• Title/Summary/Keyword: waste alkali

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Alkali activated ceramic waste with or without two different calcium sources

  • Zedan, Sayieda R.;Mohamed, Maha R.;Ahmed, Doaa A.;Mohammed, Aya H.
    • Advances in materials Research
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    • v.4 no.3
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    • pp.133-144
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    • 2015
  • The aim of this investigation is to prepare geopolymer resin by alkali activation of ceramic waste (AACW) with different sodium hydroxide (NaOH) and liquid sodium silicate (LSS) concentrations. In order to prepare geopolymer cement, AACW was replaced by 10 and 30 % by weight (wt.,) of concrete waste (CoW) as well as 10 and 30 wt., % ground granulated blast-furnace slag (GGBFS). The results showed that, the compressive strength of AACW increases with the increase of activator content up to 15:15 wt., % NaOH: LSS. All AACW hardened specimens activated by 3:3 (MC6), 6:6 (MC12), 12:12 (MC24) and 15:15 wt., % (MC30) NaOH: LSS destroyed when cured in water for 24h. The MC18 mix showed higher resistivity to water curing. The results also showed that, the replacement of AACW containing 9:9 wt., % NaOH: LSS (MC18) by 10 (MCCo10) and 30 (MCCo30) wt., % CoWdecreased the compressive strength at all ages of curing. In contrast, the MCCo10 mix showed the lower chemically combined water content compared to MC18 mix. The MCCo30 mix showed the higher chemically combined water content compared to MC18 and MCCo10 mixes. The compressive strength and chemically combined water of all AACWmixes containing GGBFS (MCS10 and MCS30) were higher than those of AACWwith no GGBFS (MC18). As the amount of GGBFS content increases the chemically combined water increases. The x-ray diffraction (XRD) proved that as the amount of CoWcontent increases, the degree of crystallinity increases. Conversely, the replacement of AACW by GGBFS leads to increase the amorphiticity character. The infrared spectroscopy (FTIR) confirms the higher reactivity of GGBFS compared to CoW as a result of successive hydration products formation, enhancing the compaction of microstructure as observed in scanning electron microscopy (SEM).

Effects of Incineration Waste Ash and Gypsum Substitution on the Properties of Blast Furnace Slag Mortar using Recycled Aggregate (소각장 애쉬 및 석고치환이 고로슬래그 미분말 기반 순환골재 모르타르의 물성에 미치는 영향)

  • Han, Min Cheol;Han, Dong Yeop;Lu, Liang Liang
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.2
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    • pp.161-167
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    • 2015
  • Nowadays, all the world face to the global warming problems due to the emission of $CO_2$. From the previous studies, recycled aggregates were used as an alkali activator in blast furnace slag to achieve zero-cement concrete, and favorable results of obtaining strength were achieved. In this study, gypsum and incineration waste ash were used as the additional alkali activation and effects of the gypsum and incineration waste ash to enhance the performance of the mortar were tested. Results showed that although the replacement ratio of 0.5% of incineration waste ash and 20% of anhydrous gypsum resulted in the low of mortar at the early age, while it improved the later strength and achieved the similar strength to that of conventional mortar (at 91 days).

Properties of artificial lightweight aggregates made from waste sludge

  • Chiou, I.J.;Chen, C.H.
    • Computers and Concrete
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    • v.8 no.6
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    • pp.617-629
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    • 2011
  • In this investigation, reservoir sediment and municipal sewage sludge were sintered to form the artificial lightweight aggregates. The sintered aggregates were compared with the commercialized lightweight aggregates to in terms of potential alkali-silica reactivity and chemical stability based on analyses of their physical and chemical properties, leaching of heavy metal, alkali-silica reactivity, crystal phase species and microstructure. Experimental results demonstrated that the degree of sintering of an aggregate affected the chemical resistance more strongly than did its chemical composition. According to ASTM C289-94, all potential alkali-silica reactivity of artificial lightweight aggregates were in the harmless zone, while the potential reactivity of artificial lightweight aggregates made from reservoir sediment and municipal sewage sludge were much lower than those of traditional lightweight aggregates.

The Experimental Study on Hardening Characteristics of Bottom ash by Alkali Activation (알칼리 활성법에 의한 Bottom Ash의 경화 특성에 관한 실험적 연구)

  • Oh, Dong-Uk;Kim, Baek-Joong;Yi, Chong-Ku;Kang, Kyung-In
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.103-106
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    • 2008
  • Because the physical·chemical properties of bottom ash are inferior, most bottom ash is disused. But the use of bottom ash helps in reducing environmental pollution and solving some bottom ash waste problems. So, we have been investigating about the optimum mixture, hardening mechanism, curing condition and environmental safety of a paste composed of a bottom ash and alkali. optimal mixing proportion of bottom ash solid was cement 5%, water 30%, NaOH 10%. After curing during 28days, bottom ash solid can be achieved compressive strength 15.13MPa. As a result, Compressive strength tests of alkali-activated bottom ash have potential as a replacement of coarse aggregate.

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Waste Glass as an Activator in Class-C fly Ash/GGBS based Alkali Activated Material

  • Sasui, Sasui;Kim, Gyu Yong;Lee, Sang Kyu;Son, minjae;Hwang, Eui Chul;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.77-78
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    • 2020
  • An alkaline activator was synthesized by dissolving waste glass powder (WGP) in NaOH-4M solution to explore its effects on the Class-C fly ash (FA) and ground granulated blast furnace slag (GGBS) based alkali-activated material (AAM). The compressive strength and porosity were measured, and (SEM-EDX) were used to study the hydration mechanism and microstructure. Results indicated that the composition of alkali solutions was significant in enhancing the properties of the obtained AAM. As the amount of dissolved WGP increased in alkaline solution, the silicon concentration increased, causing the accelerated reactivity of FA/GGBS to develop Ca-based hydrate gel as the main reaction product in the system, thereby increasing the strength. Further increase in WGP dissolution led to strength loss, which were believed to be due to the excessive water demand of FA/GGBS composites to achieve optimum mixing consistency. Increasing the GGBS proportion in a composite also appeared to improve the strength which contributed to develop C-S-H-type hydration.

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Use of waste glass as an aggregate in GGBS based alkali activated mortar

  • Sasui, Sasui;Kim, Gyu Yong;Son, Min Jae;Pyeon, Su Jeong;Suh, Dong Kyun;Nam, Jeong Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.21-22
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    • 2021
  • This study incorporates fine waste glass (GS) as a replacement for natural sand (NS) in ground granulated blast furnace slag (GGBS) based alkali activated mortar (AAm). Tests were conducted on the AAm to determine the mechanical properties, apparent porosity and the durability based on its resistance to Na2SO4 5% and H2SO4 2% concentrated solutions. The study revealed that increasing GS up to 100 wt%, increased strength and decreased porosity. The lower porosity attained with the incorporation of GS, improved the resistance of mortar to Na2SO4 and thus increasing durability. However, the durability of mortar to H2SO4 solution was negatively impacted with the further reduction of porosity observed with increasing GS above 50 wt.% believed to be caused by the stress induced as a result of expansive reaction products created when the mortar reacted with acid.

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Pozzolanic reaction of the waste glass sludge incorporating precipitation additives

  • You, Ilhwan;Choi, Jisun;Lange, David A.;Zi, Goangseup
    • Computers and Concrete
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    • v.17 no.2
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    • pp.255-269
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    • 2016
  • The waste glass sludge is a waste produced in the glass industry. It is in a dust form and disposed with water. In the disposal process, various cohesive agents are incorporated in order to precipitate the glass particles efficiently. In this paper, we investigate the pozzolanic reaction of the waste glass sludge incorporating precipitation additives experimentally. The consumption of calcium hydroxide, the setting time and the compressive strength and the pore structure were tested for two different types of the waste glass sludge depending on whether precipitation additives were used. It was found that the waste glass sludge incorporating the precipitation additives had a higher pozzolanic potential than the reference waste glass sludge without precipitation additives.