• Title/Summary/Keyword: voids

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Sensitivity of NOx Removal on Recycled TiO2 in Cement Mortar (재생 이산화티탄을 혼입한 모르타르의 NOx 저감률 민감도 분석)

  • Rhee, Inkyu;Kim, Jin-Hee;Kim, Jong-Ho;Roh, Young-Sook
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.4
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    • pp.388-395
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    • 2016
  • This paper explores the photocatalytic sensitivity of cement mortar incorporated with recycled $TiO_2$ from waste water sludge. Basically, $TiO_2$ cluster sank down slowly to the bottom of cement mortar specimen before setting and hardening process. This leads the mismatch of $TiO_2$ concentration on the top and the bottom faces of a specimen. This poorly dispersed $TiO_2$-cement mortar naturally exhibits poor NOx removal efficiency especially on the top of cementitious structure. In architectural engineering application such as building or housing structures, one can simply filp over from the bottom so that more $TiO_2$ concentrated surface can be placed outward into the air. However, in highway pavement case, this could not be applicable due to in-situ installation of concrete pavement. Hence, the dispersion of $TiO_2$ cluster inside the cementitous material is getting important issue onto road construction application. To elaborate this issue, according to our results, silica fume, high-ranged water reducer, viscosity agent, blast furnace slag were not enhanced much of dispersion characteristics of $TiO_2$ cluster. The combination of foaming agent and accelerator of hardening with viscosity agent and small grain size of fine aggregate may help the dispersion of $TiO_2$ inside cementitious materials. Even though the enhanced dispersion were applied to the specimen, NOx removal efficiency doest not change much for the top surface of the specimen. This concurrently affected by the presence of tiny air voids and the dispersion of $TiO_2$ in that these voids could easily adsorbed NOx gas with the aid of large surface area.

Effects of Fiber Surface Modification on the Flow Characteristics and Wettability in the Resin Transfer Molding Process (섬유의 표면개질이 수지이동 성형공정에서의 유동특성 및 젖음성에 미치는 영향)

  • 김세현;이건웅;이종훈;김성우;이기준
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.34-43
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    • 1999
  • Flow-induced voids during resin impregnation and poor fiber wetting have known to be highly detrimental to the performance of composite parts manufactured by resin transfer molding(RTM) process. In this study, in order to overcome these serious problems encountered in RTM, the effects of surface modification by using silane coupling agent as a surface modifier on the flow characteristics, the wetting between resin and fiber, and void content were investigated. For the experiments of microscopic flow visualization and curing in a beam mold, glass fiber mats having plain weaving structure and epoxy resin were used. Modifying the fiber surface was found to result in a significant decrease of dynamic contact angle between resin and fiber and increase of wicking rate. Therefore, it was confirmed that the surface modification employed in this study could improve the wettability of reinforcing fibers as well as micro flow behavior. In addition, It was revealed that high temperature and low penetration rate of the resin are more favorable processing conditions to reduce the dynamic contact angle. However, surface modified fiber mat was found to have lower permeability than the unmodified one, which may be explained in terms of the decrease of contact time between resin and fiber owing to improvement of wetting. It was also exhibited that surface modification had a significant influence on void formation in RTM process, resulting in a decrease of overall void content due to the improvement of wetting in cured composite parts.

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Radiologic Findings of Cervical Mass Type Cervical Pregnancy (자궁경부 종괴형 자궁경부임신의 영상 소견)

  • Cho, Jae-Ho
    • Journal of Yeungnam Medical Science
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    • v.22 no.1
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    • pp.43-51
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    • 2005
  • Background: To examine the ultrasonographic and magnetic resonance (MRI) imaging findings of a cervical mass type cervical pregnancy. Materials and Methods: The ultrasonographic and MRI findings of 5 patients pathologically confirmed as having a cervical pregnancy were analyzed retrospectively. On ultrasonography, the size and echo pattern of the uterine cervix, the shape and echo pattern of the lesion, the degree and the pattern of blood flow on the color Doppler study and the spectral Doppler pattern were analyzed. The shape, signal intensity, and degree and pattern of enhancement of the lesion were evaluated on MRI. Results: The uterine cervix was enlarged and the size of the lesion was 6.1 to 7.1 (average, 6.5) cm. The endocervical canal was irregularly dilated and showed heterogeneous echogenicity in all 5 cases. Four of the 5 lesions were heterogeneously hyper- or mixed echoic and remaining one was relatively homogeneous echogenic. Doppler ultrasonography revealed an increased vascularity of the peritrophoblastic flow pattern. In all 4 cases where MRI performed, the lesion was irregular in shape and the margin was not sharply demarcated. The T2-weighed image showed that the lesions were mixed signal intensity. Three of the 4 lesions contained high signal intensity nodular portions and a low signal intensity rim was observed along the margin of the nodular portions. The T1-weighted image revealed multiple signal voids along the periphery of the lesions and high signal intensity portions as a result of hemorrhage were noted. The dynamic enhanced study showed that the high signal intensity portions on the T2-weighted image were strongly enhanced similar to the vessels on the early phase and the contrast enhancement gradually decreased with time. Conclusion: A cervical mass type cervical pregnancy can be correctly diagnosed using the patient's clinical symptom, the elevation in the serum ${\beta}$-HCG level, and characteristic ultrasonographic and MRI findings.

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A Change of Porewater Pressure under Particle Crushing of Carbonate Sand of Sabkha Layer (Sabkha층 탄산질 모래의 입자파쇄에 따른 간극수압 변화)

  • Kim, Seok-Ju;Yi, Chang-Tok;Ji, Won-Baek;Han, Heui-Soo
    • Journal of the Korean Geotechnical Society
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    • v.30 no.2
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    • pp.19-32
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    • 2014
  • Carbonate sand of Sabkha layer in the middle east was made of deposition of shell fragments and it consisted of porous particles containing inner void. Generally, at yield stress the soil structure begins to break down, so the porewater pressure and the settlement are increased rapidly. In carbonate sand, unlike quartz sand if particle crushing happens, the inner voids are exposed and porewater pressure can be decreased under yield stress. Porewater pressure can be determined as the sum of excess porewater pressure due to increase of relative density, inner void expose of particle under particle crushing stress and rearrangement of crushed particle fragments. The porewater pressure can be negative value in case of greater amount of inner void expose, so if particle crushing is bigger, the porewater pressure value is smaller. The negative value zone of porewater pressure from triaxial test result means particle crushing effect is bigger than outer void decrease effect and the particle crushing effect dominant zone size was 1.50∼3.46% from triaxial test result of Sabkha layer.

Preliminary Hydrological Design for Sand Dam Installation at the Valley of Seosang-ri, Chuncheon (춘천 서상리 계곡부 샌드댐 설치를 위한 수문학적 예비 설계)

  • Chung, Il-Moon;Lee, Jeongwoo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.39 no.6
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    • pp.725-733
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    • 2019
  • Sand dams are structures that can be used as auxiliary water resources in case of drought as sand accumulates due to barriers crossing valley rivers and valley water is stored in the voids, increasing the water level. This structure, which is mainly used in arid regions such as Africa, has not been installed in Korea. In Korea, there are only a few cases where water is taken from debris barriers that prevent debris flow. The purpose of this study is to evaluate the effect of water supply when the sand dam is installed downstream of the existing intake barrier in Seosang-ri valley, Chuncheon. For this purpose, modeling was performed by linking the basin hydrologic model and reservoir routing model. Changes in the water level, storage and discharge in the sand dam reservoir according to the size and intake of the sand dam are presented on a case-by-case basis. As a result of application, it was found that the water supply capacity due to the sand dam installation was improved at 95% reliability. Especially, when the size is L × B × Ho = 25 m × 15 m × 1 m and the pumping rates from intake barrier and sand dam are (Q1, Q2) = (30, 20), (35, 15) ㎥/day, the efficiency was the best for water supply of 50 ㎥/day.

Physical Analysis of High Strength Concrete According to Mixing Methods of Binders for Application Analysis of Pre-Mix Cement (프리믹스 시멘트의 활용성 분석을 위한 결합재의 혼합방법에 따른 고장도 콘크리트의 물성 분석)

  • Han, Cheon-Goo;Lee, Hae-Ill
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.5
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    • pp.127-133
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    • 2009
  • It is important to increase the strength of binders in order to enhance the strength of concrete. However, when the mineral admixture used for high strength concrete is incorporated individually, its dispersibility decreases due to the phenomenon of compaction, which reduces its fluidity and results in insufficient strength being created. To solve this problem, we can pre-mix each binder in advance to disperse a mineral admixture among binders, which will strengthen the fluidity and strength of concrete. Therefore, this study analyzed the properties of high strength concrete depending on the mix method used, to determine the effect of pre-mix cements ranging from W/B 15 to 35%. It was found that the fluidity of pre-mix increased to a level higher than that of individual mix due to its dispersion and ball bearing effect. The air content was slightly decreased from the result of individual mix due to the micro filler effect, which causes fine particles of silica-fume to fill the voids among cement particles, while the setting time of pre-mix was shorter than that of individual mix, because enhanced dispersion of pre-mix affects hydration heat time. The compressive strength of pre-mix increased due to the phenomenon of compaction of gap structure, and the variation of coefficient decreased by 1.69% on average in strength variation.

Effects of the V/III ratio on a-plane GaN epitaxial layer on r-plane sapphire grown by HVPE (r-Plane sapphire 위에 HVPE에 의해 성장한 a-plane GaN에피텍셜층의 V/III족 ratio에 따른 특성 변화)

  • Ha, Ju-Hyung;Park, Mi-Seon;Lee, Won-Jae;Choi, Young-Jun;Lee, Hae-Yong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.3
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    • pp.89-93
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    • 2014
  • In this study, effects of the V/III ratio on a-plane GaN epitaxial on r-plane grown by HVPE have been investigated. According to increasing of V/III ratio, the value of FWHM of a-plane (11-20) GaN and the value of surface roughness (Ra) were decreased. Growth rate of a-plane GaN epitaxial layer were increased until V/III ratio = 7 as the increasing of V/III ratio, but it was reduced at V/III ratio = 10. At V/III ratio = 10, the FWHM of a-plane (11-20) GaN RC and the surface roughness (Ra) were 829 arcsec and 1.58 nm, respectively, as the lowest value in this study. Also for V/III ratio = 10, cracks under surface or voids were observed the lowest values in images of optical microscope. An M-shaped azimuthal dependence over $360^{\circ}$ angle range was observed for all samples. At V/III ratio = 10, the difference of FWHM of a-plane GaN between $0^{\circ}$ and $90^{\circ}$ was 439 arcsec revealed as the lowest value in the 4 samples.

Effect of Firing Temperature on Microstructure and the Electrical Properties of a ZnO-based Multilayered Chip Type Varistor(MLV) (소성온도에 따른 ZnO계 적층형 칩 바리스터의 미세구조와 전기적 특성의 변화)

  • Kim, Chul-Hong;Kim, Jin-Ho
    • Journal of the Korean Ceramic Society
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    • v.39 no.3
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    • pp.286-293
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    • 2002
  • Microstructure and the electrical porperties of a ZnO-based multilayered chip-type varistor(abbreviated as MLV) with Ag/Pd(7:3) inner electrode have been studied as a function of firing of temperature. At 1100$^{\circ}$C, inner electrode layers began to show nonuniform thickness and small voids, which resulted in significant disappearance of the electrode pattern and delamination at 1100$^{\circ}$C. MLVs fired at 950$^{\circ}$C showed large degradation in leakage current, probably due to incomplete redistribution of liquid and transition metal elements in pyrochlore phase decomposition. Those fired at 1100$^{\circ}$C and above, on the other hand, revealed poor varistor characteristics and their reproductibility, which are though to stem from the deformation of inner electrode pattern, the reaction between electrode materials and ZnO-based ceramics, and the volatilization of $Bi_2O_3$. Throughout the firing temperature range of 950∼1100$^{\circ}$C, capacitance and leakage current increased while breakdown voltage and peak current decreased with the increase of firing temperature, but nonlinear coefficient and clamping ratio kept almost constant at ∼30 and 1.4, respectively. In particular, those fired between 1000$^{\circ}$C and 1050$^{\circ}$C showed stable varistor characteristics with high reproducibility. It seems that Ag/Pd(7:3) alloy is one of the electrode materials applicable to most ZnO-based MLVs incorporating with $Bi_2O_3$ when cofired up to 1050$^{\circ}$C.

New Gain Function Based on Attenuation Characteristics of Ballast Track for GPR Analysis (GPR 분석을 위한 자갈궤도 자갈의 감쇄특성을 이용한 이득함수 개발)

  • Shin, Jihoon;Choi, Yeongtae;Jang, SeungYup
    • Journal of the Korean GEO-environmental Society
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    • v.18 no.4
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    • pp.13-21
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    • 2017
  • Ballasted track has been used as track system for more than 100 years. Ballasted track has advantages of low construction cost, flexible maintenance, low noise and vibration, and so on. However, ballasted track leads to continuous settlement which causes maintenance. Recently, increase in speed, traffic volume, and weight of train requires more frequent maintenance. Fouling, well-known phenomenon of accumulation of fine materials due to intrusion of subgrade and breakage of ballast materials, expedites the settlement (i.e., irregular settlement) of track. Ground Penetrating Radar (GPR) can be one of non-destructive tools that can evaluate fouling level of ballast. In this paper, a gain function based on the attenuation characteristics of ballast material is suggested in conjunction with Hilbert transform. Lab box tests and full-scale tests indicate that the suggested method reasonably classifies clean, fouled layers, and subgrade. However, additional study to eliminate effect of sleeper and to include the scattering features of the electromagnetic wave in ballast voids should be required in order to enhance the accuracy.

Characteristics of Amorphous Si Films Fabricated by Mesh-type PECVD and Their Crystallization Behavior Using Excimer Laser (Mesh-type PECVD 방법으로 제조된 비정질 Si박막의 특성 및 레이저 결정화)

  • Han Sang-Yong;Choi Jae-Sik;Kim Yong-Su;Park Sung-Gye;Ro Jae-Sang;Kim Hyoung-June
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.19-24
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    • 2000
  • It is increasingly necessary to use poly-Si n's as high resolution and integration of Tn for LCD. Excimer Laser Crystallization (ELC) of a-Si is mainly used as a low temperature process. But the ELC method for the fabrication of poly-Si has the eruption problems associated with hydrogen in the a-Si film. So we need a dehydro-genation process additionally. Hydrogen in a-Si film can degrade the quality of poly-Si film and electrical properties of device due to the hydrogen eruption and voids which occur during the excimer laser annealing. In this study, we propose mesh-type PECVD as the a-Si film deposition method for achieving the low concentration hydrogen. Mesh-type PECVD was found to reduce the hydrogen content substantially. We could obtain a as-deposited a-Si film with hydrogen contents less than $1\%$ at $300^{\circ}C$. We also investigated the behavior by XeCl excimer laser annealing of a-Si fabricated by mesh-type PECVB. As a result, we were able to confirm the broad process window in contrast to the narrow process range typically obtained in ELC. Hydrogen eruption was not observed in poly-Si films after ELC These results suggests that mesh-type PECVD is a viable method to achieve the low hydrogen content a-Si and improve the process windows for ELC.