• Bulletin of the Korean Chemical Society
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• 제29권10호
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• pp.1960-1964
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• 2008

The roles of coordinating ligands (TOPO, OA, HDA, and TDPA) for the synthesis of ZnO nanoparticles are investigated. Various shapes (hexagonal cone, hexagonal plate, and rod) and sizes (5-100 nm) of ZnO nanoparticles are prepared in relation to the coordinating ligands. The hexagonal shapes ($\leq$ 100 nm) are synthesized with TOPO and OA, while smaller size nanorods (5 ${\times}$ 30 nm) are with TOPO and TDPA. The relative intensities of two distinctive emission bands centered at 385 and 500 nm, which are related to the exciton and defect states, respectively, depend on the crystal qualities of ZnO nanoparticles affected by the coordinating ligands. The intense UV emissions with the reduced visible emissions are found in the monodisperse nanoparticles such as hexagonal cones and nanorods, suggesting that the monodispersity as well as the crystallinity is closely related to the coordinating ligands. The blue-shift of photoluminescence and absorption edge is observed in the nanorods, because the sizes of the nanorods are in the quantum confinement regime.

• 음성과학
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• 제15권3호
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• pp.39-51
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• 2008

Formant measurements are one of the most important factors to objectively test cross-linguistic differences among vowels produced by speakers of any given languages. However, many speech analysis softwares present erroneous estimates and some researchers use them without any verification procedures. The purposes of this paper are to examine formant measurements of complex waves which were synthesized from the average formant values of five Korean vowels using three default methods in Praat and to verify the measured values of the five vowels produced by 20 students using one of the methods. Variances along the time axis are discussed after determining absolute difference sum from the 1/3 vowel duration point. Results show that there were smaller measurement errors by the burg method. Also, greater errors were observed in the sl or lpc methods mostly caused by the inappropriate formant settings. Formant measurement deviations were greater in those vowels produced by the female students than those of the male students, which were mostly attributed to the settings for the vowels /o, u/. Formant settings can best be corrected by changing the number of formants to the number of visible dark bands on the spectrogram. Those results suggest that researchers should check the validity of the estimates from the speech analysis software. Further studies are recommended on the perception test of the original sound with the synthesized sound by the estimated formant values.

• Journal of Forest and Environmental Science
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• 제24권3호
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• pp.165-169
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• 2008

This study attempts to analyze the relationship between forest volume and age based on 5th NFI data and spectral characteristics of satellite imagery using ASTER sensor in Korea. Forest stand volume and age had the negative correlation with the spectral reflectance in all of the band (Blue, Green, Red, SWIR). With increasing of stand volume and age, spectral reflectance decrease. The spectral reflectance of band1 showed the highest correlation between stand volume and spectral reflectance among the VNIR wavelength. The spectral reflectance band 1, 2 (visible wavelength) and stand age have high correlation compared to other bands. The correlation coefficients between forest volume and vegetation indices have low relationship. This result indicates that the reflectance of blue band may be important factor to improve the potential of optical remote sensing data to estimate forest volume and age.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2003년도 추계학술대회
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• pp.222-227
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• 2003

Recent advances in room-temperature, visible and near-IR diode laser sources for telecommunication, optical data storage applications are enabling combustion diagnostics system based on diode laser absorption spectroscopy. In contrast to some traditional sampling-based gas-sensing instruments, tunable diode laser absorption spectroscopy system is advantageous because of their non-invasive nature, high sensitivity, fast response time and real-time measurement capability. So, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor system arc now appearing for a variety of applications. The objective of this research is to take advantage of distributed feed-back diode laser and measure the $CO_{2}$ concentration (by using direct absorption and wavelength modulation spectroscopy methods). In addition to survey spectra of $CO_{2}$ bands and spectroscopic parameters between 1565 and 1579 run were computed at temperatures between 296 and 1200 K (by using HITRAN 2000 database). It experimentally found out that the features of direct absorption and wavelength modulation spectroscopy methods.

• 한국작물학회지
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• 제50권2호
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• pp.142-146
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• 2005

Thirty-two germplasms of Korean adlay landraces were examined to analyse the genetic relationship through the amplified fragment length polymorphism (AFLP) approach. Total number of AFLP products generated by 12 selective primer combinations was 882. The number of polymorphic fragments by each primer combination greatly varied from 4 to 51 with a mean of 20.3, bands visible on the polyacrylamide gel. A genetic similarity coefficient was used for cluster analysis following UPGMA (unweighted pair grouping method of averages) method. The resulting clusters were represented in the form of a dendrogram. The clustering was not tight in the dendrogram. There was generally no clear grouping of the adlay according to the geographic regions in which germplasms were collected. The present AFLP analysis imply that although Korean adlay displayed a larger amount of AFLP variation within germplasms, the variation was shown independently without reflecting a clinal variation. This study demonstrated that AFLP method can be used to examine the genetic relationships among different germplasms of adlay.

• 대한화학회지
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• 제45권5호
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• pp.436-441
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• 2001

77K에서 mer-[Cr(dien)(glygly)]$ClO_4$의 방출 및 들뜬 상태 스펙트럼과 실온에서 적외선 및 가시선 스펙트럼을 측정하였다. 스핀-허용 및 스핀-금지에 해당하는 12개의 전자 전이의 성분을 배정하였다. 관측한 전이를 이용하여 Cr(Ⅲ) 착물에 배위된 원자의 결합성을 결정하기 위해서 리간드장 해석을 수행하였다. 이 연구에서 dien과 glygly 리간드의 아민 N 원자는 강한 $\sigma$-주개 특성을 갖는 반면에, glygly의 펩티드 N 원자는 Cr(Ⅲ) 이온에 약한 $\pi$-주개의 성질이 있음을 확인할 수 있었다.

• 대한원격탐사학회:학술대회논문집
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• 대한원격탐사학회 2007년도 Proceedings of ISRS 2007
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• pp.548-551
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• 2007

Among components of digital topographic maps used officially in Korea, only contours have 3D values except buildings and trees that are demanded in landscape planning. This study presented a series of processes for 3Dreconstructing landscape features such as terrain, buildings and standing trees using LiDAR (Light Detection And Ranging) data and aerial digital photo graphs. The 3D reconstructing processes contain 1) building terrain model, 2) delineating outline of landscape features, 3) extracting height values, and 4) shaping and coloring landscape features using aerial photograph and 3-D virtual data base. LiDAR data and aerial photograph was taken in November 2006 for $50km^{2}$ area in Sorak National Park located in eastern part of Korea. The average scanning density of LiDAR pulse was 1.32 points per square meter, and the aerial photograph with RGB bands has $0.35m{\times}0.35m$ spatial resolution. Using reconstructed 3D landscape features, visibility with the growing trees with time and at different viewpoints was analyzed. Visible area from viewpoint could be effectively estimated considering 3D information of landscape features. This process could be applied for landscape planning like building scale with the consideration of surrounding landscape features.

• 한국농공학회논문집
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• 제58권2호
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• pp.53-63
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• 2016

Monitoring of cyanobacteria bloom in reservoir systems is important for water managers responsible of water supply system. Cyanobacteria affect the taste and smell of water and pose considerable filtration problems at water use places. Harmful cyanobacteria bloom in reservoir have significant economic impacts. We develop a new method for estimating the cyanobacteria bloom using Landsat TM and ETM+ data. Developed model was calibrated and cross-validated with existing in situ measurements from Daecheong Reservoir's Water Quality Monitoring Program and Algae Alarm System. Measurements data of three stations taken from 2004 to 2012 were matched with radiometrically converted reflectance data from the Landsat TM and ETM+ sensor. Stepwise multiple linear regression was used to select wavelengths in the Landsat TM and ETM+ bands 1, 2 and 4 that were most significant for predicting cyanobacteria cell number and bio-volume. Based on statistical analysis, the linear models were that included visible band ratios slightly outperformed single band models. The final monitoring models captured the extents of cyanobacteria blooms throughout the 2004-2012 study period. The results serve as an added broad area monitoring tool for water resource managers and present new insight into the initiation and propagation of cyanobacteria blooms in Daecheong reservoir.

• Journal of Biosystems Engineering
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• 제38권3호
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• pp.199-207
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• 2013

Purpose: Tomatoes, an important agricultural product in fresh-cut markets, are sometimes a source of foodborne illness, mainly Salmonella spp. Growth cracks on tomatoes can be a pathway for bacteria, so its detection prior to consumption is important for public health. In this study, multispectral Visible/Near-Infrared (NIR) reflectance imaging techniques were used to determine optimal wavebands for the classification of defect tomatoes. Methods: Hyperspectral reflectance images were collected from samples of naturally cracked tomatoes. To classify the resulting images, the selected wavelength bands were subjected to two-band permutations, and a supervised classification method was used. Results: The results showed that two optimal wavelengths, 713.8 nm and 718.6 nm, could be used to identify cracked spots on tomato surfaces with a correct classification rate of 91.1%. The result indicates that multispectral reflectance imaging with optimized wavebands from hyperspectral images is an effective technique for the classification of defective tomatoes. Conclusions: Although it can be susceptible to specular interference, the multispectral reflectance imaging is an appropriate method for commercial applications because it is faster and much less expensive than Near-Infrared or fluorescence imaging techniques.

• 대한화학회지
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• 제27권2호
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• pp.150-156
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• 1983

몇 가지 용매에 대하여 옥소디피로메텐과 빌리루빈의 흡수스펙트라 이동현상을 연구하였다. 메탄올이나 아세트산용액 중에서는 옥소디피로메텐이 수소결합을 하여 컨쥬게이션이 많이 되는 형으로 존재하며, 강산 존재하에서는 엔올 형으로 흡수한다. 옥소디피로메텐이나 빌리루빈의 큰 몰흡광계수와 많은 알킬기가 치환된 옥소디피로메텐이 장파장을 흡수하는 것으로 보아 이들의 처음여기 상태는 ${\pi}{\rightarrow}{\pi}^{\ast}$전이일 것이다.