• 한국정보디스플레이학회:학술대회논문집
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• 2003.07a
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• pp.230-233
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• 2003

New photopolymers were designed and prepared using the photosensitive polymer binders. The photochemical reaction of the photosensitive polymer binder was studied by virtue of UV absorption and infrared spectroscopy. The holographic gratings were successfully fabricated in these photopolymer film samples by conventional optical interference method. We also investigated the effect of photocrosslink in the polymer binder on the diffraction behavior of the photopolymer. The dynamic behaviors of the grating formation were studied with the change of exposure intensity in terms of the diffraction efficiency. Particularly, we focused our efforts to observe the variation of the diffraction efficiency during post UV curing process.

• Polymer(Korea)
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• v.38 no.5
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• pp.573-579
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• 2014

The effect of synthesis conditions such as carbon nanotube (CNT), 2,2,2-trifluoroethylmethacrylate (3FMA), and composition of organic-inorganic material in ozone resistance and surface characteristics of ultraviolet cured organic-inorganic hybrid coating film has been investigated. Coating solution was prepared using tetraethoxysilane (TEOS), silane coupling agent methacryloyloxypropyltrimethoxysilane (MPTMS), 3FMA, various organic materials with acrylate group, and CNT, then bar-coated on substrates using applicator, and densified by UV-curing. It was found that ozone resistance and adhesion of the coating film were strongly dependent upon contents of TEOS, 3FMA, and CNT. Especially, ozone resistance, adhesion, and surface hardness of coating film with CNT were improved, relatively. Ozone resistance of coating film with a high TEOS content was increased, but adhesion was decreased. In addition, it was also found that ozone resistance of coating film was increased with contents of 3FMA. On the other hand, surface hardness was decreased with increase of 3FMA.

• Korean Journal of Materials Research
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• v.31 no.1
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• pp.8-15
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• 2021

Transparent, photocatalytic, and self-cleaning TiO2 thin film is developed by TiO2 sol-gel coating on glass and polycarbonate (PC) substrates. Acetyl acetone (AcAc) suppresses the precipitation of TiO2 by forming a yellowish (complex) transparent sol-gel. XPS analysis confirms the presence of Ti2p and O1s in the thin films on glass and PC substrates. The TiO2-sol is prepared by stabilizing titanium (IV) isopropoxide (TTIP) with diethylamine and methyl alcohol. The addition of AcAcsilane coupling solution to the TiO2-sol instantaneously turns to yellowish color owing to the complexing of titanium with AcAc. The AcAc solution substantially improves the photocatalytic property of the TiO2 coating layer in MB solutions. The coated TiO2 film exhibits super hydrophilicity without and with light irradiation. The TiO2 thin film stabilized by adding 8.7 wt% AcAc shows the highest photo-degradation for methylene blue (MB) solution under UV light irradiation. Also, the optimum photocatalytic activity is obtained for the 8.7 wt% AcAc-stabilized TiO2 coating layer calcined at 450 ℃. The thin-films on glass exhibit fast self-cleaning from oleic acid contamination within 45 min of UV-light irradiation. The appropriate curing time at 140 ℃ improves the anti-fogging and thermal stability of the TiO2 film coated on PC substrate. The watermark-free PC substrate is particularly beneficial to combat fogging problems of transparent substrates.

• Applied Chemistry for Engineering
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• v.27 no.2
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• pp.221-226
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• 2016

Production of eco-friendly and biologically harmless materials is strongly required in all industries. In particular, reducing volatile organic compounds in coating processes is extremely important to secure worker's safety. During recent two decades, extensive research works on water-borne polyurethane dispersion (PUD) have been continuously developed as an alternative to solvent-borne polyurethane. However, PUD was shown inferior mechanical properties to the organic solvent-borne polyurethane due to a limit to the molecular weight increase, which resulted in the limit of applications. To overcome this drawback, several approaches have been examined such as polymer blends and thermal/radiation induced crosslinking. Among these methods, the radiation curing system was suitable for industrialization because of the high crosslinking density and fast curing speed. In this study, we overcame the drawback for PUD via introducing benzophenone radiation curable units to PUD. We synthesized PUD films which possessed good dispersion in water for 30 days, increased Tg and Td more than $5^{\circ}C$ after UV curing film as well as improved young's modulus more than double.

• Korean Chemical Engineering Research
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• v.47 no.6
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• pp.669-675
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• 2009

A study has been made on the preparation of liquid resin of non-solvent and non-discoloration type for replacement of the soft PVC at room temperature. A new synthetic process was developed by structure-control design of polyurethane synthesis using pre-polymer and polyols as curing agent. The optimum recipe was made according to macro-glycols, molecular weight and reaction conditions, and the final products indicated that the mechanical properties such as tensile strength, tear strength and flexibility was very excellent than PVC products. Also, viscosity, hardness and color operations of the final products can be controlled by this system. And yellowing property by UV and NOx gas was improved from the various additive experiment.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.26 no.9
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• pp.447-452
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• 2014

We evaluated heat transfer characteristics of microscale wrinkles using a CFD (computational fluid dynamics) analysis. In order to verify the heat transfer effect of wrinkles having various shapes, we introduce wrinkling processes to generate few different shapes of wrinkles such as macroscale ($200{\sim}400{\mu}m$ width), microscale ($10{\sim}30{\mu}m$ width), and hierarchical (microscale on macroscale wrinkle) wrinkles, using repetitive-dividing-volume (RDV) method for single-shape of wrinkles and connected method of UV-weakly polymerization with thermal curing for hierarchical structure of winkles. The analysis results of simplified CFD model showed that heat flux on heated plate was changed by the shape of wrinkles on the plate. The increase in heat flux of about 2.6 times was achieved in the case where hierarchical wrinkle structure was used.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.179-179
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• 2010

본 연구에서는 무안경식 3 차원 입체영상 기술에 쓰이는 렌티큘러 렌즈의 제작공정 중 오차(Error)로 작용할 수 있는 몇 가지 변수를 가정하였고 이러한 변수의 오차에 의해 좌우되는 가장 중요한 성능인자인 광학적 상호간섭 (Cross-Talk)을 최소화하도록 연구를 수행하였다. 이를 위해서 초정밀절삭가공과 UV경화법을 사용하였고 광학적 상호간섭 (Cross-Talk)에 가장 큰 영향을 주는 피치공차 (Allowance)를 ${\pm}0.5{\mu}m$내로 줄여서 3차원 입체감을 향상시킬 수 있음을 확인하였다.

• Journal of the Korean Society for Precision Engineering
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• v.30 no.2
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• pp.241-246
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• 2013

This paper reports fabrication and characterization of cellulose Electro-Active Paper (EAPap) with increased thickness. Usual thickness of cellulose EAPap was $15{\mu}m$. This thickness needs to be increased to enhance the mechanical force output of EAPap. To fabricate thick cellulose EAPap, the fabrication process parameters including casting and drying processes should be investigated. In this paper, the casting thickness is increased from $800{\mu}m$ to $1500{\mu}m$, and heating times on a hot plate before and after curing process are introduced at 40 and $60^{\circ}C$ for 30 and 60 minutes, respectively. Thickness measurement, Thermal Gravitational Analysis (TGA), UV-transmittance, Young's modulus, and piezoelectric charge constant are measured. Heated EAPaps with increased thickness have similar TGA result, higher transmittance, higher Young's modulus and lower piezoelectric charge constant.

• Journal of the Korean Solar Energy Society
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• v.34 no.2
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• pp.44-52
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• 2014

The main purpose of this paper is to develop the new BIPV module equipped with vacuum glass. Beacuse BIPV module has a function of architectural materials, thermal and PV performance should be simultaneously evaluated. To improve the thermal performance of BIPV module, this study developed BIPV module equipped with a vacuum glass. Those BIPV module was tested with a variety of encapsulants. The results are as follows. When a vacuum glass is laminated with EVA or PVB, it was broken. The reason seems to be bending by unbalance of heat expansion with center and edge of vacuum glass. In case of lamination with resin, there is no breakage and no bending of vacuum glass. Because production was conducted in low pressure & low temperature conditions. And it was also found that vacuum glass does not interfere with the UV curing process.

• Applied Science and Convergence Technology
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• v.23 no.6
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• pp.376-386
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• 2014

Zinc oxysulfide nanocrystals (ZnOS NCs) were synthesized by forming ZnS phase on a ZnO matrix. ZnO nanocrystals (NCs) with a diameter of 10 nm were synthesized by forced hydrolysis in an organic solvent. As-synthesized ZnO NCs aggregated with each other due to the high surface energy. As acetic acid (AA) was added into the milky suspension of the aggregated ZnO NCs, transparent solution of well dispersed ZnO NCs formed. Finally ZnOS NCs were formed by adding thioacetic acid (TAA) to the transparent solution. The effect of recrystallization on the structural, optical and electrical properties of the ZnOS NCs were studied. The results of UV-vis absorption confirmed the band gap tunability caused by increasing the curing temperature of ZnOS thin films. This may have originated from the larger effective size due to the recrystallization of zinc sulfide (ZnS). From XRD result we identified that ZnOS thin films have a zinc blende crystal structure of ZnS without wurtzite ZnO structure. This is probably due to the small amount of ZnO phases. These assertions were verified through EDS of FE-SEM, XPS and EDS mapping of HR-TEM results; we clearly proved that ZnOS were comprised of ZnS and ZnO phases.