• Title/Summary/Keyword: varied flow

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A Study on the Elution Behavior of some Metal-N-Alkylisonitrosoacetylacetone imine Chelates by Reversed Phase High Performance Liquid Chromatography (역상 액체 크로마토그래피에 의한 몇 가지 금속-N-Alkylisonitrosoacetylacetone imine 킬레이트의 용리거동에 관한 연구)

  • Kim, Yong Jun;Kewon, Ji Hae;Lee, Won
    • Analytical Science and Technology
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    • v.5 no.1
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    • pp.63-71
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    • 1992
  • Liquid chromatographic behavior of Pd(II), Ni(II) and Co(III) in N-Alkylisonitrosoacetylacetone imine(HIAA-NR) chelates was investigated by reversed phase high perfomance liquid chromatography. The optimum conditions for the separation of IAA-NR-metal chelates were examined respect to the flow rate and mobile phase strength. The metal-N-Alkylisonitrosoacetylacetone imine chelates in solution were successfully separated on Novapak $C_{18}$ column using acetonitrile/water mixture as mobile phase. The elution order of chelates is methyl>ethyl>propyl>butyl as N-alkyl group for ligand is varied. It was found that all IAA-NR-metal chelates were eluted in an acceptable range of capacity factor value($0{\leq}log\;k^{\prime}{\leq}1$). The dependence of log k' on the volume fraction of water in the binary mobile phase was examined. Also, the dependence of k' on the liquid-liquid extraction distribution ratio(Dc) in acetonitrile-water-alkane extraction system was investigated for IAA-NR-metal chelate. Both kinds of dependence are linear, which suggests that the retention of the electroneutral metal chelates on Novapak $C_{18}$ column is largely due to the hydrophobic effect.

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River Flow Forecasting Model for the Youngsan Estuary Reservoir Operations(I) -Estimation Runof Hydrographs at Naju Station (영산호 운영을 위한 홍수예보모형의 개발(I) -나주지점의 홍수유출 추정-)

  • 박창언;박승우
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.36 no.4
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    • pp.95-102
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    • 1994
  • The series of the papers consist of three parts to describe the development, calibration, and applications of the flood forecasting models for the Youngsan Estuarine Dam located at the mouth of the Youngsan river. And this paper discusses the hydrologic model for inflow simulation at Naju station, which constitutes 64 percent of the drainage basin of 3521 .6km$^2$ in area. A simplified TANK model was formulated to simulate hourly runoff from rainfall And the model parameters were optirnized using historical storm data, and validated with the records. The results of this paper were summarized as follows. 1. The simplified TANK model was formulated to conceptualize the hourly rainfall-run-off relationships at a watershed with four tanks in series having five runoff outlets. The runoff from each outlet was assumed to be proportional to the storage exceeding a threshold value. And each tank was linked with a drainage hole from the upper one. 2. Fifteen storm events from four year records from 1984 to 1987 were selected for this study. They varied from 81 to 289rn'm The watershed averaged, hourly rainfall data were determined from those at fifteen raingaging stations using a Thiessen method. Some missing and unrealistic records at a few stations were estimated or replaced with the values determined using a reciprocal distance square method from abjacent ones. 3. An univariate scheme was adopted to calibrate the model parameters using historical records. Some of the calibrated parameters were statistically related to antecedent precipitation. And the model simulated the streamflow close to the observed, with the mean coefficient of determination of 0.94 for all storm events. 4. The simulated streamflow were in good agreement with the historical records for ungaged condition simulation runs. The mean coefficient of determination for the runs was 0.93, nearly the same as calibration runs. This may indicates that the model performs very well in flood forecasting situations for the watershed.

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Characteristics and EMCs of NPS Pollutants Runoff from a Forest-Paddy Composite Watershed (산림논복합 소유역에서의 비점부하 강우유출 특성 및 EMC 산정)

  • Song, In-Hong;Kang, Moon-Seong;Hwang, Soon-Ho;Song, Jung-Hun
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.4
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    • pp.9-17
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    • 2012
  • This study was aimed to characterize non-point source (NPS) pollutant runoff and estimate event mean concentrations (EMCs) from a small rural watershed located at the headwater area of the Gyeongan stream. The study watershed consists of the two major landuse, forest (72 %) and paddy field (28 %). The nine rainfall events ranging from 18.5 to 192.6 mm in amount were monitored in this study. Stream flow was measured at the watershed outlet using a water level gauge, while a number of water samples for each event were collected and analysed for water quality. Event pollutant loads varied greatly depending on rainfall events varying from 22.6 to 3,134.2 mg/L, 0.32 to 24.56 mg/L, 0.090 to 1.320 mg/L, and 2.3 to 149.8 mg/L for SS, TN, TP, and COD, correspondently. The respective mean EMCs were estimated by 104.2, 1.00, 0.168, and 7.9 mg/L. The Pearson correlation analysis showed that COD EMC was significantly correlated with those of SS, TN, and TP. Rainfall runoff ratio appeared to be negatively correlated with EMCs of SS, TP, and COD, although not statistically significant. The event loads from the largest rainfall was greater than the sum of those from the remaining eight events. The study results suggest that the appropriate management of intensified storm events are of greater importance in curbing NPS loads, while the estimated EMCs provide base data for the unit pollutant loads determination for the forest-paddy composite upstream watershed.

Study on Heat Transfer Characteristic of Shell-and-Tube Heat Exchanger with Plate Fin (판형 핀을 가진 원통-다관형 열교환기의 열전달 특성에 관한 연구)

  • Lim, Tae-Woo;Cho, Dong-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.1
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    • pp.46-51
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    • 2009
  • In this work, the experimental investigation was carried out to evaluate the heat transfer performance on the shell side of shell-and-plate finned tube heat exchanger with three different tube numbers(9, 13 and 19). Oil flowing on the shell side was cooled by cold water flowing inside the tubes. A shell-and-tube heat exchanger of an oil cooler consisted of one shell pass and two tube passes with the inner tube diameter of 8.82 mm and the tube length of 575 mm. Mass flow rate was varied from 1.2 to $6.0\;m^3/h$ for oil and from 0.6 to $3.0\;m^3/h$ for cold water, respectively. From the experiment of shell-and-plate finned tube heat exchanger, the overall heat transfer coefficient of heat exchanger with 9 tubes was compared with that of 13 and 19 tubes. It was found that the heat transfer coefficients in shell side of heat exchanger with 9 plate finned tubes showed averagely 1.8 times and 2.3 times higher than those of 13 and 19 tubes, respectively.

Cathode Power Development of Hall Thruster for Small Satellite using Microwave cathode (마이크로웨이브 음극을 이용한 소형 인공위성의 홀 추력기용 음극전원 개발)

  • Kang, Seokhyun;Choo, Wongyo;Choi, Junku;Jeong, Yunhwang;Kim, Younho;Kang, Seongmin;Kuninaka, Hitoshi;Cha, Hanju
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.42 no.11
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    • pp.974-980
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    • 2014
  • A power supply of cathode has been developed for hall-effect thruster for small satellite. A microwave cathode has been applied to the electric propulsion system and cathode power is necessary in oder to work securely. Anode current is varied by a flow rate controlled by anode tank pressure. Then cathode current has to be controled in proportion by anode current. So cathode power supply has been designed to offer a current proportional to anode current. Also cathode power has been tuned to work securely for cathode to emit more electron than anode within 0.03A. The function test of cathode power was performed by constructing an equivalent load for anode and cathode. It has been tested in a vacuum chamber in order to ensure a stable operation of the thruster. And it was confirmed that thruster normally has been operated in the space environment after the launch.

Diurnal Variation, Vertical Distribution and Source Apportionment of Carcinogenic Polycyclic Aromatic Hydrocarbons (PAHs) in Chiang-Mai, Thailand

  • Pongpiachan, Siwatt
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.3
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    • pp.1851-1863
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    • 2013
  • Diurnal variation of particulate polycyclic aromatic hydrocarbons (PAHs) was investigated by collecting PM10 at three different sampling altitudes using high buildings in the city center of Chiang-Mai, Thailand, during the relatively cold period in late February 2008. At site-1 (12 m above ground level), B[a]P concentrations ranged from 30.3-1,673 pg $m^{-3}$ with an average of $506{\pm}477\;pg\;m^{-3}$ contributing on average, $8.09{\pm}8.69%$ to ${\Sigma}PAHs$. Ind and B[b]F concentrations varied from 54.6 to 4,579 pg $m^{-3}$ and from 80.7 to 2,292 pg $m^{-3}$ with the highest average of $1,187{\pm}1,058\;pg\;m^{-3}$ and $963{\pm}656\;pg\;m^{-3}$, contributing on average, $19.0{\pm}19.3%$ and $15.4{\pm}12.0%$ to ${\Sigma}PAHs$, respectively. Morning maxima were predominantly detected in all observatory sites, which can be described by typical diurnal variations of traffic flow in Chiang-Mai City, showing a morning peak between 6 AM. and 9 AM. Despite the fact that most monitoring sites might be subjected to specific-site impacts, it could be seen that PAH profiles in Site-1 and Site-2 were astonishingly homogeneous. The lack of differences suggests that the source signatures of several PAHs become less distinct possibly due to the impacts of traffic and cooking emissions from ground level.

An Experimental Study of Combustion Characteristics in a Model Gas Turbine Combustor (모형 가스터빈 연소기의 기초 연소특성에 대한 실험적 연구)

  • Lee, Jang-Su;Kim, Min-Ki;Park, Sung-Soon;Yoon, Young-Bin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.263-266
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    • 2009
  • The mainly objectives of this study was a combustion dynamics and instability characteristics in a model gas turbine dump combustor which is the scale down of GE 7FA+e DLN 2.6 gas turbine combustor. Model gas turbine injector has 2-stage swirl vane and it’s reduced 1/3 size of the original one. The shape of plenum and combustor were designed for similar acoustic characteristics. Inlet air was preheated to $200{\sim}400^{\circ}C$. The flow velocity at mixing nozzle was 30 to 75 m/s and equivalent ratio was 0.4 to 1.2. The combustor length was varied for different acoustic characteristics to $375{\sim}700\;mm$. As the result, this research have been show the combustion instability was observed at lower equivalence ratios ($\Phi$ < $0.5{\sim}0.6$) and higher equivalent ratios ($\Phi$ > $1.1{\sim}1.2$).

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Directions for Muti-institutional Cooperation in Follow-up Management of Prostatic Disease Screening for the Low-income Group in Gangwon-do (강원도 저소득층의 전립선질환 검진사업과 사후관리를 위한 유관기관 협력방안)

  • Jang, Sungok;Lee, Jongseok
    • Korean Journal of Health Education and Promotion
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    • v.30 no.4
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    • pp.99-110
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    • 2013
  • Objectives: This study aimed to investigate factors related to prostate disease and follow-up procedure on health examination program in Gangwon-do. Methods: The studied population was 16,501 male aged 40 or more, who underwent screening tests for prostatic disease in 2011 health examination program designed for the low income residents in Gangwon-do. The screening tests included prostate specific antigen (PSA), international symptom score (IPSS), and maximal flow rate (Qmax). We conducted chi-square test for trend, two independent samples t-test, and binary logistic regression to find out the relationship between prostate cancer or benign prostatic hyperplasia and risk factors such as age, PSA level, and IPSS. Results: The number of subjects who turned out positive for PSA level (> 3.8ng/ml) was 971 men accounting for 5.9%. The result of post survey on them showed that 511 subjects (52.6%) got the urology check-up: 156 (30.5%) were diagnosed as normal, 286 (56.0%) as benign prostatic hyperplasia, and 69 (13.5%) as prostate cancer. The detection rate for prostate cancer was 8.8% when PSA level was between 3.81 and 9.99g/ml, and was 30.6% when PSA level was more than 10.00ng/ml. The rates of further testing varied depending on the communities from 26.7% to 68.2%, which was mainly affected by the role of local health center. Conclusions: Our findings indicate that enhanced quality control of local health center and empowerment of screening agency would increase the effort of coupled institutions between public and private sectors.

Control of Dimethyl Sulfide Emissions Using Biofiltration

  • Kong, Sei-Hun;Kim, Jo-Chun;Allen, Eric R.;Park, Jong-Kil
    • Journal of Environmental Science International
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    • v.11 no.8
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    • pp.819-827
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    • 2002
  • Laboratory scale experiments were conducted to evaluate the performance of a biofilter for eliminating dimethyl sulfide(DMS). A commercial compost/pine bark nugget mixture served as the biofilter material for the experiments. The gas flow rate and DMS concentration entering the filter were varied to study their effect on the biofilter efficiency. The operating parameters, such as the residence time, inlet concentration, pH, water content, and temperature, were all monitored throughout the filter operation. The kinetic dependence of the DMS removal along the column length was also studied to obtain a quantitative description of the DMS elimination. High DMS removal efficiencies(>95%) were obtained using the compost filter material seeded with activated sludge. DMS pollutant loading rates of up to 5.2 and 5.5 g-DMS/m$^3$/hr were effectively handled by the upflow and downflow biofilter columns, respectively. The macrokinetics of the DMS removal were found to be fractional-order diffusion-limited over the 9 to 25 ppm range of inlet concentrations tested. The upflow column had an average macrokinetic coefficient(K$\_$f/) of 0.0789 $\pm$ 0.0178 ppm$\^$$\sfrac{1}{2}$//sec, while the downflow column had an average coefficient of 0.0935 $\pm$ 0.0200 ppm$\^$$\sfrac{1}{2}$//sec. Shorter residence times resulted in a lower mass transfer of the pollutant from the gas phase to the aqueous liquid phase, thereby decreasing the efficiency.

Characteristic of wastewater treatment using Boron-doped Diamond Electrode (붕소가 도핑된 다이아몬드전극을 이용한 폐수처리특성)

  • Lee, Eun-Ju;Einaga, Y.;Fujishima, A.;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.795-798
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    • 2003
  • Toxic organics are of great environmental concern primarily because they are toxic to mammals and birds, and are relatively soluble in water to contaminate surface water and groundwater. In this study, the decomposition of phenol, a widely used organic, in aqueous solutions by Boron doped diamond(BDD) electrode was examined. Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped diamond (BDD) were used as anode for generating ozone gas by electrolysis of acid solution. In this work. we have studied ozone generating system using BDD electrode. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable for electrolyte while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte. Decomposition of phenol concentration in the reaction solution by photolytic ozonation( $UV/O_3$) was analyzed by HPLC epuipped with a UV detector.

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