• Title/Summary/Keyword: uv curing

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Fracture Behavior of Glass/Resin/Glass Sandwich Structures with Different Resin Thicknesses (서로 다른 레진 두께를 갖는 유리/레진/유리샌드위치 구조의 파괴거동)

  • Park, Jae-Hong;Lee, Eu-Gene;Kim, Tae-Woo;Yim, Hong-Jae;Lee, Kee-Sung
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.12
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    • pp.1849-1856
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    • 2010
  • Glass/resin/glass laminate structures are used in the automobile, biological, and display industries. The sandwich structures are used in the micro/nanoimprint process to fabricate a variety of functional components and devices in fields such as display, optics, MEMS, and bioindustry. In the process, micrometer- or nanometer-scale patterns are transferred onto the substrate using UV curing resins. The demodling process has an important impact on productivity. In this study, we investigated the fracture behavior of glass/resin/glass laminates fabricated via UV curing. We performed measurements of the adhesion force and the interfacial energy between the mold and resin materials using the four-point flexural test. The bending-test measurements and the load-displacement curves of the laminates indicate that the fracture behavior is influenced by the interfacial energy between the mold and resin and the resin thickness.

Process Conditions for the Fabrication of Hydrophobic Surfaces with Different Photo-curable Resins (광경화성 레진의 성분 변화에 대한 소수성 표면 제작을 위한 공정 조건)

  • Hong, Sung-Ho;Woo, Heung-Sik
    • Tribology and Lubricants
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    • v.36 no.5
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    • pp.267-273
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    • 2020
  • This study experimentally investigates hydrophobic surfaces fabricated via additive manufacturing. Additive manufacturing, commonly known as 3D printing, is the process of joining materials to fabricate parts from 3D model data, usually in a layer-upon-layer manner. Digital light processing is used to fabricate hydrophobic surfaces in this study. This method uses photo-curable resins and ultraviolet (UV) sources. Moreover, this technique generally has faster shaping speeds and is advantageous for the fabrication of small components because it enables the fabrication of one layer at a time. Two photo-curable resins with different compositions are used to fabricate micro-patterns of hydrophobic surfaces. The resins are composed of a photo-initiator, monomer, and oligomer. Experiments are conducted to determine suitable process conditions for the fabrication of hydrophobic surfaces depending on the type of resin. The most important factors affecting the process conditions are the UV exposure time and slice thickness. The fabrication capability according to the process conditions is evaluated using the side and top views of the micro-patterns observed using a microscope. The micro-patterns are collapsed and intertwined when the exposure time is short because sufficient light (heat) is not applied to cure the photo-curable resin with a given slice thickness. On the other hand, the micro-patterns are attached to each other when the exposure time is prolonged because the over-curing time can cure the periphery of a given shape. When the slice is thicker, the additional curing area is enlarged in each slice owing to the straightness of UV light, and the slice surface becomes rough.

Effects of Tape Thickness and Inorganic Fillers on the Adhesion Properties of Double-sided Acrylic Adhesive Tape by Ultraviolet Curing (자외선 경화형 아크릴 양면 점착테이프의 두께 및 무기물 충전제 종류에 따른 접착특성)

  • Kim, Dong-Bok
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.397-405
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    • 2014
  • To manufacture of high-performance semi-structural double-sided adhesive tape, 2-ethylhexyl acrylate (2-EHA) and acrylic acid (AAC) were used, and the syrup was prepared by UV irradiation in this study. The effects of the thickness, various inorganic filler contents, and filler types on the semi-structural properties of acrylic double-sided adhesive tape were investigated. The peel strength increased with increasing thickness and wetting time. In case of the thin thickness (under $250{\mu}m$) with decreasing true density of inorganic filler, the peel strength increased with increasing wetting time. The initial peel strength showed a higher value at a big size of inorganic filler, and the filler's size in adhesive tapes was confirmed by SEM images. The peel strength and dynamic shear strength increased as a proportional relationship with various inorganic fillers and contents, and these inorganic fillers in $0.1{\mu}m$ thickness indicated more effect on the dynamic shear strength of double-sided adhesive tape. From these results the thin acrylic double-sided adhesive tape determined to be use for applications as a high-performance semi-structural.

Solventless UV Curable Material for Low Cost System (저에너지 UV 경화형 무용제 소재 개발)

  • KIM, KWANGIN;LEE, JUHEON;LEE, HYUNJU;HAN, HAKSOO
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.1
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    • pp.77-84
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    • 2017
  • In this study, Poly-urethane acrylate (PUA) was synthesized by the reaction between Polycaprolactonetriol (PCLT) and Isophorone dissocyanate (IPDI) and hybridized with inorganic materials. Tetraethylortho silicate (TEOS) and nano clay (Closite 20A) were used as inorganic particles. For the hybridization of TEOS with PUA, sol-gel method is used, in which TEOS is made into spherical particle in the firsthand. In the case of Nano clay, hybridization is carried out through the dispersion as Nano clay has a layered structure. The solution of PUA hybrid was made into a film after UV curing and its thermo and electrical properties were measured. The experimental analysis and result demonstrate that the PUA hybrid shows an improved thermal properties and lower dielectric constant than that of the non-hybrid PUA. The trend of improved properties was different depending on structure of inorganic materials.

Study on the Properties of UV-curable Polyurethane acrylate with reactive diluents content (자외선 경화형 폴리우레탄 아크릴레이트 수지의 반응성 희석제 함량에 따른 물성 연구)

  • Sim, Jae Hak;Seo, Eun Sun;Lee, Won Young;Kim, Gu Ni
    • Journal of Adhesion and Interface
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    • v.18 no.4
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    • pp.159-165
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    • 2017
  • In this study, we synthesized UV-curable urethane acrylates with different contents of BA, reactive diluent and characterized their physical properties such as thermal, mechanical properties, adhesive strength and flexibility resistance. From a result of DSC, Tg of polyol and acrylate resin were separated as the BA content increased more than 40%. Also, tensile strength, elongation and adhesive strength decreased with increasing the BA content. The UV-curable urethane acrylate with 40% BA has shown good flexibility resistance compared to other resin due to poor hardness and Tm of acrylate resin.

A Study of The Photosensitive Characteristic and Fabrication of Polyimide Thin Film by Dry Processing (건식법을 이용한 폴리이미드 박막의 제조 및 광특성)

  • Lee, Boong-Joo
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.56 no.1
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    • pp.139-141
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    • 2007
  • Thin films of polyimide (Pl) were fabricated by a vapor deposition polymerization method (VDPM) and studied for the photosensitive characteristic. Polyamic acid (PAA) thin films fabricated by vapor deposition polymerization (VDP) from 6FDA and 4-4' DDE were converted to PI thin films by thermal curing. From AFM and Ellipsometer experimental, the films thickness was decreased and the reflectance was increased as the curing temperature was increased. Those results implies that thin film is uniform. From UV-Vis spectra, PI thin films showed high absorbance in 225 $\sim$ 260 [nm] region.

Effects of Fabrication Conditions on Electro-optic Properties of UV-Cured Polymer/Liquid Crystal Composite Films (UV 경화형 고분자/액정 복합체의 제조 조건에 따른 전기광학적 특성)

  • Park, Se Kwang;Park, Lee Soon;Keum, Chang Dae;Seok, Jae Wook;Ahn, Won Sool
    • Applied Chemistry for Engineering
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    • v.9 no.4
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    • pp.579-584
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    • 1998
  • Polymer dispersed liquid crystal(PDLC) composite films were made by polymerization induced phase separation method using UV-curing to investigate the effect of fabrication conditions, such as photoinitiator concentration, film thickness, polymerization temperature, and electric field during polymerization, etc., on the electro-optic properties. As the amount of photoinitiator increased, the driving voltage of PDLC device increased due to the increase of small-size liquid crystal phases. This was considered as the results from the increased interfacial area between liquid crystal (LC) and polymer matrix, since LC molecules at the interfacial regions were relatively difficult to response for the applied electric field. When the higher molecular weight oligomer (PTDA-1000) was used as matrix, the initial transmittance was observed to be relatively higher than that for the lower molecular weight oligomer (PTDA-250). Saturation transmittance for PTDA-1000 was observed at relatively lower voltage than that for PTDA-250, of which transmittance was not saturated even at 60 V. As polymerization temperature increased, the initial transmittance of resulting PDLC film increased due to the larger LC droplets formation and the more matched refractive index between LC and matrix than those cases for the lower polymerization temperature. Though driving voltage decreased for the thinner film, it was considered that optimum thickness of the film should be maintained to get some practical contrast, which is the ratio of off- and on-state transmittance. Furthermore, electro-optic properties such as initial transmittance, driving voltage, and response time were observed to be considerably affected by application of external field during polymerization.

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Effect of Liquid Isoprene Rubber on the Adhesion Property of UV Curable Acrylic Pressure-Sensitive Adhesive (액상 이소프렌 고무가 자외선 경화형 아크릴 점착제의 점착 특성에 미치는 영향)

  • Lee, Jiye;Chung, Kyungho
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.210-219
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    • 2014
  • In this study, the acrylic pressure sensitive adhesive (PSA) for the optical functionality sheet was prepared by blending liquid isoprene rubber. The acrylic PSA was synthesized with butyl acrylate, acrylic acid, 2-ethylhexyl acrylate and 2-hydroxyethyl methacrylate. Toluene was used to a solvent for polymerization. Liquid isoprene rubber (LIR-50) was blended with the acrylic PSA and blend ratio was 0 ~ 50 wt%. According to the results, the adhesive transfer, which was the big problem of acrylic adhesive, was reduced with the addition of LIR-50. The secondary bonding of LIR-50 with substrate did not occurred due to absence of polar group in LIR-50. The peel strength and adhesive transfer were decreased by UV curing and the degreed of decrease depended on the amounts of photoinitiator and UV irradiation time. On the other hand holding power increased drastically by increasing amounts of photoinitiator and UV irradiation time.

A Development on the Non-Photomask Plate Making Technology for Screen Printing (포토 마스크가 필요없는 스크린 제판 기술 개발)

  • Koo, Yong-Hwan;Ahn, Suk-Chul;Kim, Sung-Bin;Nam, Su-Yong
    • Journal of the Korean Graphic Arts Communication Society
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    • v.28 no.1
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    • pp.65-75
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    • 2010
  • Environmentally friendly, stencil and screen printing for cost-effective for maskless. In this study, UV -LED light source for the dispersion characteristics and high competence photoresist coating was prepared. Wavelength of 365nm UV-LED exposure device using the maskless lithography, 1.7kgf/$cm^2$ $2600mmH_2O$ the injection pressure and the suction pressure by using a dry photoconductor symptoms were dry emulsion on the market as a result, curing properties and adhesion, hardness, solvent resistance and excellent reproduction of fine patterns and ecological stencil technology was available and could be confirmed as a possibility.

Dynamic Behavior on the Bisphenol A diacrylate UV curing film according to change of photoinitiator concentration (광중합 개시제 첨가량의 변화에 따른 Bisphenol A diacrylate UV 경화 film의 역학적 거동)

  • 노재호
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.81.2-98
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    • 1994
  • This syudy analyzed the main bodies, marginal space, Position of the main bodies of current textbooks in high schools and "the eriteria of reading system for textbooks" which was suggested the Department of Education and Provided some suggestions for the improvement. The research methods used for the study were both literature review and survey rdsdarch with a questionaire. Inorder to research for the main body of textbook, space of margin, the optimum position of the main body, sizes of litters, spaces between letters, words, lines, length of lines, sizes of main body and margin, and margin and position of main body were checked through a related literature review. For the questionaire experiment, a questionaire based on data drawn from analysis of current textbooks, :criteria for reading system of textbook" suggested by the Department of Education, and some suggestions for improvement by the researcher was made and used for the test, targetting 384 body and girl student in high schools.n high schools.

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