• 제목/요약/키워드: volatiles

검색결과 265건 처리시간 0.028초

Analysis of Fragrance Volatiles of Korean Rosa hybrida Using Gas Chromatography-Mass Spectrometry

  • Cho, Yong-Sik;Cho, In-Hee;Park, Hong-Ju;Chun, Hye-Kyung
    • Journal of Applied Biological Chemistry
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    • 제49권4호
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    • pp.180-185
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    • 2006
  • Two different extraction procedures, SDE and SPME, were employed to determine a comprehensive and efficient fragrance profile of Korean Rosa hybrida. Both extraction methods could compensate for each other, covering compounds with diverse boiling point, polarities, and chemical properties. A total of 46 compounds were identified in Mi-hyang. The identified compounds were composed of 17 alcohols, 14 carbonyls, 7 aliphatic hydrocarbons, 2 terpene hydrocarbons, 4 benzenes, 1 ester, and 1 miscellaneous compound. Quantitatively, carbonyls($12.96{\sim}21.79%$ in essential oils of SDE and $2.89{\sim}8.44%$ in SPME headspace) and alcohols($7.98{\sim}11.73%$ in essential oils of SDE and $3.39{\sim}17.35%$ in SPME headspace) were dominant in Mi-hyang's volatiles.

붉은 대게 가공부산물 농축중의 휘발성 향기성분 변화 (Changes in Volatile Flavor Compounds in Red Snow Crab Chionoecetes japonicus Cooker Effluent during Concentration)

  • 안준석;조우진;정은정;차용준
    • 한국수산과학회지
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    • 제39권6호
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    • pp.437-440
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    • 2006
  • To develop natural crab-like flavorants from red snow crab Chionoecetes japonicus cooker effluent (RSCCE), the flavor was analyzed during the concentration of RSCCE up to $40^{\circ}Brix$. Using solid phase microextraction (SPME)/gas chromatography (GC)/mass selective detection (MSD), 30 volatile flavor compounds were detected in four RSCCE samples (10, 20, 30, and $40^{\circ}Brix$). These comprised 12 aromatic compounds, 5 N-containing compounds, 2 5-containing compounds, 2 alcohols, 2 aldehydes, and 7 miscellaneous compounds. The amounts of all volatiles except alcohols and aldehydes increased significantly with the concentration (p<0.05). Of the volatiles detected, the most abundant was a dimethyl trisulfide with an odor like onion/cooked cabbage. Of the N-containing compounds (nutty, roasted peanut-like odor), 2-ethyl-5-methylpyrazine was the most abundant, followed by 2,5-dimethylpyrazine and 2-methyl-5-isopropylpyrazine in that order (p<0.05). The N- and S-containing compounds with characteristic odors detected in this experiment are thought to play a positive role in RSCCE during concentration.

Quality Comparison of Activated Carbon Produced From Oil Palm Fronds by Chemical Activation Using Sodium Carbonate versus Sodium Chloride

  • MAULINA, Seri;HANDIKA, Gewa;Irvan, Irvan;ISWANTO, Apri Heri
    • Journal of the Korean Wood Science and Technology
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    • 제48권4호
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    • pp.503-512
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    • 2020
  • Using Na2CO3 versus NaCl as chemical activator, we compared the quality of activated carbon produced from oil palm fronds as raw material. These activators were selected for comparison because both are readily available and are environmentally friendly. In the manufacturing, we used Indonesian National Standard (SNI 06-3730-1995) parameters. For the quality comparison, we determined activated-carbon yield, moisture, ash, volatiles, and fixed-carbon contents; and adsorption capacity of iodine. The best characteristics, assessed by morphological surface analysis and Fourier transform infrared (FTIR) spectral analysis, were observed in the carbon activated by Na2CO3 at an activator concentration of 10% and carbonization temperature of 400 ℃. The results were as follows: activated-carbon yield, 84%; water content, 8.80%; ash content, 2.20%; volatiles content, 14.80%; fixed-carbon content, 68.60%; and adsorption capacity of iodine, 888.51 mg/g. Identification using the FTIR spectrophotometer showed the presence of the functional groups O-H, C=O, C=C, C-C, and C-H in the Na2CO3-activated carbon.

Effects of Photooxidation and Chlorophyll Photosensitization on the Formation of Volatile Compounds in Lard Model Systems

  • Lee, Jae-Hwan;Min, David B.
    • Food Science and Biotechnology
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    • 제18권2호
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    • pp.413-418
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    • 2009
  • Effects of chlorophyll and visible light exposure on the volatile formations and headspace oxygen content were studied in lard model systems at $55^{\circ}C$. Samples with or without addition of chlorophyll under light underwent photosensization or photooxidation, respectively. Total volatiles (TI) in lard with 5 ppm chlorophyll photosensization were 19 times higher than those in visible light photooxidized samples for 48 hr while TI in lard with chlorophyll in the dark were not significantly different from those in photooxidized samples (p>0.05). Headspace oxygen content in photosensitized lard decreased from 21 to 15% for 48 hr but that in photooxidized lard or that in lard with chlorophyll in the dark did not change significantly (p>0.05), which indicates that lard system used in this study is a photosensitizer-free model system and the presence of chlorophyll accelerated the lipid oxidation only under visible light. Oxidation mechanisms of photooxidation with or without presence of photosensitizers under visible light were not the same based on the difference of oxidized volatile profiles and headspace oxygen depletion.

캐러웨이 Sulfhydryl Oxidase를 이용한 십자화과 채소의 함황 불쾌취 억압 (Suppression of Undesirable Sulfurous Aromas of Cruciferous Vegetables with Caraway Sulfhydryl Oxidase)

  • 심기환
    • 한국식품과학회지
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    • 제22권5호
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    • pp.555-561
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    • 1990
  • 십자화과의 양배추와 브로콜리에서 함황 휘발성분 함량과 캐러웨이 종자의 sulfhydryl oxidase를 이용한 십자화과 채소의 함황 불쾌취 억압을 FID와 FPD가 동시에 연결된 개스 크로마토그래피로써 조사하였다. 양배추와 브로콜리에서 생성되는 휘발성 유황화합물은 캐러웨이 종자의 첨가량과 항온처리 시간에 따라 함량 및 생성률에 차이가 있었는데, 양배추와 브로콜리에 캐러웨이 종자를 첨가한 것이 대조구보다 methanethiol과 dimethyl disulfide 생성량이 훨씬 적었다. 또한 thiol oxidase 활성을 가진 캐러웨이 종자의 액상 슬러리를 이용하여 methanethiol과 dimethyl disulfide를 제거하는데 효과가 있었으며, 이들의 제거율은 캐러웨이 종자의 첨가량에 비례하였고, 특히 2.5% 캐러웨이 종자를 함유한 액상슬러리에서 효과적이었다.

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휘발성(揮發性) Warmed-Over Flavor의 연구(硏究)를 위한 변형(變形)된 Direct Sampling GLC법(法) (Modified Direct-Sampling GLC Method to Study Warmed-Over Flavor Related Volatiles)

  • 신승이;이종욱
    • 한국식품과학회지
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    • 제22권5호
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    • pp.562-568
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    • 1990
  • 조리(調理) 육류(肉類)의 WOF와 관련(關聯)된 휘발성(揮發性) 성분(成分)을 분석(分析)하기 위하여 변형(變形)된 Direct GLC 방법(方法)을 이용(利用)하였다. 이 변형(變形)된 방법(方法)은 기존(旣存)의 다른 방법(方法)과는 달리 수분함량(水分含量)이 많은 시료(試料)로부터 휘발성(揮發性) 성분(成分)을 분리(分離)하는데 유용(有用)하였으며, 특히 저분자량(低分子量)의 포화(飽和) $aldehyde\;(C_c-C_{15})$류(類), 불포화(不飽和)$aldehyde(C_5{\sim}C_9)$류(類)의 연구(硏究)에 적절한 것으로 판명(判明)되었다.

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과실쥬스의 동결건조 중 휘발성분 보유력 (Volatile Retention during Freeze Drying of Fruit Juices)

  • 심기환;최진상;주옥수;강갑석
    • 한국식품영양과학회지
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    • 제19권6호
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    • pp.555-564
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    • 1990
  • 과실쥬스와 같은 자연 생산물의 동결건조에 있어서 가공처리중 휘발성분의 보유력 변화를 알아보기 위하여 headspace gas chromatography 기술의 특징을 이용하여 동결건조 속도, 초기 고형물의 함량 및 압력 등이 어떠한 영향을 미치는가에 대한 실험결과는 다음과 같다. 동결건조 속도가 휘발성분의 보유력에 대한 영향은 현저하였으며, 동결시간이 길수록 뚜렷하였다. 동결 건조 제품에서 휘발성분의 보유력은 동결에 의해 영향을 받았다. 동결건조 조건하에서 가장 많은 휘발성분의 손실은 동결건조 초기단계, 즉 1~2 시간 사이에서 일어났다. 휘발성분의 보유력은 초기 고형물의 함량이 많을수록 높았다. 동결속도가 빠를 때보다는 늦을 때가 휘발성분의 보유력이 높았으며 높은 압력에서보다 낮은 압력에서 높았다.

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Regenerability of a Ni catalyst in the catalytic steam reforming of biomass pyrolysis volatiles

  • Arregi, Aitor;Lopez, Gartzen;Amutio, Maider;Barbarias, Itsaso;Santamaria, Laura;Bilbao, Javier;Olazar, Martin
    • Journal of Industrial and Engineering Chemistry
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    • 제68권
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    • pp.69-78
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    • 2018
  • A study has been carried out of the regenerability of a commercial Ni catalyst used in the steam reforming of the volatiles from biomass pyrolysis (gases and bio-oil), determining the evolution of the reaction indices (conversion, product yields and $H_2$ production) in successive reaction-regeneration cycles. The causes of catalyst deactivation (coke deposition and Ni sintering) have been ascertained characterizing the deactivated and regenerated catalysts by TPO, TEM, TPR and XRD. Catalyst activity is not fully recovered by coke combustion in the first cycles due to the irreversible deactivation by Ni sintering, but the catalyst reaches a pseudo-stable state beyond the fourth cycle, reproducing its behaviour in subsequent cycles.

Tobacco Growth Promotion by the Entomopathogenic Fungus, Isaria javanica pf185

  • Lee, Yong-Seong;Kim, Young Cheol
    • Mycobiology
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    • 제47권1호
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    • pp.126-133
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    • 2019
  • Isaria javanica pf185 is an important entomopathogenic fungus with potential for use as an agricultural biocontrol agent. However, the effect of I. javanica pf185 on plant growth is unknown. Enhanced tobacco growth was observed when tobacco roots were exposed to spores, cultures, and fungal cell-free culture supernatants of this fungus. Tobacco seedlings were also exposed to the volatiles of I. javanica pf185 in vitro using I-plates in which the plant and fungus were growing in separate compartments connected only by air space. The length and weight of seedlings, content of leaf chlorophyll, and number of root branches were significantly increased by the fungal volatiles. Heptane, 3-hexanone, 2,4-dimethylhexane, and 2-nonanone were detected, by solid-phase micro-extraction and gas chromatography-mass spectrophotometry, as the key volatile compounds produced by I. javanica pf185. These findings illustrate that I. javanica pf185 can be used to promote plant growth, and also as a biocontrol agent of insect and plant diseases. Further studies are necessary to elucidate the mechanisms by which I. javanica pf185 promotes plant growth.