• Journal of the Korean Chemical Society
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• v.39 no.11
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• pp.856-862
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• 1995

The tungsten oxo-nitrosyl complexes (n-Bu4N)2[W5O12(NO)2{RC(NH2)NHO}2{RC(NH)NO}2] (R=(CH3)2CH, CH3CH2CH2, CH3SCH2) have been synthesized by the reactions of polyoxotungsten complex (n-Bu4N)2[W6O19] and tungsten dinitrosyl monomeric complex [W(NO)2(acac)(CH3CN)2](BF4) with butylamidoxime derivatives. The prepared complexes have been characterized by elemental analysis, infrared, UV-visible, 1H NMR and 13C NMR spectroscopy. The pentanuclear species was formed by the interaction of the electron-withdrawing {W(NO)2}2+ unit between the two dinuclear tungsten {W2O5}2+ cores. We can estimate to exist large proton interactions viewed from the four doublet in 1H NMR spectrum of (n-Bu4N)2[W5O12(NO)2{(CH3)2CHC(NH2)NHO}2{(CH3)2CHC(NH)NO}2]. We also drew informations of the two different coordination mode and symmetry of the complexes because two ligands appear in 13C NMR spectra instead of four. The {W(NO)2}2+ unit has been cis-form and C2v symmetry in geometric structure.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2012.05a
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• pp.797-798
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• 2012

• Korean Journal of Food Science and Technology
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• v.40 no.4
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• pp.389-393
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• 2008

This study examined the effects of cooking temperature and onion (Allium cepa L.) tissue concentrate on heterocyclic amine (HCA) formation in fried ground beef patties. Various amounts of onion tissue (2.0, 5.0, and 10.0%, w/w) were added to the ground beef patties, which were then fried at two different temperatures (190 and $225^{\circ}C$) for 10 min/side. The ground beef patties fried at $190^{\circ}C$ and containing 10.0% (w/w) onion showed a 51% decrease in mutagenicity, and formation of 2-amino-3,8-dimethylimidazo[4,5-f]quinoxaline (MeIQx) and 2-amino-1-methyl-6-phenylimidazo[4,5-b]-pyridine (PhIP) was reduced by 58% and 63%, respectively. For the patties fried at $225^{\circ}C$, total mutagenicity decreased by 35% and 48% with the additions of 5.0 and 10.0% (w/w) onion, respectively, and PhIP formation was reduced 50, 60, and 71% with the additions of 2.0, 5.0, and 10.0% (w/w) onion, respectively.

• Journal of the Korean Chemical Society
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• v.37 no.7
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• pp.655-661
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• 1993

The neutral monomeric compounds $[Mo(NO)_2Cl_2(phen)]$ and $[W(NO)_2Cl_2(phen)]$ (phen= 1,10-phenanthroline) have been prepared by reactions of polymeric compounds $[{Mo(NO)_2Cl_2}n],\;[{W(NO)_2Cl_2}n]$ with chelate ligands. Additions of one equivalent of silver(I) perchlorate to these cis-dinitrosyl compounds in acetone solution produce $[Mo(NO)_2(phen)(S)Cl][ClO_4]\;and\;[W(NO)_2(phen)(S)Cl][ClO_4]$ (S = acetone). The homo- and hetero-dinuclear complexes, $[Cl(phen)(NO)_2M(pyz)M'(NO)_2(phen)Cl][ClO_4]_2$ (M = Mo, W) and $[Cl(phen)(NO)_2M(pyz)M'(NO)_2(phen)Cl][C1O_4]_2$ (M = Mo, M' = W) have been prepared by these monocationic complexes with pyrazine ligand respectively. These complexes characterized by elemental analysis, $1^H-\;and\;^{13}C-NMR$, infrared, and UV-visible spectroscopy are reported. The spectral data indicate that homo- and hetero-dinuclear complexes were symmetrical structures of $C_{2v}$.

• Korean Journal of Materials Research
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• v.10 no.6
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• pp.415-421
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• 2000

The effect of silica binder content on the mechanical properties of zircon shell mold was investigated. Content of binder silica sol to refractory powder in weight[$R_W$] was adjusted from 0.18 to 0.43. Sintering of the shell mold was carried out in the temperature range of $871^{\circ}C$ to $1400^{\circ}C$. Green strength of the shell mold at room temperature increased with increasing $R_W$ and sintering temperature up to $1300^{\circ}C$. However, the mold with $R_W$ of 0.43 that sintered at $1400^{\circ}C$ for 3 hours showed relatively low strength and large level of porosity. The mechanical behavior of the shells is supposed to attributed to the difference in thermal expansion coefficient between refractory powder and binder silica. The optimum value of $R_W$ for zircon-based shell molds was found to be 0.33.

• The KIPS Transactions:PartC
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• v.17C no.4
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• pp.361-370
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• 2010

OTP(One Time Password) is a user authentication using secure mechanism to authenticate each other in a way to generate a password, an attacker could intercept the password to masquerade as legitimate users is a way to prevent attacks. The OTP can be implemented as H/W or S/W. Token and card type OTP, implemented as H/W, is difficult to popularize because of having problem with deployment and usability. As a way to replace it implemented as S/W on Mobile or PC is introduced. However, S/W products can be target of malicious attacks if S/W products have vulnerability of implementation. In fact, FSA said the OTP implemented on a mobile have vulnerability of implementation. However, the OTP implemented on a PC have no case about analysis of vulnerability. So, in this paper derive security review and vulnerabilities analysis of implemented on a PC.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3401-3406
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• 2007

This study was performed to acquire the reliable in-situ thermal conductivity of closed type ground heat exchanger used in ground source heat pump. We selected four sites(Cheonan, Daejeon, Daegu, Gwangju) which are central area of South Korea. Test results show that the effective thermal conductivities are 2.33 W/m$^{\circ}C$, 2.50 W/m$^{\circ}C$, 2.75 W/m$^{\circ}C$ and 2.86 W/m$^{\circ}C$. From this data, we can see that thermal conductivity varies about the range of 23% with the sites. Also, thermal conductivity increases up to 20% by changing grouting material from low salica sand to high one.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.909-912
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• 2001

This paper presents the validities of the removal time of side forms considering the relationship between rebound number of P type schmidt hammer and compressive strength. According to test results, compressive strength of 40% of W/C at 12 hours shows 16kgf/$cm^{2}$ and 50% of W/C at 15 hours, 13kgf/$cm^{2}$. Rebound number at 9 hours after casting shows 13 and 9 (W/C 40% and W/C 50%). According to the regression analysis, rebound number of P type schmidt hammer to gain 50kgf/$cm^{2}$ of is estimated 20.1. It is thought that desirable rebound number of P type schmidt hammer to gain 50kgf/$cm^{2}$ is determined 25 considering safety factor.

• Proceedings of the Korea Concrete Institute Conference
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• 1995.04a
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• pp.130-135
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• 1995

We can consider that the study on early evaluation of strength of concrete is useful to raise safety of building and utility of quality control of concrete is useful to raise safety of building and utility of quality control of concrete. In this paper, was proposed to method early to predict strength of concrete with key parameters, such as Water/Cement(W/C) ratio and Sand / Aggregate(S/A) ratio. Through a series of experiment, the obtained results are summarized as follow. $\circled1$ The ratio of resistance was decteased as the increase of W/C ratio. $\circled2$ The maximum value for the ratio of resistance and compressive strength was presented in the case of 40% S/A ratio. $\circled3$ The relationship. of the ratio of resistance and compressive strength on 28days according to the change of W/C and S/A ratio is to be: $F_{28}=-0.00104R^2 + 2.263R - 935.5$ (W/C Ratio) $F_{28} = 0.007R^2 - 10.693R - 4269.1$ (S/A Ratio)

• Proceedings of the Korea Concrete Institute Conference
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• 2002.05a
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• pp.737-742
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• 2002

The chief factors for the penetration and diffusion of chloride ions in concrete are water-cement ratio(w/c), aging, thickness of cover concrete, chloride ions concentration of given environment, wet and dry conditions and etc. In this study, effect of w/c and aging on the characteristics of chloride ions diffusion in concrete were researched when environmental factors for the penetration and diffusion of chloride ions were constant. For this purpose, the voltages passing through the diffusion cell were measured by using accelerated test method using potential difference, and then diffusion coefficients of chloride ions by using Andrade's method were estimated for 44%, 49.5% and 55% of w/c, respectively. As a result, correlation among diffusion coefficients of chloride ions, w/c and aging were concluded through multiple regression model.