• Carbon letters
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• v.13 no.3
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• pp.167-172
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• 2012

Most heavy metals are well-known toxic and carcinogenic agents and when discharged into wastewater represent a serious threat to the human population and the fauna and flora of the receiving water bodies. The present study aims to develop a procedure for Pb (II) removal. This procedure is based on using powdered activated carbon, which was prepared from walnut shells that were generated as plant wastes and modified with potassium carbonate and phosphoric acid as chemical agents. The main parameters, such as effect of pH, effect of sorbent dosage, Pb (II) concentrations, and various contact times influence the sorption process. The experimental results were analyzed by using Langmuir, Freundlich, Tempkin, and Dubinin-Radushkevich adsorption models. The kinetic study of Pb (II) on activated carbon from walnut shells was performed based on pseudo- first order and pseudo- second order equations. The data indicate that the adsorption kinetics follow the pseudo- second order rate. The procedure was successfully applied for Pb (II) removal from aqueous solutions.

• Biotechnology and Bioprocess Engineering:BBE
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• v.9 no.3
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• pp.223-228
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• 2004

Agricultural waste products, beech wood and walnut shells, were hydrolyzed at 40$^{\circ}C$ using mixed crude enzymes produced by Penicillium sp. AHT-1 and Rhizomucor pusillus HHT-1. D-xylose, 4.1 g and 15.1 g was produced from the hydrolysis of 100 g of beech wood and walnut shells, respectively. For xylitol production, Candida tropicalis IFO0618 and the waste product hydrolyzed solutions were used. The effects on xylitol production, of adding glucose as a NADPH source, D-xylose and yeast extract, were examined. Finally, a 50% yield of xylitol was obtained by using the beech wood hydrolyzed solution with the addition of 1% yeast extract and 1% glucose at an initial concentration.

• Journal of the Korean Applied Science and Technology
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• v.38 no.1
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• pp.29-36
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• 2021

Among natural products, the shells of black walnut(Juglans nigra), which are not used commercially and mostly discarded, were examined to investigate the physiological activity and the efficacy for the cosmetic application. DPPH radical scavenging activity of hot water extract of black walnut shells was 76.06% at 300 ㎍/mL. ABTS radical scavenging activity of the extract was 61% at 1000 ㎍/mL, showing excellent antioxidant activity. When the black walnut shell extract was applied to HaCaT cells, a skin keratinocyte, the viability of the cells was 92.6% at 250 ㎍/mL, showing a remarkably low effect on cell viability. At the concentration of 500 ㎍/mL, 67.35% of nitric oxide(NO) production was inhibited. It also showed an inhibitory effect on Hyaluronidase 31 times higher than that of Vitamin C at 100 ㎍/mL concentration. In conclusion, the black walnut shell extract showed high potentials for the cosmeceutical applications, suggesting the possibility of using it as a high value-added natural material in various industries such as food, fragrance, healthcare, and pharmaceuticals.

• Carbon letters
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• v.13 no.2
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• pp.115-120
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• 2012

Most heavy metals are well-known toxic and carcinogenic agents and when discharged into wastewater represent a serious threat to the human population and the fauna and flora of the receiving water bodies. The present study aims to develop a procedure for Pb(II) removal. The study was based on using powdered activated carbon, which was prepared from walnut shells generated as plant wastes and modified with potassium carbonate or phosphoric acid as chemical agents. The main parameters, such as effect of pH, effect of sorbent dosage, Pb(II) concentrations, and various contact times influence the sorption process. The experimental results were analyzed by using Langmuir, Freundlich, Tempkin and Dubinin-Radushkevich adsorption models. The kinetic study of Pb(II) on activated carbon from walnut shells was performed based on pseudo-first order and pseudo-second order equations. The data indicate that the adsorption kinetics follow the pseudo-second order rate. The procedure was successfully applied for Pb(II) removal from aqueous solutions.

• Journal of the Korean Wood Science and Technology
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• v.26 no.3
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• pp.48-52
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• 1998

Residues such as walnut, pinenut and peanut shells were used as a filler in adhesive for bonding radiata pine plywood. The nutshell residues were prepared by simply drying to 8% moisture content and grinding the dry material using a laboratory Wiley mill with a $75{\mu}m$ (200 mesh) screen. The nutshells residues were compared to a commercial filler commonly used in adhesives by the structural plywood and laminated veneer lumber industry in the United States. The adhesive mixes were made by following the recommended procedure of Georgia-Pacific Resins, Inc., using phenol-formaldehyde resin. For each filler type, three-ply plywoods, 6 mm nominal thickness and 30 by 30 cm in size, were fabricated at two press times (4 and 5 min) and around 30 minute assembly time. Evaluations of the nutshell residues were carried out by tension shear tests after cyclic boil tests on plywood. The results of the performance test included tension shear strength and wood failure. All plywoods made with the nutshell fillers were comparable to those made with the control filler. These results indicate that nutshell residues would be suitable as filler for plywood adhesives.

• Transactions on Electrical and Electronic Materials
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• v.2 no.2
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• pp.5-15
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• 2001

The experiment established optimal conditions for over-carbonization. With the use of the electron microscopy and X-ray phase analysis the regularities of carbon deposit formation in process of methane and propane pyrolysis on the zeolites, Kazakhstan natural clays, chrome and bauxite sludge containing metal oxides of iron subgroup, have been studied. In process of over-carbonization the trivalent iron was reduced to metal form. In addition, the carbon tubes of divers morphology had been impregnated with ultra-dispersed metal particles. The kinetic parameters of carbon formation in process of methane decomposition on the zeolite - CoO mixture surface were investigated by method of thermo-gravimetric analysis. The morphology and structure of formed carbon fibrils, with the metal particles fixed at their ends, have been investigated, the formation of branched carbon fibrils pattern, so called octopus, being found. Also, the walnut shells and grape kernel carbonization, their immobilization by the cells of selective absorption of heavy metal and sulfur dioxide ions have been studied. The example of metal-carbon composites used as adsorbents for wastewater purification, C$_3$- C$_4$ hydrocarbon cracking catalysts and refractory materials with improved properties have been considered.

• Journal of Korean Society of Forest Science
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• v.96 no.4
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• pp.455-461
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• 2007

This research was processed on morphological and physical characteristics of 'Yongdong' cultivar nuts. (1)Morphological properties of 'Yongdong' cultivar nuts were significantly different from the control, native species, in respect of all properties. (2) 'Yongdong' cultivar nuts showed higher figures than the native species on 9 items of morphological properties (kernel weight, size, length and width of pad on suture and etc.), whereas other 6 items (height of pad on suture, thickness of shell and septem, fragment numbers of isolated kernel, roundness index, and etc.) showed lower figures than those of the control. (3) In physical properties of the nut shells, 'Yongdong' cultivar was superior to the control at all items with the exception of compressive prove distance. Accordingly, it was also verified as effective cultivar of shelled walnut with suture line direction applied the minimum strength. (4) 'Yongdong' cultivar, 21.9 kg, was approximately twice lower than the control, 42.6 kg, on maximum compressive weight. It was demonstrated that the 'Yongdong' cultivar characterized by easily crushing shell by small strength was great in cracking properties. (5) On the study of yield strength, the native species being twice higher than 'Yongdong' cultivar showed the properties of the small elasticity and the shell hardness. While, the suture line of 'Yongdong' cultivar having the lowest yield strength 15.6 kg and 16.0 kg was identified the shell crushed easily. (6) The movement distance of the compressive prove of 'Yongdong' cultivar, 4.2 mm, was longer than that of the control, 2.7 mm. Subsequently, it means that the amount of loss possibly occurring to distribution process was not great, whereby productive value was high. (7) The compressive strength of the suture line of 'Yongdong' cultivar, $9.1kg/cm^2$, was much lower than total average of that $12.4kg/cm^2$. It was also statistically different with other properties. (8)The hardness examination by the compressive position revealed that the suture line of 'Yongdong' cultivar, $149.8kg/cm^2$, was lowest in contrast with the control, $300.9kg/cm^2$.