• Title/Summary/Keyword: uv-spectra

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Measuring gas metallicity of local AGNs using UV spectra

  • Shin, Jae-Jin;Woo, Jong-Hak
    • The Bulletin of The Korean Astronomical Society
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    • v.37 no.1
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    • pp.50.1-50.1
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    • 2012
  • As a tracer of star formation history, metallicity provides crucial information for understanding galaxy evolution. In the case AGN, gas metallicity is often derived from the flux ratio of UV emission lines, i.e., NV1240 and CIV1549. To investigate the dependence of metallicity on AGN luminosity, black hole mass, and accretion rate, we measure NV1240 and CIV1549 line fluxes and derive gas metallicity of a sample of 73 local Seyfert 1 galaxies and QSOs, using archival UV spectra obtained with the HST and IUE. In this work, we will present the metallicity of local AGN and its relation with AGN properties.

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Emission Spectroscopy of Unstable Molecules using a Fourier Transform Spectrometer (Fourier Transform 분광기를 이용한 불안정한 분자의 방출분광학)

  • Sang Kuk Lee;Un Sik Kim
    • Journal of the Korean Chemical Society
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    • v.37 no.4
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    • pp.371-377
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    • 1993
  • Fourier Transform UV/VIS spectrometer has been modified for emission spectroscopy with the technique of supersonic expansion, in which the unstable molecular radical $CH_3S$ has been generated in a jet by a high voltage DC discharge. The fluorescence spectra of the supersonically cooled radical have been recorded on a Fourier Transform UV/VIS spectrometer. The ratio of signal to noise of the spectra has been improved substantially. Also the rotational structure has been clearly resolved for $CH_3S$ molecular radical.

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A Study on the Properties of Langmuir-Blodgett Films of Polyamic Acid containing p-Methoxyazobenzene (p-Methoxyazobenzene을 함유한 Polyamic acid의 Langmuir-Blodgett막 물성에 관한 연구)

  • Park, Keun-Ho;Lee, Seong-Rak
    • Journal of the Korean Applied Science and Technology
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    • v.15 no.1
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    • pp.55-62
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    • 1998
  • The absorption spectra of polyamic acid containing p-methoxyazobenzene in a mixture of N, N-dimethylacetamide(DMAC) and benzene(1:1 by volume) solution was induced photoisomerization by UV and visible light irradiation. This solution is influenced on temperature according to measure by UV-Vis Spectrophotometer. Ultra thin film of polyamic acid containing p-methoxyazobenzene was prepared on the hydrophilic quartz plate by Langmuir-Blodgett(LB) method. The precursor LB film was heated in a vacuum dry oven at $120^{\circ}C$ in order to convert it into the LB film of polyimide. The absorption spectra of LB films were also induced photoisomerization by UV and visible light irradiation.

A Study on UV Degradation of SBR and NR Containing Polymeric UV Stabilizer (고분자형 자외선 안정제를 함유한 SBR과 NR의 UV 노화 거동에 관한 연구)

  • Kaang, Shin-Young;Nam, Kyoung-Tae;Hong, Chang-Kook;Chae, Kyu-Ho
    • Elastomers and Composites
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    • v.41 no.3
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    • pp.182-193
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    • 2006
  • The retardation effects of a new polymeric UV stabilizer, DGEBA-HALS, on the UV degradation of SBR and NR were investigated in this study. The UV degradation behaviors of three different rubber compounds, without any photostabilizer and with commercial Cyabsorb UV-3529 and DGEBA-HALS, were compared. Also, the physical characteristics such as Young's modulus, tensile strength, blow-off deformation and crosslink density were examined. The Young's modulus was increased by UV irradiation for all samples, and the tensile strength, after UV irradiation, of the compound with UV stabilizer was better than that of the compound without stabilizer. Especially, the tensile strength of UV irradiated NR was improved by adding DGEBA-HALS. The results of blow-off deformation were in accord with those of Young's modulus. The degree of transmission of SBR compounds obtained from UV-vis transmission spectra was improved about 4% by adding the UV stabilizer. Commercial Cyabsorb UJV-3529 and DGEBA-HALS showed similar trends of transmission. The SEM photographs of SBR surface showed that the size of cracks created by UV irradiation became smaller by adding UV stabilizer. In particular, it is observed that the stabilization effect of DGEBA-HALS was better than that of commercial Cyabsorb UV-3529.

Effect of Film Thickness on Structural, Electrical, and Optical Properties of Sol-Gel Deposited Layer-by-layer ZnO Nanoparticles

  • Shariffudin, S.S.;Salina, M.;Herman, S.H.;Rusop, M.
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.2
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    • pp.102-105
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    • 2012
  • The structural, electrical, and optical properties of layer-by-layer ZnO nanoparticles deposited using sol-gel spin coating technique were studied and now presented. Thicknesses of the thin films were varied by increasing the number of deposited layers. As part of our characterization process, XRD and FE-SEM were used to characterize the structural properties, current-voltage measurements for the electrical properties, and UV-Vis spectra and photoluminescence spectra for the optical properties of the ZnO thin films. ZnO thin films with thicknesses ranging from 14.2 nm to 62.7 nm were used in this work. Film with thickness of 42.7 nm gave the lowest resistivity among all, $1.39{\times}10^{-2}{\Omega}{\cdot}cm$. Photoluminescence spectra showed two peaks which were in the UV emission centered at 380 nm, and visible emission centered at 590 nm. Optical transmittance spectra of the samples indicated that all films were transparent (>88%) in the visible-NIR range. The optical band gap energy was estimated to be 3.21~3.26 eV, with band gap increased with the thin film thickness.

Color Enhancement of Natural Sapphires by High Pressure High Temperature Process

  • Song, Jeongho;Noh, Yunyoung;Song, Ohsung
    • Journal of the Korean Ceramic Society
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    • v.52 no.2
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    • pp.165-170
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    • 2015
  • We employed the high-pressure high temperature (HPHT) process to enhance the colors of natural sapphires to obtain a vivid blue. First, we analyze the content of the coloring agent $Fe_2O_3$ using the wavelength dispersive X-ray fluorescence (WD-XRF) method. The HPHT procedure operates under 1 GPa at various temperatures of 1700, 1750, and $1800^{\circ}C$ for 5 minutes using a cubic press. We determine the color changes using the optical microscopic images, UV-VIS near-infrared (NIR) spectra, micro-Raman spectra, and Fourier transform-infrared (FT-IR) spectra for all sapphire samples before and after the treatment. The optical microscopic results indicate that the HPHT process can enhance the sapphire color to a vivid blue at temperatures above $1750^{\circ}C$. The UV-VIS-NIR spectra identify the color changes explicitly and quantitatively through providing the Lab color scales and color differences. Both results demonstrate that the colors of natural sapphires can be enhanced to a vivid blue using the HPHT process above $1750^{\circ}C$ under 1 GPa for 5 minutes.

A New Iron Emission Template for Active Galactic Nuclei

  • Park, Daeseong;Barth, Aaron J.;Ho, Luis C.;Laor, Ari
    • The Bulletin of The Korean Astronomical Society
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    • v.44 no.2
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    • pp.36.2-36.2
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    • 2019
  • Fe II emission is a prominent and ubiquitous feature in the spectra of broad-line Active Galactic Nuclei (AGN) by producing a pseudo-continuum from UV to optical with complex and strong blends of the numerous emission lines themselves, other emission lines, and continuum. Since theoretical modeling of such intricate Fe II emission is very difficult and still far from able to reproduce observed data in detail, an empirical iron emission template, derived from observations of a narrow-line Seyfert 1 galaxy, is an essential and practical tool to obtain accurate measurements of all the emission lines and continuum in AGN spectra. However, the existing iron templates, based on the single prototypical strong Fe II emitter I Zw 1, are suffering from inadequate S/N and non-simultaneous, inconsistent data with limited wavelength coverage, which consequently limit the accuracy of all the spectral measurements. To overcome the limitations and construct an improved iron template with wide spectral coverage, high-quality UV and optical spectra for the new and better identified template galaxy, Mrk 493, were successfully obtained from our HST STIS program (GO-14744). We will show the preliminary results for multicomponent spectral decomposition of the data and template construction with application tests to various AGN spectra and comparison with previous templates.

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A study of defect structures in $LiNbO_{3}$ single crystals by optical absorptions (광흡수에 의한 $LiNbO_{3}$ 단결정의 결함 구조 연구)

  • 김상수
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.3
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    • pp.327-340
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    • 1996
  • In this study, a series of $LiNbO_{3}$ crystals with different [Li]/[Nb] ratios, congruent $LiNbO_{3}$ crystals with doped Mg and with Mg and codoped with Mn were grown by the Czocharalski method. These were investigated by UV and IR spectrophotometry. Stoichiometry dependences of the UV absorption edge and the $OH^{-}$ absorption spectra were studied with different [Li]/[Nb] ratios. The position of the UV absorption edge adn the shape and peak point of the $OH^{-}$ absorption spectra changed monotonously upto a critical concentration of Mg ions. The mechanism of the incorporation of Mg ions changes at this concentration. The decomposition of the $OH^{-}$ absorption spectra using a Gaussian lineshape function showed that in Li-deficient crystals the absorption spectra consist of five components in contrast to more or less perfect stoichiometric crystals which reveal to three components. On the basis of these results, the intrinsic and the extrinsic defect structure models in $LiNbO_{3}$ crystals were examined. The behaviour of $\nu$ (OH) reflects the defect structure and supports the Li-site vacancy model as the intrinsic defect structure model and the corresponding extrinsic defect model. A brief discussion is also given of the behaviour of $\nu$ (OH) in $LiNbO_{3}$ crystals simultaneously doped with several kinds of impurity.

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EFFECT OF PHOTOCHEMICAL REACTIONS ON LUMINESCENCE OF CRYSTALLINE RDX

  • Kim, Hack-Jin;Kang, Tai-Jong
    • Journal of Photoscience
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    • v.2 no.2
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    • pp.83-87
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    • 1995
  • Luminscence spectra and decay of crystalline hexahydro-1,3,5-trinitro-1,3,5-s-tetrazine (RDX) are observed at 90 K and the effects of photochemical reaction on the luminescence of RDX are investigated. The uv light from high power Hg lamp is used for the photochemical reaction of RDX. While no significant changes are observed in the luminescence spectra after the photochemical reaction, the intensity profile of the spectra changes with the progress of chemical reactions. The biexponential decay of luminescence is modified by chemical reactions. Features of the electronic states of crystalline RDX are discussed in relation to the luminescence.

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Separation and Characteristics of Antioxidative Substances in Fermented Soybean Sauce (양조간장으로부터 항산화성 물질의 분리 및 그 특성)

  • Moon, Gab-Soon;Cheigh, Hong-Sik
    • Korean Journal of Food Science and Technology
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    • v.22 no.4
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    • pp.461-465
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    • 1990
  • Fermented soybean sauce was fractionated by gel filteration chromatography and the physico-chemical properties of each fraction were investigated for the study on the separation and characteristics of antioxidative substances in the soybean sauce. The brown coloured melanoidin fractions(MF-I) collected by Sephadex G-10 column were found to contain nitrogeneous compounds and to have strong antioxidative activity and reducing power. The freeze dried MF-I was further fractionated with Sephadex G-50 and G-100 successively and then MF-II and MF-III fractions were observed to be the most effective antioxidant and reducing power among the fractions. The UV-VIS and IR absorption spectra of the each fraction were also determined and discussed.

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