• Title/Summary/Keyword: waste slag

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A Study on the Properties of Converter Slag Modified by Addition of Waste Foundry Sand (폐주물사를 첨가한 전로슬랙의 개질특성에 관한 연구)

  • 김영환;김종학;고인용
    • Resources Recycling
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    • v.8 no.1
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    • pp.44-51
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    • 1999
  • Converter slag was reduced and modified by the simultaneous addition of carbon and waste foundry sand as a $SiO_2$ source. The basic properties such as phase distribution, composition, specific density, hardness. absorption of water and compressive strength of modified slags were measured. The Iron recovery was significantly affected by the basicity of slag. The properties of slow cooled-modified slags of basicity 1.34 arc very similar to the natural aggregates.

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Strength and durability of ultra fine slag based high strength concrete

  • Sharmila, Pichaiya;Dhinakaran, Govindasamy
    • Structural Engineering and Mechanics
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    • v.55 no.3
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    • pp.675-686
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    • 2015
  • The use of ground granulated blast furnace slag (GGBFS) from steel industries waste is showing perspective application in civil engineering as partial substitute to cement. Use of such waste conserves natural resources and minimizes the space required for landfill. The GGBFS used in the present work is of ultra fine size and hence serves as micro filler. In this paper strength and durability characteristics of ultra fine slag based high strength concrete (HSC) (with a characteristic compressive strength of 50 MPa) were studied. Cement was replaced with ultra fine slag in different percentages of 5, 10, and 15% to study the compressive strength, porosity, resistances against sulfate attack, sorptivity and chloride ion penetration. The experiments to study compressive strength were conducted for different ages of concrete such as 7, 28, 56, and 90 days. From the detailed investigations with 16 mix combinations, 10% ultra fine slag give better results in terms of strength and durability characteristics.

Upgrading of Iron from Waste Copper Slag by A Physico-chemical Separation Process (Physico-chemical 분리 공정에 의한 폐동슬래그로부터 철의 품위향상)

  • Lee, Kwang-Seok;Jo, Seul-Ki;Shin, Doyun;Jeong, Soo-Bock;Lee, Jae-Chun;Kim, Byung-Su
    • Resources Recycling
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    • v.23 no.3
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    • pp.30-36
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    • 2014
  • A large amount of waste copper slag containing about 35 ~ 45% iron has been generated and discarded every year from pyrometallurgical processes for producing copper from copper concentrate. Thus, recovery of iron from the waste copper slag is of great interest for comprehensive use of mineral resource and reduction of environment problems. In this study, a physico-chemical separation process for upgrading iron from the waste copper slag discharged as an industrial waste has been developed. The process first crushes the waste copper slag below 1 mm (first crushing step), followed by carbon reduction at $1225^{\circ}C$ for 90 min (carbon reduction step). And then, resulting material is again crushed to $-104{\mu}m$ (second crushing step), followed by wet magnetic separation (wet magnetic separation step). Using the developed process, a magnetic product containing more than 66 wt.% iron was obtained from the magnetic separation under a magnetic field strength of 0.2 T for the waste copper slag treated by the reduction reaction. At the same conditions, the percentage recovery of iron was over 72%. The iron rich magnetic product obtained should be used as a iron resource for making pig iron.

Dynamic and Durability Properties of the Low-carbon Concrete using the High Volume Slag (High Volume Slag를 사용한 저탄소 콘크리트의 역학 및 내구특성)

  • Moon, Ji-Hwan;Lee, Sang-Soo
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.4
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    • pp.351-359
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    • 2013
  • Blast furnace slag (BFS) have many advantages that are related to effective value improvement on applying to concrete while side effects of blast furnace slag also appear. Thus, research team conducted an experiment with high volume slag to see if the attribute of waste alkali accelerator for mixing rate, mixed use of NaOH and $Na_2SiO_3$, and early strength agent for mixing rate for replacement ratio and for the types of the stimulants in order to increase the use of blast furnace slag1s powder. As the result of the experiment, when it comes to compression strength, all of the alkali stimulants have been improved as the replacement rate increases except for sodium hydroxide. Among the alkali stimulants, sodium silicate was high on dynamic elastic modulus and absorption factor. In case of early strength agent, the mix of mixing 1.5% and blast furnace slag 75% have showed high strength enhancement. In event of Waste Alkali accelerator, it has showed different consequences for each experiment.

Blast Furnace Slag as Media for an Anaerobic Fixed-Film Process (고로(高爐) 슬래그를 이용한 혐기성(嫌氣性) 생물막(生物膜) 공법(工法)에 관한 연구(硏究))

  • Choi, Eui So
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.9 no.2
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    • pp.135-141
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    • 1989
  • Blast furnace slag presents coarse surface for microbes to grow on and high calcium and magnesium contents to neutralize acid to be produced during anaerobic digestion. Also, slag contains aluminum and iron oxides which would promote biological flocculation, and minerals which would stimulate microbial growth. Acid wastes like dairy waste, carbohydrate waste, sanitary landfill leachate and molases wastes were applied without neutralization to laboratory reactors to examine the applicability of blast furnace slag as media. The study results indicated slag media was effective to neutralize pH and maintain microbial population in the system. Particularly, COD removal efficiency was greater than those from plastic media operations treating dairy waste at higher loading rates.

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Manufacturing Characteristics of Environmental-friendly Waste Ash Brick with Industrial By-Products (산업부산물을 이용한 친환경 연소재벽돌의 제조특성)

  • Kim, Han-Seok;Jung, Byung-Gil;Kim, Dae-Yong;Kang, Dong-Hyo;Jang, Seong-Ho
    • Journal of Environmental Health Sciences
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    • v.35 no.3
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    • pp.226-234
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    • 2009
  • The main objective of this study was to evaluate the effects on shape and size, compressive strength, water absorption and heavy metals leaching with various weight mixing ratios in waste ash brick products using waste recycling MSWI(Municipal Solid Waste Incinerator) bottom ash, steel slag and waste building material. The manufacturing processes for the waste ash brick consist of screening, mixing, conveyor transmission, compaction.forming, and curing steps of raw materials. The weight mixing ratios of steel slag around bottom ash were adjusted within the ranges of 10% to 30%. The reported results show that the width and thickness of the manufactured waste ash brick could be satisfied with $90{\pm}2mm\;and\;57{\pm}2mm$, respectively which are K.S. standards of products qualities. And in case of length, only 20-Ba50Ss30, 20-Ba60Wb20 and 20-Ba50Wb30 for the mixing ratios could be satisfied with $190{\pm}2mm$ that is K.S. standards of products quality. The compressive strength and water absorption for 20-Ba50Ss30 and 20-Ba70Wb10 were over $8N/mm^2$ and below 15% respectively that are K.S. standards of manufactured waste ash brick. The results of tests for the heavy metals leaching in the all manufactured waste ash bricks are also passed to the wastes management regulations. The cost analysis of 20-Ba50Ss30 is evaluated. The manufacturing cost is evaluated 34.3 won/brick with 8 hours and 20tons of raw material per day. Incinerators with problems in bottom ash disposal can therefore derive significant benefits from the application of waste ash brick production.

A Study on the Replacement of a Light Burnt Dolomite with a Waste MgO-C Refractory Material for a Steel-Making Flux in Electric Arc Furnace (폐 MgO-C계 내화재의 전기로(EAF) 제강 Flux용 경소돌로마이트 대체 사용 연구)

  • Hyun-Jong Kim;Jong-Deok Lim;Hang-Goo Kim;Jei-Pil Wang
    • Resources Recycling
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    • v.31 no.6
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    • pp.44-51
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    • 2022
  • In the steelmaking process using an electric arc furnace (EAF), light-burnt dolomite, which is a flux containing MgO, is used to protect refractory materials and improve desulfurization ability. Furthermore, a recarburizing agent is added to reduce energy consumption via slag foaming and to induce the deoxidation effect. Herein, a waste MgO-C based refractory material was used to achieve the aforementioned effects economically. The waste MgO-C refractory materials contain a significant amount of MgO and graphite components; however, most of these materials are currently discarded instead of being recycled. The mass recycling of waste MgO-C refractory materials would be achievable if their applicability as a flux for steelmaking is proven. Therefore, experiments were performed using a target composition range similar to the commercial EAF slag composition. A pre-melted base slag was prepared by mixing SiO2, Al2O3, and FeO in an alumina crucible and heating at 1450℃ for 1 h or more. Subsequently, a mixed flux #2 (a mixture of light-burnt dolomite, waste MgO-C based refractory material, and limestone) was added to the prepared pre-melted base slag and a melting reaction test was performed. Injecting the pre-melted base slag with the flux facilitates the formation of the target EAF slag. These results were compared with that of mixed flux #1 (a mixture of light-burnt dolomite and limestone), which is a conventional steelmaking flux, and the possibility of replacement was evaluated. To obtain a reliable evaluation, characterization techniques like X-ray diffraction (XRD) analysis and X-ray fluorescence (XRF) spectrometry were used, and slag foam height, slag basicity, and Fe recovery were calculated.

Removal of Phosphorus by Blast Furnace Slag as a Filter Medium in a Self-Purifying Swage Treatment System (제강 슬래그를 여재로 사용한 자연정화 하수처리장의 인(P)제거 효과)

  • Chung, Dong Yang
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.7 no.2
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    • pp.68-74
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    • 2004
  • A blast furnace slag(BFS) has been used as a filter medium for the treatment of domestic waste waters during the period of 9-month. More than 90% of phosphorus was removed while the hardness of the treated water increased by 5 times and the pH was significantly raised from 6.8 to 10.8. The high hardness and pH of the treated water indicated dissolution of BSF by the sewage. The experimental results suggest that BFS could be utilized for the removal of phosphorus in the waste water treatment plant using aquatic plants and gravels.

The Experience Study on the Floating Properties of Concrete with Recycled Coarse Aggregate used Blast Furnace Slag (고로슬래그 미분말을 사용한 재생굵은골재 콘크리트의 유동특성에 관한 실험적 연구)

  • Kim, Ho-So;Baek, Chul-Woo;Choi, Sung-Woo;Ban, Seong-Soo;Ryu, Deuk-Hyun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.356-359
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    • 2004
  • Recently, owing to the deterioration of reconstruction and the construction, much of the construction waste is discharged in our construction field, and the amount of construction waste are rapidly increased. These waste are raised to financial and environmental problems, so the method of reusing waste concretes has been studied and carried out many direction. Especially being want of resources, if waste concrete could be recycled as aggregate for concrete, it will contribute to solve the exhaustion of natural aggregate, in terms of saving resources and protecting environment. This study is that the floating properties of concrete with recycled coarse aggregate were investigated for the substitution of recycled coarse aggregate. The result of this study, floating properties increases and strength development of concrete is showing a clear strength increase effect compare to blast furnace slag non-mixing according to age passing in case of use blast furnace slag. The Quality of recycled coarse aggregate concrete was improved by water reducing.

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A Study on the Increasement of Strength about Soft ground improvement material using waste residual by fire (소각잔재물을 활용한 연약지반개량재의 강도증진에 관한 연구)

  • Lee, Kwang-Joon;Lee, Jae-Yeol
    • Proceedings of the Korean Geotechical Society Conference
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    • 2004.03b
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    • pp.692-697
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    • 2004
  • This study is on the increasement of strength about soft ground improvement material using waste residual(paper fly ash, coke ash, slag) by fire. Through this study the authors have analyzed the strength improvement of mixed soft silty sand with improvement materials. The strength of mixed soils with high mixture ratio and more curing days increased. But CA-30(cokes 60%) make more low strength improvement than others. Therefore the authors find out that paper fly ash+cokes, paper fly ash+slag or cokes+slag improvement material is more effect in improvement of soft silty sand than cokes+cenlent. And Ettringite reaction is free mixed soils with more than two materials.

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