• Bulletin of the Korean Chemical Society
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• v.25 no.3
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• pp.373-376
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• 2004

A novel Er(III) complex with oxydiacetate and 1,10-phenanthroline was synthesized and its structure and luminescence properties were characterized. The complex of $[Er(ODA){\cdot}(phen){\cdot}4H_2O]^+$ crystallizes in the monoclinic space group $P2_1$/n with a = 12.216(4) ${\AA}$, b = 16.680(2) ${\AA}$, c = 12.627(3) ${\AA}$, ${\beta}=108.30(2)^{\circ}$, V = 2442.7(11) ${\AA}^3$, Z = 4 and ${\rho}=1.841 g/cm^3$. When the complex is excited at the He-Cd 325-nm line, it produces two broad bands spanning the regions 350-650 nm and 1200-1650 nm. The emission band of the complex is characterized by a series of spectral dips in the visible emission profile. The complex exhibits sensitized near- IR emission via two kinds of energy transfers from phen to Er(III): nonradiative and radiative energy transfers.

• Bulletin of the Korean Space Science Society
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• 2009.10a
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• pp.49.3-49.3
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• 2009

Geostationary Ocean Colour Imager (GOCI) is the first ocean color instrument that will be operating in a geostationary orbit from 2010. GOCI will provide the crucial information of ocean environment around the Korean peninsula in high spatial and temporal resolutions at eight visible bands. We report an on-going development of imaging and radiometric performance prediction model for GOCI with realistic data for reflectance, transmittance, absorption, wave-front error and scattering properties for its optical elements. For performance simulation, Monte Carlo based ray tracing technique was used along the optical path starting from the Sun to the final detector plane for a fixed solar zenith angle. This was then followed by simulation of red-tide evolution detection and their radiance estimation, following the in-orbit operational sequence. The simulation results proves the GOCI flight model is capable of detecting both image and radiance originated from the key ocean phenomena including red tide. The model details and computational process are discussed with implications to other earth observation instruments.

• Bulletin of the Korean Chemical Society
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• v.26 no.6
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• pp.903-908
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• 2005

The sharp-line absorption and emission spectra of $(H_{13}O_6)${$trans-[Cr(Me_2tn)_2Br_2]$}$_2Br_2(ClO_4)\;(Me_2$tn = 2,2-dimethyl-1,3-diaminopropane) have been measured between 13000 $cm^{-1}$ and 16000 $cm^{-1}$ at 5 K. The 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex ion. The zero-phonon line in the sharp-line absorption spectrum splits into two components by 286 $cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the Me2tn ligand have a strong $\sigma$-donor character, but the bromide has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2007.06a
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• pp.394-394
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• 2007

Transparent conductive films can serve as a critical component in displays, solar cells, lasers, optical communication devices, and solid state lighting. Carbon nanotube (CNT) based transparent conductive films are fabricated on glass and polymer substrates. CNTs typically exist in form of quasi-crystalline bundles or highly entangled bundles containing tens of individual nanotubes. To achieve full potential, CNTs must be dispersed in a solvent or other organic media. CNTs are acid treated with nitric acid then the stable dispersion of CNTs in polar solvent such as alcohols, DMF, etc. is achieved by sonication. The solubility of CNTs correlates well with the area ratio of the D and G bands from Raman spectrum. Thin films are formed from well dispersed CNT solutions using spray coating method. CNT thin films exhibit a sheet resistance ($R_s$) of nearby $10^3\;{\Omega}/sq$ with a transmittance of around 80% on the visible light range, which is attributed by excellent dispersion and interaction among CNTs, solvents and polymeric binders.

• Macromolecular Research
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• v.16 no.4
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• pp.367-372
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• 2008

We fabricated tetra(5-n-nonyl-8-tert-butyl-2,3-pyrazino[2,3-b]indolo)porphyrazinato copper(II) (Cu-Pc-$C_8$) Langmuir-Blodgett (LB) films. We further investigated the influence of arachidic acid (AA) as a transfer promoter, as well as the effect of dipping speed, on the deposition of the films on hydrophilic and hydrophobic substrates. In the case of pure Cu-Pc-$C_8$ LB deposition on a hydrophilic substrate, the transfer ratio was close to one for up-stroke depositions, but the previously deposited film was peeled off and re-spread onto water at down-stroke depositions. Whereas the stability of the Cu-Pc-$C_8$ LB films was not improved by AA addition on hydrophilic substrates, the deposition of Cu-Pc-$C_8$ was significantly improved by the presence of AA on a hydrophobic substrate. The AA-assisted deposition had transfer ratio of close to 1 and was essentially stable up to 10-layer depositions. Comparison of the UV-visible spectrum of a Cu-Pc-$C_8$/AA LB film with that of Cu-Pc-$C_8$/AA solution in dichloroethane revealed that the Soret and Q bands for the Cu-Pc-$C_8$/AA LB film were broadened and red-shifted due to the aggregation of phthalocyanines upon assembly in the LB film.

• Korean Journal of Remote Sensing
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• v.18 no.3
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• pp.141-146
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• 2002

Chlorophyll-a concentration maps of Yongdam reservoir in September and October, 2001 were produced using Landsat ETM imagery and the in-situ water quality measurement data. In-situ water samples were collected on 16th September and 18th October during the satellite overpass. The correlations between the DN values of the imagery and the values of chlorophyll-a concentration were analyzed. The visible bands(band 1, 2, 3) and the near infrared band(band 4) data of September image showed the correlation coefficient values higher than 0.9. The October image showed correlation coefficient values of about 0.7 due to the low variations of chlorophyll-a concentration. Regression models between the DN values of the Landsat ETM image and the chlorophyll-a concentration have been developed for each image. The developed regression models were then applied to each image, and finally the chlorophyll-a distribution maps of Yongdam reservoir were produced. The produced maps showed the spatial distribution of the chlorophyll-a in Yongdam reservoir in a synoptic way so that the tropic state could be easily monitored and analysed in the spatial domain.

• Korean Journal of Remote Sensing
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• v.15 no.4
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• pp.367-375
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• 1999

This paper describes the development, operations, and applications of ROCSAT-l and its Ocean Color Imager (OCI) remote-sensing payload. It is the first satellite program of NSPO. The satellite was successfully launched by Lockheed Martin's Athena on January 26, 1999 from Cape Canaveral, Florida. ROCSAT-l is a Low Earth Orbit (LEO) experimental satellite. Its circular orbit has an altitude of 600km and an inclination angle of 35 degrees. The satellite is designed to carry out scientific research missions, including ocean color imaging, experiments on ionospheric plasma and electrodynamics, and experiments using Ka-band (20∼30GHz) communication payloads. The OCI payload is utilized to observe the ocean color in 7 bands (including one redundant band) of Visible and Near-Infrared (434nm∼889nm) range with the resolution of 800m at nadir and the swath of 702km. It employs high performance telecentric optics, push-broom scanning method using Charge Coupled Devices (CCD) and large-scale integrated circuit chips. The water leaving radiance is estimated from the total inputs to the OCI, including the atmospheric scattering. The post-process estimates the water leaving radiance and generates different end products. The OCI has taken images since February 1999 after completing the early orbit checkout. Analyses have been performed to evaluate the performances of the instrument in orbit and to compare them with the pre-launch test results. This paper also briefly describes the ROCSAT-l mission operations. The spacecraft operating modes and ROCSAT Ground Segment operations are delineated, and the overall initial operations of ROCSAT-l are summarized.

• Structural Monitoring and Maintenance
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• v.2 no.3
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• pp.181-197
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• 2015

Assessing the condition of paint on civil structures is an important but challenging and costly task, in particular when it comes to large and complex structures. Current practices of visual inspection are labour-intensive and time-consuming to perform. In addition, this task usually relies on the experience and subjective judgment of individual inspectors. In this study, hyperspectral imaging and classification techniques are proposed as a method to objectively assess the state of the paint on a civil or other structure. The ultimate objective of the work is to develop a technology that can provide precise and automatic grading of paint condition and assessment of degradation due to age or environmental factors. Towards this goal, we acquired hyperspectral images of steel surfaces located at long (mid-range) and short distances on the Sydney Harbour Bridge with an Acousto-Optics Tunable filter (AOTF) hyperspectral camera (consisting of 21 bands in the visible spectrum). We trained a multi-class Support Vector Machines (SVM) classifier to automatically assess the grading of the paint from hyperspectral signatures. Our results demonstrate that the classifier generates highly accurate assessment of the paint condition in comparison to the judgement of human experts.

• Journal of Positioning, Navigation, and Timing
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• v.9 no.4
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• pp.319-325
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• 2020

In order to propose new satellite navigation signals, it is essential to analyze the increased level of interference effect that the existing signals suffer. In this paper, a method for estimating the power density of the interference signals on GPS signals is proposed before and after the additional transmission of the KPS signals in the L1, L2 and L5 bands. For estimation, we assume the number of visible satellites observed over the Korean peninsular and the minimum received power of the satellite navigation signals. The comparison of the estimated values shows that the power density of the interfering signal increases by up to 1.37 dB due to the introduction of KPS, but this leads to an increase in interference plus noise power density below 0.47 dB.

• Current Optics and Photonics
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• v.6 no.2
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• pp.151-160
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• 2022

Fundus images can reflect ocular diseases and systemic diseases such as glaucoma, diabetes mellitus, and hypertension. Thus, research on fundus-detection equipment is of great importance. The fundus camera has been widely used as a kind of noninvasive detection equipment. Most existing devices can only obtain two-dimensional (2D) retinal-image information, yet the fundus of the human eye also has spectral characteristics. The fundus has many pigments, and their different distributions in the eye lead to dissimilar tissue penetration for light waves, which can reflect the corresponding fundus structure. To obtain more abundant information and improve the detection level of equipment, a snapshot nonmydriatic fundus imaging spectral system, including fundus-imaging spectrometer and illumination system, is studied in this paper. The system uses a microlens array to realize snapshot technology; information can be obtained from only a single exposure. The system does not need to dilate the pupil. Hence, the operation is simple, which reduces its influence on the detected object. The system works in the visible and near-infrared bands (550-800 nm), with a volume less than 400 mm × 120 mm × 75 mm and a spectral resolution better than 6 nm.