residual fractions whereas that of Cd as non-residual fractions. Cadmuim occurs predominantly as exchangeable/water-acid soluble phase in soils, and Cd is more mobile and bioavailable than Cu, Pb and Zn.

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해수의 광학적 성질과 해양기초생산 -동열대 대서양 Oligotrophic zone을 중심으로- (Optical Properties of Ocean Water and Marine Primary Production -A Study on the Oligotrophic Zone in the Eastern Tropical Atlantic Ocean-)

  • 윤홍주;류청로;김기태;김현주
    • 한국수산과학회지
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    • 제28권2호
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    • pp.174-182
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    • 1995
  • Using the optical data from the EUMELI 3 and 4 missions, the optical properties are discussed in relation to primary production in the oligotrophic zone of the Eastern Atlantic Ocean. The depth of euphotic layer $(Z_{eu})$, the total accumulated concentration of pigment $(C_{TOT})$ and the concentration of pigment (C) are 88m, $12.4mgm^{-2}\;and\;0.14mgm^{-3}$, respectively for the EUMELI 3 mission and 101.7m, $10.0mgm^{-2}\;and\;0.10mgm^{-3}$, respectively for the EUMELI 4 mission. The concentration of pigment is higher in autumn (EUMELI 3) than in spring (EUMELI 4). This indicates that the concentration of photosynthetic pigment has a close correlation with vertical attenuation coefficient $(K(\lambda))$ that changes seasonally in the euphotic layer. While the spectral distributions of downward Irradiance$(E_d)$ for the wave length of 470nm increase with depth, those of upward irradiance $(E_u)$ for the wave length range between 410nm and 490nm are constant, because the study area is covered with the blue and clear oceanic deep waters. The vertical attenuation coefficients of downward irradiance $(K_d)$ and upward irradiance $(K_u)$ have low values between 0.02 and $0.06m^{-1}$ due to the low absorption and scattering by the photosynthetic pigment of phytoplankton. Therefore this zone has the characteristics of the case 1 waters with low concentrations of photosynthetic pigment, and can be classifed into IB.

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세프테졸 부티로락톤 에스텔의 합성 및 생물약제학적 특성 (Synthesis and Biopharmaceutical Properties of Ceftezole Butyrolactone Ester, a Novel Prodrug of Ceftezole)

  • 이진환;박재영;최준식;고재원
    • Journal of Pharmaceutical Investigation
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    • 제31권3호
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    • pp.143-150
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    • 2001
  • Butyrolactone ester of ceftezole (CFZ-BL) was synthesized by esterification of ceftezole (CFZ) with ${\alpha}-bromo-{\gamma}-butyrolactone$. The synthesis was confirmed by spectroscopic analysis. CFZ-BL was more lipophilic than CFZ when the lipophilicity was assessed by partition coefficients between n-octanol and water at various pH. CFZ-BL itself did not show any microbiological activity in vitro, but serums taken after oral administration of CFZ-BL showed substaintial microbiological activity indicating that CFZ-BL is converted to microbiologically active metabolite, probably CFZ, in the body. The conversion was confirmed by in vitro incubation study, in which CFZ-BL was incubated in some body tissues of rabbit. Liver homogenate showed fastest conversion of CFZ-BL among the tissues tested (blood and intestine). Thus, CFZ-BL appeares to be rapidly metabolized in the liver to CFZ following oral administration. The metabolism process appears to be hydrolysis of the ester to CFZ, the parent drug of CFZ-BL. In vivo metabolism of CFZ-BL to CFZ was confirmed by analying CFZ by HPLC. CFZ concentration in the serum samples taken after oral administration of CFZ-BL were higher than those in the serum samples taken after oral administration of equivalent amount of CFZ. Oral bioavailability of CFZ-BL, a prodrug of CFZ, was 1.45-fold higher than that of CFZ in rabbits possibly due to enhanced lipophility and absorption of the prodrug.

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국립공원 지역 시정장애 현상의 물리.화학적 특성 (Physico-Chemical Characteristics of Visibility Impairment in a National Park Area)

  • 김경원
    • 한국대기환경학회지
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    • 제25권4호
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    • pp.325-338
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    • 2009
  • National parks provide recreation, health, and science to human being. The provision of beautiful landscape view of the national park improves an economic and social phase of a nation. However, visibility impairment frequently occurred in the national park area of Gyeongju. The purpose of this study is to investigate the physical and the chemical characteristics of visibility reduction observed at the national park area of Gyeongju. Optical, chemical, meteorological characteristics and scenic monitoring were performed at the visibility monitoring station of Gyeongju University located at the Seoak section of Gyeongju national park from April 28 to May 9, 2008. Light extinction, light scattering, and light absorption coefficients were continuously measured using a transmissometer, a nephelometer, and an aethalometer, respectively. In order to investigate the impact of aerosol chemistry on visibility impairment, size-resolved aerosols were collected at intervals of 2-hour (from 8 A.M. to 6 P.M.) and 14-hour (from 6 P.M. to 8 A.M.) interval each sampling day. The average light extinction coefficient and the average visual range were measured to be $270{\pm}135\;Mm^{-1}$ and $14.5{\pm}6.3\;km$ during the intensive monitoring period, respectively. It was revealed that sulfate particle was the largest contributor to the light extinction under hazy condition. Organic mass accounted for about 26% of the average light extinction. The mass extinction efficiencies for $PM_{1.0}$, $PM_{2.5}$, and $PM_{10}$ were estimated to be 9.0, 4.7, and $2.7\;m^2\;g^{-1}$ under the consideration of water growth function of hygroscopic aerosols, respectively.

적외 광투과 Chalcogenide계 유리의 제조 및 특성 (Preparasion and Characterization of Chalcogenide Glass with IR-Transmittance)

  • 송순모;최세영
    • 한국세라믹학회지
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    • 제32권12호
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    • pp.1424-1432
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    • 1995
  • Chalcogenide glasses having IR (8~12${\mu}{\textrm}{m}$) transmittance were prepared and their densities, thermal and mechanical properties, IR-transmittances and chemical durabilities were determined. Glass transition temperatures (Tg) of Ge-As-Se, Ge-As-Se-Te and Ge-SE-Te system glasses were in the range of 280~3$65^{\circ}C$, 210~236$^{\circ}C$ and 210~26$0^{\circ}C$, respectively. Crystallization temperature (Tc) of Ge-Se-Te system glass was in the range of 305~40$0^{\circ}C$. Their thermal expansion coefficients($\alpha$) were in the range of 11.7~15.2$\times$10-6/K, 15.4~16.0$\times$10-6/K and 17.4~27.8$\times$10-6/K, respectively. Their MOR, hardness and fracture toughness were in the range of 15.2~18.6MPa, 36.1~58.2Kg/$\textrm{mm}^2$, 1.0~1.3 MPa.mm1/2, 18.9~24.9 MPa, 40.9~65.1Kg/$\textrm{mm}^2$, 1.3~1.5 MPa.mm1/2, and 24.1~30.8 MPa, 40.9~86.0Kg/$\textrm{mm}^2$, 1.4~1.8 MPa.mm1/2, respectively. IR transmittance of Ge-Se-Te system glass was about 60%. Ge-O extrinsic absorption peaks at 8, 12 ${\mu}{\textrm}{m}$ were significantly eliminated by the addition of Mg. Chemical durabilities in deionizied water of Ge-Se-Te system glass were good and IR-transmittances decreased with leaching time and temperature.

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