• Title/Summary/Keyword: uniform CA

Search Result 134, Processing Time 0.029 seconds

Mössbauer Study of Two Discernable Fe Sites in CaFe2O4

  • Yoon, Sung-Hyun
    • Journal of Magnetics
    • /
    • v.14 no.2
    • /
    • pp.86-89
    • /
    • 2009
  • Structural and magnetic properties of polycrystalline $CaFe_2O_4$ prepared by the solid state reaction method were studied using powder X-ray diffraction (XRD) and $M{\ddot{o}}ssbauer$ spectroscopy. The structure of $CaFe_2O_4$ belongs to an orthorhombic system (space group: Pnma) with the lattice parameters $a=9.2373\;{\AA}$, $b=3.0237\;{\AA}$, and $c=10.7124\;{\AA}$. Results of structural refinement indicate, however, that there are two slightly different iron sites in the sample. The $M{\ddot{o}}ssbauer$ spectrum at 4.2 K shows a hyperfine sextet with a hyperfine magnetic field and an isomer shift of 47.3 T and 0.36 mm/s, respectively. An examination of the spectrum revealed that the line widths of the spectral lines were not uniform. The degree of asymmetric line broadening decreases with increasing temperature, suggesting that the difference in the degree of crystalline distortions between two $FeO_6$ octahedra is eliminated as the temperature rises.

Textural Characteristics and Microstructure of Soybean Curds Prepared with Different Coagulants (응고제를 달리하여 제조한 두부의 질감과 구조 특성)

  • Lee, Hun-Joo;Hwang, In-Kyeong
    • Korean journal of food and cookery science
    • /
    • v.10 no.3
    • /
    • pp.284-290
    • /
    • 1994
  • To prepare soybean curds, the concentration of $CaCl_2,\;MgCl_2,\;CaSO_4$ and glucono-%{\delta}$-lactone fresh solution as coagulants were determined by transmittance of whey using spectrophotometer. The concentrations of four coagulants at which the transmittance had the highest value were chosen. Moisture content, yield and protein recovery of soybean curds prepared with four coagulants were investigated. The textural properties were examined by Instron Universal Testing Machine, and sensory evaluation was carried out. The microstructure of soybean curds was examined by SEM. Soybean curds obtained with $CaCl_2\;and\;MgCl_2$ were hard and coarse, and had roasted nutty taste, whereas those with $CaSO_4$ and GDL revealed very smooth, soft and uniform. Soybean curd prepared with GDL had the lowest acceptability because of sour taste. The texture and acceptability of soybean curds were influenced by the type of coagulant.

  • PDF

Characteristic Polynomial of 90 UCA and Synthesis of CA using Transition Rule Blocks (90 UCA의 특성다항식과 전이규칙 블록을 이용한 CA 합성법)

  • Choi, Un-Sook;Cho, Sung-Jin
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.13 no.3
    • /
    • pp.593-600
    • /
    • 2018
  • Cellular automata (CA) have been applied to effective cryptographic system design. CA is superior in randomness to LFSR due to the fact that its state is updated simultaneously by local interaction. To apply these CAs to the cryptosystem, a study has been performed how to synthesize CA corresponding to given polynomials. In this paper, we analyze the recurrence relations of the characteristic polynomial of the 90 UCA and the characteristic polynomial of the 90/150 CA whose transition rule is <$00{\cdots}001$>. And we synthesize the 90/150 CA corresponding to the trinomials $x^{2^n}+x+1(n{\geq}2)$ satisfying f(x)=f(x+1) using the 90 UCA transition rule blocks and the special transition rule block. We also analyze the properties of the irreducible factors of trinomials $x^{2^n}+x+1$ and propose a 90/150 CA synthesis algorithm corresponding to $x^{2^n}+x^{2^m}+1(n{\geq}2,n-m{\geq}2)$.

Low Temperature Synthesis of the Microwave Dielectric (Pb0.5Ca0.5)(Fe0.5Nb0.5)O3 Nano Powders by the Metal-citrate Process (Metal-citrate Process를 이용한 마이크로파 유전체용 (Pb0.5Ca0.5)(Fe0.5Nb0.5)O3 나노 분말의 저온 합성)

  • Lee, Dong-Wook;Won, Jong-Han;Shim, Kwang-Bo;Kang, Seung-Gu;Hyun, Boo-Sung
    • Journal of the Korean Ceramic Society
    • /
    • v.39 no.11
    • /
    • pp.1113-1118
    • /
    • 2002
  • Nano sized $(Pb_{0.5}Ca_{0.5})(Fe_{0.5}Nb_{0.5})O_3$ (PCFN) powders with the stoichiometric composition and the uniform size distribution were successfully synthesized by the metal-citrate process through the calcination of the polymeric precursor which consisted of the metal ions and the organic network. The crystallization of the initial amorphous powders began at $400{\circ}$ and completed at $700{\circ}$. The pyrochlore phase was detected caused by the dissociation of PbO above $900{\circ}$. Single phase perovskite PCFN powders with 40 nm size and uniform shape were obtained through the calcination at $700{\circ}$.

Mechanical and thermal properties of Homo-PP/GF/CaCO3 hybrid nanocomposites

  • Parhizkar, Mehran;Shelesh-Nezhad, Karim;Rezaei, Abbas
    • Advances in materials Research
    • /
    • v.5 no.2
    • /
    • pp.121-130
    • /
    • 2016
  • In an attempt to reach a balance of performances in homo-polypropylene based system, the effects of single and hybrid reinforcements inclusions comprising calcium carbonate nanoparticles (2, 4 and 6 phc) and glass fibers (10 wt.%) on the mechanical and thermal properties were investigated. Different samples were prepared by employing twin-screw extruder and injection molding machine. In morphological studies, the uniform distribution of glass fibers in PP matrix, relative adhesion between glass fibers and polymer, and existence of nanoparticles in polymer matrix were observed. $PP/CaCO_3$ (6 phc) as compared to pure PP and PP/GF had superior tensile and flexural strengths, impact resistance and deformation temperature under load (DTUL). $PP/GF/CaCO_3$ (6 phc) composite displayed comparable tensile and flexural strengths and impact resistance to neat PP, while its tensile and flexural moduli and deformation temperature under load (DTUL) were 436%, 99% and $26^{\circ}C$greater respectively. The maximum impact resistance was observed in $PP/CaCO_3$(6 phc). The highest DTUL was perceived in PP hybrid nanocomposite containing 10 wt.% glass fiber and 4 phc $CaCO_3$ nanoparticle.

Luminescence Properties of $Eu^{2+}$-doped $Ca_2Si_5N_8$ Thin Films ($Eu^{2+}$-doped $Ca_2Si_5N_8$ 박막의 광학특성)

  • Jang, Bo-Yun;Pakr, Joo-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.11a
    • /
    • pp.25-27
    • /
    • 2007
  • $Eu^{2+}$-doped $Ca_2Si_5N_8$ was grown on Si(100) substrate using metal-organic deposition (MOD) method and post-annealed at $900^{\circ}C$ in various atmosphere. Luminescence properties of these thin films were investigated with variations of $Eu^{2+}$-doped concentrations and annealing atmosphere. Thin film was formed with clean surface and uniform thickness of about 72 nm. From the measurements of luminescence properties of thin films, film must be post-annealed in nitrogen or mixture of nitrogen and hydrogen atmosphere to emit a sufficient light. For $Ca_{1.5}Eu_{0.5}Si_5N_8$ thin film annealed at $900^{\circ}C$ in nitrogen atmosphere, excitation band from 380 to 420 nm was detected with the maximum intensity at 404 nm and two broad emission bands from 530 to 630 nm were observed. These broad excitation and emission bands must be attributed to the nitrogen incorporations into the films. From the results, $Ca_{2-x}Eu_xSi_5N_8$ thin film has probability for next generation thin film lighting applications such as light emitting diode (LED) or electro-luminescence (EL).

  • PDF

Fuel Stratification Process in a Lean Burn Internal Combustion Engine by Using Planar Laser Induced Fluorescence (PLIF를 이용한 희박연소엔진에서의 연료 성층화에 관한 연구)

  • 정경석
    • Transactions of the Korean Society of Automotive Engineers
    • /
    • v.11 no.3
    • /
    • pp.7-12
    • /
    • 2003
  • Mixture formation in the cylinder of a lean bum engine has been observed by Laser Induced Fluorescence technique. XeCl laser (308nm) was used to produce a laser sheet. 3-pentanone has been added to iso-octane fuel to produce fluorescence, the intensity of which is proportional to the concentration of the fuel. The laser sheet was introduced through the piston window and the fuel distribution in the vertical plane was observed through a side window. Comparison has been made for the cases of selected fuel injection timing as 0, 360, 405, and 450 CA. For the case of 0 and 360 CA injection, uniform fuel distribution in the combustion chamber has been obtained at the ignition time which is favorable for the high load mode. And the late injection cases, 405 and 450 CA, revealed the stratified formation of rich mixture around the spark plug. That extends the lean misfire limit and reduces cyclic variation in the low load mode.

Influence of Ca-Si Addition on Anodic Polarization Chgaraqcteristics of Al-Zn-In Anodes (海水中 Al-Zn-In 合金陽極의 分極特性에 미치는 Ca-Si 添加의 影響)

  • Seo, Chang-Je
    • Journal of the Korean institute of surface engineering
    • /
    • v.12 no.1
    • /
    • pp.3-10
    • /
    • 1979
  • Many excellent Al-Zn-In anode have been developed up to the present. But for the purpose of the better performance of Al-Zn-In anodes in sea water the effect of calcium silicon addition on anodic polarization and current capacity of Al-Zn-In anodes was measured and analysed in sea water and artificial sea water. The results and conclusions obtained are summarized as follows. 1) Being compared with Al-Zn-In anodes, Al-Zn-In anodes containing 0.05% calcium silicon had superior characteristics in both anodic polarization and current capacity. 2) Corrosion patterns of the anodes containing calcium silicon were much more uniform than those of Al-Zn-In anodes. 3) In this experiment the most useful anode was Al-4% Zn-0.03% In-0.05% (Ca-Si). It had a capacity of 2.60Amp-hr of current/g and a voltage of 1.13(SCE reference) at anodic current density 1,000 4{\mu}A/cm^2$.

  • PDF

Preparation and Sound Insulation Properties of Thermoplastic Elastomer Composites with CaCO3 Filler (탄산칼슘 분말을 충진시킨 열가소성 탄성체 복합재의 제조 및 차음 특성)

  • Choi, Jung-Woo;Hwang, Yeon
    • Korean Journal of Materials Research
    • /
    • v.20 no.9
    • /
    • pp.467-471
    • /
    • 2010
  • Composites of ceramic powders and an elastomer-based matrix were prepared by mixing $CaCO_3$ powders with polyethylene and polypropylene elastomers, and their mechanical and sound insulation properties were measured. $CaCO_3$ powders with 0.7 ${\mu}m$ and 35 ${\mu}m$ particle size were added to elastomers up to 80 wt%. Scanning electron microscopy photographs showed uniform distribution of the $CaCO_3$ powders in the matrix. While density and surface hardness increased, melt index, tensile strength and elongation of the composites decreased as the amount of added $CaCO_3$ powders increased. As more $CaCO_3$ powders were added sound transmission loss of the composites increased owing to the increase of density. Addition of 0.7 ${\mu}m$ sized $CaCO_3$ powders resulted in a slightly higher transmission loss than the addition of 35 ${\mu}m$ sized powders because of the increased interface area between the elastomer matrix and the $CaCO_3$ powders. Composites with a polyethylene matrix showed higher transmission loss than those with a polypropylene matrix because the tensile strength and hardness of the polyethylene-based composites were low and their elongation was high.

Reaction between Calcium-doped Lanthanum Chromite and Yttria Stabilized Zirconia (칼슘이 첨가된 란탄-아크롬산 염과 이트리아 안정화 지르코니아 계면간의 반응)

  • Choe, Jin-Sam
    • Korean Journal of Materials Research
    • /
    • v.11 no.6
    • /
    • pp.460-464
    • /
    • 2001
  • The ceramic diffusion coupling with the green body of calcium-doped lanthanum chromite(La$_{0.8}$Ca$_{0.2}$CrO$_3$CLC- G) and sintered calcium-doped lanthanum chromite(La$_{0.8}$Ca$_{0.2}$CrO$_3$ CLC) by Pechini's method on yttria stabilized zirconia(YSZ) plate has been investigated. The X-ray diffraction pattern of CLC sides at the reacted CLC-G/ CLC and CLC/YSZ interface were identified as La$_{1-x}$ Ca$_{x}$CrO$_3$ and the unreacted YSZ side was cubic-ZrO$_2$ at the treated condition, 1300~1500 C for 10 hr in air, respectively. The order of migration components between CLC/YSZ interface was Zr>La>>Cr>>>Ca and these changes were not dependent upon the treated conditions. The grain shape and size at the interface of CLC-G/CLC was appeared to have a uniform distribution with increasing temperature. The bonding reaction of YSZ/CLC was occurred without a large amount change of the compositions in SEM photos.os.otos.os.

  • PDF