• Title/Summary/Keyword: unburned-carbon

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Evaluation of the Fluidity of Fly Ash Cement Paste (플라이 애시 혼합 시멘트 페이스트의 유동성 평가)

  • 이승헌;김홍주;판정열;대문정
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.1221-1226
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    • 2000
  • Influence of characters of fly ash on the fluidity of cement paste with polycarboxylic acid type superplasticizer has been investigated in connection with the particle size of distribution, unburned carbon content, specific surface area and shape of fly ash. The fluidity of paste is increased with increasing roundness of fly ash and it is decreased with increasing n-value of Rosin-Rammler distribution function. There is a linear correlation between roundness/n-value and fluidity of fly ash cement paste.

Comparison of Plant Community Structures in Cut and Uncut Areas at Burned Area of Mt. Gumo-san (금오산(金烏山)의 산화지(山火地)에서 벌목지(伐木地)와 비벌목지(非伐木地)의 식물(植物) 군집구조(群集構造) 비교(比較))

  • Che, Sang-Hoon;Kim, Woen
    • Journal of Korean Society of Forest Science
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    • v.86 no.4
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    • pp.509-520
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    • 1997
  • This is a report on the early vegetation, plant community structure, and secondary succession of cut and uncut sites of burned areas in Mt. Gumo-sun. The forest fire occurred on April, 1994 and the pine forest and its floor vegetation were burned down. The investigation was carried out from April, 1995 to October, 1996. The results are summarized as follows : The floristic composition of cut and uncut sites of burned area and unburned area were composed of 32, 36, and 34 kinds of vascular plants respectively. The biological spectra showed the $H(G)-D_1-R_5-e$ type, $H(M)-D_1-R_5-e$ and $M(N)-D_1-R_5-e$ in cut, uncut, and unburned site respectively. The dominant species based on $SDR_3$ of the cut site were Miscanthus sinensis var. purpurascens(100.00). Caret humilis(52.27), Quercus serrata(51.19) and Lysimachia clethroides(39.40), however, in the uncut sites the dominant species were Quercus acutissima(56.91), Pinus densiflora(26.83) in the tree layer, Quercus serrata(50.43), Lindera glauca(40.51), Lespedeza bicolor(37.85) in the shrub layer, and Miscanthus sinensis var. purpurascens(72.27), Pteridium aquilium var. latiusculum(60.92), Carex humilis(63.63) in the herb layer. Pinus densiflora(99.88), Miscanthus sinensis var. purpurascens(82.74), Quercus serrata(77.47) and Carex humilis(74.02) were dominant in the unburned site. The species diversity(H) and evenness index(e) were 1.05, 0.70 and 1.32, 0.85 in the cut and uncut site, respectively and 0.22, 0.63 in the unburned site. Dominance index(C) was 0.15, 0.06 and 0.96 in the cut, uncut site and unburned site, respectively. Degree of succession(DS) was 345.19, 747.47 and 674.34 in cut, uncut and unburned site, respectively. The index of similarity(CCs) was 0.66 between cut and uncut sites, 0.50 between unburned and cut sites and 0.61 between unburned and uncut sites. The amount of exchangeable sodium, calcium, magnesium and soil pH were increased, but the amount of organic matter, available phosphous, total nitrogen, total carbon and exchangeable potassium were decreased in cut site after fire.

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NOx Emission Characteristics Depending on the Variations in Yaw Angle of the Secondary Air Nozzles in a Coal Fired Boiler (연소용 이차공기 수평분사각에 따른 질소산화물(NOx) 배출특성)

  • Kim, Young-Joo;Park, Ho-Young;Lee, Sung-No
    • Journal of Korean Society of Environmental Engineers
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    • v.31 no.4
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    • pp.272-277
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    • 2009
  • Three dimensional numerical analysis for the coal fired boiler has been performed to investigate the effect of yaw angle variation of the secondary air nozzles on the combustion characteristics and NOx emission. It was found that the prediction gives a good agreement with plant data. The increase in yaw angle up to $20^{\circ}$ have results in the decrease in NOx emission at furnace exit and recirculation flow intensity, together with the increase of unburned carbon in ash. It also has been recognized the remarkably change in configuration of fire ball with increase in yaw angle. The results from this study would be valuable in the case of the combustion modification of the corner firing coal-fired utility boiler.

The Biomass Pre-treatment Effect on the Combustion Characteristics of Coal and Biomass Blends (바이오매스 전처리 기술에 따른 혼소 특성에 관한 실험적 연구)

  • KIM, JONG-HO;PARK, KYEONG-HOON;KIM, GYEONG-MIN;PARK, KYEONG-WON;JEONG, TAE-YONG;LEE, YOUNG-JOO;JEON, CHUNG-HWAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.1
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    • pp.81-89
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    • 2018
  • Fuel blend technique is one of the most effective way of using biomass to replace the coal. Many studies on combustion characteristics with coal and biomass blends have been conducted. In this study, char reactivity and emission characteristics of coal (Suek) and biomass (EFB) blends has been investigated by TGA and DTF to evaluate the applicability of the pre-treated (torrefaction, ash removal technology) EFB to pulverized coal boiler. In all blending cases, char reactivity improved as the blending ratio increases (10, 20, and 30%), especially torrefied EFB blended at 30%. Also, unburned carbon decreased as the blending ratio increases in all types of EFB. NOx emission showed the increase and decrease characteristics according to the content of fuel-N of raw EFB and torrefied EFB. But the amount of NOx emission at ashless EFB blends is greater than that of Suek despite of lower fuel-N. It indicated that co-firing effect of using the pretreatment biomass fuel is relatively better than those of the untreated biomass fuel about char reactivity and emission characteristics.

A Study on the Regeneration of SCR Catalyst Deactivated by Unburned Carbon Deposition (탄소침적으로 피독된 탈질 촉매의 재생에 관한 연구)

  • Moon, Seung-Hyun;Lee, Seung-Jae;Ryu, In-Soo
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.10
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    • pp.928-935
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    • 2010
  • A bag filter system was partially burnt down during a trial run of waste wood incineration boiler. This brought about unburned hydrocarbon which caused a rapid deactivation of low temperature SCR catalyst set up in two stage after the bag filter. The deactivated catalyst was investigated in order to trace the origin by several characterization methods such as XRD, EDX, BET, TGA, SEM. The deactivated catalyst was regenerated by different methods such as acid washing, water washing in ultrasonication, and calcination treatment under air condition. It is found the calcination treatment under air condition at $450^{\circ}C$ for 2 hours to be the best regeneration method. The catalytic activity was measured in the form of 2 cm ${\times}$ 2 cm ${\times}$ 10 cm (catalyst weight 10 g) honeycomb type. A deNOx efficiency of the regenerated catalyst showed 100% at $180^{\circ}C$ which is the same level of fresh one.

Properties of Carbon-Rich Particles and Purified Ash Obtained from Countercurrent Column Flotation (부유분리법에 의해 분리한 고순도 정제석탄회와 고탄소 석탄회의 특성)

  • 이정언;안영철;김성찬;구재현;나성수;신진혁;이재근
    • Resources Recycling
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    • v.8 no.4
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    • pp.11-19
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    • 1999
  • Fly ash generated from (he pulverized coal power plant have caused the serious ocean pollution due to the disposal in the ash pond, the life reduction of a power plant and the waste of re-utilizable resource The research to reuse the unburned carbon and mineral composing of the ash has been progressed. In this study. the physical and chemical characteristics of high grade ash and unburned carbon particles obtained from countercurrent column flotation are investigated. The cleaned ash of the less 0,5% loss on Ignition(LOI) in carbon content is a spherical sphere and 39.8${\mu}m$ in size of MMD(Mass Median Diameter). 2.22 $m^2/g$ of specific area. The morphology of high LOI carbon particles is a amorphousness, 76.6 ${\mu}m$ of particle size and 15.2 $m^2/g$ of specific The high grade cleaned ash and the high LOI ash have some difference in the light of physical. chemical and morphological characteristics

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Synthesis of $\beta$-Sialon Powder from Fly Ash (Fly Ash를 이용한$\beta$-Sialon 분말합성)

  • 최희숙;노재승;서동수
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.871-876
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    • 1996
  • It is believed that fly ash could be suitable for preparing the sialon by carbothermal reduction method because the total amount of SiO2 and Al2O3 is above 80% and the unburned residual carbon is above 5% within the fly ash. The effects of reaction temperature (1350, 1400, 145$0^{\circ}C$) reaction time (1, 5, 10 hours) and the amount of carbon additions (C/SiO2=2, 3, 4 mole) on the $\beta$-sialon synthesis were obserbed, It was conformed that $\beta$-sialon (Z=2.15~2.18) was formed as major phase under all of the synthesis conditions and small amount of Si2ON2 SiC, AlN and Si3N4 was formed depending on the synthesis conditions. FeSix intermetal-lic compound was formed above 140$0^{\circ}C$ reaction temperature due to the large amount of iron oxides within the raw fly ash.

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Effects of Fire on Forest Vegetation in Mt. Samma (산불이 삼마산의 삼림식생에 미치는 영향)

  • Kim, Woen;Park, Jung-Hye;Cho, Young-Ho
    • The Korean Journal of Ecology
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    • v.22 no.3
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    • pp.145-153
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    • 1999
  • Authors report the changes of the community structure and secondary succession after fire in Mt. Samma (333 m). Approximately six ha of the red pine (Pinus densiflora) forest and its floor vegetation were burned and cutted down. The vegetation and soil properties were investigated in the burned and unburned sites from April to October, 1998. The dominant species based on SDR₃ in the burned site were Lespedeza cyrtobotrya (96.87), Quercus serrata (77.90), Cyperus amuricus (46.22) and Miscanthus sinensis var. purpurascens (38.33), whereas the dominant species in the unburned site were Pinus densiflora (100.00) and Q. variabilis (66.10) at the tree layer, Q. serrata (100.00) and Zanthoxylum schinifolium (29.64) at the shrub layer., and Q. serrata (76.30) and M. sinensis var. purpurascens (72.84) at the herb layer. The biological spectra based on SDR₃ were Th-D₁-R/sub 5/-e for the burned and H (M)-D₁-R/sub 5/-e type for the unburned site, respectively. The index of similarity (CCs) between the burned and unburned sites was 0.41. The degree of succession (DS) were 609 for the burned and 1168 for the unburned site, respectively. The species diversity (H) and evenness indices (e) of the burned site were lower than those of the unburned site, but the dominance indices (C) was higher in the burned site. In the analysis of soil properties, pH, the content of NO₃/sup -/-N, available phosphrous, and exchangeable cations (K/sup +/, Ca/sup 2+/, Na/sup +/, Mg/sup 2+/) in the burned site were higher than those in the unburned site, whereas the contents of organic matter, total carbon, total nitrogen and NH₄/sup +/-N were lower in the burned site. The results show that dominant species in the burned site change from Miscanthus-Lespedeza→Lespedeza→Quercus and finally to Quercus forest, and the changes of soil properties also affect the early vegetational succession after fire.

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Clean Flotation Process to Recycle useful Materials from Fly Ash (비산재로부터 유용성분을 회수하는 청정부유선별공정)

  • Han, Gwang Su;Kim, Dul-Sun;Lee, Dong-Keun
    • Clean Technology
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    • v.26 no.3
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    • pp.177-185
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    • 2020
  • All coal ash, generated from coal-fired power plants, is entirely dumped onto a landfill site. As coal ash contains 80% fly ash, a clean floating process was developed in this study to recover useful components from coal ash and to use them as high value-added industrial materials. When the unburned carbon (UC) was recovered from the fly ash, soybean oil, an eco-friendly vegetable oil, was used as collector instead of a non-ionic kerosene collector to prevent the occurrence of odor from the kerosene. After the UC was separated by flotation, particulate ceramic microsphere (CM) was recovered, without generating acidic wastewater, through hydro-cyclone instead of sulfuric acid solution in order to separate ceramic microsphere (CM) and cleaned ash (CA) from the residue. By utilizing soybean oil as a collector, the recovery rate of UC turned high at 85.8% due to the increased adsorption of UC, the high viscosity of soybean oil, and the increase in floating properties caused by the linoleic acid contained in soybean oil. All of the combustible components contained in the recovered UC were carbon components, with the carbon content registering high when soybean oil was used. The recovered UC had many pores with a rough surface; thus, it could be easily ground and then used as an industrial material for its fine particles. The CM and CA recovered by the clean separation process using hydro-cyclone had a spherical shape, and the particles were clearly separated without clumping together. The average diameter (D50) of the particles was 5 ㎛, so it was possible to realize the atomization of CM through a process change.

Air Fuel Ratio Determination Method for Alternative Fuel Based on Carbon Balance and Linear Equation (탄소 균형과 1차식에 의한 대체 연료의 공연비 산정법)

  • Lee, Jae-Won;Kwon, Soon-Tae;Park, Chan-Jun;Ohm, In-Young
    • Journal of Energy Engineering
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    • v.17 no.4
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    • pp.182-188
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    • 2008
  • This paper is to compare the carbon-balanced and liner air-fuel ratio determination methods for alternative fuels. In the previous work, expansion of Eltinge chart, unburned hydrocarbon compensation, comparison of the results from various methods were discussed. It has been also concluded that Eltinge method might be regarded as the most general equation of AFR determination among the existing ones. In the recent years, however, increasing demand for the environmental preservation, including global warming-up protection, and energy conservation lead to introduce the alternative fuel to the internal combustion engine. Therefore, the exact calculations of AFR for these fuels are needed. Especially, for the fuel that contains oxygen, all AFR calculation equations except Eltinge have to be re-formulated. In this paper, the AFR for alternative fuel were calculated by re-formulated carbon balance, accuracy of which was already confirmed, and linear equations, which are newly proposed by statistical method for each fuel. The results show that AFRs based on carbon balance have a little more error compared with gasoline, however, the accuracy is enough for this formula to apply to various fuel. The proposed linear equation also have excellent accuracy below $\lambda=1.2$.