• Title/Summary/Keyword: uv-shielding

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Accumulation of Chlorogenic Acid as a near UV-shielding Compound in Cauliflower Grown under Enhanced UV-B Radiation

  • Shibata, Hitoshi;Tanaka, Tomoyuki;Yonemura, Takeshi;Sawa, Yoshihiro;Ishikawa, Takahiro
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.436-438
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    • 2002
  • Since solar radiation contains wavelength essential for photosynthesis accompanying with near-UV light, UV-B effects on biological parameters and acclimation mechanisms are influenced by photosynthetically active radiation (PAR). Therefore, to elucidate near-UV shielding mechanism in higher plants, we cultivated cauliflower under usual solar radiation and increased UV-B from fluorescent lamps, two- or three-fold excess over continuously estimated UV-B dose in PAR during daytime, using computer regulated systems. Increased UV-B radiation had little effect on growth expressed as fresh weigh and leaf area. Water soluble low molecular weight compounds showing absorption in near UV region were enhanced according to the irradiated UV-B dose. One of compounds in cauliflower leaves was identified as chlorogenic acid. This was found to have no near-UV photosenSitizerable activity and is known to have an ability to scavenge a wide species of active oxygen. Another pro-oxidant compound that generates superoxide anion radical under near-UV irradiation was not induced by increased UV-B during cultivation, and identified as lumazine, a degradation product from folic acid.

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Gamma radiation shielding properties of poly (methyl methacrylate) / Bi2O3 composites

  • Cao, Da;Yang, Ge;Bourham, Mohamed;Moneghan, Dan
    • Nuclear Engineering and Technology
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    • v.52 no.11
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    • pp.2613-2619
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    • 2020
  • This work investigated the gamma-ray shielding performance, and the physical and mechanical properties of poly (methyl methacrylate) (PMMA) composites embedded with 0-44.0 wt% bismuth trioxide (Bi2O3) fabricated by the fast ultraviolet (UV) curing method. The results showed that the addition of Bi2O3 had significantly improved the gamma shielding ability of PMMA composites. Mass attenuation coefficient and half-value layer were examined using five gamma sources (Cs-137, Ba-133, Cd-109, Co-57, and Co-60). The high loading of Bi2O3 in the PMMA samples improved the micro-hardness to nearly seven times that of the pure PMMA. With these enhancements, it was demonstrated that PMMA/Bi2O3 composites are promising gamma shielding materials. Furthermore, the fast UV curing exerts its great potential in significantly shortening the production cycle of shielding material to enable rapid manufacturing.

The Effect of Anti-UV Agents on UV Shielding and Photolytic Aging of Paper

  • Park Saung Bae;Hyun Byung Doo;Eom Tae Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.5 s.108
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    • pp.36-43
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    • 2004
  • The behaviors of deterioration in the mechanical and optical properties of paper during sunlight exposure are mainly attributed to UV irradiation. The effect of different additives (anti-UV agents) on paper properties during exposure was studied. The results showed negligible changes in the mechanical properties of samples prepared with two different ways, whereas the shielding ability was increased when the additives were applied to the surface of hand sheets. Also, the paper which is treated with anti UV agents can keep freshness more effectively of agricultural products from UV irradiation.

Green synthesis of Lead-Nickel-Copper nanocomposite for radiation shielding

  • B.M. Chandrika;Holaly Chandrashekara Shastry Manjunatha;R. Munirathnam;K.N. Sridhar;L. Seenappa;S. Manjunatha;A.J. Clement Lourduraj
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4671-4677
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    • 2023
  • For the first time Pb, Ni, and Cu nanocomposites were synthesized by versatile solution combustion synthesis using Aloevera extract as a reducing agent, to study the potential applications in X-ray/gamma, neutron, and Bremsstrahlung shielding. The synthesized Lead-Nickel-Copper (LNC) nanocomposites were characterized by PXRD, SEM, UV-VIS, and FTIR for the confirmation of successful synthesis. PXRD analysis confirmed the formation of multiphase LNC NCs and the Scherrer equation and the W-H plot gave the average crystal sizes of 19 nm and 17 nm. Surface morphology using SEM and EDX confirmed the presence of LNC NCs. Strong absorption peaks were analyzed by UV visible spectroscopy and the direct energy gap is found to be 3.083 eV. Functional groups present in the LNC NCs were analyzed by FTIR spectroscopy. X-ray/gamma radiation shielding properties were measured using NaI(Tl) detector coupled with MCA. It is found to be very close to Pb. Neutron shielding parameters were compared with traditional shielding materials and found LNC NCs are better than lead and concrete. Secondary radiation shielding known as Bremsstrahlung shielding characteristics also studied and found that LNC NCs are best in secondary radiation shielding. Hence LNC NCs find shielding applications in ionizing radiation such as X-ray/gamma and neutron radiation.

A Study on Adhesion of Mechanical Properties of Rubber by MgCl2 (투명 차폐 필름 구현을 위한 전도성 복합 바인더의 입자구조에 따른 성능 평가)

  • Park, Ji-won;Back, Jong-Ho;Lee, Tae-Hyung;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.18 no.2
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    • pp.59-67
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    • 2017
  • Recently, integration of parts is accelerating according to the growth of the smart mobile industry. The integration of these parts causes problems of interference phenomena between the parts, and the importance of electromagnetic wave shielding technology to solve this problem is highlighted. Electromagnetic wave shielding technology is implemented so as to reflect or absorb electromagnetic waves, and generally conductive materials are utilized for electromagnetic wave shielding. Transparent shielding technology is required according to recent industrial changes. In this research, we propose transparent the shielding film using imprint technology with conductive composite binder. Utilizing UV polymerized acrylic binder to produce a conductive composite binder. Spherical, plate and stacked silver particles were used for conductivity. The changes of the curing characteristics, conductivity and adhesion were observed according to the structural characteristics of the silver particles. The use of spherical particles was the most efficient in the curing process, and an additional curing system was required to complement the UV-shadowing structure. In the conductivity evaluation, the stacked structure showed excellent characteristics. The adhesion of spherical system was the best. It is evaluated as a result of irregularities on the surface. Ultimately, the patterned film using this showed excellent transparency characteristics.

The Effect of SiO2 Shell on the Suppression of Photocatalytic Activity of TiO2 and ZnO Nanoparticles

  • Lee, Min Hee;Patil, Umakant Mahadev;Kochuveedu, Saji Thomas;Lee, Choon Soo;Kim, Dong Ha
    • Bulletin of the Korean Chemical Society
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    • v.33 no.11
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    • pp.3767-3771
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    • 2012
  • In this study, we investigate the potential use of $TiO_2@SiO_2$ and $ZnO@SiO_2$ core/shell nanoparticles (NPs) as effective UV shielding agent. In the typical synthesis, $SiO_2$ was coated over different types of $TiO_2$ (anatase and rutile) and ZnO by sol-gel method. The synthesized $TiO_2@SiO_2$ and $ZnO@SiO_2$ NPs were characterized by UV-Vis, XRD, SEM and TEM. The UV-vis absorbance and transmittance spectra of core@shell NPs showed an efficient blocking effect in the UV region and more than 90% transmittance in the visible region. XRD and SAED studies confirmed the formation of amorphous $SiO_2$ coated over the $TiO_2$ and ZnO NPs. The FESEM and TEM images shows that coating of $SiO_2$ over the surface of anatase, rutile $TiO_2$ and ZnO NPs resulted in the increase in particle size by ~30 nm. In order to study the UV light shielding capability of the samples, photocatalytic degradation of methylene blue dye on $TiO_2@SiO_2$ and $ZnO@SiO_2$ NPs was performed. Photocatalytic activity for both types of $TiO_2$ NPs was partially suppressed. In comparison, the photocatalytic activity of ZnO almost vanished after the $SiO_2$ coating.

Preparation of ZnO Nano Powder and High-transparent UV Shielding Dispersion Sol (ZnO 나노분말 및 고투명성 자외선 차단 분산 졸의 제조)

  • Lee, Hun Dong;Kim, Jin Mo;Son, Dae Hee;Lee, Seung-Ho;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.24 no.4
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    • pp.391-395
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    • 2013
  • In this study, zinc oxide (ZnO) nano powder, well known as an UV absorbing material, was synthesized with three synthetic conditions by the hydrothermal method. After ZnO nano powder was surface-modified with various silane coupling agents to improve dispersion property, a dispersion sol was prepared with dispersant for 72 h by the ball-milling of surface-modified ZnO nano powder. The dispersion sol, prepared by modifying the surface of the ZnO nano powder with an average size of about 30 nm using 3-chloropropyl trimethoxy silane, showed an excellent dispersion stability with a high UV-shielding and visible trnasparency.

Modification of a cosmological hydrodynamic code for more realistic baryonic physics

  • Chun, Kyungwon;Shin, Jihye;Kim, Sungsoo S.
    • The Bulletin of The Korean Astronomical Society
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    • v.39 no.2
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    • pp.45.1-45.1
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    • 2014
  • structure of matters of Lambda cold dark matter (CDM) cosmology on detailed numerical simulations. To accomplish our research goal, we have added the following baryonic physics on the existing cosmological hydrodynamic code, Gadget-2: 1) radiative heating and cooling, 2) reionization of the Universe and UV shielding, 3) star formation, 4) energy and metallicity feedback by supernova. In addition, we included cluster formation to distinguish clustered star formation inside the very high density gas clumps from the field star formation. Our simulations cover a cubic box of a side length 4Mpc/h with 130 million particles. The mass of each particles is $3.4{\times}104Msun$, thus the GCs can be resolved with more than hundreds particles. We discuss various properties of the GCs such as mass function, specific frequency, baryon-to-dark matter ratio, metallicity, spatial distribution, and orbit eccentricity distribution as functions of redshift. We also discuss how the formation and evolution of the GCs are affected by UV shielding.

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X-ray/gamma radiation shielding properties of Aluminium-Bariume-Zinc Oxide nanoparticles synthesized via low temperature solution combustion method

  • K.V. Sathish;K.N. Sridhar;L. Seenappa;H.C. Manjunatha;Y.S. Vidya;B. Chinnappa Reddy;S. Manjunatha;A.N. Santhosh;R. Munirathnam;Alfred Cecil Raj;P.S. Damodara Gupta;B.M. Sankarshan
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1519-1526
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    • 2023
  • For the first time Aluminium-BariumeZinc oxide nanocomposite (ZABONC) was synthesized by solution combustion method where calcination was carried out at low temperatures (600℃) to study the electromagnetic (EM) (X/γ) radiation shielding properties. Further for characterization purpose standard techniques like PXRD, SEM, UV-VISIBLE, FTIR were used to find phase purity, functional groups, surface morphology, and to do structural analysis and energy band gap determination. The PXRD pattern shows (hkl) planes corresponding to spinel cubic phase of ZnAl2O4, cubic Ba(NO3)2, α and γ phase of Al2O3 which clearly confirms the formation of complex nano composite. From SEM histogram mean size of nano particles was calculated and is in the order of 17 nm. Wood and Tauc's relation direct energy band gap calculation gives energy gap of 2.9 eV. In addition, EM (X/γ) shielding properties were measured and compared with the theoretical ones using standard procedures (NaI (Tl) detector and multi channel analyzer MCA). For energy above 356 keV the measured shielding parameters agree well with the theory, while below this value slight deviation is observed, due to the influence of atomic/crystallite size of the ZABONC. Hence synthesized ZABONC can be used as a shielding material in EM (X/γ) radiation shielding.

Radiation parameterizations and optical characterizations for glass shielding composed of SLS waste glass and lead-free materials

  • Thair Hussein Khazaalah;Iskandar Shahrim Mustafa ;M.I. Sayyed
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4708-4714
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    • 2022
  • The novelty in the present search, the Soda-Lime-Silica (SLS) glass waste to prepare free lead glass shielding was used in order to limit the accumulation of glass waste, which requires extensive time to decompose. This also saves on the consumption of pure SiO2, which is a finite resource. Furthermore, the combining of BaO with Bi2O3 into a glass network leads to increased optical properties and improved attenuation. The UV-Visible Spectrophotometer was used to investigate the optical properties and the radiation shielding properties were reported for current glass samples utilizing the PhysX/PDS online software. The optical property results indicate that when BaO content increases in glass structure, the Urbach energy ΔE, and refractive index n increases while the energy optical band gap Eopt decreases. The result of the metallisation criteria (M) revealed that the present glass samples are nonmetallic (insulators). Furthermore, the radiation shielding parameter findings suggest that when BaO was increased in the glass structure, the linear attenuation coefficient and effective atomic number (Zeff) rose. But the half-value layer HVL declined as the BaO concentration grew. According to the research, the glass samples are non-toxic, transparent to visible light, and efficient radiation shielding materials. The Ba5 sample is considered the best among all the samples due to its higher attenuation value and lower HVL and MFP values, which make it a suitable candidate as transparent glass shield shielding.