• Title/Summary/Keyword: vapors

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A Study on Treatment Efficiency of Toluene and CO2 using Vortex Cyclones (보텍스 사이클론을 이용한 Toluene과 CO2 처리효율에 관한 연구)

  • 임계규
    • Journal of Korean Society for Atmospheric Environment
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    • v.20 no.4
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    • pp.493-501
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    • 2004
  • The principle of vortex tube and cyclone was introduced to enhance the treatment efficiency of waste air streams containing particulate matters, toluene, and others developed by Hangreen Tech, Ltd. and Hoseo Chemical and Industrial Technology R&D Center. Adsorption, condensation, and/or coagulation could be induced at low temperature zone formed by vortex tube and Joule-Thomson expansion. The pressurized air was introduced at the tangential direction into the cyclone system applied with the coaxial funnel tube. Easily condensible vapors such as toluene. carbon dioxide, and water vapor were adsorbed enforcedly on coagulated or condensed materials which were formed as cores for coagulation or condensation by themselves. These types of coagulation or condensation rates were rapidly promoted as the diameter being growing up. The maximum removal efficiency for carbon dioxide and toluene was achieved to about 87 and 90 percent, respectively. The Joule-Thomson coefficients were increased with the pressure of air injected in the range of the relative humidities between 10% and 30%. An optimum value was observed within the range of the tested temperatures at a fixed pressure. In conclusion. it could be identified that the treatment efficiency would be depended on the pressure of the process air introduced and physical and chemical characteristics of waste air streams containing target materials for a designed system. The final design parameters should be decided depending upon the given system and target materials.

A Study on the CdTe Single Crystal Growth by Vertical Bridgman Method (수직 Bridgman 법에 의한 CdTe 단결정 성장에 관한 연구)

  • Lee, Jong-Ki;Kim, Wook;Baik, Hong-Koo
    • Journal of Korea Foundry Society
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    • v.10 no.4
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    • pp.324-331
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    • 1990
  • The single crystal of CdTe was grown by modified 6 zone Bridgman method under the conditions of excess Te and excess Cd. To prevent the constitutional supercooling, the crystal growth was done under the temperature gradient of $17^{\circ}C/cm$ in front of the solid /liquid interface and the growth rate was 3mm/hr. The grain morphologies and the growth mechanism were investigated in excess Te and excess Cd conditions. The grain size of excess Te crystal was increased with an increase of the distance from the tip but, in the case of excess Cd crystal, single crystal was not obtained because of the cavities due to the excess Cd vapors so that the grain size was not increased with an increase of the distance from the tip. In addition, the growth of single crystal of CdTe was done with repeated necking ampoule. It was found that the necking had no effects on the grain selection because the cavities trapped in the necking portion acted as heterogeneous nucleation sites.

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Review on Toxic Substances in the Liquid and Gas Phases of Electronic Cigarettes (전자담배 액상 및 기체상 중 유해물질 고찰)

  • Shin, Ho-Sang
    • Journal of Environmental Health Sciences
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    • v.39 no.6
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    • pp.483-491
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    • 2013
  • Objectives: Electronic cigarettes are battery powered devices that convert a nicotine-containing liquid into an inhalable vapor. The device aerosolizes nicotine so that it is readily entrained into the respiratory tract, from where it enters the bloodstream. Information on the safety of E-cigarettes is required. Methods: Seventeen articles on studies analyzing toxic substances in the liquid and gas phases of electronic cigarettes were reviewed. Results: Tobacco-specific nitrosamines, bis(2-ethylhexyl) phthalate, formaldehyde and acetaldehyde, known to be carcinogenic agents in humans or animals, were detected in the liquid and gas phases. In addition, diethyl phthalate, acetone, ethanol, cresol, xylene, propylene, styrene, triethylene glycol, tetraethylene glycol, pentaethylene glycol cis-3-hexen-1-ol, methyl cinnamate and undecane were identified in the liquid and gas phases of E-cigarettes. Propylene glycol, glycerin, 1-methoxy-2-propanol, 1-hydroxy-2- propanone, acetic acid, 1-menthone, 2,3-butanediol, menthol, carvone, maple lactone, benzyl alcohol, 2-methyl-2-pentanoic acid, ethyl mantel, ethyl cinnamate, myosamine, benzoic acid, 2,3-bipyridine, cotinine, hexadecanoic acid, and 1'1-oxybis-2-propanol were detected in the vapors of E-cigarettes. Conclusion: The hazardous compounds identified in the liquid and gas phases of E-cigarettes should be controlled for the lowest concentrations in the raw materials and production procedures.

Risk Assessment for Metalworking Fluids and Respiratory Outcomes

  • Park, Robert M.
    • Safety and Health at Work
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    • v.10 no.4
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    • pp.428-436
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    • 2019
  • Background: Metalworking fluids (MWFs) are mixtures with inhalation exposures as mists, dusts, and vapors, and dermal exposure in the dispersed and bulk liquid phase. A quantitative risk assessment was performed for exposure to MWF and respiratory disease. Methods: Risks associated with MWF were derived from published studies and NIOSH Health Hazard Evaluations, and lifetime risks were calculated. The outcomes analyzed included adult onset asthma, hypersensitivity pneumonitis, pulmonary function impairment, and reported symptoms. Incidence rates were compiled or estimated, and annual proportional loss of respiratory capacity was derived from cross-sectional assessments. Results: A strong healthy worker survivor effect was present. New-onset asthma and hypersensitivity pneumonitis, at 0.1 mg/㎥ MWF under continuous outbreak conditions, had a lifetime risk of 45%; if the associated microbiological conditions occur with only 5% prevalence, then the lifetime risk would be about 3%. At 0.1 mg/㎥, the estimate of excess lifetime risk of attributable pulmonary impairment was 0.25%, which may have been underestimated by a factor of 5 or more by a strong healthy worker survivor effect. The symptom prevalence associated with respiratory impairment at 0.1 mg/㎥ MWF was estimated to be 5% (published studies) and 21% (Health Hazard Evaluations). Conclusion: Significant risks of impairment and chronic disease occurred at 0.1 mg/㎥ for MWFs in use mostly before 2000. Evolving MWFs contain new ingredients with uncharacterized long-term hazards.

A Vapor Sensor Based on a Porous Silicon Microcavity for the Determination of Solvent Solutions

  • Bui, Huy;Nguyen, Thuy Van;Nguyen, The Anh;Pham, Thanh Binh;Dang, Quoc Trung;Do, Thuy Chi;Ngo, Quang Minh;Coisson, Roberto;Pham, Van Hoi
    • Journal of the Optical Society of Korea
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    • v.18 no.4
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    • pp.301-306
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    • 2014
  • A porous silicon microcavity (PSMC) sensor has been made for vapors of solvent solutions, and a method has been developed in order to obtain simultaneous determination of two volatile substances with different concentrations. In our work, the temperature of the solution and the velocity of the air stream flowing through the solution have been used to control the response of the sensor for ethanol and acetone solutions. We study the dependence of the cavity-resonant wavelength shift on solvent concentration, velocity of the airflow and solution temperature. The wavelength shift depends linearly on concentration and increases with solution temperature and velocity of the airflow. The dependence of the wavelength shift on the solution temperature in the measurement contains properties of the temperature dependence of the solvent vapor pressure, which characterizes each solvent. As a result, the dependence of the wavelength shift on the solution temperature discriminates between solutions of ethanol and acetone with different concentrations. This suggests a possibility for the simultaneous determination of the volatile substances and their concentrations.

A Study on Worker Exposure to Organic Solvents in Korea (우리나라 산업장 근로자의 유기용제 폭로에 관한 연구)

  • Paik, Nam Won;Lee, Young Hwan;Yoon, Chung Sik
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.8 no.1
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    • pp.88-94
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    • 1998
  • Korea has been rapidly industrialized during the past 35 years. During this period, Korea has emphasized only production and workers health has been ignored. Workers are most frequently exposed to organic vapors, such as thinners. This study was performed to evaluate worker exposures to organic solvents by size and type of industry. Results are summarized below. Workers were exposed to mixtures of toluene, xylenes, trichloroethylene, n-hexane, acetone, methanol, n-butanol, n-butyl acetate, and MIBK. Considering additive effects of the compounds, exposure indices (EIs) were calculated. It was found that worker exposures to organic solvents were highest in small industries and lowest in large industries. During a day shift, the highest exposure was indicated 3 - 5 p.m. in the afternoon. Workers in small industries had potential exposures exceeding permissible exposure limits for organic solvents. Local exhuast systems were inappropriate and respiratory protective devices were not supplied to the workers in small industries. Neither program for safe use and storage of toxic materials nor program for respirators was found in any of the plants investigated. Based on the results of the study, workers of small scale industries should be considered first in industrial health.

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Particle-size-dependent aging time scale of atmospheric black carbon (입자 크기의 함수로 나타낸 대기 중 블랙카본의 변성시간척도)

  • Park, Sung Hoon
    • Particle and aerosol research
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    • v.5 no.2
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    • pp.45-52
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    • 2009
  • Black carbon, which is a by-product of combustion of fossil fuel and biomass burning, is the component that imposes the largest uncertainty on quantifying aerosol climate effect. The direct, indirect and semi-direct climate effects of black carbon depend on its state of the mixing with other water-soluble aerosol components. The process that transforms hydrophobic externally mixed black carbon particles into hygroscopic internally mixed ones is called "aging". In most climate models, simple parameterizations for the aging time scale are used instead of solving detailed dynamics equations on the aging process due to the computation cost. In this study, a new parameterization for the black carbon aging time scale due to condensation and coagulation is presented as a function of the concentration of hygroscopic atmospheric components and the black carbon particle size. It is shown that the black carbon aging time scale due to condensation of sulfuric acid vapors varies to a large extent depending on the sulfuric acid concentration and the black carbon particle size. This result indicates that the constant aging time scale values suggested in the literature cannot be directly applied to a global scale modeling. The aging time scale due to coagulation with internally mixed aerosol particles shows an even stronger dependency on particle size, which implies that the use of a particle-size-independent aging time scale may lead to a large error when the aging is dominated by coagulation.

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Emission Properties of Electrodeless Sulfur Lamp by Additives (화합물 첨가에 따른 무전극 황램프의 발광특성)

  • Lee, Jong-Chan;Kim, Kwang-Soo;Park, Dae-Hee;Hwang, Myung-Keun;Park, Cheol-Soon
    • Proceedings of the KIEE Conference
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    • 2002.07c
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    • pp.1890-1892
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    • 2002
  • The technology of sulfur lamps that has physical and electrical characteristics comparable to current HID source has been reported. The fundamental principles of the operation of microwave discharges that are used to convert microwave energy to broad spectrum visual light are known. In this paper, emission dependance of microwave discharges in mixture content of sulfur with noble gases was studied. It is shown that the excitation of this gaseous mixture is carried out in two phases: (l) ionization of noble gas atoms by a microwave field and (2) the consequent maintenance of slightly ionized nonequilibrium plasma by the field. These two processes have essentially various thresholds for the microwave pump. The purpose of this work is to investigate spectral properties of the high frequency discharges in a mixture sulfur vapors with noble gases.

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Formation of Thermal Bubble from Particle-Filled Microcavity (미세 입자로 충전된 캐비티에서의 열 기포 형성)

  • Jeong, Kwang-Hun;Lee, Heon-Ju;Chang, Young-Soo;Lee, Yoon-Pyo;Kim, Ho-Young
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.31 no.3 s.258
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    • pp.248-255
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    • 2007
  • Thermal bubble formation is a fundamental process in nucleate boiling heat transfer and many microelectromechanical thermal systems. One of the established facts is that heterogeneous nucleation is originated from vapors trapped inside cavities. Based on this, we performed an experimental study on the formation of thermal bubbles from microcavity fabricated by microfabrication technology on a copper plate. The cavity was filled with aluminum particles to enhance thermal bubble formation. We observed the thermal bubble behaviors, such as bubble incipience, diameter, frequency and coalescence during nucleate boiling. The experimental data showed that the superheat required to trigger the bubble formation was significantly reduced when the cavity was filled with microparticles. We found that the initial increase of superheat led to the increase of both the departure diameter and frequency while the further increase of superheat caused multiple bubbles to coalesce resulting in the decrease of departure frequency.

Comparison of Calibration Models for GPS Antenna Phase Center Variations (GPS 안테나 위상중심변동 보정모델 비교)

  • Park, Kwan-Dong;Won, Ji-Hye
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.24 no.4
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    • pp.319-326
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    • 2006
  • To get the highly-accurate and precise position of a GPS receiver, they should consider the state-of-the-art GPS force and measurement models. Especially, the phase center variations (PCV) of a GPS antenna can cause several centimeters of positioning errors in the vertical direction. In this study, we implemented four different models of PCV and evaluated their impact on the computed coordinates. The test data were taken from the 14 National Geography Information Institute permanent GPS stations and 30 Minisry of Government Administration and Home Affairs sites. For different combinations of calibration methods, an average of 1.3-2.6cm of height difference was observed. Also, we found a maximum error of ${\sim}4mm$ in the estimates of the precipitable water vapors.