• Title/Summary/Keyword: unsymmetrical

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Synthesis of Unsymmetrical Trisannelated Benzenes (비대칭적으로 삼고리화된 벤젠의 합성)

  • Mahmoodi, Nosrat O.;Fatemeh, Mostaghni
    • Journal of the Korean Chemical Society
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    • v.46 no.1
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    • pp.52-56
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    • 2002
  • Synthesis of unsymmetrical trisannelated benzenes such as 2,3,4,5,6,7,8,9,10,11-decahydro-1H-cyclopenta[l]phenanthrene (1c) and 1,2,3,4,5,6,7,8,9,10-decahydrobenz[e]-as-indacene (1d) is described. The synthetic approach involves efficient condensation of pre-formed enones such as bicyclohexyliden-2-one (3), bicyclohexyl-1-en-2-one (4) and bicyclopentyliden-2-one (5) in the presence of cyclopentanone and cyclohexanone using anhydrous $CuCl_2$ as a catalyst.

mPW1PW91 Calculated and Experimental UV/IR Spectra of Unsymmetrical trans-Stilbenes

  • Choe, Jong-In;Park, Seong-Jun;Cho, Chul-Hee;Kim, Chul-Bae;Park, Kwang-Yong
    • Bulletin of the Korean Chemical Society
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    • v.31 no.8
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    • pp.2175-2179
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    • 2010
  • Quantum mechanical properties of unsymmetrical and unfunctionalized trans-stilbene derivatives 1-3, which had been prepared by solid-phase parallel syntheses, were characterized using mPW1PW91/6-311G(d,p) (hybrid HF-DF) calculations. The total electronic energies, normal vibrational modes, Gibbs free energies, and HOMOs and LUMOs of sixteen different structures from three different groups were analyzed. The energy differences between the HOMOs and LUMOs of the various unsymmetrical trans-stilbenes are in accord with the maximum absorption peaks of the experimental UV spectra of 1-3. The calculated normal vibrational modes of 21 were comparable with its experimental IR spectrum. The $\pi$-conjugation in the para-connected biphenyl group of 2 is better than the one in the metaconnected biphenyl group on the shorter side of 3.

Novel Fast Peak Detector for Single- or Three-phase Unsymmetrical Voltage Sags

  • Lee, Sang-Hoey;Cha, Han-Ju
    • Journal of Electrical Engineering and Technology
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    • v.6 no.5
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    • pp.658-665
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    • 2011
  • In the present paper, a novel fast peak detector for single- or three-phase unsymmetrical voltage sags is proposed. The proposed detector is modified from a single-phase digital phase-locked loop based on a d-q transformation using an all-pass filter (APF). APF generates a virtual phase with $90^{\circ}$ phase delay. However, this virtual phase cannot reflect a sudden change of the grid voltage in the moment of voltage sag, which causes a peak value to be significantly distorted and to settle down slowly. Specifically, the settling time of the peak value is too long when voltage sag occurs around a zero crossing, such as phase $0^{\circ}$ and $180^{\circ}$. This paper describes the operating principle of the APF problem and proposes a modified all-pass filter (MAPF) to mitigate the inherent APF problem. In addition, a new fast peak detector using MAPF is proposed. The proposed detector is able to calculate a peak value within 0.5 ms, even when voltage sag occurs around zero crossing. The proposed fast peak detector is compared with the conventional detector using APF. Results show that the proposed detector has faster detection time in the whole phase range. Furthermore, the proposed fast peak detector can be effectively applied to unsymmetrical three-phase voltage sags. Simulation and experimental results verify the advantages of the proposed detector and MAPF.

A Study on the Conclusion Bearing Capacity ol Polluted Soils Owing to Difference of Water Content (함수량이 다른 오염지반의 지지력 결정에 관한 연구)

  • 안종필;박상범;박경호
    • Proceedings of the Korean Geotechical Society Conference
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    • 1999.03a
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    • pp.481-488
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    • 1999
  • This study, investigates the existing theoretical backgrounds in order to examine the behavior of lateral flow owing to the plasticity of soils when unsymmetrical surcharge is worked on polluted soils by the increase of water content compares and analyzes the results measured through model tests. Unsymmetrical surcharge is increased at regular intervals to soil tank made up the polluted soils and then the amounts of settlement, lateral displacement and upheaval are observed. Critical surcharge was decided q$\sub$cr/= 3.42 C$\sub$u/ similar to those had proposed Terzaghi and JHI, and the value of ultimate capacity was decided q$\sub$ult/= 7.71 C$\sub$u/ similar to that of Tschebotarioff and JHI.

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A study on sound radiation from isotropic plates stiffened by unsymmetrical beams (비대칭 보에 의해 보강된 등방성 평판의 음향방상에 관한 연구)

  • Kim, Taek-Hyun;Oh, Taek-Yul;Kim, Jong-Tye
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.4
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    • pp.753-761
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    • 1998
  • The determination of sound pressure radiated from periodic plate structures is fundamental in the estimation of noise level in aircraft fuselages or ship hull structures. As a robust approach to this problem, here a very general and comprehensive analytical model is developed for predicting the sound radiated by a vibrating plate stiffened by periodically spaced orthogonal unsymmetrical beams subjected to a sinusoidally time varying point load. The plate is assumed to be infinite in extent, and the beams are considered to exert both line force and moment reactions on it. Using this theoretical model, the sound pressure levels on axis in a semi-infinited fluid (water) bounded by the plate were calculated using three numerical tools such as the Gauss-Jordan method, the LU decomposition method and the IMSL numberial package. Especially, the variation in the sound pressure levels and their modes were investigated according to the change in frequency, bay spacing and bay distance.

A Simplified Modulation Strategy for Three-leg Voltage Source Inverter Fed Unsymmetrical Two-winding Induction Motor

  • Sinthusonthishat, Saliltip;Chuladaycha, Nontawat
    • Journal of Electrical Engineering and Technology
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    • v.8 no.6
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    • pp.1337-1344
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    • 2013
  • This paper presents a simplified modulation strategy for the three-leg VSI fed two-winding induction motor. The strategy provides independent unbalanced voltage control for the main and auxiliary windings. This make the motor can be reversed rotation through the range of motor speed operation without limitation of voltage boost of the auxiliary winding. To study the advantages of the proposed drive, the experimental results such as voltage stresses, hysteresis band of the currents in locus, and also acoustic noise levels of the three-leg VSI are compared with those of the conventional two-leg topology. The results obviously show that the proposed technique achieves superior performance compared with the traditional scheme in case of dramatic increase of DC bus utilization, effective reduction of harmonic voltages content, and also significant enhancement of motor efficiency.

Electrical characteristics of PET film for wire insulation of transformer in fluorocarbon (Fluorocarbon에서의 변압기권선 절연용 PET필름의 전기적 특성연구)

  • 허창수;이재복
    • Electrical & Electronic Materials
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    • v.9 no.5
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    • pp.483-489
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    • 1996
  • Power transformer have many unsymmetrical structure and electric field is enhanced in that area. Those unsymmetrical area are not covered oftenly by solid insulating material which is used as a framework specially in gas transformer. By that result there is a possibility to decrease the total insulation class of the transformer. So in this study the electrical characteristic of $FC+SF_6$ mixture gas which is used as coolants for large power gas insulated transformer and its effects on electrical characteristics of structural material are investigated. Also breakdown characteristic with the tension of taping and curvature of the coil are studied which could be used as a design factor of large power transformer.

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The VSI active power filter in 3-phase unsymmetrical voltage system (3상 불평형 전압 시스템에서의 전압원 active power filter)

  • Kim, Gap-Dong;Lee, Wan-Soo;Kim, Min-Tae;Oh, Sung-Up;Joo, Hyung-Joon;Lee, Jin;Sung, Se-Jin
    • Proceedings of the KIPE Conference
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    • 1999.07a
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    • pp.667-670
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    • 1999
  • An active power filter is used to eliminate harmonic currents. This paper applied the extension pq theory to harmonic currents compensation. An active power filter based on extension pq theory is more effective than pq theory in 3-phase unsymmetrical voltage system. When extension pq theory is used, the result of simulation present source current is not distorted. Pulse-width modulation method is CRPWM(Current-Regulated PWM).

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