• Title/Summary/Keyword: volume change behavior

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Influence of the Water Vapor Content on the Hydrogen Reduction Process of Nanocrystalline NiO

  • Jung, Sung-Soo;An, Hyo-Sang;Lee, Jai-Sung
    • Korean Journal of Metals and Materials
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    • v.48 no.4
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    • pp.315-319
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    • 2010
  • In this study, the hydrogen reduction behavior of ball-milled NiO nanopowder was investigated depending on the partial pressure of water vapor. The hydrogen reduction behavior was analyzed by thermogravimetry and hygrometry under heating to 873 K in hydrogen. In order to change the partial pressure of the water vapor, the dew point of hydrogen was controlled in the range of 248 K~293 K by passing high-purity hydrogen through a saturator that contained water. Interestingly, with the increase in the dew point of the hydrogen atmosphere, the first step of the hydrogen reduction process decreased and the second step gradually increased. After the first step, a pore volume analysis revealed that the pore size distribution in the condition with a higher water vapor pressure shifted to a larger size, whereas the opposite appearedat a lower pressure. Thus, it was found that the decrease in the pore volume during the chemical reaction controlled process at a dew point of 248 K caused a reduction in retardation in the diffusion controlled process.

A novel triaxial testing device for unsaturated soils with measurement of suction and volumetric strains

  • Qian-Feng Gao;Mohamad Jrad;Mahdia Hattab;Said Taibi;Jean M. Fleureau
    • Geomechanics and Engineering
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    • v.37 no.2
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    • pp.109-122
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    • 2024
  • Standard triaxial cells are commonly used to measure the mechanical behavior of saturated soils. However, this type of standard system is difficult to use for unsaturated soil specimens since it cannot measure the changes in the pore-air volume and pressure. This paper proposes to extend the measurement possibilities of the standard triaxial testing device in a simple way and to adapt it to partially saturated soils. The system is supplied by two hygrometers installed at each end of the cylindrical unsaturated specimen to measure local relative humidity, which allows the derivation of suction. The volumetric strain of the specimen is calculated by analyzing digital photos captured from the outside of the transparent cell wall. Specimens made of kaolin clay, having different hydraulic properties, were tested to verify the reliability of the measurements, and thus, the relevance of the proposed techniques to study the mechanical behavior of unsaturated soils.

Deformation Analysis of Miniature Metal Bellows Charged Nitrogen for Temperature Change to Cryogenic Condition (극저온까지 온도변화에 따른 질소 충전 소형 금속 벨로우즈의 변형 해석)

  • Lee, Seung-Ha;Lee, Tae-Won
    • Journal of the Korean Society for Precision Engineering
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    • v.26 no.10
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    • pp.81-88
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    • 2009
  • Bellows is used to control temperature of a Joule-Thomson micro cryocooler. It is made of Nickelcobalt alloy that retains mechanical properties from cryogenic temperature to temperature of 570K. The geometry of bellows is an axisymmetric shell and Nitrogen with high pressure was charged at temperature of 293K. During cool-down process, the pressure and volume of Nitrogen are changed and must be satisfied with state equation. At cryogenic temperature, Nitrogen can exist as a part liquid and part vapor. Pressure-density-temperature behavior under this vaporliquid phase equilibrium is closely given by the Modified-Benedict-Webb-Rubin(MBWR) state equation. To evaluate deformation of bellows for temperature change, the numerical calculation of the volume within bellows and finite element analysis of bellows under internal pressure were iteratively performed until MBWR state equation is satisfied. The numerical results show that deformation of the bellows can be analyzed by the present method in a wide range of temperature including cryogenic temperature.

A Study on HEMT Device Process (Part II. Ohmic Contact Resistance in GaAs/AlGaAs Hetero-Structure) (HEMT소자 공정 연구 (Part II. HEMT 구조에서의 Online 접촉저항))

  • 이종람;이재진;박성호;김진섭;마동성
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.26 no.10
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    • pp.1545-1553
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    • 1989
  • The ohmic contact behavior in HEMT structure was compared with that in MESFET one throughout the specific contact resistance and microstructural change in both structures. A Au-Ge-Ni based metallization scheme was used and the alloying temperature of the ohmic materials was changed from 330\ulcorner to 550\ulcorner. The alloying temperature to obtain the minimum specific contact resistance in HEMT structure was 60k higher than that in MESFET. The volume fraction of NiAs (Ge) in MESFET structure increases with alloying temperature and/or the alloying time, which makes the decrease of specific contact resistance at the initial stage of ohmic metallization. In contrast, the volume fraction of NiAs(Ge) in HEMT structure was not dependent upon the specific contact resistance, which implies that the ohmic contacts are dominantly formed by the Ge diffusion to 2-DEG(two dimensional electron gas) layer.

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Study on Determining Consolidation Parameters of Soft Clay Ground Improved by Sand Pile (모래말뚝이 타설된 연약점토지반의 압밀정수결정에 관한 연구)

  • You, Seung-Kyong;Matsui, Tamotsu;Hong, Won-Pyo;Kim, Tae-Hyung
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.03a
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    • pp.264-271
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    • 2005
  • Sand pile method, such as sand drain method and sand compaction pile method, has been popularly used as an improvement method for soft clay grounds. The effect of accelerating consolidation of soft clay grounds has been evaluated with Barron's solution. By the way, the consolidation behavior of soft clay ground with sand piles strongly depends on both the nonlinear mechanical interaction between sand piles and surrounding clays and the degradation permeability of clays. In this paper, the method for determining consolidation parameters of soft clay ground with sand drains by using Barron's solution was proposed, through a series of numerical simulations. Through the method, the change in both volume compressibility and permeability during consolidation was reasonably evaluated.

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Finite Element Analysis of PSC Reactor Containment Vessels (프리스트레스트 콘크리트 원자로 격납고의 유한요소해석)

  • 송하원;최강룡;김경단;변근주
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2002.04a
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    • pp.377-384
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    • 2002
  • In this palter, a finite element technique is applied to both reinforced concrete and prestressed concrete containment vessels to predict the ultimate pressure capacity of the vessels subjected to internal pressure due to accident. The so-called volume-control technique is utilized to control the change in volume enclosed by the cylindrical containment vessels and layered shell elements equipped with a pressure node is utilizing to model the PSC vessels. The finite element analysis is carried out to obtain both global and local failure behavior of prestressed concrete nuclear containment vessels. nalytical results are verified by comparison with experimental data.

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The Influence of Temperature and Strain Rate on the Mechanical Behavior in Uranium

  • Lee, Key-Soon;Park, Won-Koo
    • Nuclear Engineering and Technology
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    • v.10 no.2
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    • pp.73-78
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    • 1978
  • The effect of temperature and strain rate on the deformation behavior of $\alpha$-uranium was investigated in the temperature ranged 300$^{\circ}$ to 55$0^{\circ}C$ by strain, rate change test. Strain rate sensitivity, activation volume, strain rate sensitivity exponent and dislocation velocity exponent were determined. The strain rate sensitivity exponent and dislocation velocity exponent were determined. The strain rate sensitivity exponent increases with strain below 40$0^{\circ}C$, while the exponent decreases with strain above 50$0^{\circ}C$. It is believed that the increase of strain rate sensitivity exponent with strain below 40$0^{\circ}C$ can be attributed to an increase in internal stress as a result of work hardening while decrease of the exponent with strain above 50$0^{\circ}C$ is due to predominance of thermal softening over work hardening because more slip, system are active in deformation above about 50$0^{\circ}C$.

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Application of Multi-Agent Transport Simulation for Urban Road Network Operation in Incident Case (유고상황 시 MatSIM을 활용한 도시부 도로네트워크 운영 분석)

  • Kim, Joo-Young;Yu, Yeon-Seung;Lee, Seung-Jae;Hu, Hye-Jung;Sung, Jung-Gon
    • International Journal of Highway Engineering
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    • v.14 no.4
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    • pp.163-173
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    • 2012
  • PURPOSES : The purpose of this study is to check the possibilities of traffic pattern analysis using MatSIM for urban road network operation in incident case. METHODS : One of the stochastic dynamic models is MatSIM. MatSIM is a transportation simulation tool based on stochastic dynamic model and activity based model. It is an open source software developed by IVT, ETH zurich, Switzerland. In MatSIM, various scenario comparison analyses are possible and analyses results are expressed using the visualizer which shows individual vehicle movements and traffic patterns. In this study, trip distribution in 24-hour, traffic volume, and travel speed using MatSIM are similar to those of measured values. Therefore, results of MatSIM are reasonable comparing with measured values. Traffic patterns are changed according to incident from change of individual behavior. RESULTS : The simulation results and the actual measured values are similar. The simulation results show reasonable ranges which can be used for traffic pattern analysis. CONCLUSIONS : The change of traffic pattern including trip distribution, traffic volumes and speeds according to various incident scenarios can be used for traffic control policy decision to provide effective operation of urban road network.

Improving buckling response of the square steel tube by using steel foam

  • Moradi, Mohammadreza;Arwade, Sanjay R.
    • Structural Engineering and Mechanics
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    • v.51 no.6
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    • pp.1017-1036
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    • 2014
  • Steel tubes have an efficient shape with large second moment of inertia relative to their light weight. One of the main problems of these members is their low buckling resistance caused from having thin walls. In this study, steel foams with high strength over weight ratio is used to fill the steel tube to beneficially modify the response of steel tubes. The linear eigenvalue and plastic collapse FE analysis is done on steel foam filled tube under pure compression and three point bending simulation. It is shown that steel foam improves the maximum strength and the ability of energy absorption of the steel tubes significantly. Different configurations with different volume of steel foam and composite behavior is investigated. It is demonstrated that there are some optimum configurations with more efficient behavior. If composite action between steel foam and steel increases, the strength of the element will improve, in a way that, the failure mode change from local buckling to yielding.

Wear Behavior of SUS304 Stainless Steels in Corrosive Environment (부식 환경에서 SUS304 스테인레스 강의 마모 거동)

  • Lee Kwang-Jin;Yoon Sang-Don;Koo Young-Pil;Kim Hyung-Ja
    • Tribology and Lubricants
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    • v.20 no.2
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    • pp.91-96
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    • 2004
  • Wear behavior of self-mated stainless steels in NaCl solution has been investigated. The experiment was done in the corrosive liquid of which NaCl concentration of $0\~3\%$ and temperature of $15\~90^{\circ}C$. Two kinds of wear type were observed: one is 'severe wear' type which shows gradually increasing wear volume with increasing sliding distances, the other is 'mild wear' type which shows change of wear rate from high value to low at transition distance. The specific wear rate in severe wear type was not sensitive to the liquid temperature and concentration of NaCl but stable at value of $1\times10^{-3}\;mm^3$ approximately.