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Performance of carbon nanotube-coated steel slag for high concentrations of phosphorus from pig manure

  • Kang, Kyeong Hwan;Kim, Junghyeon;Jeon, Hyeonjin;Kim, Kyoungwoo;Byun, Imgyu
    • Membrane and Water Treatment
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    • v.11 no.1
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    • pp.59-68
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    • 2020
  • The study objective was to evaluate the enhanced removal of high concentrations of phosphorus from synthetic wastewater (solely phosphorus-containing) and real wastewater (pig manure) by using carbon nanotube (CNT)-coated steel slag. Generally, phosphorus removal by steel slag is attributed to Ca2+ eluted from the slag. However, in this study, CNT was used to control the excess release of Ca2+ from steel slag and increase the phosphorus removal. The phosphorus removal rate by the uncoated steel slag was lower than that of the CNT-coated steel slag, even though the Ca2+ concentrations were higher in the solution containing the uncoated steel slag. Therefore, the phosphorus removal could be attributed to both precipitation with Ca2+ eluted from steel slag in aqueous solution and adsorption onto the surface of the CNT-coated steel slag. Furthermore, the protons released from the CNT surface by exchanging with divalent cations acted to reduce the pH increase of the solution, which is attributed to the OH- eluted from the steel slag. The adsorption isotherm and kinetics of the CNT-coated steel slags followed the Freundlich isotherm and pseudo-second-order model, respectively. The maximum adsorption capacity of the uncoated and CNT-coated steel slags was 6.127 and 9.268 mg P g-1 slag, respectively. In addition, phosphorus from pig manure was more effectively removed by the CNT-coated steel slag than by the uncoated slag. Over 24 hours, the PO4-P removal in pig manure was 12.3% higher by the CNT-coated slag. This CNT-coated steel slag can be used to remove both phosphorus and metals and has potential applications in high phosphorus-containing wastewater like pig manure.

Palmitoylpolysaccharide-coated Liposomes As A Potential Oral Drug Carrier (경구용 약물수송체로서의 팔미토일 치환 다당체로 코팅된 리포좀)

  • Hahn, Yang-Hee;Yi, Jung-Woo;Choi, Young-Wook
    • Journal of Pharmaceutical Investigation
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    • v.24 no.2
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    • pp.73-83
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    • 1994
  • Applications of liposomes as a drug carrier for the oral delivery of poorly-absorbable macromolecular drugs have been limited, because of their instability in gastrointestinal environments including pH, bile salts, and digestive enzymes. Two polysaccharides, dextran(DX) and pullulan(PL), were introduced to the preformed liposomes in order to enhance the stability. Palmitoyl derivatives of polysaccharides, palmitoyldextran(PalDX) and palmitoylpullulan(PalPL), were synthesizd and introduced to the liposomes during preparation for the same purpose of stability. The effects of these polysaccharides coating were evaluated basically by physical properties of particle size distribution and optical microscopy, then compared with uncoated liposomes by the observations of both in vitro stability and in vovo absorption characteristics. The geometric mean diameters of polysaccharide-coated liposomes were greater than that of uncoated liposome, showing the outermost polysaccharide-coated layer under the optical microscopy. In vitro stabilities of uncoated or polysaccharides-coated liposomes were measured by turbidity changes in various pH buffer solutions containing sodium choleate as bile salts. While uncoated liposome was very sensitive to bile salts, polysaccharides-coated liposomes were stable in relatively higher concentrations of sodium choleate, giving the results of better stability of PalDX- and PalPL-coated liposomes than that of DX- and PL-coated liposomes. After liposomal encapsulation of acyclovir(ACV), an antiviral agent as a model drug, it has been administered orally to rats as dose of ACV 40 mg/kg. Plasma concentrations of ACV were assayed by HPLC and analyzed by model-independent pharmacokinetics. Pharmacokinetic parameters of Cmax, tmax, and [AUC] have been compared.

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Bond Strength and Corrosion Resistance of Coated Reinforcing Bar Using Hybrid-Type Polymer Cement Slurry (Hybrid형 폴리머 시멘트 슬러리로 도장한 철근의 부착강도와 부식저항성)

  • Jo, Young-Kug
    • Journal of the Korea Institute of Building Construction
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    • v.8 no.3
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    • pp.93-99
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    • 2008
  • The purpose of this study is to evaluate the bond strength and corrosion resistance of coated reinforcing bar using hybrid-type polymer cement slurry(PCS). PCS coated steels, which is made from two types of polymer dispersions such as St/BA and EVA are prepared, and tested for bond strength and various corrosion resistances such as autoclaved cure, carbonation and H2SO4 solution. From the test results, the bond strength of PCS coated reinforcing bar using ordinary portland cement at 1-5, 2-1 and 4-5 of mixes is higher than that of uncoated regular steel. However, bond strength of almost PCS coated reinforcing bars using ultra rapid high strength cement is higher than that of epoxy coated bar, is also in ranges of 102% to 123% compared to that of uncoated regular steel. In autoclaved accelerating test, the ratio of corrosion of uncoated regular steel is increased with the increase in NaCl content, but the corrosion of PCS coated steel was very small. In the acceleration test for carbonation, increasing the amount of NaCl the corrosion of coated steel did not produce. The corrosion of uncoated regular steel is increased with the increase in the amount of NaCl. It can be seen that the NaCl following the acceleration test for carbonation can lower the corrosion resistance of concrete. As a result, the corrosion of steel largely is affected by the acceleration curing, chloride ion penetration and carbonation and shown more severe corrosion by applying complex factors. These corrosions of steel can be suppressed by the coating of PCS.

Characteristics of Thermal Radiation Pastes Containing Graphite and Carbon Nanotube (흑연 및 탄소나노튜브 혼합 방열도료의 특성)

  • Lee, Ji Hun;Song, Man-Ho;Kang, Chan Hyoung
    • Journal of the Korean institute of surface engineering
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    • v.49 no.2
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    • pp.218-224
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    • 2016
  • Thermal radiation pastes were prepared by dispersing carbon materials as fillers with a content of 1 weight percent in an acrylic resin. The kind of fillers was as follows; $25{\mu}m$ graphite, $45{\mu}m$ graphite, $15{\mu}m$ carbon nanotube(CNT), a 1:1 mixture of $25{\mu}m$ graphite and $15{\mu}m$ CNT, and a 1:1 mixture of $45{\mu}m$ graphite and $15{\mu}m$ CNT. Thermal emissivity was measured as 0.890 for the samples with graphite only, 0.893 for that with CNT only, and 0.892 for those containing both. After coating prepared pastes on a side of 0.4 mm thick aluminium plate and placing the plate over an opening of a box maintained at $92^{\circ}C$ with the coated side out, the temperatures on the uncoated side of the plates were measured. The samples containing graphite and CNT showed the lowest temperatures. The paste with mixed fillers was coated on the back side of the PCB of an LED module and thermal analysis was carried out using Thermal Transient Tester (T3ster) in a still air box. The thermal resistance of the module with coated PCB was measured as 14.34 K/W whereas that with uncoated PCB was 15.02 K/W. The structure function analysis of T3ster data revealed that the difference between junction and ambient temperatures was $13.8^{\circ}C$ for the coated case and $18.0^{\circ}C$ for the uncoated. From the infrared images of heated LED modules, the hottest-spot temperature of the module with coated PCB was lower than that of the uncoated one for a given period of LED operation.

Protection Effect of ZrO2 Coating Layer on LiCoO2 Thin Film

  • Lee, Hye-Jin;Nam, Sang-Cheol;Park, Yong-Joon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.5
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    • pp.1483-1490
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    • 2011
  • The protection effect of a $ZrO_2$ coating layer on a $LiCoO_2$ thin film was characterized. A wide and smooth $LiCoO_2$ thin film offers sufficient opportunity for careful observation of the reaction at the interface between cathode (coated and uncoated) and electrolyte. The formation of a $ZrO_2$ coating on a $LiCoO_2$ thin film was confirmed by secondary ion mass spectrometry. Scanning electron and atomic force microscopy were used to characterize the surface morphologies of coated and uncoated films before and after cycling. A $ZrO_2$-coated $LiCoO_2$ film showed a higher discharge capacity and rate capability than an uncoated film. This may be associated with a surface protection effect of the coating. The surface of a pristine film was damaged during cycling, whereas the coated film maintained a relatively clear surface under the same measurement conditions. This result clearly demonstrates the protection effect of a $ZrO_2$ coating on a $LiCoO_2$ thin film.

Studies on Water Vapor Sorption through Hard Gelatin Capsules (경(硬)캅셀제(劑)의 흡습(吸濕)에 관(關)한 연구(硏究))

  • Park, Joung-Hoon
    • Journal of Pharmaceutical Investigation
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    • v.2 no.1
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    • pp.40-51
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    • 1972
  • Water vapor sorption of corn starch in various protective film coated capsules in 100% RH chamber for 14 days were as follows: The percent of water vapor sorption were 28.63% in uncoated capsule, 25.16% in hydroxy propylcellulose(HPC) coated capsule, 15.59% in 2-methyl-5-vinyl pyridine-methyl acrylated-methacrylic acid (MPM) coated capsule and 15.50% in polyvinyl acetal diethyl amino acetate(AEA) coated capsule. 2. Water vapor sorotion of magnesium trisilicate in various protective film coated capsules in 100% RH chamber for 14 days were as follows. The percent of water vapor sorption were 13.91% in uncoated capsule, 13.30% in HPC-coated capsule, 10.87% in MPM-caated capsule and 9.9% in AEA-coated capsule. 3. Water vapor sorption of magnesium carbonate in various protective film coated capsules in 100% RH chamber for 14 days were as follows: The percent of water vapor sorption were 12.48% in uncoated capsule, 10.72% in HPC-coated capsule, 8.10% in MPM coated capsule and 7.8% in AEA-coated capsule. 4. MPM-coated capsules and AEA-canted capsules were mere effective to protect water vapor sorption than HPC-coated capsules.

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Damage Mechanism of Particle Impact in a $Cr_2O_3$ Plasma Coated Soda-lime Glass ($Cr_2O_3$ 플라스마 용사 코팅된 유리의 입자충격에 의한 손상기구)

  • Suh, Chang-Min;Lee, Moon-Whan;Kim, Sung-Ho;Jang, Jong-Yun
    • Journal of Ocean Engineering and Technology
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    • v.12 no.3 s.29
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    • pp.49-59
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    • 1998
  • The damage mechanism of $Cr_2O_3$ plasma coated soda-lime glass and uncoated glass by steel ball particle impact was analyzed in this study. And the shape variation of the cracks was investigated by stereo-microscope according to the impact velocity and steel ball diameter. In order to improve the damage reduction effect by $Cr_2O_3$ coating layer, crack size was measured and surface erosion state was observed for both of two kinds of specimen after impact experiment. And the results were compared with each other. The 4-point bending test was performed according to ASTM D790 testing method to evaluate the effect of coating layer for bending strength variation. As a result, it was found that the crack size of $Cr_2O_3$ coated specimen was smaller than that of uncoated one, because of the impact absorption by interior pores in the coating layer and the load dispersion by the structural characteristic of the coating layer. For the specimens subjected to the steel ball impact, the bending strength of coated specimen was higher than that of uncoated specimen.

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High Temperature Wear of STD 61 Tool Steels Sliding Against Al-9%Si Coated Steels Used for Hot Press Forming (STD 61 공구강과 상대재인 핫 프레스 가공용 Al-9%Si 코팅강의 고온 미끄럼 마모)

  • Choi, Byung-Young;Kim, Hong-Ki
    • Korean Journal of Metals and Materials
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    • v.47 no.10
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    • pp.667-674
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    • 2009
  • High temperature wear of STD 61 tool steels sliding against the Al-9%Si coated steels used for hot press forming has been studied in comparison with that of the tool steels sliding against the uncoated steels. Wear tests have been performed using a pin-on-disc configuration under an applied normal load of 50N for 20 min with heating the coated and uncoated steels up to 800$^{\circ}C$. It was found on the worn surface of the STD 61 tool steels sliding against the Al-9%Si coated steels that the formation of the glazed layers containing Al transferred from the coated tribopair may contribute to a reduction of the coefficient of friction, and detachment in part occur due to delamination wear, resulting in higher specific wear rate. On the other hand the Fe-oxide wear debris entrapped on the softer surface of the uncoated steels can act as a tribosurface, leading to decreased adhesive wear of the STD 61 tool steels, resulting in a lower specific wear rate.

Quality Characteristics and Processing of Rice Coated with Bamboo Extract (대나무 추출액을 이용한 코팅쌀 제조 및 품질 특성)

  • Jung Gi-Tai;Ju In-Ok;Ryu Jeong;Choi Joung-Sik
    • Food Science and Preservation
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    • v.11 no.3
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    • pp.325-330
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    • 2004
  • This study was conducted to investigate optimal processing conditions, cooking characteristics, antioxidant activity and packaging method of rice coated with bamboo extract. In sensory evaluation of cooked rice, rice coated with bamboo ethanol extract was higher smell and taste than the other extraction methods, but texture showed no difference. As coating concentration increasing, L, a and b values of coated rice were increased. But L value of coated rice after cooking was decreased. On sensory evaluation of cooked rice, smell and taste were best in 10$\%$ coated with bamboo ethanol extract. Mineral contents of coated rice with bamboo extract were higher than those of uncoated. Water absorption and volume expansion of coated rice were lower than uncoated rice but showed higher toyo value. Hardness, gumminess and chewiness values of cooked rice with coated rice were higher than uncoated rice. Antioxidant activity of coated rice was higher than uncoated rice about twice times. Toyo values and alkali digestive values of coated rice were highest in paper package than the other packaging conditions. The total bacterial counts of rice coated with bamboo extract after cooking was lower than uncoated rice during storage at 25 and 6O$^{\circ}C$.

Cooking Characteristics of Coated Rice with Water Homogenate of Citrus Fruits Peel (감귤과피 물 균질액으로 가공한 유색미의 취반 특성)

  • 서성수;김미향;노홍균;김순동
    • Journal of the East Asian Society of Dietary Life
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    • v.12 no.4
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    • pp.318-325
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    • 2002
  • Cooking characteristics of coated rice with water homogenate of citrus fruit peels (1% for rice) were investigated. The color of the coated rice both before and after cooking was dark yellow. The total content of carotenoids, hesperidin and naringin were 10.74, 2173.12 and 1468.40 mg% for citrus fruit peels, 0.46, 108.65 and 73.35 % for its water homogenate, 0.12, 21.73 and 14.62 mg% for coated rin, and 0.05, 8.67 and 5.87 mg% fur cooked coated rice, respectively. Citrus fruits peel contained 94.22 mg% of asparagine, 24.88 mg% of methionine, 19.64 mg% of alanine, and 15.37 mg% of ${\gamma}$-aminoisobutyric acid as the majority free amino acids, accounting for 70% of the total free amino acids present. Total free amino acid content of the cooked coated rice increased by 15% compared to those of cooked uncoated rice. The majority of minerals in the citrus fruit peels were K and Ca, accounting for 56% of total minerals present. The mineral content of cooked coated rice was generally higher than that of the cooked uncoated rice. The cooked coated rice showed comparable hardness, gumminess and brittleness, but higher cohesiveness and springiness than the cooked uncoated rice. There were no differences in sweet and bitter taste between the cooked uncoated and coated rice. However, the cooked coated rice showed higher sensory scores fur color acceptability, savory taste and overall acceptability than the cooked uncoated rice.

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