• Journal of the Korean Society of Propulsion Engineers
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• v.3 no.4
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• pp.58-66
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• 1999

The flow characteristics of supersonic ejectors is often subject to compressibility, unsteadiness and shock wave systems. The numerical works carried out thus far have been of one-dimensional analyses or some Computational Fluid Dynamics(CFD) which has been applied to only a very simplified configuration. For the design of effective ejector-pump systems the effects of secondary mass flow on the supersonic ejector flow should be fully understood. In the present work the supersonic ejector-pump flows with a secondary mass flow were simulated using CFD. A fully implicit finite volume scheme was applied to axisymmetric compressible Navier-Stokes equations. The standard two-equation turbulence model was employed to predict turbulent stresses. The results obtained showed that the flow characteristics of constant area mixing tube types were nearly independent of the secondary flow rate, but the flow fields of ejector system with the second-throat were strongly dependent on the secondary flow rate due to the effect of the back pressure near the primary nozzle exit.

• International Journal of Concrete Structures and Materials
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• v.7 no.2
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• pp.95-110
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• 2013

We report various synchrotron radiation laboratory based techniques used to characterize cement based materials in nanometer scale. High resolution X-ray transmission imaging combined with a rotational axis allows for rendering of samples in three dimensions revealing volumetric details. Scanning transmission X-ray microscope combines high spatial resolution imaging with high spectral resolution of the incident beam to reveal X-ray absorption near edge structure variations in the material nanostructure. Microdiffraction scans the surface of a sample to map its high order reflection or crystallographic variations with a micron-sized incident beam. High pressure X-ray diffraction measures compressibility of pure phase materials. Unique results of studies using the above tools are discussed-a study of pores, connectivity, and morphology of a 2,000 year old concrete using nanotomography; detection of localized and varying silicate chain depolymerization in Al-substituted tobermorite, and quantification of monosulfate distribution in tricalcium aluminate hydration using scanning transmission X-ray microscopy; detection and mapping of hydration products in high volume fly ash paste using microdiffraction; and determination of mechanical properties of various AFm phases using high pressure X-ray diffraction.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.58-65
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• 2016

Hydraulic analysis of the natural gas transmission pipeline is to determine whether adequate flow can be sustained throughout the design life of pipeline under all expected flow conditions. Many factors have to be considered in the hydraulic design of long-distance pipelines, including the nature, volume, temperature and pressure of fluid to be transported, the length and elevation of pipeline and the environment of terrain traversed. This study reviewed the available gas operation data provided by pipeline construction project in the arctic area and discussed the gas properties such as viscosity and compressibility factor that influence gas flow through a pipeline. Pipeline inside diameter was calculated using several flow equations and pipeline wall thickness was calculated from Barlow's equation applying a safety factor and including the yield strength of the pipe material. The AGA flow equation was used to calculate the pressure drop due to friction, gas temperature and pipeline elevation along the pipeline. The hydraulic design in this study was compared with the report of Alaska Pipeline Project.

• Journal of the Korean Geosynthetics Society
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• v.8 no.2
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• pp.55-62
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• 2009

Recently, new development projects are being carried out with the soft ground located along the West coast and the South coast. As soft grounds have complex engineering properties that the load bearing capacity is low and high compressibility, it needs to solve this problems Prior to structures are constructed by the method of improvement of soft ground. The sand mat is usually being used for improvement of soft ground as a horizontal drain material and loading base. But, as the volume is enormous and an amount of demanded sand is increased, it is state of short in supply. This paper presents the feasibility study to use of precious slag ball instead of sand mat as the replacing material through the basic soil property tests, the medium of discharge capacity test and analysis of settlement character.

• Transactions of the Korean Society of Mechanical Engineers
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• v.18 no.1
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• pp.139-149
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• 1994

A numerical simulation of unsteady axisymmetric turbulent flow was performed for a reciprocating engine including port/valve assembly. The governing equations based on a nonorthogonal coordinate formulation with Cartesian velocity components were used and discretised by the finite volume method with non-staggered variable arrangements. The modified $\kappa-\xi$. turbulence model which included the effect of compressibility was used. The results of twodimensional transient calculation for the axisymmetric configuration were compared with the experimental data. Although slightly low rms velocity was predicted compared to the experimental data, predicted velocity distributions at the valve exit and in-cylinder region showed good agreements with the experimental data. The flow at the valve exit was separated at the same valve lift position with the experimental data. Two vortices incylinder region were generated during the initial intake process. The clockwise main vortex became strong and moved upward to the top wall. The counter-clockwise second vortex became weak and stick to the upper left corner of the cylinder. After middle intake process, new vortex adjacent to upper cylinder wall appeared by the piston motion and therefore, the in-cylinder flow was formed into three vortices. The cylinder pressure just before bottom dead center of piston was higher than inlet pressure and then the reverse flow occured at the valve exit. The in-cylinder flow characteristics were strongly dependent on piston motion, but insensitive to valve motion.

• Journal of the Korean Chemical Society
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• v.20 no.2
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• pp.118-128
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• 1976

The significant structure theory of liquids and the Bragg-Williams approximation of phase transition theory have been applied to the calculation of the thermodynamic properties of p-azoxyanisole which exhibits a liquid crystal phase of the nematic type. The isotropic phase was treated as a normal liquid; and for the nematic phase, in addition to its liquidity, the effect due to the arrangement of molecular-dipoles was considered. The liquidity of the p-azoxyanisole was described by the significant structure theory of liquids, and the Bragg-Williams approximation was used to consider the effect due to the arrangement of molecular-dipoles. The molar volume, vapor pressure, heat capacity at constant pressure, thermal expansion coefficient, compressibility, entropy and enthalpy change at the nematic-isotropic phase transition point, absolute entropy, and absolute Helmholtz free energy were calculated over the temperature range of the nematic and isotropic phases. The calculated results of the thermodynamic properties were compared with the experimental data.

• Journal of the Korean Geophysical Society
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• v.4 no.3
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• pp.197-203
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• 2001

The vertical distribution of pore water pressure in the highly saturated sand layer under the oscillating water pressure (water wave) us studied theoretically and experimentally. By the experiments it is shown that the water pressure acting on the sand surface propagates into the sand layer with the damping in amplitude and the lag in phase, and that the liquefaction, the state that the effective stress become zero, occurs under certain conditions. These experimental results are explained fairly well by the same theoretical tearment as for ground water problems in the elastic aquifer. The main characteristics of liquefaction clarified by the analysis are as follows: 1) The depth of the liquified layer increases with the increase of the amplitude and the frequency of the oscillating water pressure. 2) The increase of the volume of the air in the layer increases the liquified depth. Especially the very small amount of the air affects the liquefaction significantly. 3) The liquefied depth decrese rapidly with the increase of the compressibility coefficient of the sand. 4) In the range beyond a certain value of the permeability coefficient the liquified depth decrease with the increase of the coefficient.

• The Journal of Engineering Research
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• v.4 no.1
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• pp.125-135
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• 2002

The vertical distribution of pore water pressure in the highly saturated sand layer under the oscillating water pressure (water wave) is studied theoretically and experimentally. By experiments it is shown that the water pressure acting on the sand surface propagates into the sand layer with the damping in amplitude and the lag in phase, and that the liquefaction, the state that the effective stress becomes zero, occurs under certain conditions. These experimental results are explained fairly well by the same theoretical treatment as for the ground water problems in the elastic aquifer. The main characteristics of liquefaction clarified by the analysis are as follows: 1) The depth of the liquefied layer increases with the increase of the amplitude and the frequency of the oscillating water pressure. 2) The increase of the volume of the water and the air in the layer increases the liquefied depth. Especially the very small amount of the air affects the liquefaction significantly. 3) The liquefied depth decrease rapidly with the increase of the compressibility coefficient of the sand. 4) In the range beyond a certain value of the permeability coefficient the liquefied depth decrease with the increase of the coefficient.

• Geomechanics and Engineering
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• v.7 no.2
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• pp.183-200
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• 2014

The expansivity of clayey soils is a complicated phenomenon which may affect the stability of geotechnical structures and geo-environmental projects. In all common factors for the monitoring of soil expansion, less attention is given to anion type of pore space solutions. Therefore, this paper is concerned with the impact of various concentrations of different inorganic salts including NaCl, $Na_2SO_4$, and $Na_2CO_3$ on the macro and microstructure behavior of the expandable smectite clay. Comparison of the responses of the smectite/NaCl and smectite/$Na_2SO_4$ mixtures indicates that the effect of anion valance on the soil engineering properties is not very pronounced, regardless of the electrolyte concentration. However, at presence of carbonate as potential determining ions (PDIs) the swelling power increases up to 1.5 times compared to sulfate or chloride ions. The samples with $Na_2CO_3$ are also more deformable and show lower osmotic compressibility than the other mixtures. This demonstrates that the barrier performance of smectite greatly decreases in case of anions with the non-specific adsorption (e.g., $Cl^-$ and $SO{_4}^{2-}$) as the salinity of solution increases. Based on the results of the X-ray diffraction and sedimentation tests, the high soil volumetric changes upon exposure to carbonate is attributed to an increase in the repulsive forces between smectite basic unit layers due to the PDI effect of $CO{_3}^{2-}$ and increasing the pH level which enhance the buffering capacity of smectite. The study concluded that the nature of anion through its influence on the re-arrangement of soil microstructure and osmotic phenomena governs the hydro-mechanical parameters of expansive clays. It seems not coinciding with the double layer theory of the Gouy-Chapman double layer model.

• Journal of the Korean Chemical Society
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• v.31 no.5
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• pp.413-418
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• 1987

Rates of the reaction for p-nitro benzyl chloride, benzyl chloride and p-methyl benzyl chloride with pyridine in methanol solvent have been measured by an electric conductivity method at 40$^{\circ}$C and 50$^{\circ}$C under various pressures (1∼2000bar). Pseudo first-order rate constants and second-order rate constants were determined. Rates of these reactions were increased in the order p-NO$_2$ < p-H < p-CH$_3$ and increased with temperature, pressure and concentration of pyridine. From those rate constants, the activation parameters were evaluated. The activation volume and the activation compressibility coefficient are both negative values, but the activation enthalpy is positive and the activation entropy is large negative value. From the evaluation of the ground state and transition state which was resulted from substituents and pressure, it was found that this reaction proceeds through S$_N$2 reaction, and S$_N$2 fashion is slightly disappeared as pressure increases.