• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2014년도 춘계 학술논문 발표대회
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• pp.208-209
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• 2014

Recently, many environmental problems occur due to the waste shells in South Korea. In case of oyster and cockle, utilizing waste shells to produce fertilizer once also, but due to sluggish consumption, production is no longer difficult. The stored amount of waste shells in the fertilizer manufacturing company is overfilled, and thus cannot accept any more of the waste shells. As a result, landfill and dumping of waste shells have become an increasingly environmental problems. In this research, the basic physical properties and interfacial bonding form of the mortar mixed with waste shells (manila clam, cockle, clam, sea mussel, oyster) were evaluated.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2013년도 추계 학술논문 발표대회
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• pp.146-147
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• 2013

The oyster shells of about 240,000 tons have been annually produced in south coast of South Korea. However, about 25% of the oyster shells (60,000tons) was recycled as oyster seeding and fertilizer due to the limited amount of consumption for such purposes. The stored amount of oyster shell in the fertilizer manufacturing company is overfilled, and thus cannot accept any more of the waste oyster shells. As a result, landfill and illegal dumping of waste oyster shells have become an increasingly serious issue since 2011. In this research, the problems generated by the oyster shells were investigated through surveying activities. One of the possible alternative solutions that can process large amount of waste economically was found to be the application of oyster shells as a construction materials.

• 한국건축시공학회지
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• 제14권6호
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• pp.523-529
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• 2014

국내에서는 많은 양의 패류가 생산되고 있으나, 이로 인해 발생하는 대량의 패각을 처리하는데 많은 어려움을 겪고 있다. 따라서 본 연구에서는 이러한 패각을 대량으로 처리하기 위하여 건설재료로서의 가능성을 평가하고자 한다. 모르터의 잔골재를 패각으로 치환하여 흡수율, 압축강도를 측정하고 계면결합 형태를 관찰하였다. 대체적으로 패각의 치환율이 증가함에 따라 흡수율은 증가하였으며, 압축강도는 감소하였다. 예외적으로 꼬막 패각을 치환한 모르터는 치환율이 증가함에 따라 압축강도가 증가하였다. 패각 치환율의 증가에 따른 흡수율의 증가 및 압축강도의 감소는 패각 주위에 발생한 다공성 때문인 것으로 파악되었으며, 꼬막 패각을 치환한 모르터는 패각과 시멘트 입자간의 계면결합 형태가 양호하였기 때문에, 오히려 강도가 상승한 것으로 판단된다.

• 환경위생공학
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• 제16권4호
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• pp.38-46
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• 2001

The purposes of this study were to examine applicability of waste egg shells as conditioning agent, to determine the optimum conditions for improving digested sludge dewaterability and to compare with before and after adding them. It estimated that the optimum conditions were dosage 30 g/L, particle size 10mesh, temp. $30^{\circ}C$, pH 7 and dewatering pressure $2.66{\pm}10^4{\;}N/m^2$. On the basis of induced optimum conditions, if adding waste egg shells in digested sludge, its specific resistance was $1.13{\pm}10^{12}{\;}m/kg$ and was low about 3 times than raw digested sludge $3.5{\pm}10^{12}{\;}m/kg $. Therefore, in view of waste recycling, it seemed that we could utilize waste egg shells as conditioning assent for improving dewaterability of digested sludge.

• 한국환경보건학회지
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• 제23권4호
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• pp.133-138
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• 1997

The technology of removing phosphorous, considered as one of the most important control nutrients causing eutrophication in various water bodies, have been investigated by many researchers. Recently, phosphorous crystallization process is emerging as a new technology for phosphorous removal. In this study, waste oyster shells which can be easily obtained from the ocean, were used as a seed crystal, and their effects of several physical/chemical factors on the phosphorous removal efficiencies were examined by batch tests. Ca$^{2+}$ and pH affected phosphorous crystallization process using waste oyster shells. As alkalinity of wastewater increased, phosphorous removal efficiencies gradually decreased. Phosphorous removal efficiencies were increased, as specific area and contact efficiency per unit area of waste oyster shells were increased. In case of high temperature, phosphorous crystallization process was rapidly advanced and phosphorous removal efficiencies were increased. Dependig on X-ray diffraction analysis, it was showed that generation materials extracted from the surface of waste oyster shells with short reaction time were dominated by $CaHPO_4\cdot 2H_2O$, but progressed to $Ca_5(OH)(PO_4)_3$. The SEM observation reveals that the evident variations were hardly seen, but particle sizes of waste oyster shells were relatively bigger and showed forms of smaller plate than before.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2013년도 추계 학술논문 발표대회
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• pp.148-149
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• 2013

Recently, the construction industry in South Korea, has experienced many difficulties in lack of supply with construction materials. Since waste shells can be possibly used as replacement materials of fine aggregate, the successful application can resolve, to some extent at least, the economic problems and environmental problems. In this research, the basic physical properties of the mortar which was used as fine aggregate substitute (clam, cockle, manila clam, oyster) were evaluated. According to the experimental results, the absorption rate and compressive strength of samples with various shells were equivalent to that of plain mortar. The mortar which replaced 25% of oyster shell with sand showed approximately 30% lower compressive strength and twice as much absorption as plain mortar. It was found that waste shells can be used as replacement materials of fine aggregate, but the oyster shell requires further experimental works in order for its successful application.

• 유기물자원화
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• 제7권1호
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• pp.13-21
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• 1999

본 연구에서는 폐기물의 재활용 측면에서 폐달걀껍질에 의한 중화능을 파악하는 동시에 중금속 제거 가능성을 고찰하였다. 폐달걀껍질 자체내에 Ca와 같은 알칼리성 성분으로 인하여 pH 상승효과가 탁월하며, 또한 폐수중의 중금속은 pH 상승으로 인하여 수산화물로 침전 제거되는 것으로 여겨진다. 폐달걀껍질은 응집 침전 및 흡착제로써 역할을 하기 때문에 주입량과 흡착질 농도에 영향을 받는 것으로 여겨진다. 흡착강도 1/n 값은0.35~0.44의 범위이며 Cu>Pb>Cr의 순으로 높게 나타났으나 흡착용량 k 값은 2.61~3.26의 범위이며 Pb>Cr>Cu의 순으로 높게 나타내었다.

• 한국응용과학기술학회지
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• 제27권4호
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• pp.427-436
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• 2010

Much oyster shell is breeding by character and conduct of oyster-industry for a long time among them. An experimental study was carried out to investigate the recycling possibility of waste oyster shells, which induce environmental pollutions by piling up out at the open or the temporary reclamation. The purpose of this study is to develope eco-friendly binder using waste oyster shells, and to reinforce soils fur soft soil improvement. In this paper, a series of laboratory tests including compressive pot tests were performed to evaluate characteristics of soils treated by developed waste oyster shells with different water content of soils. Based on test results, eco-friendly Supporter manufactured from waste oyster shells were estimated as good resource materials for soft soil improvements. We got the conclusion by a series of experiment, It is verified that change of pH of soil is improved by mixing with oyster shells. The homogenization method for deducing apparent of oyster shells, which can consider micro-structure of mixed soil, is introduced. The improvement treatment leaded to enlarge fluctuation of soil moisture content. The effect of calcium concentration was good though improvement treatment of physical property. In addition, the crop yield in amelioration plots increased. It means that the increase of crop yield was caused by improvement of soil physical properties rather than improvement of calcium concentration.

• 한국환경보건학회지
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• 제27권2호
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• pp.17-21
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• 2001

The object of this study is to find out the characteristics of waste oyster shells and determine the proper dosage of powdered waster oyster shells as the conditioning agent for water treatment sludge dewatering process. The large amount of waste oyster shells which discharges from the oyster farming, occurs serious environmental hazards. However, oysters shell contain large amount(about 38% by weight) of alkaline minerals, such as calcium and magnesium and so on, this natural material is thought to have the petential ability as a good conditioning agent. The results of this study are as follows. The optimum condition for improvement of the water treatment sludge dewaterability is when 6 g of waste oyster shell powder added to 200$m\ell$ of water treatment sludge. At optimum condition, the solid contents can reach to 31.78% and the specific resistance of conditioned sludge is 0.16$\times$10$^{8}$ sec$^2$/g. However, exceeding the of powdered waste oyster shell is needed to get the effective result. Consequently, the waste oyster shell can be a recyclable material to improve the dewaterability of water treatment sludges.

• 한국결정성장학회지
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• 제10권2호
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• pp.159-165
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• 2000

본 연구에서는 남해안 일대의 굴 고막, 바지락 패각에 대한 부존환경을 조사하였으며 그리고 부존환경 개선, 환경오염 방지 등을 위한 패각의 재활용 방안을 확립하였다. 패각의 부존환경은 공유수면의 불법매립 또는 연안지역에 야적 .방치된 상태였다. 부존패각의 효율적인 재활용을 위하여 성인 메카니즘 그리고 XRD, TG-DTA분석을 행한 결과, 탄산칼슘으로의 제조가 최적임을 알았다. 본 연구에서는 부존 패각을 탄산칼슘과 과립형의 패화석비료로 재활용하였다.