• Title/Summary/Keyword: waste material

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Study on Oxidation or Reduction Behavior of Cs-Te-O System with Gas Conditions of Voloxidation Process (휘발산화 공정 조건에 따른 Cs-Te-O 시스템의 산화 환원 거동 연구)

  • Park, Byung Heung
    • Korean Chemical Engineering Research
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    • v.51 no.6
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    • pp.700-708
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    • 2013
  • Pyroprocessing has been developed for the purpose of resolving the current spent nuclear fuel management issue and enhancing the recycle of valuable resources. Pyroprocessing has been developed with the dry technologies which are performed under high temperature conditions excluding any aqueous processes. Pyro-processes which are based on the electrochemical principles require pretreatment processes and a voloxidation process is considered as a pretreatment step for an electrolytic reduction process. Various kinds of gas conditions are applicable to the voloxidation process and the understanding of Cs behavior during the process is of importance for the analyses of waste characteristics and heat load on the overall pyroprocessing. In this study, the changes of chemical compounds with the gas conditions were calculated by analyzing gas-solid reaction behavior based on the chemical equilibria on a Cs-Te-O system. $Cs_2TeO_3$ and $Cs_2TeO_4$ were selected after a Tpp diagram analysis and it was confirmed that they are relatively stable under oxidizing atmospheres while it was shown that Cs and Te would be removed by volatilization under reducing atmosphere at a high temperature. This work provided basic data for predicting Cs behavior during the voloxidation process at which compounds are chemically distributed as the first stage in the pyroprocessing and it is expected that the results would be used for setting up material balances and related purposes.

Developing Wastepaper Demand-Supply Model and Policy Measures to Increase Wastepaper Recycling Rate (폐지시장(廢紙市場)의 수요(需要)·공급(供給) 모델의 개발(開發)과 회수율(回收率) 제고방안(提高方案))

  • Choi, Kwan;Han, Sang-Yoel
    • Journal of Korean Society of Forest Science
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    • v.83 no.2
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    • pp.133-147
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    • 1994
  • Wastepaper recycling has significant implications not only in providing scarce raw material input for the paper industry but in environmental concerns such as reducing solid waste disposal, energy conservation and preservation of forest resources. The objectives of this study was (1) to develop an econometric model of demand for and supply of wastepaper, (2) to forecast wastepaper consumption and price to the year 2000 applying the econometric models estimated and (3) to estimate the elasticity of variables which are included in the wastepaper supply and demand equations. In this study wastepaper was classified into three groups, old newsprint, old corrugated and mixed For each group such as demand and supply equation were estimated. The demand equations were estimated as a function of paper and paper product consumption and wholesale price index and supply equations as a function of wastepaper price, one year lagged paper and paperproduct consumption and transportation price. Applying the econometric models to forcasting results in the future consumption and supply of wastepaper projected as 11.645 million MT and 7.396 million MT in 2000, respectively. The rate of wastepaper self-supply is forcasted about 63.5% in 2000. Especially, the rate of old neswprint self-supply is predicted about 16% which means about 2.2 million MT of old newsprint should be imported from foreign countries. Lastly, some policy measures to promote wastepaper recycling rate based upon economic and physical characteristics of wastepaper and market structure are suggested.

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Study on Recycling of Incombustion Materials from MSWI Fluidized Bed Incinerator Ash (생활쓰레기 유동상(流動床) 소각로(燒却爐) 불연물(不燃物)의 재활용에 관한 연구(硏究))

  • Choi, Woo-Zin;Park, Eun-Kyu;Kang, Seung-Kyun
    • Resources Recycling
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    • v.17 no.4
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    • pp.3-9
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    • 2008
  • The total amount of fluidized bed incinerator ash, i.e. incombustion materials generated from the municipal solid waste incineration(MSWI) in Korea was approximately 14,000 tons in 2006. Most of the ash after ferrous metal separation is finally discard to the landfill sites. In the present work, possibility for recycling of the ash is studied to utilize the ash as raw materials for ceramic products. Incombustion materials obtained from the two different incinerators were used to recover the raw materials by applying the magnetic separation and screening process to remove metallic particles. The raw materials show relatively low heavy metals content obtained from the KSLP leaching tests. The ceramic products were prepared by mixing the clay with the various amounts of the raw material. The physical properties, i.e. shrinkage rate, absorbancy and compressive strength of the ceramic products sintered at $1,000^{\circ}C$ and $1,050^{\circ}C$, respectively were improved by increasing the addition amounts of the incinerator ash. Based on the leaching tests the ceramic products also be satisfied with the standard limits on the leachability of heavy metals because most of the metallic materials are effectively removed from the incombustion materials by appling the separation processes.

Food Materials for School Foodservices on High-quality Products, Local Products and Fresh-cut Products - Dietitian's Choice in Elementary, Middle and High Schools in Gyeong-gi Province - (학교급식 식재료로서 지역 농산물, 고품질농산물과 신선편이 채소의 이용현황과 필요에 관한 연구 - 경기지역 초.중.고등학교를 중심으로 -)

  • Kang, Heui-Yun;Jung, Eun-Hee;Rhie, Seung-Gyo
    • The Korean Journal of Community Living Science
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    • v.20 no.3
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    • pp.397-411
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    • 2009
  • The use of local product foods and fresh-cut products, the dietitian's recognition, the required items and the quality for school foodservice was investigated to increase the consumption of high-quality agricultural products. Data from 578 elementary schools, 228 middle schools and 116 high schools were collected by school foodservice personnels in each regional Education Administration in Gyeong-gi province. The first criteria of buying food materials was reliability/safety for all school foodservice. The second criteria were the origin of the product and freshness/ripeness for elementary and middle schools and high school, respectively. The most important consideration for selecting a supplier was the quality of the material. The appearance/status of the food was the first factor for buying food materials. The origin and the seasonality were very important for buying farm products. Dietitians in Gyeong-gi province recognized the local products, and used them weekly. The advantages of using local products were the quick supply, freshness and safety. On the other hand, the disadvantages were the lack of information and the uncertainty of supply. Sixty eight percent of the subjects had experienced the high-quality agricultural products in school meals, but the frequency was low. The main reasons for not servicing high-quality agricultural products were the high cost and the lack of trust on the quality. Among fresh-cut products, seasonings and root vegetables were purchased most frequently, but leaf vegetables was 5.7% only. The purchase of fresh-cut products was not frequent, but usually satisfied. The advantages of fresh-cut products were the reduced workload and waste, but the reason for not using them were poor hygiene and the high price. The diverse supply system and the promotion of the local product foods would be necessary since the most food materials were purchased through suppliers. In addition, the problems related to the high cost and distrust should be resolved to expand the consumption of the high-quality agricultural products and the fresh-cut vegetables. The institutions for certifying the quality should be needed to increase the confidence of these products.

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Immobilization of Nitrifier Consortium for the Removal of Ammonium Ion in the Recirculating Aquaculture System (양어장수내의 암모니아성 질소제거를 위한 질화세균군의 고정화)

  • KIM Sung-Koo;SEO Jae-Koan;LEE Jong-Seok;KONG In-Soo;SUH Keun-Hack
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.30 no.5
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    • pp.816-822
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    • 1997
  • The immobilization of a microorganism has been rapidly progressed with the development of biotechnology in recent years. Although it has been used as a tool to isolate products from biological media in various areas, it has not yet been practiced in the treatment of waste water. In this paper, we suggest a possibility to apply the immobilization technique In the recirculating aquaculture system. We examined the ability of $NH_4^+$ removal by nitrifier consortium immobilized in $Ba^{++}-alginate$, k-carrageenan and agar bead at the concentration of 50 g/L, respectively. In order to use the immobilized nitrifier consortium as media in the fludized bed reactor, the strength of bead was measured. $Ba^{++}-alginate$ as a support material showed higher strength of bead. Also, the nitrifier consortium immobilized in $Ba^{++}-alginate$ showed higher nitrification activity that could remove 20 mg/L ammonium ion than those immobilized in other two support materials, carrageenan and agar. The immobilized nitrifier consortium showed better nitrification activity than free nitrifier consortium.

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Identifying Potential Industrial Symbiosis through GIS Based Resource Circulation Information (GIS 기반 자원순환정보 구축을 통한 잠재적 산업공생관계 파악 연구)

  • Chung, Hyun-Wook;Park, Sun-Hyung;Kim, Jung-Hoon;Lee, Sang-Yoon;Park, Hung-Suck;Kwon, Chang-Ki
    • Journal of the Korean Association of Geographic Information Studies
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    • v.13 no.3
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    • pp.74-90
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    • 2010
  • The objectives of this paper are to introduce the GIS based resource circulation information, and to identify additional(or potential) industrial symbiosis based on existing industrial symbiosis and linkage-pair of industry by material. The resource circulation information contains information of the reuse of materials, water, and energy for all manufacturing companies in Ulsan Metropolitan City. The information can further be classified into the three steps -- input information(raw materials), flow information (products), and output information (by-products). The survey data from 3,768 industries and institutions in Ulsan Metropolitan area were collected and built into the GIS to analyze the mechanism of the industrial symbiosis. The results of this study strongly suggest that there are some additional industrial symbioses using by-products(materials, steam, waste water) and further efforts should be given to make them more effective. We expect that the methodology of building the resource circulation information of this study can be helpful to other local governments that try to build similar system.

Determination of Tributyl Phosphate Degradation Products by Ion Chromatography (이온크로마토그래피에 의한 Tributyl Phosphate(TBP) 분해산물의 정량)

  • Han, Sun Ho;Lee, Hyo Jin;Yang, Han Beom;Park, Yang Soon;Joe, Kih Soo
    • Analytical Science and Technology
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    • v.15 no.4
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    • pp.329-334
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    • 2002
  • Tributyl phosphate(TBP) is used in solvent extraction process for radioactive waste. This compound may be degraded to dibutyl phosphate($DBP^-$), monobutyl phosphate($MBP^{2-}$) and ${PO_4}^{3-}$ by radioactive material. Amount of $DBP^-$ and $MBP^{2-}$ in TBP must be monitored because they production of these compounds means degradation of which leads to a decrease in the extraction yield. Retention behavior for $DBP^-$, $MBP^{2-}$, $F^-$, $Cl^-$, ${NO_2}^-$, ${NO_3}^-$, ${SO_4}^{2-}$ and ${PO_4}^{3-}$ are studied with AS4A-SC(Dionex) analytical column and $Na_2CO_3$/NaOH eluent by Ion chromatography. Optimum condition for these anions is 2 mM $Na_2CO_3$/1 mM NaOH eluent. All anions by this condition is well separated within 15min. Dynamic range is $10{\mu}g/mL$ - $100{\mu}g/mL$ for DBP and $5{\mu}g/mL$ - $50{\mu}g/mL$ for $MBP^{2-}$, respectively. The Detection limit for AS4A-SC are $1{\mu}g/mL$ for $DBP^-$ and $0.5{\mu}g/mL$ for $MBP^{2-}$ in this system with a $25{\mu}L$ sample loop.

Charcoal Properties and Temperature Change of a Kiln's Inner and Outer Walls in Carbonization Process Using an Improved Kiln (개량형탄화로를 이용한 제탄과정 중 탄화로 내·외벽 온도변화 및 목탄 특성)

  • Kwon, Gu-Joong;Kwon, Sung-Min;Jang, Jae-Hyuk;Hwang, Won-Joung;Kim, Nam-Hun
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.3
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    • pp.230-237
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    • 2011
  • The study was performed to investigate the characteristics of charcoal and temperature change of a kiln's inner and outer walls in carbonization process using improved kiln. In this kiln system, carbonization process was completed in eight days. In the kiln, the ignition temperature was kept about $720^{\circ}C$. And then the temperature were increased gradually prior to be refined. Finally, the temperature in refining process was reached to maximum point, $1,000^{\circ}C$. In the chimney, the temperature was increased gradually from $90^{\circ}C$ at ignition to $750^{\circ}C$ at refining. The temperature change of the kiln wall resembles a temperature change progress curve during a carbonization process. The highest temperature of the kiln wall that appeared by a carbonization process was around $500^{\circ}C$. As a result of having measured an inner wall and the outer wall of the kiln using an infrared thermography camera, it was judged with there being considerable latent heat on kiln wall and ceiling. Fixed carbon contented of charcoal was 85.9~89.9%. Refining degree of charcoal, hardness, calorific value and pH were l, 12, 7,047~7,456 kcal/kg, 9.0~9.9, respectively. The yield of wood charcoal was 13.8%, and compared to conventional kiln's yield increased 1.5%.

The Study of RIA Development Direction using Suggestion System (제안제도를 활용한 RIA 발전 방향에 관한 연구)

  • Shin, Young-Kyun;Chun, Jun-Hong;Kim, Yeon-Ok;Lee, Seon-Ho;Kim, Seong-Ho;Yoo, Seon-Hee
    • The Korean Journal of Nuclear Medicine Technology
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    • v.15 no.1
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    • pp.106-112
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    • 2011
  • Purpose: Until now, the process was improved by the needs of experimenters personally. But recently, suggestion system in hospital has been activated in various ways. So the department of nuclear medicine laboratory is also aware of the need of operation improvement using suggestion system. It is intend to assist in the development by sharing excellent suggestion cases with other hospitals. Material & Method: A total of 124 suggestion cases from January 2007 to March 2010 were analyzed. Suggestion cases were divided into customer satisfaction, cost reduction, improved testing methods, equipment, environmental improvement, and computational system. Result: Suggestion cases of environmental improvement and computational system were accounted for 26.6% as 33 cases, respectively. Suggestion for customer satisfaction is 25.8% as 32 in a total of 124 cases. Conclusion: Activation of the awareness of operation improvement is induced by suggestion system. By securing system of operation improvement, employees' ideas can lead to the production and systematization. Furthermore, it enhances hospital competitiveness and promotes the development of the hospital.

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Production of Lactulose by Biological Methods and Its Application (생물학적 방법을 통한 기능성 이당 lactulose의 생산과 응용 연구)

  • Kim, Yeong-Su;Kim, Do-Yeon;Park, Chang-Su
    • Journal of Life Science
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    • v.26 no.12
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    • pp.1477-1486
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    • 2016
  • Lactulose (4-O-${\beta}$-D-galactopyranosyl-D-fructose) is a non-digestible synthetic ketose disaccharide which can used in food and pharmaceutical fields due to its useful functions for encephalopathy, chronic constipation, hyperammonemia, etc. Therefore, the lactulose is regarded as one of the most important disaccharides and have been concentrated much interesting as an attractive functional material in the current industry. From this reason, the research related on the production of lactulose has been carried out various academic and industrial research groups. To produce lactulose, two main methods, chemical production and enzymatic production have been used. Commercially lactulose produced by alkaline isomerization of lactose as chemical production method but it has many disadvantages such as rapid lactulose degradation, purification, and waste management. From these reasons, lactulose produced by enzymatic method which solves these problems has been suggested as a proper method for lactulose production. Two different enzymatic methods have been reported as methods for lactulose production. Lactulose can be obtained through hydrolysis and transfer reaction catalyzed by a ${\beta}$-galactosidase which requires fructose as co-substrate and exhibits a low conversion. Alternatively, lactulose can be produced by direct isomerization of lactose to lactulose catalyzed by cellobiose 2-epimerase which requires lactose as a single substrate and achieves a high lactulose yield. This review summarizes the current state of lactulose production by chemical and biological methods.