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A Study on the comparison on Adsorption characteristics of Zeolite and DETOX for the removal of H2S (H2S 제거를 위한 Zeolite와 DETOX의 흡착 특성 비교 연구)

  • Park, Dae-Seok;Lim, Ji-Young;Cho, Young-Gun;Song, Seung-Jun;Kim, Jin-Han
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4675-4681
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    • 2014
  • This study examined the $H_2S$ removal characteristics, such as breakthrough time, adsorption capacity, and adsorption rate of adsorbents between Zeolite 3A and DETOX in terms of the $H_2S$ inflow concentration and adsorption temperature. The adsorption capacity of Zeolite 3A increased with increasing mass flow rate of hydrogen sulfide($H_2S$) inflow, but the breakthrough time decreased. On the other hand, both the adsorption capacity and breakthrough time of DETOX decreased with increasing mass flow rate of $H_2S$ inflow. The adsorption capacity and breakthrough time of Zeolite 3A decreased with increasing adsorption temperature but those of DETOX increased. The adsorption capacity of DETOX was higher than that of Zeolite 3A by a factor of 2.5 - 16.4 because the collision frequency that overcomes the activation energy barrier increased with increasing adsorption temperature. For Zeolite 3A and DETOX, the adsorption rate of $H_2S$ increased with increasing mass flow rate of $H_2S$ inflow and adsorption temperature. The adsorption rate of $H_2S$ for Zeolite 3A was 4 times as much as that for DETOX. For the removal of $H_2S$ in biogas, DETOX had an advantage over Zeolite 3A because DETOX had a much longer breakthrough time and greater adsorption capacity in the temperature range of 308~318K than Zeolite 3A.

A Study on the Utilization and Satisfaction of Local Residents in College Campus with the Attention Restoration Theory (집중력 회복이론을 통한 지역거주민들의 대학캠퍼스 이용실태 및 만족도)

  • Lee, Shi Young;Park, Gun
    • Journal of the Korean Institute of Landscape Architecture
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    • v.42 no.4
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    • pp.37-47
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    • 2014
  • This study aims to examine the usage of and satisfaction with neighborhood parks and university campuses and compare through the RPRS analysis of them to figure out how university campuses, as substitutive green spaces, play the role of curative environment for neighboring people. This study relied on two methods: a descriptive method of researching publications and related scholastic writings and an empirical study of researching how the park and campus has been utilized and researching whether the residents are satisfied with the currently existing space and the environment or not, and finally researching how the university campus open space as a curative environment impacts the satisfaction and utilization through reliability analysis. As a result, contribution of healing environment has a relatively high average contribution of 4 or more points, respectively. These results suggest that urban people think that a relationship between man and nature is very important in the overabundance of stress in modern society. It shows that neighborhoods are higher than university campuses in the explanatory of the Attention Restoration Theory, but the campus is higher than the neighborhood park in similarity of configuration. The result of RPRS analysis shows that the therapeutic qualities of the landscape may be very useful to evaluate a college campus open space in "the Revised Perceived Restoration Scale." The results showed that, in future studies, it will be a great help by widespread use of pre-evaluation of the characteristics of restorative environments in the planning, design and other works. To study the impact of the curative features on evaluating future research locations, the location should provide a variety of purposes and motives. At the same time, it should provide specific design ideas to design-related designers by using perceived restoration scale.

Estimation of Gas-particle partitioning Coefficients (Kp) of Carcinogenic polycyclic Aromatic hydrocarbons in Carbonaceous Aerosols Collected at Chiang - Mai, Bangkok and hat-Yai, Thailand

  • Pongpiachan, Siwatt;Ho, Kin Fai;Cao, Junji
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.4
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    • pp.2461-2476
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    • 2013
  • To assess environmental contamination with carcinogens, carbonaceous compounds, water-soluble ionic species and trace gaseous species were identified and quantified every three hours for three days st three different atmospheric layer at the heart of chiang-Mai, bangkok and hat-Yai from December 2006 to February 2007. A DRI model 2001 Themal/Optical Carbon Analyzer with the IMPROVE thermal/optical reflectance (TOR) protocol was used to quantify the organic carbon(OC) and elemental carbon content in $PM_{10}$. Diurnal and vertical variability was also carefully investigated. In general, OC and EC contenttration shoeed the highest values at the monitoring period o 21.00-00.00 as consequences of human activities at night bazaar coupled with reduction of mixing layer, decreased wind speed and termination of photolysis nighttime. Morning peaks of carboaceous compounds were observed during the sampling period of 06:00 -09:00, emphasizing the main contribution of traffic emission in the three cities. The estimation of incremental lifetime partculate matter exposure (ILPE) raises concern of high risk of carbonaceous accumulation over workers and residents living close to the observatory sites. The average values of incremental lifrtime particulate matter exposure (ILPE) of total carbon at Baiyoke Suit Hotel and Baiyoke Sky Hotel are approsimately ten time shigher then those air sample collected at prince of songkla University Hat-Yai campus corpse incinerator and fish-can maufacturing factory but only slightly higher than those of rice straw burnig in Songkla province. This indicates a high risk of developing lung cancer and other respiratory diseases across workers and residents living in high buildings located in Pratunam area. Using knowledge of carbonaceous fractions in $PM_{10}$, one can estimate the gas-particle partitioning of polycyclic aromatic hydrocarbons (PAHs). Dachs-Eisenreich model highlights the crucial role of adsorption in gas-particle partitioning of low molecular weight PAHs, whereas both absorption and adsorption tend to account for gas-particle partitioning of high molecular weight PAHs in urban residential zones of Thailand. Interestingly, the absorption mode alone plays a minor role in gas-partcle partitiining of PAHs in Chiang-Mai, Bangkok and hat-Yai.

The Characteristics of Odonata Community According to Age and Size of Pond (연못 조성년도와 크기에 따른 잠자리 군집 특성)

  • Kim, Ji-Suk;Pi, Jae-Hwang;Jung, Tae-Jun;Lee, Kyong-Jae
    • Korean Journal of Environment and Ecology
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    • v.28 no.3
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    • pp.293-301
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    • 2014
  • 15 artificial ponds in Seoul have been examined to find out the characteristics of Odonata community according to age and size of pond. We found 6 Families 36 Species of Odonata community, and Libellulidae was the most frequent and 19 Species were observed among Libellulidae. Considering relative importance with frequency of appearance and density, Ischnura asiatica and Orthetrum albistylum was the most frequent. Also, 16 Species including Lestes temporaris, Sympetrum parvulum, and Anax nigrofasciatus were relatively rare. The result of dominant species tells that Ischnura asiatica in 1 ~ 3 year old ponds, Pantala flavescens-Orthetrum albistylum-Crocothemis servilia mariannae in order of mention in 4 ~ 6 year old ponds, Platycnemis phyllopoda-Ischnura asiatica in order of mention in 10 or more year old ponds are the dominant species. Species diversity index regarding age of pond has been researched, and species diversity index in 10 year old pond was higher than that of in 1 ~ 3 year old pond. Having done the analysis of variance for types of spawn, there are many species Endophytic egg-layers and pasting in mud or sand in 10 year old artificial ponds. The wider ponds get, the higher species diversity index gets. And, we suggest that desirable size for making artificial ponds to increase the species diversity index of Odonata is $100{\sim}300m^2$.

Estimating Quantiles of Extreme Rainfall Using a Mixed Gumbel Distribution Model (혼합 검벨분포모형을 이용한 확률강우량의 산정)

  • Yoon, Phil-Yong;Kim, Tae-Woong;Yang, Jeong-Seok;Lee, Seung-Oh
    • Journal of Korea Water Resources Association
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    • v.45 no.3
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    • pp.263-274
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    • 2012
  • Recently, due to various climate variabilities, extreme rainfall events have been occurring all over the world. Extreme rainfall events in Korea mainly result from the summer typhoon storms and the localized convective storms. In order to estimate appropriate quantiles for extreme rainfall, this study considered the probability behavior of daily rainfall from the typhoons and the convective storms which compose the annual maximum rainfalls (AMRs). The conventional rainfall frequency analysis estimates rainfall quantiles based on the assumption that the AMRs are extracted from an identified single population, whereas this study employed a mixed distribution function to incorporate the different statistical characteristics of two types of rainfalls into the hydrologic frequency analysis. Selecting 15 rainfall gauge stations where contain comparatively large number of measurements of daily rainfall, for various return periods, quantiles of daily rainfalls were estimated and analyzed in this study. The results indicate that the mixed Gumbel distribution locally results in significant gains and losses in quantiles. This would provide useful information in designing flood protection systems.

A Study on Optimal Time Distribution of Extreme Rainfall Using Minutely Rainfall Data: A Case Study of Seoul (분단위 강우자료를 이용한 극치강우의 최적 시간분포 연구: 서울지점을 중심으로)

  • Yoon, Sun-Kwon;Kim, Jong-Suk;Moon, Young-Il
    • Journal of Korea Water Resources Association
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    • v.45 no.3
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    • pp.275-290
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    • 2012
  • In this study, we have developed an optimal time distribution model through extraction of peaks over threshold (POT) series. The median values for annual maximum rainfall dataset, which are obtained from the magnetic recording (MMR) and the automatic weather system(AWS) data at Seoul meteorological observatory, were used as the POT criteria. We also suggested the improved methodology for the time distribution of extreme rainfall compared to Huff method, which is widely used for time distributions of design rainfall. The Huff method did not consider changing in the shape of time distribution for each rainfall durations and rainfall criteria as total amount of rainfall for each rainfall events. This study have suggested an extracting methodology for rainfall events in each quartile based on interquartile range (IQR) matrix and selection for the mode quartile storm to determine the ranking cosidering weighting factors on minutely observation data. Finally, the optimal time distribution model in each rainfall duration was derived considering both data size and characteristics of distribution using kernel density function in extracted dimensionless unit rainfall hyetograph.

A Study on Highway Capacity Variation According to Snowfall Intensity (강설에 따른 고속도로 용량 변화에 관한 연구)

  • Son, Young Tae;Lee, Sang Hwa;Im, Ji Hee
    • Journal of Korean Society of Transportation
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    • v.31 no.6
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    • pp.3-11
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    • 2013
  • Under the consumption of bad weather situation affects traffic flows, the study scope is focused on highway capacity and speed variations among other highway traffic flow characteristic changes according to snowfall density. Thus, this study carried out through the data collection and statistical analysis by focusing on capacity and speed changes. Traffic volume, speed and density were selected as factors to explain the property change of a traffic flow for analysis, and 7 basic sections such as 3 highways in Gyeonggi-do and 4 highways near the meteorological observatory were selected as survey points for data collection. Snowfall levels were classified into 3 steps(Light, Medium, Heavy Snow) to analyze the capacity change by snowfall levels. As a result of analysis, the change of capacity depending on snowfall levels decreased 13.2% in case of light snow compared to a good weather, 18.6% in case of medium snow and 32.0% in case of heavy snow, so the capacity reduction rate increased as the snowfall level increased. The worsening weather appeared to have a very big possibility to act as a factor to reduce the operational efficiency of a road, so a road design and operation method considering this should be presented in the future.

The impact of service composition factor on organizational performance of long term care facilities for the elderly people (노인장기요양시설의 서비스 구성요인이 조직성과에 미치는 영향에 관한 연구)

  • Juang, Han Chea;Lim, Hyun Sung;Go, Dae Young;Kang, Sung Ok
    • Asia-Pacific Journal of Business Venturing and Entrepreneurship
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    • v.9 no.1
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    • pp.133-140
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    • 2014
  • The purpose of this research was to identify how service composition factor impact organizational performance of long-term care facilities for elderly people. The target population was the staffs who were working at long-term care facilities for elderly people in urban areas of Seoul, Inchon and cities in Kyonggi-do as of September 2012. Independent variables, main factors for organizational performances, are leadership, educational training, compensation, initiative, and service quality. Dependent variables are selected as duty satisfaction, job performance, financial aptitude and beneficiary-oriented policy. SPSS ver18.0 statistical computer program was conducted in order to analyze the multivariate statistical data. The results are examined in detail in terms of the influence of two managing systems in the senior-care service on the organizational performance and the evaluations of the relation and difference caused by the input variables in two managing systems. In one case of the influence of two managing systems in the senior-care service on the organizational performance, the findings show 1) the influence of the service managing factor is clearly related to duty satisfaction with the result of 0.001 (F=37.429) regression data, 2) the influence of the service managing factor is clearly related to job performance with the result of 0.001 (F=55.099) regression data, 3) the influence of the service managing factor is closely related to financial aptitude with the result of 0.001 (F=56.904) regression data, and 4) the influence of the service managing factor is also clearly related to beneficiary-oriented policy with the result of 0.001 (F=61.367) regression data.

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Construction and Applicability of GIS-Based Grave Management System (GIS기반 분묘관리시스템의 구축 및 적용)

  • Lee, Jin-Duk;Lee, Seong-Hwan
    • Journal of the Korean Association of Geographic Information Studies
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    • v.14 no.4
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    • pp.208-220
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    • 2011
  • Korean traditional practice that gets a gravesite for burial and reckless grave establishment not only obstructs systematic national land management and reasonable urban development, but also causes a serious factor which has a harmful effect on natural environment and residential space in reality that our country is limited in area and national and social bases for use and establishment of graves are still inadequite. Though government and local governments have tried to cope with these problems by enacting legislation on funeral and others and so forth, they still have a variety of problems due to the shortage of grave management systems and information of accumulated individual graves. This study describes about the development of a GIS-based grave management system for making administrative management for individual cemeteries the prime object. As a result of application to a pilot area, the system developed in this study was able to be applied for supporting the time-limited burial system and managing cemeteries for those who left no relatives behind by constructing the database with grave-related position/attribute information which are collected by administrative system or direct survey. In addition, it is expected that this system will be utilized as a systematic management method that can be handed down the present or the future descendants under the tradition of the family-oriented funeral culture.

Characteristics of Odonata Communities Based on Habitat Types of Superb Biotope in Wonju City, Korea (원주시 우수비오톱 서식처 유형별 잠자리군집 특성)

  • Kim, Ji-Suk;Kwak, Jeong-In;Noh, Tai-Hwan;Yi, Pyong-In
    • Korean Journal of Environment and Ecology
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    • v.27 no.2
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    • pp.209-218
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    • 2013
  • This study was conducted to analyze the characteristics of odonata communities as habitat types in Wonju City, Korea. The 33 plots were installed at 4 types of biotope like abandoned paddy fields, natural type reservoir, natural type river and forest valley in Wonju city. From the survey, the 9 family and 38 species were identified. As the result of comparative investigation of the species composition of each habitat through TWINSPAN analyzing, the difference of species composition was definite in abandoned paddy field, natural type reservoir and forest valley, however, it was uncertain in natural type river. The dominant species and the subdominant species of each habitat were mainly Sympetrum frequens and Sympetrum infuscatum but the distributions of Paracercion hieroglyphicum, Epophthalmia elegans, and Anax parthenope julius were different as haibtat types. The order of the index of species diversity was not different between abandoned paddy fiedls, natural type reservoir and natural type river, but forest valley was low. The abandoned paddy field was shown the most diverse spawning type of odonata, it is considered that hydrophyten play an important role in the abundant of odonata since the sorts of odonata spawning in plants are majority. As the result of analyzing interspecies relationship, Crocothemis servilia mariannae and Orthetrum albistylum, Crocothemis servilia mariannae-Platycnemis phyllopoda, Lyriothemis pachygastra-Sympetrum parvulum are shown the positive correlation, however, they have a difference in preferred habitat between high correlation species.