• Title/Summary/Keyword: viscosity reduction

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Quality Properties of Lightweight Foamed Concrete with Variances in Incorporating Ratio of CKD and Adding Ratio of Stability Agent (CKD 치환율 및 증점안정화제 혼입율 변화에 따른 경량기포 콘크리트의 품질특성)

  • Shin, Hyun-Sub;Yoo, Seung-Yeup;Jeong, Wang-Bok;Pei, Chang-Chun;Kim, Seong-Soo;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2006.11a
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    • pp.67-70
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    • 2006
  • This study investigates the properties of light weight foamed concrete designed with various incorporating ratios of CKD and adding ratios of PS. Test showed that increase of CKD and PS decreased fluidity of fresh concrete, which need more addition of superplasticizer to secure proper fluidity. As for the sinking depth of specimens, using more CKD or PS decreased the value, due to the improvement of viscosity by micro particles of CKD and reduction of air loss by PS. Those methods are very effective to solve the sinking problem of light weight foamed concrete, which has been highly concerned. For the hardened concrete, compressive strength of specimens exhibited that using around 10% of CKD or 0.02% of PS increased the strength value, but decreased when incorporated or added more amounts of that, due to reduction of the sinking depth, caused by filling effect of the micro particle and improvement of the viscosity.

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Effects of Propylene Glycol on the Physical Properties of Poly(vinyl alcohol) Solutions and Films

  • Cho, Yong-Han;Kim, Byoung-Chul;Dan, Kyung-Sik
    • Macromolecular Research
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    • v.17 no.8
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    • pp.591-596
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    • 2009
  • To trace the plasticizing effects of propylene glycol (PG) on poly(vinyl alcohol) (PVA), the rheological properties of PVA solutions in dimethyl sulfoxide (DMSO) and the physical properties of PVA films were discussed in terms of PG content. Both properties were closely related to the hydrogen bond breaking effects of PG The 6 and 12 wt% PVA solutions containing PG exhibited Bingham behavior, which was more noticeable at lower plasticizer content and higher polymer concentration. The 6 wt% PVA solutions containing more than 30 wt% PG showed a sudden decrease of viscosity over the frequency range of 0.08 and 0.2 rad/s. However, the 12 wt% PYA solutions showed no viscosity reduction even at a PG content up to 40 wt%. The glass transition temperature of the PVA/PG films was almost linearly decreased with increasing PG content but an abrupt reduction was observed at a plasticizer content 30 wt%, suggesting that the hydrogen bond breaking effects of PG on PVA became dominant between 20 and 30 wt%. This effect was further supported by the similar tendency of the tensile properties.

Effect of Chemical Composition, Molecular Weight, Carbon Black Concentration and Temperature on the Flow Behavior of Styrene/Butyl Methacrylate Homo- and Co-polymer Particles (화학적 구성, 분자량, 카본블랙의 농도 및 온도에 따른 스티렌/부틸메타크릴레이트 단일중합체 및 공중합체 입자의 유동성)

  • Park, Moon-Soo;Moon, Ji-Yeon
    • Polymer(Korea)
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    • v.35 no.1
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    • pp.23-29
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    • 2011
  • We measured shear viscosity of polymeric particles, prepared by suspension polymerization with hydrophobic silica as a stabilizer at $75^{\circ}C$, by a capillary rheometer. Shear viscosity displayed a non-Newtonian behavior with an increase in weight average molecular weight. Measurement of shear viscosity at 170 and $190^{\circ}C$ with copoly(styrene/butyl methacrylate) (co-PSB) particles by varying the ratio between styrene (St) and butyl methacrylate (BMA) showed that shear viscosity was a function of molecular weight, temperature and compositional ratio. When the ratio was 7/3, 5/5 and 3/7, shear viscosity slightly reduced with an increase in BMA concentration despite similar weight average molecular weights. We found that shear viscosity of copolymers with BMA concentrations exceeding 70% displayed a sharp reduction at high shear rates. It is speculated that increased PBMA chain length contributes to enhanced flowability of copolymers. When carbon black was incorporated into co-PSB, shear viscosity progressively increased with increasing carbon black concentration. The increase in shear viscosity, however, was less pronounced compared to the cases of molecular weight increase.

Optimization of Hobakjook (pumpkin soup) with Added Glutinous Rice Powder (호박 재료 배합비율을 달리한 호박죽의 품질 특성 연구)

  • Kim, Hyun-Ah;Kim, Jae-Hwan
    • Journal of the East Asian Society of Dietary Life
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    • v.25 no.1
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    • pp.162-175
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    • 2015
  • The purpose of this thesis was to develop pumpkin soup with different ratios of ingredients, using high-nutrient sweet pumpkins. P10G0 without sweet pumpkin and glutinous rice powder showed the highest moisture content, whereas, P5G0 whit Cheongdung pumpkin and sweet pumpkin at the same ratio whitout glutinous rice powder showed the lowest moisture content. For chromaticity lightness of control pumpkin soup scored the lowest. Lightness of P10G0 without sweet pumpkin and glutinous rice powder also scored the lowest. For redness, the P5 group with Cheongdung pumpkin and sweet pumpkin at the same ratio scored the highest while the P10 group without sweet pumpkin scored the lowest. As for yellowness, increased ratio of glutinous rice powder in pumpkin soup scored resulted in reduced yellowness in all groups P5 (p<0.01), P7 and P10 (p<0.001) A higher ratio of Cheongdung pumpkin was thus generally associated whit reduced yellowness (p<0.001). For the spread-ability, higher ratio of sweet pumpkin to Cheongdung pumpkin resulted in significant reduction of spread-ability. However, groups with 12% glutinous rice powder showed no significant differences. Spread-ability of the P5 and P10 groups significant increased and thereafter decreased according to the addition ratio of glutinous rice powder, viscosity of the G0 and G4 groups decreased according to the addition ratio of Cheongdung pumpkin, whereas they first decreased and then increased in the G8 and G12 groups. All groups showed increased viscosity whit more glutinous rice powder. For the sensory evaluation, P5G8 was mostly preferred in all aspects. P7G4 was superior in all aspects except for flavor. P10G4 scored the highest in all aspects except viscosity. For acceptance test, except for the control group, P7G4 whit added of 70% Cheongdung pumpkin, 30% sweet pumpkin and 4% glutinous rice powder was the most preferred in all aspects except color (gloss, viscosity, flavor, taste and overall quality).

Rheology of hydrophobic-alkali-soluble-emulsions (HASE) and the effects of surfactants

  • Lau, A.K.M.;Tiu, C.;Kealy, T.;Tam, K.C.
    • Korea-Australia Rheology Journal
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    • v.14 no.1
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    • pp.1-9
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    • 2002
  • Steady and dynamic shear properties of two hydrophobically modified alkali soluble emulsions (HASE), NPJI and NPJ2, were experimentally investigated. At the same polymer concentration, NPJ1 is appreciably more viscous and elastic than NPJ2. The high hydrophobicity of NPJ1 allows hydrophobic associations and more junction sites to be created, leading to the formation of a network structure. Under shear deformation, NPJ1 exhibits shear-thinning behaviour as compared with Newtonian characteristics of NPJ2. NPJ1 and NPJ2 exhibit a very high and a low level of elasticity respectively over the frequency range tested. For NPJ1, a crossover frequency appears, which is shifted to lower frequencies and hence, longer relaxation times, as concentration increases. Three different surfactants anionic SDS, cationic CTAB, and non-ionic TX-100 were employed to examine the effects of surfactants on the rheology of HASE. Due to the different ionic behaviour of the surfactant, each type of surfactant imposed different electrostatic interactions on the two HASE polymers. In general, at low surfactant concentration, a gradual increase in viscosity is observed until a maximum is reached, beyond which a continuous reduction of viscosity ensues. Viscosity development is a combined result of HASE-surfactant interactions, accompanied by constant rearrangement of the hydrophobic associative junctions, and electrostatic interactions.

The Bildegradability of Carrageenan-based Film by Microorganisms (Carrageenan 필름의 미생물에 의한 생분해도 측정)

  • Kang, Seong Gook;Jung, Soon-Teck;Park, Hyun Jin;Rhim, Jong Whan
    • Microbiology and Biotechnology Letters
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    • v.23 no.6
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    • pp.702-709
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    • 1995
  • Degradation Of $\kappa $-carrageenan-based film by microorganisms screened from carrageenan source and activated sludge of a carrageenan producing factory was investigated by measuring changes of pH, viscosity, total sugar and total organic carbon (TOC) of the medium containing $\kappa $-carrageenan as a carbon source. Initially fifteen strains of microorganism were isolated from carrageenan source and activated sludge and then three organisms among them were selected based on the ability of growing in the medium including 0.3% $\kappa $-carrageenan as a sole carbon source. They were identified as Escherichia coli, Saccharomyces cerevisiae and Aspergillus niger. As indices of biodegradability Of $\kappa $-carrageenan based film, the changes of pH, viscosity, total sugar, and TOC of the carrageenan film-based medium were tested by the cultivation of single or mixed strains of the identified organisms. Mixed culture showed the highest biodegradability, which resulted in the changes of pH from 6.5 to 3.0, viscosity from 164 cps to 15.6 cps, total sugar content from 2.35 g/l to 0.53 g/l and TOC from 5721 ppm to 232 ppm after 30 days of cultivation. The biodegradability determined as the reduction rate of TOC by pure cultures of Asp. niger, E. coli, Sacch. cerevisiae and mixed culture of the three organisms were 94%, 86%, 80% and 96%, respectively.

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Measurement of Viscosity and Numerical Analysis of High Speed Injection Molding for Thin-Walled LGP (박형 도광판의 고속사출성형을 위한 수지 점도 측정 및 수치해석)

  • Jung, T.S.;Kim, J.S.;Ha, S.J.;Cho, M.W.
    • Transactions of Materials Processing
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    • v.23 no.1
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    • pp.41-48
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    • 2014
  • The light guide plate has become the major component for the backlight module in general information technology products (e.g. mobile phones, monitors, etc.). High speed injection molding has been adopted for thin walled LGP giving advantages such as weight, shape, size, and reduction in production costs. In the current study, the rheological characteristics of high liquidity plastic resin PC(HL8000) were measured using a capillary rheometer to improve the reliability of the numerical analysis for high speed injection molding. With the measured viscosity and PVT of PC(HL8000), numerical analysis of injection molding was conducted using the simulation software(Moldflow). Filling time and deflection were predicted and compared with those of traditional PC resins(H3000, H4000). The results show that PC(HL8000) has significantly different rheological characteristics during high speed injection molding. Hence proper properties of the resin should be used to improve the accuracy of numerical predictions.

Study on physical characteristics of grouts for backfilling ground heat exchanger (수직 밀폐형 지중 열교환기용 뒤채움재의 물리적 특성 연구)

  • Lee, Chul-Ho;Gil, Hu-Jeong;Choi, Hang-Seok;Choi, Hyo-Pum;Woo, Sang-Baik
    • Proceedings of the Korean Geotechical Society Conference
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    • 2008.03a
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    • pp.533-544
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    • 2008
  • To obtain the physical properties of grout materials, that is the thermal conductivity and viscosity, which are used for backfilling ground heat exchangers, nine bentonite grouts and cement grouts being adapted in the United State have been considered in this study. The bentonite grouts show that the thermal conductivity and viscosity increase with the content of bentonite or filler (silica sand). The saturated cement grouts appear to possess much higher thermal conductivity than the saturated bentonite grouts, and the reduction of thermal conductivity in the cement grouts after drying specimens is less than the case of the bentonite grouts. To investigate the performance of cement grouts, fifteen samples were prepared by varying the water/cement ratio and the amount of sand and bentonite added into the cement mortar. Maintaining the moisture content of grouts is a crucial factor in enhancing the efficiency of ground heat exchangers.

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MEASUREMENT OF FLOW DISTRIBUTION IN A STRAIGHT DUCT OF RAILWAY TUNNEL MOCK-UP USING PIV AND COMPARISON WITH NUMERICAL SIMULATION (PIV 기법을 이용한 모형철도터널 직관덕트에서 유동 분포 계측 및 수치해석 결과와의 비교분석)

  • Jang, Y.J.;Jung, W.S.;Park, I.S.
    • Journal of computational fluids engineering
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    • v.15 no.3
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    • pp.39-45
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    • 2010
  • The turbulent flows in a tunnel mock-up($10L{\times}0.5W{\times}0.25H$ m3 : scale reduction 1/20) with rectangular cross section were investigated. The instantaneous velocity fields of Re = 49,029, 89,571 were measured by the 2-D PIV system which is consisted of double pulsed Nd:Yag laser and the tracer particles in the straight-duct mock-up where the flows were fully developed. The mean velocity profiles were taken from the ensemble averages of 1,000 instantaneous velocity fields. Simultaneously, numerical simulations(RANS) were performed to compare with experimental data using STREAM code. Non-linear eddy viscosity model (NLEVM : Abe-Jang-Leschziner Eddy Viscosity Model) was employed to resolve the turbulent flows in the duct. The calculated mean velocity profiles were well compared with PIV results. In the log-law profiles, the experimental data were in good agreement with numerical simulations all the way to the wake region except the viscous sub-layer (near wall region).

Reduction of Drying Energy for After Dryers Using Oxidized Starch Ester (산화에스테르전분을 이용한 표면사이징 공정의 건조에너지 저감)

  • Jeong, Young Bin;Lee, Hak Lae;Youn, Hye Jung;Jung, Kwang Ho;Ji, Kyoung Rak;Kim, Young Seok
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.4
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    • pp.9-15
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    • 2013
  • An oxidized starch ester was prepared and used for surface sizing. Esterification of starch decreased both Brookfield viscosity and Brabender viscosity substantially even though the solids level was increased by 2% from 14% to 16%. Surface sizing with the esterified starch gave better performance in tensile strength, stiffness and compressive strength than surface sizing with oxidized starch in the laboratory. Advantages in strength improvement, however, were not obtained when it was applied in commercial papermaking process. This was attributed to the fact that the influence of starch types has been nullified by high pressure penetration that occurs in the commercial papermaking process. Drying energy consumption, however, decreased by 3.3% by substituting the low solids oxidized starch with a high solids starch ester.