• Journal of the Korean Ceramic Society
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• v.48 no.2
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• pp.183-188
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• 2011

In this article, the effect of the crystal structural environment of $Pr^{3+}$ ions on the photoluminescence (PL) characteristics of double tungstates, such as $A(M_{1-X}Pr_X)W_2O_8$ (A=Li, Cs, M = In, Y, Sc, La; $0.007{\leq}x{\leq}0.1$) and $La_{1.96}Pr_{0.04}W_3O_{12}$ are characterized. By varying the ion radius in A and M sites, the structural environment of $Pr^{3+}$ ions were modified. The structural criteria, that is, the point charge electrostatic potentials V around the $Pr^{3+}$ activator, were calculated using the crystal structural parameters. The point charge potential V can be a valid criterion for $^3P_o$ quenching in various double tungstates. When the calculated V values are large (> 6.0), the luminescence from the $^3P_0$ level becomes dominant. When the calculated V values are about 3.8, the $^1D_2$ line appears weakly but $^3P_0$-level luminescence is absent. When the calculated V values are small (< 2.0), the luminescence from the $^1D_2$ level becomes dominant and $^3P_0$-level luminescence is absent. At 2.0$^3P_o$ quenching to $^1D_2$ level occurs substantially in accordance with the structural criterion of the point charge potential model.

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.376.2-376.2
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• 2014

마이크로볼로미터 적외선 센서는 인체감지, 전자부품의 품질검사, 에너지 절감, 산업시설감시 및 군사용으로 다양하게 적용되고 있다. 기존에 이러한 적외선 센서의 감지재료로 VOx 또는 비정질 Si이 가장 많이 사용되고 있으며, VOx는 감도가 높고, 세계적으로 가장 많이 사용되고 있는 물질이다. 본 연구에서는 기존의 VOx 박막 증착법을 개선하여 Zn 산화물 박막을 혼용한 적외선 감지재료를 이용한 마이크로볼로미터 제작 및 특성에 대해 보고한다. RF sputtering 방법으로 약 140 nm의 VOx/ZnO/VOx 샌드위치 박막을 증착하고, 산소분위기에서 열처리함으로써 온도저항계수(TCR)가 약 -3.0 %/K의 값을 갖는 특성을 구현하였다. 갓 증착된 V-Zn 박막에서는 XRD 스펙트럼에서는 V2O5 관련 피크가 주로 관측되었으며, 산소열처리에 의해 VO2 피크가 새롭게 관측되었다. 볼로미터 감지소자는 유효면적 $50{\times}50{\mu}m^2$ 으로 bulk micromaching 공정을 통해 제작하였다. Si 기판위에 SiNx 박막을 PECVD 장치를 이용하여 증착하였으며, 적외선 감지층으로 V-Zn 산화물을 RF sputtering 방법으로 증착하여 열처리 후 SiNx passivation 박막으로 보호하였다. 열적고립을 위해 패터닝 후 Si 기판을 KOH 용액을 이용하여 약 $20{\mu}m$ 식각하여 소자를 구현하였다. 제작된 소자의 특성을 평가한 결과 반응도는 1.57e+4 V/W, 탐지도는 $8.79e+7cmHz^{1/2}/W$를 얻을 수 있었다. 소자의 동작 특성을 평가하기 위해 진공 압력을 1e-3 torr 이하에서 thermoelectric cooler를 장착한 metal package를 제작하여 동작온도에 따른 특성을 평가하였다. 동작온도를 $10^{\circ}C{\sim}40^{\circ}C$로 하여 측정한 결과 동작온도가 증가할수록 신호전압은 감소함을 알 수 있었다.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.467-471
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• 2016

New electron deficient moiety, 6,7-difluoro-2,3-dihexylquinoxaline, was developed for the push-pull type copolymer for organic photovoltaics (OPVs). The PFDTQxF with lower HOMO energy level was synthesized using fluorene and 6,7-difluoro- 2,3-dihexylquinoxaline by Suzuki polymerization. The PFDTQxF thin film shows two absorption peaks at 368 and 493 nm. The HOMO and LUMO energy levels of PFDTQxF are calculated -5.55 and -3.91 eV, respectively. The device comprising PFDTQxF showed a $V_{OC}$ value of 0.47 V, a $J_{SC}$ value of $4.48mA/cm^2$, and a FF of 0.32, which yielded PCE of 0.78%, under the illumination of AM 1.5.

• Journal of The Korean Astronomical Society
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• v.49 no.5
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• pp.175-192
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• 2016

CCD photometric observations of the globular cluster (GC), M53 (NGC 5024), are performed using the 1.8 m telescope at the Bohyunsan Optical Astronomy Observatory in Korea on the same nights (2002 April and 2003 May) as the observations of the GC M92 (NGC 6341) reported by Cho and Lee using the same instrumental setup. The data for M53 is reduced using the same method as used for M92 by Cho and Lee, including preprocessing, point-spread function fitting photometry, and standardization etc. Therefore, M53 and M92 are on the same photometric system defined by Landolt, and the photometry of M53 and M92 is tied together as closely as possible. After complete photometric reduction, the V versus B − V , V versus V − I, and V versus B − I color-magnitude diagrams (CMDs) of M53 are produced to derive the relative ages of M53 and M92 and derive the various characteristics of its CMDs in future analysis. From the present analysis, the relative ages of M53 and M92 are derived using the Δ(B − V ) method reported by VandenBerg et al. The relative age of M53 is found to be 1.6 ± 0.85 Gyr younger than that of M92 if the absolute age of M92 is taken to be 14 Gyr. This relative age difference between M53 and M92 causes slight differences in the horizontal-branch morphology of these two GCs.

• Journal of The Korean Astronomical Society
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• v.48 no.6
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• pp.333-341
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• 2015

A search for hot and bright white dwarfs (WDs) in the Milky Way globular clusters M13 (NGC 6205) and M22 (NGC 6656) is carried out using the deep and homogeneous V I photometric catalog of Anderson et al. and and Sarajedini et al., based on data taken with the ACS/WFC aboard the Hubble Space Telescope (HST). V versus V − I color-magnitude diagrams (CMDs) of M13 and M22 are constructed and numerous spurious detections are rejected according to their photometric quality parameters qfit(V ) and qfit(I). In the case of M13, further radial restriction is applied to reject central stars with higher photometric errors due to central crowding. From each resultant V versus V −I CMD, sixteen and thirteen WD candidates are identified in M13 and M22, respectively. They are identified as stellar objects in the accompanying ACS/WFC images and are found to be randomly distributed across the central regions of M13 and M22. Their positions in the CMDs are in the bright part of the DA WD cooling sequences indicating that they are true WDs. In order to confirm their nature, follow-up spectroscopic observations are needed.

• Journal of the Korea institute for structural maintenance and inspection
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• v.14 no.3
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• pp.123-130
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• 2010

The aim of this paper is a seismic performance evaluation of metallic damper devices which are efficient in workability and installation process. For this V shape and S shape dampers is considered. The strut figures of dampers are V shape and S shape and, the research parameters are strut height and angle of the dampers. ABAQUS program is used for nonlinear finite element analysis. The analysis is performed with the hysteretic curve that has maximum displacement with 50mm and has increased progressive. As a results of evaluating the yield strength, maximum strength and energy dissipation capacity of each device, V and S shape have a good strength capacity and the devices with strut angle $60^{\circ}$ and strut height 140 and 200mm are evaluated stable in seismic behaviors. The response of S shape is more efficient than that of V shape. In the yield strength estimation process, proposed formula can not estimate the yield strength of V and S shape dampers. Even though, the formula can not consider the variation of strut heights and strut angles. Finally the S shape damper is recommended in seismic performance than V shape damper.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.7
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• pp.139-146
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• 2019

This study examined the effect of various arrangement methods for forming peripheral closed hoops in the jacket section on the axial behavior of section enlargement strengthening columns. Four types of peripheral closed hoops arranged in the jacket section were prepared as follows: 1) Closed connection of prefabricated bar units (column P); 2) V-clip installation across the overlapped legs of channel-type bars (column V); 3) Use of glass fiber mesh for an alternative of steel bars (column F); and 4) combination of prefabricated bar units and glass fiber mesh (column PF). The V-clip is designed to form the closed hoops in the jacket section using the overlapped channel-type bars, preventing the opening of the channel bar legs. The glass fiber mesh is to examine the feasibility to apply for closed hoops in the jacket section as an alternative for steel bars, considering the easy construction. In the jacket section of all the strengthened columns, V-ties were arranged for supplementary ties, avoiding the interruption of the existing column. The axial stiffness and strength of the strengthened columns were insignificantly affected by the arrangement methods of closed hoops in the jacket section. The axial ductility ratio of the strengthened columns P, V, and PF was enhanced more than twice of that measured in the non-seismic existing column. However, the column F exhibited a lower ductility than the other strengthened columns because of the fracture of the mesh at the ultimate strength of the column. The V-clip approach was favorable to enhance the ductility of the strengthened column, preventing the opening of the legs of channel-type bars.

• Korean Journal of Crystallography
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• v.1 no.2
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• pp.84-90
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• 1990

1,3-Diazatricyclo (5.2.1.Os .to) decane-2,11-dione , C8H10N2O2. MW=166.15, Monoclinic, P2/n a= 6.585(7) , b=9.089(4), c=12.937(10)A, β=95.72(5)˚, V=770.4A3, Z=4, Dc=1.43(4) g/cm3, λ (Mo Ka)=0.7093A, r=1.Ocm-1, T=295˚K, final R=0.037 for 698 unique observed reflections. The compound is the product of the intramolecular (2+2) photocycloaddition of Nl-(w-butenyl)uracil and belongs to a (5.2.1.O5.10) tricyclic system. A pair of molecules related by the inversion symmetry are held together by the strong hydrogen bonding interactions between 02 and H3 of the uracil moiety.

• Journal of the Korean Chemical Society
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• v.49 no.2
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• pp.239-242
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• 2005

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.55 no.1
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• pp.31-34
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• 2006

A infrared rays sensor or ultrasonic sensor can detect the object at the narrow area, however a pressure sensor can detect man and animal at the wide area. It is necessary to manufacture the sensor by using Pb-free ceramics in the respect of environmental protection. Piezoelectric properties of ceramics added 0.2wt% $La_2O_3\;into\;0.96Bi_{0.5}(Na_{0.84}K_{0.16})_{0.5}+0.04SrTiO_3$ were 0.4 of kp, $31{\times}$10^{-3}Vm/N\;of\;g_{33}$. The output voltage of the pressure sensor is 0.48 V at 20 in$H_2O$. The output voltage of the pressure sensor with driving circuit is 9.8 V, 37 ms width.