Laboratory experiments for the reaction with supercritical $CO_2$ under the $CO_2$ sequestration condition were performed to investigate the mineralogical and geochemical weathering process of the sandstones and mudstones in the Pohang basin. To simulate the supercritical $CO_2$-rock-groundwater reaction, rock samples used in the experiment were pulverized and the high pressurized cell (200 ml of capacity) was filled with 100 ml of groundwater and 30 g of powdered rock samples. The void space of the high pressurized cell was saturated with the supercritical $CO_2$ and maintained at 100 bar and $50^{\circ}C$ for 60 days. The changes of mineralogical and geochemical properties of rocks were measured by using XRD (X-Ray Diffractometer) and BET (Brunauer-Emmett-Teller). Concentrations of dissolved cations in groundwater were also measured for 60 days of the supercritical $CO_2$-rock-groundwater reaction. Results of XRD analyses indicated that the proportion of plagioclase and K-feldspar in the sandstone decreased and the proportion of illite, pyrite and smectite increased during the reaction. In the case of mudstone, the proportion of illite and kaolinite and cabonate-fluorapatite increased during the reaction. Concentration of $Ca^{2+}$ and $Na^+$ dissolved in groundwater increased during the reaction, suggesting that calcite and feldspars of the sandstone and mudstone would be significantly dissolved when it contacts with supercritical $CO_2$ and groundwater at $CO_2$ sequestration sites in Pohang basin. The average specific surface area of sandstone and mudstone using BET analysis increased from $27.3m^2/g$ and $19.6m^2/g$ to $28.6m^2/g$ and $26.6m^2/g$, respectively, and the average size of micro scale void spaces for the sandstone and mudstone decreased over 60 days reaction, resulting in the increase of micro pore spaces of rocks by the dissolution. Results suggested that the injection of supercritical $CO_2$ in Pohang basin would affect the physical property change of rocks and also $CO_2$ storage capacity in Pohang basin.
KSCE Journal of Civil and Environmental Engineering Research
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v.14
no.3
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pp.669-678
/
1994
The BOD removal characteristics of submerged biofilters filled with three kinds of filter media respectively were experimentally examined with constant temperature, pH value and variable BOD loading and recirculation ratio. Obtained results are as follows; 1. The BOD removal ratio decreases with the increasing $BOD_5$ volumetric loading rate, and the loading rate for the BOD removal over 90% is lower thean $1.6kg{\cdot}BOD_5/m^3{\cdot}d$ for the plastic media of Netring and cubic wire meshes. This is a much large value than $0.3{\sim}0.8kg{\cdot}BOD_5/m^3{\cdot}d$ for conventional activated sludge process. The required submerged biofilter volume is found to be much samller than that of conventional activated sludge process. 2. The decreasing order of BOD removal is Netring (random plastic media), cubic wire meshes (plastic module), and then gravel (stone media). This is mainly due to the media characteristics such as void ratio, specific surface area and media shapes. 3. The $BOD_5$ removal rate increases with the recircuration ration, but the rate of increases becomes samaller as the recirculation ratio increases over 20. When $BOD_5$ loading is $1.8kg{\cdot}BOD_5/m^3{\cdot}d$, the required recirculation rationto obtain 90% $BOD_5$ removal is about 20 for Netring and it was about 30 for cubic wire meshes. 4. Reynold's Number increases with recirculation ratio, and the Reynold's Numbers corresponding to the recircuration ratio of 10~50 are less than 52, showing laminar up flows in the filter. The settled and effluent sludges increase with increase of Reynol's Number, and there are the definite Reynold's Numbers at which the settling sludge concentrations become nearly constant respectively in each filters. 5. In this submerged biofilter system, small volume of sludge hopper can be substituted for a separated settling tank.
Journal of Korean Tunnelling and Underground Space Association
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v.17
no.3
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pp.353-362
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2015
Platform screen door (PSD) installed at underground subway station has reduced the safety accident, but it may cause poor air ventilation condition due to the isolated exhaust duct in the subway tunnel area. In this study, the additional ventilation system was suggested, which can be installed at a void space (i.e., storage room under stairs) of platform in order to improve efficiency of air ventilation rate. Exhausted air from platform was directed to underneath of platform and joined with existing ventilation duct of train exhaust system (TES). One subway station in Seoul city was selected to predict the effectiveness of the suggested lower exhaust system by using the computational fluid dynamics (CFD) analysis. The predicted mean age of air was decreased by 16.5% which proves the improvement of air ventilation efficiency when the suggested lower exhaust system was applied.
This paper presents sedimentation and consolidation characteristics of dredged soils mixed with sand materials through the self-weight consolidation tests adopting stepwise filling method. After completely throwing away dredged soils daily by flour kinds of S-C, which is the quantity of sand contained, results fi:om laboratory tests are compared with those from a new method using hyperbolic, which considers stage settling and consolidating characteristics, and those from the existing analyzing method. Liquid limit up to 65% had a large effect on consistency properties. Assuming that the settlement occurred only by clay content of dredged soils, it is shown that the clay void ratio is less than 2 and 4 respectively in case S-C is 0% and 50%. In the applied hyperbolic method, reinitialized curve has a linear behavior of a coefficient of correlation of almost 1, and the coefficient of slope and intercept except fur the specimen with the height of 10cm and 20cm had a tendency to fellow exponent function and a shape of zone settling and dispersing settling. The results computed by the applied hyperbolic method rather than the existing analyzing method coincide with those of laboratory tests. It is shown that the former is more suitable than the latter for the area considering the influence, of sand materials.
Journal of Dental Rehabilitation and Applied Science
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v.19
no.4
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pp.269-279
/
2003
This study investigated the mechanical properties of precious metal-ceramic alloy joined by the laser-welding and the soldering compared with the parent metal. Twenty-four tensile specimens were cast in precious metal-ceramic alloy and divided into three groups of eight. All specimens in the control group(group 1) were left in the as-cast condition. Group 2 and 3 were the test specimens, which were sectioned at the center. Eight of sectioned specimens were joined by soldering with a propane-oxygen torch, and the remaining specimens were joined by laser-welding. After joining, each joint diameter was measured, and then tested to tensile failure on an Instron machine. Failure loads were recorded, and then fracture stress(ultimate tensile strength), 0.2% yield strength and % elongation calculated. These data for three groups were subjected to a one-way analysis of variance(ANOVA). Neuman-Keuls post hoc test was then used to determine any significant differences between groups. The fracture locations, fracture surfaces were examined by SEM(scanning electron microscope). The results were as follows: 1) The tensile strength and 0.2% yield strength of the soldered group($280.28{\pm}49.35MPa$, $160.24{\pm}26.67MPa$) were significantly less than both the as-cast group($410.99{\pm}13.07MPa$, $217.82{\pm}17.99MPa$) and the laser-welded group($383.56{\pm}59.08MPa$, $217.18{\pm}12.96MPa$). 2) The tensile strength and 0.2% yield strength of the laser-welded group were about each 98%, 99.7% of the as-cast group. There were no statistically significant differences in these two groups(p<0.05). 3) The percentage elongations of the soldered group($3.94{\pm}2.32%$) and the laser-welded group($5.06{\pm}1.08%$) were significantly less than the as-cast group($14.25{\pm}4.05%$) (p<0.05). 4) The fracture of the soldered specimens occurred in the solder material and many porosities were showed at the fracture site. 5) The fracture of the laser-welded specimens occurred also in the welding area, and lack of fusion and a large void was observed at the center of the fracture surface. However, the laser-welded specimens showed a ductile failure mode like the as- cast specimens. The results of this study indicated that the tensile strengths of the laser-welded joints were comparable to those of the as-cast joints and superior to those of the soldered joints.
Journal of the Korean Association of Oral and Maxillofacial Surgeons
/
v.35
no.2
/
pp.112-119
/
2009
Extracellular matrix(ECM) is known to function as a reservoir of endogenous growth factors, can be an effective delivery system of growth factor that easily lost bioactivity in solution. Fibrillar collagens like type I collagen, are the major constituent of the ECM and structural protein of bone. Also, it can be a scaffold for osteoblast migration. The purpose of this study was to compare the effects of absorbable Atelo-collagen Sponge($Teruplug^{(R)}$) insertion in tooth extraction sites on periodontal healing of the mandibular second molar after the extraction of the impacted third molar. The study population comprised 31 cases who had been scheduled for surgical removal of impacted mandibular third molars. All patients were in good general health and were not using any medication that would influence wound healing after surgery. In 15 cases control group, none was inserted into the tooth extraction site. In 16 cases experimental groups, $Teruplug^{(R)}$ was inserted into the tooth extraction site. We evaluated tooth mobility, pocket depth, gingival margin level preoperatively and 1 week, 2 weeks, 4 weeks, and 3 months postoperatively. The change was compared with two groups using Mann-Whitney test. The results were as follows. 1. There was no significant change of tooth mobility on both groups. 2. There was tendency of decreasing of previous pocket depth causing tooth extraction on both groups. 3. On gingival margin level, there was various change according to initial swelling and loss of attachment on both groups. 4. There was tendency of decreasing of gingival margin level on both groups because of removal of inflammation and decreasing of previous pocket depth. 5. There was large change of pocket depth on buccal middle, distal, lingual distal area because of tooth extraction and bone reduction. Compared with the control group and experimental group, we observed significant difference during some periods. The results of this study suggest that absorbable atelo-collagen sponge($Teruplug^{(R)}$) is relatively favorable bone void filler with prevention of tissue collapse, food packing and enhance periodontal healing.
Journal of the Korea institute for structural maintenance and inspection
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v.17
no.6
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pp.130-137
/
2013
This research was performed through the experimental design to get the statistical analysis on foamed concrete mixed plaster with hydrogen peroxide. In this experiment, we set the ratio of each material, which part of lightweight concrete, as experimental factors and evaluated on the mechanical properties by statistical analysis for response variables obtained from experiments. Experimental factors are plaster replacement, water binder ratio, and hydrogen peroxide ratio. Response variables are dry density, compressive strength, and flexural strength. Mixing design of the foamed concrete set up a total of 15 experimental points by Box-Behnken (BB) method of the response surface analysis. Thus, the results of a study were summarized as follows. Values of the probability in experimental factors (plaster replacement, water binder ratio and hydrogen peroxide ratio) on the response variables were estimated to be significant at the 95% of confidence limit. On response surface analysis for dry density of foamed concrete, water binder ratio and hydrogen peroxide ratio were estimated to be significant (${\alpha}$ = 0.05), and the relationship between the amount of void and the water content for dry density is inverse proportional. On response surface analysis for the compressive strength of foamed concrete, water binder ratio, hydrogen peroxide ratio and (hydrogen peroxide ratio)$^2$ was estimated to be significant (${\alpha}$ = 0.05). On response surface analysis for the flexural strength of foamed concrete, water binder ratio, hydrogen peroxide ratio was estimated to be significant (${\alpha}$ = 0.05). Through multi response surface analysis, we found the optimal area that meets performance goals.
Kim, Soo-Lo;Park, Sung-Bin;Choi, Byung-Hee;Yun, Jung-Mann;Jeong, Gyo-Cheol
Tunnel and Underground Space
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v.26
no.6
/
pp.455-465
/
2016
The collapse of underground mine development void for mineral resources can cause the subsidence of ground surface. In order to prevent the subsidence of ground, data such as maps or pictures of past mining site is important information for current mine reclamation works. In particular, mine subsidence management was based on mining maps and pictures. The process of the mining area surveys, safety evaluation, and ground reinforcement are normally possible with information such as maps and pictures in past mining. During the Japanese colonial period and 1960's, a lot of mines were developed in Korea indiscriminately. However, mining information at that time is limited to use. In the future, mining information will become even more rare. MIRECO intends to establish a realistic alternative solution. In this study, the basic numerical information of developed mine tunnels in Korea is statistically reviewed, and advanced underground cavity measuring technology was studied. 4,473 mine tunnel opening data of 1,784 abandoned mines in korea were collected and sorted. As a result of the analysis, the average value of small mine tunnel openings in Korea was 1.982 m in height and 1.959 m in width. The mean value of shape factor was analyzed as 0.485. The summary of these numerical mine data will be helpful for understanding and researching Korean abandoned mines. Therefore, the development of measurement technology for abandoned mine cavities and tunnels is expected to facilitate more effective mine subsidence management works in Korea.
To identify and interpret the distribution and the characteristics of the gas hydrate layers in the Ulleung Basin, we have surveyed and gathered the multi-channel seismic data, Chirp sub-bottom profiler, SeaBeam and 12 m piston core samples since 1996. In previous works, high-resolution seismic profiles showed acoustic anomalies such as acoustic void, acoustic turbidity and pock mark which indicate the presence of gas-charged sediments. The patterns of horizontal degassing cracks originated from free methane expansion is the strong indicator of shallow gas-charged sediments in the core samples. The observation of submarine slides and slumps from destabilizing the sediments in the southern part of the Ulleung Basin may also point out that the gas had been released from gas hydrate dissociation during lowstand of sea level. The multi-channel seismic data show BSR, blanking and phase reversal. The gas hydrate layers above which large-scale shallow gases are distributed exist at the depth of about 200 m from the sea-floor with water depth of 2,100 m. From the interpretation of seismic sections in the southern Ulleung Basin, gas hydrate layers occur in the Pleistocene-Holocene sediments. These gas-charged sediments, acoustic anomalies and BSR may be all related to the existence of gas hydrate layers in the study area.
The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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v.13
no.3
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pp.286-294
/
2008
In order to understand the physical properties of deep-sea sediments, which mainly consist of pelagic red clays, sediment samples were collected at 24 stations using a multiple corer in the Clarion-Clipperton fracture zone of the northeast equatorial Pacific. The sampled sediment cores were examined for the mass physical properties(i.e. grain size distribution, mean grain size, water content, specific grain density, wet bulk density, void ratio, and porosity) and the geotechnical properties(i.e. shear strength and consistency limits) with the content of biogenic opal and mineral composition. Although KR1 and KR2 areas on the same latitude are logitudinally far from each other, the mass physical properties of these areas are not distinctly different except for shear strengths. The maximum shear strength of surface sediments in KR2 area is higher than that in KR1 due to the appearance of a consolidated lower layer(Unit 3) in the sediment core from KR2.
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