• Title/Summary/Keyword: volatile sulfur compounds

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A Before and After Study about the Effects of Korean Medical Treatment on Halitosis Patients: Using OralChroma$^{TM}$ (구취 환자의 한방 치료 효과에 대한 전.후 비교 연구: OralChroma$^{TM}$를 이용하여)

  • Choi, Jane;Kim, Jin-Sung;Jang, Seung-Won;Son, Ji-Yeong;Baek, Seung-Hwan;Han, Seong-Jun;Lee, Eom-Jee;Ryu, Bong-Ha
    • The Journal of Internal Korean Medicine
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    • v.35 no.4
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    • pp.532-545
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    • 2014
  • Objectives: The purpose of this study was to evaluate the clinical effect of Korean medical treatments such as herbal medicine, acupuncture, and electroacupuncture by using the portable gas chromatograph OralChroma$^{TM}$ (Abimedical, Japan) in halitosis patients. Methods: We surveyed 30 halitosis patients who had visited the Oral Diseases Clinic in the Korean Medical Hospital of Kyunghee University from October, 2013 to November, 2014. Before starting Korean medical treatment, the subjects were evaluated on sociodemographic characteristics, severity of discomfort using visual analogue scale (VAS), unstimulated salivary flow rate (USFR), and halitosis associated life-quality test (HALT) score. To evaluate the therapeutic effect, we measured the volatile sulfur compounds (VSCs) in breath by using OralChroma$^{TM}$ before and after 3 weeks treatment. Results: The concentration of total VSCs measured by OralChroma$^{TM}$ significantly decreased (p=0.001). Furthermore, the level of hydrogen sulfide and methyl mercaptan also significantly decreased (p<0.05). However, although the level of dimethyl sulfide decreased as well, there was no significance(p>0.05). Conclusions: Korean medical treatment was effective in treating halitosis by decreasing VSCs. Further study, with well-designed randomized controlled trials with larger number of cases will be needed in the future.

The Effects of Tongue Coating on Volatile Sulfur Compounds Production in the Oral Malodor Patients (구취 환자에서 설태가 휘발성 황화합물의 생성에 미치는 영향에 관한 연구)

  • Lee, Hun;Lee, Seung-Ryeul;Kim, Young-Ku
    • Journal of Oral Medicine and Pain
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    • v.26 no.3
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    • pp.243-252
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    • 2001
  • 본 연구에서는 구강 내 공기 중 설태 제거 전후의 휘발성 황화합물 농도를 gas chromatography를 이용하여 비교 분석하였다. 피검자로는 서울대학교 치과병원 구취클리닉에 내원한 환자 중에서 치주 건강 상태가 양호하며 구취를 호소하는 환자 18 명(평균연령 31.4세; 남자 8명, 여자 10명)을 대상으로 하였으며 구취를 측정하기 전에 모든 피검자들은 실험 전날 취침 전부터 실험 당일 실험시작 전까지 음식 섭취나 양치질 등의 모든 구강 활동을 금지하였다. 구취 시료는 채취 전에 피검자로 하여금 3분간 입을 다물게 한 후 입을 약 2cm정도 벌린 상태에서 시행하였으며 시료 채취 후 설태를 제거하였다. 설태 제거 후에 구강 내 공기를 다시 채취한 후 gas chromatography를 통하여 휘발성 황화합물의 각 성분별 농도를 분석하였다. 분석과정에서는 과거에 휘발성 황화합물의 검출 시 사용되어진 sampling loop와 isothermal run condition 대신 좀더 효율적인 직접표본주입방법과 oven temperature programmed analysis를 시행하였다. 1. 전체 휘발성 황화합물은 Hydrogen sulfide (59.96%), Methyl mercaptan (25.08%), Dimethyl sulfide (14.96%)로 구성되었다. 이 중 Hydrogen sulfide는 전체 휘발성 황화합물중 약 60%를 차지하여 치주상태가 양호한 구취환자에서의 주요한 구취 구 성 성분이었다. 2. 설태 제거 후 전체 휘발성 황화합물의 농도감소는 제거 전에 비하여 41.71%로 유의 하게 감소하였다(p<0.01). 3. 설태 제거 후에 Hydrogen sulfide의 농도감소는 43.62% (p<0.01), Methyl mercaptan 의 농도감소는 38.88% (p<0.05), 그리고 Dimethyl sulfide의 농도감소는 30.21% (p<0.01)로 각각 유의하게 감소하였다. 4. 전체 휘발성 황화합물의 구성비율은 설태 제거 전후에 유의한 차이가 없었다 (p>0.05).

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Effect of Bad Breath on Olfactory Identification Ability and on Olfactory Detection Threshold for CH3SH (구취가 후각인지도 및 methyl mercaptan에 대한후각감지역치에 미치는 영향)

  • Do, Young-Hwan;Choi, Jae-Kap;Ahn, Hyoung-Joon
    • Journal of Oral Medicine and Pain
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    • v.26 no.4
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    • pp.309-318
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    • 2001
  • The purposes of the study were (1) to evaluate the olfactory identification ability in those who have bad breath, (2) to determine the olfactory detection threshold for methyl mercaptan in normal subjects and those who have bad breath, and (3) to evaluate the effect of oral hygiene care on the olfactory detection threshold for methyl mercaptan. Sixteen male subjects with bad breath (male odor group), 9 male subjects without bad breath (male non-odor group), and 10 female subjects without bad breath (female non-odor group) were included for the study. Olfactory identification ability was assessed by administrating the Cross-Cultural Smell Identification Test (CC-SIT), and the olfactory detection threshold for methyl mercaptan was measured by two-alternative forced-choice single-staircase detection threshold procedure in a double-blinded condition. The geometric mean of the last four staircase reversal points of a total of seven reversals is used as the threshold. For the male odor group, after 1 month of intensive oral hygiene care for reducing oral volatile sulfur compounds (VSC) concentration, the olfactory detection threshold for methyl mercaptan was measured again and compared to the initial value. The ANOVA was used to test the group difference of olfactory threshold and olfactory identification ability and the paired t-test was used to test the difference of olfactory threshold between before and after reduction of oral VSC in male odor group. The results were as follows : 1. There was no significant difference in olfactory identification ability among those who have bad breath and normal male or female subjects. 2. The olfactory detection threshold for methyl mercaptan was about 8.4 ppb in normal male and female. 3. There was a tendency that male subjects with bad breath showed a higher olfactory detection threshold for methyl mercaptan when compared to those of no bad breath. 4. The olfactory detection threshold for methyl mercaptan returned to a normal level after 1 month of intensive oral hygiene care for reducing oral VSC.

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Odor Emission from Sediments in Sewer Systems and Odor Removal using an Electrolytic Oxidation Process (하수관거에 퇴적된 유기물에 의한 악취 발생과 산화전리시스템을 이용한 악취 저감)

  • Ahn, Hae-Young;Shin, Seung-Kyu;Song, Ji-Hyeon
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.6
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    • pp.703-710
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    • 2011
  • Odor emission from domestic sewer systems has become a serious environmental problem. An investigation on a sewer manhole revealed that anaerobic decay of sediment organic matters (SOMs) and related declines of oxidation reduction potential (ORP) in the sediment layer were the main reason of the production of volatile sulfur compounds. In addition, as the anaerobic decaying period continued, the odor intensity rapidly increased with increasing concentrations of $H_2S$ and dimethyl sulfide. As a feasible method to control SOMs and to minimize odor emission potentials, an electrolytic oxidation process has been employed to the sediment sludge phase. In this study, voltages applied to the electrolytic oxidation process were varied as a main system parameter, and its effects on odor removal efficiencies and reaction characteristics were investigated. At the applied voltages greater than 20 V, the system efficiently oxidized the organic matter, and the ORP in the sludge phase increased rapidly. As a consequence, the removal efficiency of hydrogen sulfide was found to be >99% within 60 minutes of the electrolytic oxidation. Overall, the electrolytic oxidation process can be an alternative to control odor emission from sewer systems, and a threshold input energy needs to be determined to achieve effective operation of the process.

Association Between Halitosis and Periodontal Disease Related Parameters in Dogs (개에서 구취와 치주질환 지표의 상관성에 관한 연구)

  • Kim, Se-Eun;Shim, Kyung-Mi;Yoo, Kyeong-Hoon;Ryu, Ji-Won;Koh, Hong-Bum;Moon, Chang-Jong;Kim, Jong-Choon;Kim, Sung-Ho;Kang, Seong-Soo;Bae, Chun-Sik
    • Journal of Veterinary Clinics
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    • v.24 no.2
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    • pp.192-196
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    • 2007
  • Oral malodor in companion animals is noticed by owners at first and it makes owners unpleasant. Therefore oral malodor affects the relationship between pet and owner. Oral malodor is produced by some putrefactive bacteria which putrefy proteins to volatile sulfur compounds (VSC) such as methyl mercaptan, hydrogen sulfide and dimethyl sulfide in the food remnants. And oral malodor is mostly consisted with these VSC. On oral examinations in dogs with oral malodor, it is common that plaque and calculus index were increased than normal dogs'. But organoleptic method is subjective to evaluate halitosis, in this study we measured VSC using organoleptic method and portable sulfide monitor to clarify the relationship between halitosis and periodontal disease in dogs with halitosis. And we found that plaque index and calculus index were significantly related with VSC (P<0.05, P<0.05) in measurement using Halimeter. However there was not significant relationship between gingivitis index and VSC. In conclusion, there was the significant, positive relationship between periodontal disease and halitosis.

Emission Characteristics of Air Pollutants and Black Carbon from Wood-pellet Stove and Boiler (목재 펠릿 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성)

  • Park, Sung Kyu;Lyu, Kun Jung;Kim, Daekeun;Kim, Dong Young;Jang, Young Kee;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.6 no.1
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    • pp.41-47
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    • 2015
  • This study was carried out simulating domestic utilization conditions of a wood pellet stove and a wood pellet boiler in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the pellet stove were: for TSP 4.58 g/kg, for $PM_{10}$ 3.35 g/kg, for $PM_{2.5}$ 2.48 g/kg, CO 119.23 g/kg, NO 14.40 g/kg, $SO_2$ 0.17 g/kg, TVOC 37.73 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the pellet boiler appliance: for TSP 4.73 g/kg, for $PM_{10}$ 3.41 g/kg, for $PM_{2.5}$ 2.63 g/kg, CO 161.51 g/kg, NO 13.67 g/kg, $SO_2$ 0.19 g/kg, TVOC 45.22 g/kg, $NH_3$ 0.02 g/kg.

Emission Characteristics of Air Pollutants and Black Carbon from Wood Stove and Boiler (화목 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성)

  • Park, Sung Kyu;Choi, Sang Jin;Kim, Dae keun;Kim, Dong Young;Jang, Young Kee;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.6 no.1
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    • pp.49-54
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    • 2015
  • Manually fed firewood burning appliances, i.e., stove and boiler, were tested in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the wood stove were: for TSP 15.45 g/kg, for $PM_{10}$ 6.53 g/kg, $PM_{2.5}$ 4.16 g/kg, CO 175.49 g/kg, NO 1.58 g/kg, $SO_2$ 0.15 g/kg, TVOC 48.02 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the wood boiler appliance: for TSP 12.23 g/kg, for $PM_{10}$ 5.84 g/kg, $PM_{2.5}$ 3.66 g/kg, CO 146.74 g/kg, NO 1.42 g/kg, $SO_2$ 0.15 g/kg, TVOC 47.78 g/kg, $NH_3$ 0.01 g/kg.

Effects of water temperature for oral rinse and the use of toothpastes and tongue cleaners on halitosis (잇솔질 시 양칫물 온도, 치약 사용, 혀클리너 사용에 따른 구취의 영향)

  • Hwang, Soo-Jeong;Jung, Yoon-Zy;Lee, Soo-Kyoung;Lee, Ji-Eun;Lee, Hee-So;Jeon, Hee-Ju;Kim, Do-Kyeong
    • Journal of Korean Academy of Dental Administration
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    • v.7 no.1
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    • pp.44-49
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    • 2019
  • Halitosis is primarily caused by oral conditions. In particular, volatile sulfur compounds (VSCs) are mainly responsible for intra-oral halitosis. They are closely associated with the water temperature. In this study, we investigated the association between halitosis and water temperature for oral rinse (10℃, 30℃, and 45℃) using the BB checker and oral chroma. The application of BB checker on an empty stomach revealed that halitosis decreased with the use of tongue cleaners (p=0.001) and toothpastes (p=0.002). Furthermore, halitosis decreased after drinking milk (VSCs-induced food intake) (p=0.000). There were no significant differences in the results of oral chroma. Finally, we measured halitosis on an empty stomach and after drinking milk. The BB checker showed increased halitosis after drinking milk (p<0.001). The oral chroma showed decreased hydrogen sulfide (p<0.001) and increased methyl mercaptan (p=0.009) and dimethyl sulfide (p=0.002) after drinking milk. In conclusion, halitosis cannot be modulated using water temperature for oral rinse. The findings of this study cannot be generalized because of the small sample size and the limits of age and sex. Further studies are required to extensively analyze both sexes and various age groups, with more number of subjects.

Design and Function Analysis of Dust Measurement Platform based on IoT protocol (사물인터넷 프로토콜 기반의 미세먼지 측정 플랫폼 설계와 기능해석)

  • Cho, Youngchan;Kim, Jeongho
    • Journal of Platform Technology
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    • v.9 no.4
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    • pp.79-89
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    • 2021
  • In this paper, the fine dust (PM10) and ultrafine dust (PM2.5) measurement platforms are designed to be mobile and fixed using oneM2M, the international standard for IoT. The fine dust measurement platform is composed and designed with a fine dust measurement device, agent, oneM2M platform, oneM2M IPE, and monitoring system. The main difference between mobile and fixed is that the mobile uses the MQTT protocol for interconnection between devices and services without blind spots based on LTE connection, and the fixed uses the LoRaWAN protocol with low power and wide communication range. Not only fine dust, but also temperature, humidity, atmospheric pressure, volatile organic compounds (VOC), carbon monoxide (CO), sulfur dioxide (SO2), nitrogen dioxide (NO2), and noise data related to daily life were collected. The collected sensor values were managed using the common API provided by oneM2M through the agent and oneM2M IPE, and it was designed into four resource types: AE and container. Six functions of operability, flexibility, convenience, safety, reusability, and scalability were analyzed through the fine dust measurement platform design.

Air Pollution Trends in Japan between 1970 and 2012 and Impact of Urban Air Pollution Countermeasures

  • Wakamatsu, Shinji;Morikawa, Tazuko;Ito, Akiyoshi
    • Asian Journal of Atmospheric Environment
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    • v.7 no.4
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    • pp.177-190
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    • 2013
  • Air pollution trends in Japan between 1970 and 2012 were analyzed, and the impact of air pollution countermeasures was evaluated. Concentrations of CO decreased from 1970 to 2012, and in 2012, the Japanese environmental quality standard (EQS) for CO was satisfied. Concentrations of $SO_2$ dropped markedly in the 1970s, owing to use of desulfurization technologies and low-sulfur heavy oil. Major reductions in the sulfur content of diesel fuel in the 1990s resulted in further decreases of $SO_2$ levels. In 2012, the EQS for $SO_2$ was satisfied at most air quality monitoring stations. Concentrations of $NO_2$ decreased from 1970 to 1985, but increased from 1985 to 1995. After 1995, $NO_2$ concentrations decreased, especially after 2006. In 2012, the EQS for $NO_2$ was satisfied at most air quality monitoring stations, except those alongside roads. The annual mean for the daily maximum concentrations of photochemical oxidants (OX) increased from 1980 to 2010, but after 2006, the $98^{th}$ percentile values of the OX concentrations decreased. In 2012, the EQS for OX was not satisfied at most air quality monitoring stations. Non-methane hydrocarbon (NMHC) concentrations generally decreased from 1976 to 2012. In 2011, NMHC concentrations near roads and in the general environment were nearly the same. The concentration of suspended particulate matter (SPM) generally decreased. In 2011, the EQS for SPM was satisfied at 69.2% of ambient air monitoring stations, and 72.9% of roadside air-monitoring stations. Impacts from mineral dust from continental Asia were especially pronounced in the western part of Japan in spring, and year-round variation was large. The concentration of $PM_{2.5}$ generally decreased, but the EQS for $PM_{2.5}$ is still not satisfied. The air pollution trends were closely synchronized with promulgation of regulations designed to limit pollutant emissions. Trans-boundary OX and $PM_{2.5}$ has become a big issue which contains global warming chemical species such as ozone and black carbon (so called SLCP: Short Lived Climate Pollutants). Cobeneficial reduction approach for these pollutants will be important to improve both in regional and global atmospheric environmental conditions.