• Analytical Science and Technology
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• v.23 no.3
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• pp.261-268
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• 2010

This study was performed to evaluate the PCBs-containing wastes using official test method. Ninety samples of transformer oil and various solid waste were collected to assess the analytical results. In the analysis of PCBs-containing wastes, the PCBs levels were detected in the range of 7.6 mg/kg to 23.8 mg/kg for transformer oils, $0.02\sim0.54\;{\mu}g/100cm^2$ for plat solid wastes, and 0.01~0.071 mg/kg for amorphous solid waste. In the cupper wire waste of the transformer with oil concentration level of 23 mg/kg, the analytical result exceed PCBs regulation level of 0.04 mg/kg. The new proposed analytical method for PCBs containing waste can be forced to effective management of the wastes.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.1
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• pp.88-95
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• 2009

This study is for understanding the domestic possibilities of the high temperature incineration of waste containing Polychlorinated Biphenyls (PCBs) with the analysis of normal operation case and waste gas, fly ash, dioxin about bottom ash, Total-PCBs, Co-PCBs, and the for analysis the heavy metal leaching feature included by bottom ash and fly ash, heavy metal leaching experiment was implemented. The result shows the dioxin density of the waste gas from waste containing PCBs was $0.00699{\sim}0.00763ng-TEQ/Nm^3$, which is lower than $0.0192ng-TEQ/Nm^3$ from the normal operation case. And each Co-PCBs and total PCBs shows $0.00043{\sim}0.00112ng-TEQ/Nm^3$ and $3.06{\sim}3.87ng/m^3$ respectively. The bottom ash test result shows Dioxin 0.00225~0.00630ng-TEQ/g, Co-PCBs 0.00027~0.00082ng-TEQ/g, Total PCBs 0.9~2.6ng/g, and the fly ash shows Dioxin 0.00164~0.00344ng-TEQ/g, Co-PCBs 0.00053~0.00054ng-EQ/g, Total PCBs 0.64~0.84ng/g. The bottom ash and fly ash experiments for heavy metal leaching did not show any leaching but when it comes to the ingredients of the fly ash, Pb elements shows 31.01~237.7ppm, higher than leaching criterion. The analysis of the density of all air pollution material from the waste gas shows the lower value than permissible criterion.

• Analytical Science and Technology
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• v.21 no.3
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• pp.201-211
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• 2008

The treatment efficiency of PCBs containing wastes has been investigated. The samples treated by electron beam and de-chlorination method were analyzed to verify the byproducts before treatment and after treatment. In the treated samples by electron beam irradiation, PCBs were not detected by comparing the peak matching using the Korean official waste test method. On the other hand, PCBs congeners were detected by analyzing individual isotope method using HRGC/HRMS. Most of PCB congeners in waste were decomposed to 3-chlorobiphenyls, lower chlorinated congener produced during the treatment of electron beam. In the chemical dechlorination treatment, it was found that the concentrations of PCBs in treated samples were lower than those of regulation criteria in Waste & POPs management law and the after treatment concentration were satisfied to the regulation criteria. Also, dioxins were not observed after the physio-chemical treatment processes of PCBs containing wastes.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2005.04a
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• pp.199-201
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• 2005

This paper describes a simple procedure for the quantitative analysis of 7 PCBs (polychlorinated biphenyls) in soils on the waste reclaimed land, The procedure involved sample clean up using silicagel column, acetonitrile partition and sulfuric acid procedures. The instrumental technique is applied GC/PDD(gas chromatography/pulsed discharge detector) and GC/ECD(gas chromatography/electron capture detector). Concentration of $sub-{\mu}g/g$ level was attainable with 20g soils on the waste reclaimed land.

• Analytical Science and Technology
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• v.21 no.3
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• pp.174-182
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• 2008

The study on the development of rapid analytical method of PCBs containing waste was performed by considering the extraction, column cleanup process, analytical condition and so on. In the established method, new sample clean-up procedure, new quantification peaks and temperature program were introduced. Method detection limit of the method was 0.5 mg/L, and the method could save the total run time to 2/3, therefore save the analysis cost, The new rapid analytical method of transformer oil was suggested to the waste official test method.

• Resources Recycling
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• v.24 no.1
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• pp.66-72
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• 2015

Various waste PCBs arose during disassembly of LCD TVs and monitors in which they originally functioned for transmission of imaging signal, power supply, and imaging control. In those functional PCBs, gold and copper are contained at far more acceptable level, exceeding mining grade ores. Those valuable metals and their contents widely vary with functionality and end use of PCBs. Therefore, compositional analysis of individual waste PCBs from disassembled LCD TVs and monitors were performed in the present study to classify them into three categories: high gold yield and low gold yield PCBs and those without gold contents. Besides, additional chemical analysis was made to reveal gold and copper contents in the waste PCBs arising from actual disassembly/separation of end-of-life LCD TVs and monitors.

• Journal of Korean Society of Environmental Engineers
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• v.32 no.9
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• pp.870-878
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• 2010

We investigated the concentration and the sources of ubiquitous persistent organic pollutants [i.e., 17 toxic polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs), 12 coplanar polychlorinated biphenyls (Co-PCBs), and 16 priority polycyclic aromatic hydrocarbons (PAHs)] in waste papers and lumbers from industrial complexes. The total concentrations in waste papers and lumbers ranged from 9.69~176.77 pg/g-dry and 0.14~0.25 pg/g-dry for 17 PCDD/Fs, 109.95~4097.25 pg/g-dry and 28.23~59.88 pg/g-dry for 12 Co-PCBs and 9.30~52.18 ng/g-dry and 0.82~1.82 ng/g-dry for 16 PAHs respectively. Generally, the concentration of these pollutants in waste papers was higher than those in waste lumbers. OCDD was dominant in waste papers and lumbers and the PCDD/F patterns of these samples were similar with that of stack gas. The distribution patterns of Co-PCBs in wastes were related with commercial PCB products, indicating the effect of commercial PCB products on ubiquitous environment. The diagnostic ratios of several PAH compounds in waste paper showed that they were related with pyrogenic sources.

• Environmental Analysis Health and Toxicology
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• v.19 no.2
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• pp.227-233
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• 2004

The main objectives of this study were to identify from literature review the potential sources and to provide a preliminary national emission inventory for the unintentionally produced polychlorinated biphenyls (PCBs) (i.e., by - product PCBs). In Korea, fuel combustion, waste combustion, thermal industrial processes, and transportation were identified as potential sources of by -product PCB s. According to the availability of the emission factors and/or activity data, emission inventory could be assessed only for fuel combustion, waste combustion, steel industry, non-ferrous industry, and non-metallurgical industry. The total national emission of by-product PCBs was estimated to be 1087kg for the year 2000. The preliminary estimation further indicated that the steel manufacturing was the single dominant emission category, contributing 93％ to the total emission. Of the steel manufacturing processes, the contribution of the electric arc furnace was about 80％ of the total emission. Due to high uncertainty associated with both the emission factors and activity statistics, the emission estimates in this study are likely to contain significant errors. However, the results of the present work could serve the first step toward future efforts to establish national source and emission inventories of by-product PCBs.

• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.814-818
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• 1997

The chemical waste treatment, APEG (alkali/polyethylene glycol) process has been shown to be effective for the dechlorination of PCBs in transformer oil. Considerable amount of PCBs, however, still remains in the waste exceeding the 25-50 ppm limit set by regulatory agency. A new thermal regeneration technology has been developed in our laboratory for disposal of hazardous organic wastes. Due to the limited oxidation of carbon surface through the reverse movement of flame front to oxidant flow, this technology was termed counterflow oxidative system (COS). Specially, the oxidant flow in the COS process is a principal parameter which determines the optimum conditions regarding acceptable removal and destruction efficiency of adsorbed organic wastes at minimal carbon loss. The COS process, under optimum conditions, was found to be very effective and the removal and destruction efficiency of 99.99% or better was obtained for residual PCBs in the waste while bulk (≥90%) of carbon was recovered. Any toxic formation of polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzo furans (PCDFs) were not detected in the regenerated carbon and impinger traps. The results of surface area measurement showed that the adsorptive property of regenerated carbon is mostly reclaimed during the COS process.

• Bulletin of the Korean Chemical Society
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• v.28 no.4
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• pp.520-528
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• 2007

A practical and efficient disposal of PCBs (polychlorinated biphenyls) in waste transformer oil by a chemical dechlorination process has been reported. The transformer oil containing commercial PCB mixtures (Aroclor 1242, 1254 and 1260) was treated by the required amounts of PEG 600 (polyethylene glycol 600), potassium hydroxide (KOH) and aluminum (Al), along with different reaction temperatures and times. The reaction of PEG with PCBs under basic condition produces arylpolyglycols, the products of nucleophilic aromatic substitution. The relative efficiencies of PCB treatment process were assessed in terms of destruction and removal efficiency (DRE, %). Under the experimental conditions of PEG600/KOH/Al/100 oC/2hr, average DRE of PCBs was approximately 78%, showing completely removal of PCBs containing 7-9 chlorines on two rings of biphenyl which appear later than PCB no. 183 (2,2',3,4,4',5',6-heptaCB) in retention time of GC/ECD. However, when increasing the reaction temperature and time to 150 oC and 240 min, average DRE of PCBs including the most toxic PCBs (PCB no. 77, 105, 118, 123 and 169) in PCB family reached 99.99% or better, with the exception of PCB no. 5 and 8 (2,3-diCB and 2,4'-diCB). In studying the reaction of PEG with PCBs, it confirmed that the process led to less chlorinated PCBs through a stepwise process with the successive elimination of chlorines. The process also permits complete recovery of treated transformer oil through simple segregating procedures.