• Title/Summary/Keyword: varying thickness

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A Polymer Interface for Varying Electron Transfer Rate with Electrochemically Formed Gold Nanoparticles from Spontaneously Incorporated Tetrachloroaurate(III) Ions

  • Song, Ji-Seon;Kang, Chan
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1683-1688
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    • 2007
  • This paper presents a novel simple method for introducing gold nanoparticles in a poly(4-vinylpyridine) (PVP) polymer layer over a glassy carbon (GC) electrode with the aim of forming a tunable electrochemical interface against a cationic ruthenium complex. Initially, AuCl4 ? ions were spontaneously incorporated into a polymer layer containing positively charged pyridine rings in an acidic media by ion exchange. A negative potential was then applied to electrochemically reduce the incorporated AuCl4 ? ions to gold nanoparticles, which was confirmed by the FE-SEM images. The PVP layer with an appropriate thickness over the electrode blocked electron transfer between the electrode and the solution phase for the redox reactions of the cationic Ru(NH3)6 2+ ions. However, the introduction of gold nanoparticles into the polymer layer recovered the electron transfer. In addition, the electron transfer rate between the two phases could be tuned by controlling the number density of gold nanoparticles.

Electro-Optical Hysteresis by the In-plane Modulation of the Molecular Reorientation in Highly Twisted Nematic Liquid Crystal Devices

  • Yu, Chang-Jae;Jeong, Cherl-Hyun;Hong, Sun-Kwang;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1147-1150
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    • 2004
  • We studied on an electro-optical (EO) hysteresis, coming from the in-plane modulation of the molecular reorientation, in highly twisted nematic liquid crystal devices. Varying a ratio d/$P_0$ of the cell thickness d to the natural pitch $P_0$, the EO hysteresis and the twisted angle transition were observed and analyzed in terms of the periodicity of the in-plane modulation within the continuum theory.

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Frost Formation on a Cold Cylindrical Surface in Cross Flow (직교류내 원통형 냉각표면에서의 착상)

  • Lee, Kwan-Soo;Lee, Dong-Hoon;Yang, Dong-Keun
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.8 s.227
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    • pp.989-995
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    • 2004
  • This paper presents a semi-empirical model to predict the frost growth formed on the cold cylinder surface. The model is composed of the correlations for frost properties including the various frosting parameters and local heat transfer coefficient. The effects of varying the correlations for local heat transfer coefficient on the frost growth are examined to establish the model. The numerical results are compared with experimental data obtained by the previous researchers. The results agree well with the experimental data within a maximum error of $13\%$. As the results, the frost thickness decreases with changing angular position from front stagnation to separation point. Also, the effects of air velocity on the frost growth are negligible, as compared to the other frosting parameters.

Shape accuracy and curing characteristics of photopolymer during fabrication of three-dimensional microstructures using microstereolithography (마이크로광조형법을 이용한 미세삼차원구조물의 제조공정 중 형상정밀도 및 경화특성에 관한 연구)

  • Jung, Dae-Jun;Kim, Sung-Hoon;Jeong, Sung-Ho
    • Journal of the Korean Society for Precision Engineering
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    • v.21 no.1
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    • pp.46-50
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    • 2004
  • The curing characteristics of a liquid photopolymer during microstereolithography and the shape accuracy of thereby fabricated microstructures were investigated experimentally. A He-Cd laser with a wavelength of 442nm and a photopolymer consisted of a commercial resin from SK chemical and a photoinitiat or were used for the experiment. By varying the laser beam power and scanning speed of the focused laser beam, minimum curing thickness of 50 ${\mu}ㅡ$ was obtained. The distortion of solidified structure due to adhesion force was measured and the optimum fabrication conditions were determined. Also, the feasibility of direct fabrication of three-dimensional microstructures by Super IH process was examined.

Smooth and uniform coated films on flexible substrates by optimization of slot-die process parameters

  • Jeong, Guk-Chae;Jeong, Tae-Jeong;Kim, Yeong-Guk;Choe, Cheol-Jin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.179-179
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    • 2009
  • For the deposition of the semiconductor nanocrystals or quantum dots, it is required to have the substrates with smooth surface roughness. Slot-die coating method wad adopted and optimized varying the processing parameters like coating speed, gap distance, solution concentration, etc to get the smooth coated films on flexible substrates. The coating speed in slot-die method was varied from 1 m/min to 2.5 m/min focusing especially on its industrial usage. The gap distance between the substrate surface and slot-die lip was changed also to control mainly the thickness of coated films.

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Optimal Design of the Rotor Structure by using Box-Behnken Method for IPMSM (Box-Behnken법을 이용한 매입형 영구자석 동기전동기의 회전자 구조 최적설계)

  • Han, Jung-Ho;Kim, Won-Ho;Jang, Ik-Sang;Kim, Mi-Jung;Lee, Ki-Doek;Lee, Jae-Jun;Lee, Ju
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.949-950
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    • 2011
  • There are various ways of optimizing rotor design of Interior Permanent Magnet Synchronous Motors(IPMSM). In this paper, the best optimized design value was found by varying the Bridge thickness of PM in the rotor and changing Rib. The set design values were torque, 5 harmonics, 7 harmonics, and safety factor. Also, in order to make practical design value easily and quickly for optimization, Box-Behnken of Response Surface Method(RSM) method was used. Therefore, IPMSM resulted an optimized design model with high torque, low harmonics, and constant value of safety factor.

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Analysis of Dielectric-Loaded Surface Plasmon Polariton Waveguides at Telecommunication Wavelengths (광통신 대역에서의 유전체 직각 릿지 표면 플라즈몬 도파로 해석)

  • Jung, Jae-Hoon
    • Journal of the Institute of Electronics Engineers of Korea TC
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    • v.47 no.11
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    • pp.43-48
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    • 2010
  • The main features of a dielectric-loaded surface plasmon polariton waveguide are analyzed such as mode effective index and propagation length. These parameters are calculated using the finite element method for different metal-polymer pairs while varying the ridge width and thickness. As a performance metric, we employ the 2D figure of merit including two conflicting parameters i.e. mode effective index and propagation length. The results obtained here allow one to identify the parameter range for realizing the dielectric-loaded surface plasmon polariton waveguide and to choose dimension and material of the ridge for subwavelength confinement and moderate propagation loss at telecom wavelengths.

Lateral Arm Flaps : Its Clinical Applications and Superiority (외측 상완 피판 : 그 응용과 우수성)

  • Park, Myong-Chul;Park, Dong-Ha;Lee, Byeong-Min;Kim, Kwan
    • Archives of Reconstructive Microsurgery
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    • v.5 no.1
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    • pp.62-69
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    • 1996
  • Lateral arm flap has been used for the reconstruction of the various defects in hand, head and neck region. This flap is highly dependable as a free flap because of its thin flap thickness, constant vascular anatomy and possibility of osteocutaneous flap and fascial flap. Recently, many authors tried extended approach for vascular pedicle and distal flap extension for bigger defects. In this study, we review previous articles and 14 cases used lateral arm flaps for coverage of the varying defect on head and neck, upper and lower extremities succesfully. In conclusion, lateral arm flap has constant anatomical structure and can overcome the disadvantages such as short pedicle length and limited flap size, then the range of its application can be very widened.

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Elastic Modulus Prediction for Design of Sintered Aluminum by Ultrasonic (초음파에 의한 알루미늄 소결체 설계를 위한 탄성계수 예측)

  • Nam, Young-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.7
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    • pp.590-596
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    • 2008
  • The ultrasonic velocities of sintered aluminum with varying density were measured in order to deduce the mechanical properties for optimum design of the sintered aluminum. Specimens with different densities were prepared by the plasma activated sintering machine. The density distribution of sintered aluminum becomes partially inhomogeneous because of the friction between the powder and the die during compaction. The elastic moduli are increased as the ultrasonic velocity is increased. Furthermore, Poisoon's ratio is depending on not only the density but also the size and distribution of voids. As the specimen's thickness increases, the center frequency in the frequency spectrum of the reflection wave is shifted to the low frequency. The attenuation coefficient of ultrasonic wave is decreased inversely as the density increased.

Analysis for Shielding Effectiveness of an Enclosure with a Dielectric-B acted Rectangular Aperture (유전체로 막힌 사각 개구를 갖는 함체의 차폐 효과 해석)

  • Kim, Su-Han;Lee, Jae-Hyun
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.20 no.1
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    • pp.60-66
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    • 2009
  • A new analytical method is presented for the shielding effectiveness(SE) of an enclosure with a dielectric-backed aperture. The previously proposed methods cannot consider the effect of the dielectric on the aperture. The comparisons among our method, previous method, and commercial programs give good correspondence. The method is used to calculate SE with varying permittivity and thickness of dielectric sheet, probe position, width and height of aperture.