• Title/Summary/Keyword: waste generation

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Influence of operation of thermal and fast reactors of the Beloyarsk NPP on the radioecological situation in the cooling pond: Part II, Macrophytes and fish

  • Aleksei Panov ;Alexander Trapeznikov;Vera Trapeznikova ;Alexander Korzhavin
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.707-716
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    • 2023
  • The influence of waste technological waters of thermal and fast reactors of Beloyarsk NPP (Russia) on the accumulation of 60Co, 90Sr and 137Cs in macrophytes and ichthyofauna of the cooling pond has been studied. Critical radionuclides, routes of their entry into the ecosystem and periods of maximum discharge of radioisotopes into the cooling pond have been determined. It is shown that the technology of electricity generation at the Beloyarsk NPP, based on fast reactors, has a much smaller effect on the release of artificial radionuclides into the environment. Therefore, during the entire period of monitoring studies (1976-2019), the decrease in the specific activity of radionuclides of NPP origin in macrophytes was 13-25800 times, in ichthyofauna 1.5-44.5 times. The maximum discharge of artificial radionuclides into the Beloyarsk reservoir was noted during the period of restoration and decontamination work aimed at eliminating the emergencies at the AMB reactors of NPP. The factors influencing the accumulation of artificial radionuclides in the components of the freshwater ecosystem of the Beloyarsk cooling pond have been determined, including: the physicochemical nature of radioisotopes, their concentration in surface water, the temperature of the aquatic environment, the trophicity of the reservoir, the species of hydrobionts.

Basic Study on the IoT Micro Boiler (IoT 마이크로 보일러에 대한 기초 연구)

  • Jang, Sung-Cheol
    • Journal of Internet of Things and Convergence
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    • v.8 no.1
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    • pp.23-29
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    • 2022
  • The product to be developed in this study is a heat recovery device which generates steam or hot water at high temperature and high pressure by heating water using exhaust gas from diesel engine, gas engine, gas turbine, etc. as an exhaust gas boiler off heat boiler(EGB) type for ship and power generation. The steam vapor or the created warm water is used as the power source required for the steerage heating and hot water facility or the HFO heating of the ship, and the turbine drive. The principle of waste heat boilers serves to heat water as high temperature exhaust gas with heat pass through the tube of the boiler. The heated water is a structure that is sent to a cabin or turbine device in the form of steam. In this study, the objective of this study is to maximize the efficiency by increasing the heat transfer surface by replacing the tube which is the heat transfer part of EGB with the plate tube.

High-temperature electrochemical corrosion behavior of SA106 Grade B carbon steel with corrosion inhibitors in HyBRID solution

  • Sung-Wook Kim;Sang-Yoon Park;Chang-Hyun Roh;Sun-Byeong Kim
    • Nuclear Engineering and Technology
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    • v.55 no.6
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    • pp.2256-2262
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    • 2023
  • The electrochemical corrosion behaviors of SA106 Grade B (SA106B) carbon steel in H2SO44-N2H4 and H2SO4-N2H4-CuSO4 solutions at 95 ℃ have been investigated with the addition of commercial corrosion inhibitors (CI#30 and No. 570S), to determine the stability of SA106B in the hydrazine-based reductive metal ion decontamination (HyBRID) process. The potentiodynamic polarization experiment revealed that the corrosion inhibitors were capable of lowering the corrosion rate of SA106B in H2SO4-N2H4 solution. It was found that the corrosion inhibitors induced formation of fixed surface layer on the carbon steel upon the corrosion. This corrosion inhibition performance was reduced in the presence of CuSO4 in the solution owing to the chemical reactions between organic compounds in the corrosion inhibitors and CuSO4. CI#30 showed a better corrosion inhibition effect in the H2SO4-N2H4-CuSO4 solution. Although the corrosion inhibitors can provide better stability to SA106B in the HyBRID solution, their application should be carefully considered because it may result in reduced decontamination performance and increased secondary waste generation.

Comparative research on expansive soil stabilization using ecofriendly materials versus nano-materials

  • Ali Hasan Hammadi Algabri;Seyed Alireza Zareei;Mohamed Jassam Mohamed Al Taee;Niloofar Salemi
    • Advances in nano research
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    • v.17 no.2
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    • pp.125-136
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    • 2024
  • In the present research the durability and geotechnical properties of an expensive clayey soil stabilized by two different compositions of additives were investigated and compared. The first composition consisted of environmentally and ecofriendly materials: BOF steel slag ranging from 0-20% as well as rice husk ash (RHA) ranged 0-16%wt of dry soil. The other composition consisted of relatively new generation of materials including nanomaterials: nano-CaCO3 as well as nano-SiO2. Atterberg limits test, free swell percent test, swelling pressure test and unconfined compressive test were used to assess the stabilizers influences upon expansive soil geotechnical characteristics. Also, the recurrent wet-dry cycles test was exerted on experimental and non-experimental samples for estimating stabilizers effects on durability. According to the results, each of the BOF slag and RHA enhances the expansive soil properties individually, while combination of slag-RHA led to better improvement of the soil properties. Also, the composition of nano-CaCO3 and SiO2 dramatically improved the clay soil operation. The optimum values of slag+RHA were suggested as 20% slag+12% RHA to enhance percent of swelling, pressure of swelling in addition to UCS as much as 95%, 96%, and 370%, respectively. The optimum value for the second stabilizer in this study was found to be 2%nano-SiO2+2% nano-CaCO3 which led to 318% increase in UCS and 86% decrease in swelling pressure.

Evaluation of Landfilling Method of Organic Sludge from Mix of Pre-treated Organic Sludge and Municipal Solid Waste (전처리된 유기성오니와 생활폐기물 혼합에 따른 유기성오니 매립방법 평가)

  • Ko, Jae-Young;Phae, Chae-Gun;Do, In-Hwan;Park, Joon-Seok
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.3
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    • pp.278-285
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    • 2008
  • This research was performed to evaluate the landfilling method of organic sludge from mix of pre-treated organic sludge (OS) and municipal solid waste(MSW). Organic sludges were dried, composted, and solidified as pre-treatment and the OS and MSW were mixed in ratios of 2 to 8 and 4 to 6. Approximately 1,800$\sim$2,500 L of landfill gas(LFG) was generated in the lysimeter with solidified-OS, which was higher than 1,150$\sim$1,650 L of the dried- and composted- ones. Maximum H$_2$S concentration was found in the following order : Composted-20(80 ppmv) > Composted-40(55 ppmv) > Dried-20(30 ppmv) > Dried-40 $\fallingdotseq$ Solidified-20 $\fallingdotseq$ Solidified-40 (20 ppmv). BOD$_5$ at initial leachate generation period was 38,000 mg/L for Composted-40, 28,000 mg/L for Dried-40, 26,000 mg/L for Dried-20, 21,000 mg/L for Composted-20 and Solidified-40, and Solidified-20 for 17,000 mg/L. In the final period of experiment, BOD$_5$ was low as 300$\sim$500 mg/L in the lysimeter with solidified-OS and MSW and showed 2,000$\sim$3,500 mg/L in dried- and composted- ones. As the results, landfilling by mix of solidified-OS and MSW was evaluated as the most appropriate method for biodegradable organics. Direct landfilling of OS is permitted for landfill site with CDM facility. Therefore, mixed landfilling of solidified-OS and MSW should be considered for much more LFG generation as methane.

Nanoscale Pattern Formation of Li2CO3 for Lithium-Ion Battery Anode Material by Pattern Transfer Printing (패턴전사 프린팅을 활용한 리튬이온 배터리 양극 기초소재 Li2CO3의 나노스케일 패턴화 방법)

  • Kang, Young Lim;Park, Tae Wan;Park, Eun-Soo;Lee, Junghoon;Wang, Jei-Pil;Park, Woon Ik
    • Journal of the Microelectronics and Packaging Society
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    • v.27 no.4
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    • pp.83-89
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    • 2020
  • For the past few decades, as part of efforts to protect the environment where fossil fuels, which have been a key energy resource for mankind, are becoming increasingly depleted and pollution due to industrial development, ecofriendly secondary batteries, hydrogen generating energy devices, energy storage systems, and many other new energy technologies are being developed. Among them, the lithium-ion battery (LIB) is considered to be a next-generation energy device suitable for application as a large-capacity battery and capable of industrial application due to its high energy density and long lifespan. However, considering the growing battery market such as eco-friendly electric vehicles and drones, it is expected that a large amount of battery waste will spill out from some point due to the end of life. In order to prepare for this situation, development of a process for recovering lithium and various valuable metals from waste batteries is required, and at the same time, a plan to recycle them is socially required. In this study, we introduce a nanoscale pattern transfer printing (NTP) process of Li2CO3, a representative anode material for lithium ion batteries, one of the strategic materials for recycling waste batteries. First, Li2CO3 powder was formed by pressing in a vacuum, and a 3-inch sputter target for very pure Li2CO3 thin film deposition was successfully produced through high-temperature sintering. The target was mounted on a sputtering device, and a well-ordered Li2CO3 line pattern with a width of 250 nm was successfully obtained on the Si substrate using the NTP process. In addition, based on the nTP method, the periodic Li2CO3 line patterns were formed on the surfaces of metal, glass, flexible polymer substrates, and even curved goggles. These results are expected to be applied to the thin films of various functional materials used in battery devices in the future, and is also expected to be particularly helpful in improving the performance of lithium-ion battery devices on various substrates.

Numerical Study on Thermochemical Conversion of Non-Condensable Pyrolysis Gas of PP and PE Using 0D Reaction Model (0D 반응 모델을 활용한 PP와 PE의 비응축성 열분해 기체의 열화학적 전환에 대한 수치해석 연구)

  • Eunji Lee;Won Yang;Uendo Lee;Youngjae Lee
    • Clean Technology
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    • v.30 no.1
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    • pp.37-46
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    • 2024
  • Environmental problems caused by plastic waste have been continuously growing around the world, and plastic waste is increasing even faster after COVID-19. In particular, PP and PE account for more than half of all plastic production, and the amount of waste from these two materials is at a serious level. As a result, researchers are searching for an alternative method to plastic recycling, and plastic pyrolysis is one such alternative. In this paper, a numerical study was conducted on the pyrolysis behavior of non-condensable gas to predict the chemical reaction behavior of the pyrolysis gas. Based on gas products estimated from preceding literature, the behavior of non-condensable gas was analyzed according to temperature and residence time. Numerical analysis showed that as the temperature and residence time increased, the production of H2 and heavy hydrocarbons increased through the conversion of the non-condensable gas, and at the same time, the CH4 and C6H6 species decreased by participating in the reaction. In addition, analysis of the production rate showed that the decomposition reaction of C2H4 was the dominant reaction for H2 generation. Also, it was found that more H2 was produced by PE with higher C2H4 contents. As a future work, an experiment is needed to confirm how to increase the conversion rate of H2 and carbon in plastics through the various operating conditions derived from this study's numerical analysis results.

A Relay Selection Scheme with Q-Learning (Q-Learning을 이용한 릴레이 선택 기법)

  • Jung, Hong-Kyu;Kim, Kwang-Yul;Shin, Yo-An
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.49 no.6
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    • pp.39-47
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    • 2012
  • As a scheme to efficiently reduce the effects of multipath fading in next generation wireless communication systems, cooperative communication systems have recently come into the spotlight. Since these cooperative communication systems use cooperative relays with diverse fading coefficients to transmit information, having all relays participate in cooperative communication may result in unnecessary waste of resources, and thus relay selection schemes are required to efficiently use wireless resources. In this paper, we propose an efficient relay selection scheme through self-learning in cooperative wireless networks using Q-learning algorithm. In this scheme, we define states, actions and two rewards to achieve good SER (Symbol Error Rate) performance, while selecting a small number of cooperative relays. When these parameters are well-defined, we can obtain good performance. For demonstrating the superiority of the proposed Q-learning, We compared the proposed scheme with Q-learning and a relay selection scheme with a mathematical analysis. The simulation results show that, compared to a scheme that obtains optimum relays through a mathematical analysis, the proposed scheme uses resources efficiently by using smaller numbers of relays with comparable SER performance. According to these simulation results, the proposed scheme can be considered as a good attempt for future wireless communication.

Reverse Osmosis Treatment of Swine Wastewater with Various Pretreatment Systems (축산 폐수의 전처리 방법과 역삼투압 처리)

  • Park, Soon Ju;Kim, Moon Il;Kim, Do Yun;Chang, Ho Nam;Chang, Seung Teak
    • Clean Technology
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    • v.9 no.2
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    • pp.49-55
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    • 2003
  • The generation of livestock wastewater in Korea amounts to $130,000m^3/day$, 0.43% of the total waste water volume, but which corresponds to 8.6% of total BOD loading. Furthermore this wastewater contains a large amount of nitrogen and phosphorus that are major causes of eutrophication in rivers and lakes. The average volume of livestock wastewater in a Korea's single farm is only $2.5m^3/day$, which necessitates development of a simple and economical process for the removal of nitrogen and phosphorus. Introduction of filtration method removes more than 90% of suspended solids. Subsequent application of reverse osmosis removes more then 95% of total nitrogen and phosphorus in the wastewater. The effluent of this treatment will yield less than 200 mg/L of total nitrogen and 1 mg/L of total phosphorous, which are lower than 260 mg/L of total N and 50 mg/L of total P, the regulation values of Ministry of Environment, Korea. Treating $2m^3/day$ of livestock wastewater was found to be feasible with the application of filtration and reverse osmosis and the electricity requirement was estimated to be about 30 Kwh/month.

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Reaction Characteristics of Kaolinite-based Additives and Alkali Salts (Kaolinite 계열의 첨가제와 알칼리염의 반응 특성)

  • Jun, HyunJi;Choi, Yujin;Shun, Dowon;Han, Keun-Hee;Bae, Dal-Hee;Rhee, Young-Woo
    • Clean Technology
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    • v.26 no.3
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    • pp.221-227
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    • 2020
  • When the waste solid fuel (SRF, Bio-SRF) is burnt in a boiler, a problem occurs in the combustion process involving the alkali components (Na, K) contained in large amounts in the fuel. The alkaline component has a low melting point, which usually forms low melting point salt in the temperature of the furnace, with the resulting low melting point salts attaching to the heat pipe to form a clinker. Various additives are used to suppress clinker generation, and the additive based on the kaolinite has alkali-aluminum-silica to inhibit the clinker. In this study, the reactivity of the additives based on the kaolinite was compared. The additives utilized were R-kaolinite, B-kaolinite, and A-kaolinite. Also silica and MgO were sourced as the comparison group. The experimental group was employed as a laboratory-scale batch horizontal reactor. The additive and alkaline salts were reacted at a weight ratio of 1 : 1, and the reaction temperature was performed at 900 ℃ for 10 hours. The first measurement of HCl occurring during the experiment was performed 30 minutes after the detection tube was used, and the process was repeated every hour after the experiment. After the reaction, solid residues were photographed for characterization analysis by means of an optical microscope. The reaction characteristics of the kaolinite were confirmed based on the analysis results.