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High Energy Density Germanium Anodes for Next Generation Lithium Ion Batteries (다음세대 리튬이온 배터리용 고에너지 밀도 게르마늄 음극)

  • Ocon, Joey D.;Lee, Jae Kwang;Lee, Jaeyoung
    • Applied Chemistry for Engineering
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    • v.25 no.1
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    • pp.1-13
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    • 2014
  • Lithium ion batteries (LIBs) are the state-of-the-art technology among electrochemical energy storage and conversion cells, and are still considered the most attractive class of battery in the future due to their high specific energy density, high efficiency, and long cycle life. Rapid development of power-hungry commercial electronics and large-scale energy storage applications (e.g. off-peak electrical energy storage), however, requires novel anode materials that have higher energy densities to replace conventional graphite electrodes. Germanium (Ge) and silicon (Si) are thought to be ideal prospect candidates for next generation LIB anodes due to their extremely high theoretical energy capacities. For instance, Ge offers relatively lower volume change during cycling, better Li insertion/extraction kinetics, and higher electronic conductivity than Si. In this focused review, we briefly describe the basic concepts of LIBs and then look at the characteristics of ideal anode materials that can provide greatly improved electrochemical performance, including high capacity, better cycling behavior, and rate capability. We then discuss how, in the future, Ge anode materials (Ge and Ge oxides, Ge-carbon composites, and other Ge-based composites) could increase the capacity of today's Li batteries. In recent years, considerable efforts have been made to fulfill the requirements of excellent anode materials, especially using these materials at the nanoscale. This article shall serve as a handy reference, as well as starting point, for future research related to high capacity LIB anodes, especially based on semiconductor Ge and Si.

An influence on some university students' drinking quality and the plan for cutting down on drinking (일부 대학생들의 음주량에 미치는 영향과 절주방안)

  • Kim, Seung-Dae;Kim, Myung-Gwan
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.9
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    • pp.221-227
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    • 2016
  • The purpose of this study is to investigate the effect of social factors and social stress with respect to alcohol consumption for university students and to provide basic data in efforts to develop educational method that teaches how to decrease alcohol consumption and deny demanding drinking. Questions concerning typical features and social stress from drinking were revised through 300 university students' self-recording surveys between April 8 and 9 in 2015. It consisted of 10 questions using a 4-point Likert scale. Moreover, the reliability of tool was Cronbach ${\alpha}=.82$. We used SPSS 18.0 and conducted frequency, ${\chi}^2$ and path analysis. If the frequency of drinking (B=.206, p<.001) gets low and the social stress from drinking is low (B=-.397, p<.001), the amount of drinking increases, particularly for men more than women (B=.169, p<.05). For women more than men (B=.274, p<.01), if monthly income is high (B=.178, p<.05) and stress from drinking is low (B=-.349, p<.01), the frequency of drinking is high. If the culture of practice in drinking has not formed voluntarily through education or publication, legal restriction that increases the cost of drinking has to be established, like smoking, to reduce the volume of drinking and promote moderation in drinking. The publication and education that teaches drinking leads to bad situations have to be conducted, much like the education programs involved for smoking. Also, discrimination of non-drinker has to be removed with the change of culture to reduce the stress by drinking.

An Economic Evaluation on the Direct Payment System for Environment-friendly Agriculture in Korea Using AGE Model (AGE모형을 이용한 친환경농업직불제의 경제적 성과계측)

  • Kim, Myung-Su;Lee, Young-Ho;Kim, Bae-Sung
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.10
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    • pp.39-45
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    • 2016
  • This study analyses the macroeconomic effects of the direct payment system (DPS) for environment-friendly agriculture in Korea. We utilized the applied general equilibrium model (AGE model) for the general agricultural sector as well as the environmentally-friendly agricultural sector. We considered several scenarios based on various direct payment amounts to measure and analyze economic impacts. Scenario 1 considers the current direct payment system. Scenario 2 examines an additional 5% increase from the direct payment amount in scenario 1. Scenario 3 reviews an increase of 10% in direct payment amount while Scenario 4 considers an additional increase of 15% compared with Scenario 1. Lastly, scenario 5 examines a 20% increase in direct payment amounts compared with scenario 1. In addition, the baseline considers conditions prior to the introduction of the direct payment system. The simulation analysis results show that capital formation, production volume, and labor productivity increased in the environment-friendly agricultural sector. In contrast, employment in the environment-friendly agricultural sector decreased. The price of environment-friendly agricultural products following the introduction of the DPS remain consistent with the price of environment-friendly agricultural product before introducing the DPS. This results from price elasticity of supply and demand are inelastic, and there is no change in the income of consumers during the analysis period. However, additional research is necessary for improvement of the model using complementary statistical data for the environmental-friendly agriculture sector.

The Value of Preoperative MRI and Bone Scan in Percutaneous Vertebroplasty for Osteoporotic Vertebral Compression Fractures (골다공증성 척추체 압박골절에 대한 경피적 척추성형술시 자기공명영상과 골 주사 검사의 의의)

  • Kim, Se Hyuk;Lee, Wan Su;Seo, Eui Kyo;Shin, Yong Sam;Zhang, Ho Yeol;Jeon, Pyoung
    • Journal of Korean Neurosurgical Society
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    • v.30 no.7
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    • pp.907-915
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    • 2001
  • Objective : Percutaneous vertebroplasty is often complicated by the presence of multiple fractures or non-localizing pain in the patients with osteoporotic vertebral fractures. The purpose of this study is to estimate the value of preoperative radiologic studies in the localization of symptomatic vertebrae and to determine the factors which can influence on the clinical results. Materials and Methods : We retrospectively reviewed the clinical and radiologic data of 57 vertebrae in 30 patients underwent percutaneous vertebroplasty for osteoporotic vertebral compression fractures. Inclusion criteria was severe pain(McGill-Melzack score 3, 4 or 5) associated with the acute vertebral fractures and absence of spinal nerve root or cord compression sign. Acute symptomatic vertebral fracture was determined by the presence of signal change on MR images or increased uptake on whole body bone scan. Results : Pain improvement was obtained immediately in all patients and favorable result was sustained in 26 patients(86.7%) during the mean follow-up duration of 4.7 months(5 complete pain relief, 21 marked pain relief). Those who underwent vertebroplasty for all acute symptomatic vertebrae had significantly better clinical result than those who did not. Further vertebral collapse and eventual bursting fracture occurred in 1 vertebra which showed intradiskal leakage of bone cement and disruption of cortical endplate on postoperative CT scan. Conclusion : Preoperative MR imaging and whole body bone scan are very useful in determining the symptomatic vertebrae, especially in the patients with multiple osteoporotic vertebral fractures. To obtain favorable clinical result, the careful radiologic evaluation as well as clinical assessment is required. Control of PMMA volume seems to be the most critical point for avoiding complications.

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Property Change of Heat-reservoir Refractory Brick With Varying Compositions and Sintering Conditions Utilizing Mill-scale and Red-firing Clay As Raw Materials (밀스케일과 적점토를 원료로한 축열재에서 원료성분과 소성조선에 따른 특성 변화)

  • Kim, Jeong-Seog;Kim, Hong
    • Resources Recycling
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    • v.8 no.1
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    • pp.23-28
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    • 1999
  • Firing characteristics, transverse rupture strength, and heat capacity were studied of the heat-reservoir refractory materials made of red-firing clay, mill scale, and water glass. The firing shrinkage increased with increase of the clay proportion in samples. The volume of fired bodies showed shrinkage by drying up to $300^{\circ}C$, steady expansion in the 300-$700^{\circ}C$ range due to phase transition of iron oxides. and drastic expansion above $1200^{\circ}C$. Flexural strength decreased from 5.6 Mpa to 2.35 Mpa with the decrease of the ratio of clay to mill scale from 1:1 to 1:3 Heat capacities changed from 1.1 Joul/g$^{\circ}$C to 1.35 Joul/g$^{\circ}$C with the ratio of millscale to clay ratio from 1:1 to 1:3. Mill scale in the specimen appears to exist as liquid phase during firing. Firing the specimens in air leads to the eruption of the molten mill scale to the sample surfaces. Contrarily, firing samples in a refractory sagger with a cover suppressed the eruption of the molten mill scale to the surfaces. The addition of mill scale gave rise to porous sintered bodies which would delay cooling rates of heat-reservoir brick.

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The Fundamental Properties of Foamed Concrete as the Eco-friendly Ground Repair System for Cast in Site Using the CSA (CSA를 사용한 친환경 지반보수용 현장 기포콘크리트의 기초 특성 검토)

  • Woo, Yang-Yi;Park, Keun-Bae;Ma, Young;Song, Hun-Young
    • Resources Recycling
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    • v.29 no.1
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    • pp.53-61
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    • 2020
  • This study aimed to develop a foam concrete material for a ground repair system that has low strength and low fluidity by using an eco-friendly binder, which substitutes industrial by-products for more than 90% of cement. Basic properties were evaluated after substituting a small amount of calcium sulfo aluminate (CSA) for the binder to improve the sinking depth rate and volume change, commonly found when it had a large amount of industrial by-products. The substitution rates of CSA for the eco-friendly binder used for the foam concrete were 2.5, 5, and 10%. Fresh properties, hardened properties, pore structure, and hydrates were analyzed. Experimental results showed that using only 2.5% of CSA could improve the deep sinking depth which occurred when using an eco-friendly binder. As a result, the weight difference between the upper, middle, and lower parts of cast specimens was improved even after being hardened. The addition of CSA also contributed to the formation of small, uniformly sized closed pores and improved initial strength. However, when the proportion of CSA increased, the long-term strength decreased. However, it satisfied the target strength when 5% or less of CSA was used. The results of this study revealed that it was possible to manufacture foam concrete with low strength and high fluidity for repairing ground satisfying target qualities by adding 2.5% of CSA to the eco-friendly binder containing a large amount of industrial by-products.

Study of Factors for development of Advanced Media filter for Ballast water Treatment (밸러스트 수 처리용 메디아 필터 개발을 위한 여과특성에 관한 연구)

  • Park, Seon-Jeong;Lim, Jae-Dong;Kim, Dong-Geun;Kim, In-Soo
    • Journal of Navigation and Port Research
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    • v.32 no.6
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    • pp.499-503
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    • 2008
  • As the conference result of MEPC in IMO, development of ballast water management system corresponding to newly established ballast water management standard (D2 regulation) of shipping is being made an active progress over the whole world. The ballast water management system should treat particular material of more than $10{\mu}m$ in high capacity of more than 500t per hour in the event of filtration process. Also, it is very difficult to develop a practical management system since a limited element which a narrow space of the ship should be designed in the minimal volume is assumed. Therefore, the study promoted a study on the next generation auto back wash media filter to overcome such a limited element. Also, the study performed pressure and flux measurement test followed by thickness of each filter medium for filtration by each size to grasp a relation between absorption and pressure at the time of vacuum filtration and mechanical analysis and turbidity change observation of filtered water after vacuum filtration.

Autologous Transfusion in Pregnant Women with Significant Risk for Hemorrhage (출혈위험 임산부에서의 자가수혈)

  • Kim, Gee-Deuk;Bae, Chul-Sung;Park, Yoon-Kee;Kim, Jong-Wook;Koh, Min-Whan;Lee, Sung-Ho
    • Journal of Yeungnam Medical Science
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    • v.7 no.1
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    • pp.95-103
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    • 1990
  • Autologous transfusion, storage of one's own blood for subsequent infusion if needed, is safe and effective in a variety of scheduled operative procedures. Obstetric involvement in such programs is very limited, however, because of concern over the possibility of inducing premature labor or causing fetal distress by blood volume change or vasovagal reactions. We describe our experience with pregnant women in this program. The incidence of vagovagal reactions of autologous donation was 9.5% (2/21). After entry into this program, 17pastients received a total 37pints, which consist of 19 Autologous and 18 Homologous. Homologous transfusion was avoided in 30% of patients receiving blood. The values of the mean haematocrits before and after hpebotomy were 34.1 % and 31.8 % respectively. It was statically significant(p<0.01). We recommended that autologous blood donation by pregnant women in third trimester is safe for mothers or infants and it should be strongly encouraged for patient with placenta previa and repeated cesarean section.

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Evaluation of Physical Properties of Resin Containing Zinc Nanoparticle. (아연나노입자함유 교정용 레진의 물리적 특성 평가)

  • Jo, Jeong-Ki
    • Journal of Digital Convergence
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    • v.17 no.10
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    • pp.373-379
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    • 2019
  • Polymethyl methacrylate (PMMA), a self-polymerizing resin for removable orthodontic devices, has been used as a dental orthodontic device for many years because of its advantages such as color stability, volume stability, and tissue compatibility. However, such a removable orthodontic device has a disadvantage that the longer the use in the oral cavity due to the low strength of the PMMA fracture of the orthodontic device resin in use. In this study, zinc nanoparticles (ZNP) were mixed with orthodontic PMMA to introduce strength effect. Rectangular samples ($1.4{\times}3.0{\times}19.0mm$) of orthodontic PMMA (0, 0.5, 1.0, 2.0 and 4.0%) containing ZNP were prepared. The finished specimen was tested for three-point bending strength at a speed of 1 mm / min, and the Vickers hardness was measured three times using a hardness tester. The surface roughness was measured with a surface roughness. As a result, the 3-point bending strength did not change significantly (p>0.05). Surface energy increased significantly. As a result, we successfully synthesized ZNP in this study and prepared the dispersed resin specimen for calibration. It will be possible to develop high-density dental orthodontic resins.

The Change of Soil Physicochemical Properties by Mixture Ratio of Inorganic Soil Amendments (무기성 토양개량제들의 혼합비율에 따른 토양이화학성의 변화)

  • Kim, Young-Sun;Kim, Tack-Soo;Ham, Suon-Kyu
    • Asian Journal of Turfgrass Science
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    • v.23 no.2
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    • pp.271-278
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    • 2009
  • This study was conducted to investigate the effect of the mixture ratio of the inorganic soil amendments on the soil physicochemical properties. In this experiment, three kinds of soil amendments which had similar pH, EC and particle size, the A, B and C, were tested. The mixture ratio of soil amendment were 0%, 3%, 5%, 7% and 10% (V/V) incorporated with sand which met to the USGA(United State of Golf Association) particle standard. To analyze the effects of amendment on chemical soil properties, pH, EC(electrical conductivity) and CEC(cation exchangeable capacity) were measured. The porosity, bulk density and hydraulic conductivity also measured to analyze the changes of physical properties. In the chemical properties, pH was significantly related to the mixture ratios of amendments, A and C(P<0.05), CEC and EC also related to the ratios of C(P<0.01). When the results were applied to the USGA standard of the soil physical properties, the optimum mixture ratios of each amendment were 3% in A and B, and 7~10% in C. To analyze the corelation of mixture ratio versus to physical character, volume of porosity was significantly related to the ratio of B (P<0.05), and showed similar corelation in porosity and hydraulic conductivity with ratio of C(P<0.05). These results indicate that types and mixture ratio of inorganic soil amendments should affect on soil physio-chemical properties of root zone on USGA sand green.