• Bulletin of the Korean Chemical Society
• /
• 제28권12호
• /
• pp.2377-2381
• /
• 2007

Solvolyses of 3,4-dimethoxybenzenesulfonyl chloride (DSC) in water, D2O, CH3OD, and in aqueous binary mixtures of acetone, acetonitrile, 1,4-dioxane, ethanol, methanol, and 2,2,2-trifluoroethanol (TFE) have been investigated at 25.0 oC. Kinetic solvent isotope effects (KSIE) in water and in methanol and product selectivities in alcohol-water mixtures are also reported. The Grunwald-Winstein plot of first-order rate constants for the solvolyic reaction of DSC with YCl shows marked dispersions into separated lines for various aqueous mixtures. With use of the extended Grunwald-Winstein equation, the l and m values obtained are 1.12 and 0.58 respectively for the solvolyses of DSC. The relatively large magnitude of l is consistent with substantial nucleophilic solvent assistance. From Grunwald-Winstein plots the rate data are dissected approximately into contributions from two competing reaction channels. This interpretation is supported for alcohol-water mixtures by the trends of product selectivities, which show a maximum for ethanol-water mixtures. From the KSIE of 1.45 in methanol, it is proposed that the reaction channel favored in methanolwater mixtures and in all less polar media is general-base catalysed and/or is possibly (but less likely) an addition-elimination pathway. Also, the KISE value of 1.35 for DSC in water is expected for SN2-SN1 processes, with minimal general base catalysis, and this mechanism is proposed for solvolyses in the most polar media.

• 한국의상디자인학회지
• /
• 제10권1호
• /
• pp.69-78
• /
• 2008

A new coinage which calls a modern was appeared variously by values, taste, feature of lifestyle and the meaning of a new coinage has influence in the change of lifestyle. Particularly a popular star is a person who situates in the center of a new coinage, his role, behavior, and appearance have great influence in the birth of a new coinage. He is a fashion leader as well as the object of fashion imitation to the new generation being sensitive for fashion. As his fashion is appeared with important fashion icon in fashion market, fashion companies have developed actively star marketing marking him as an advertising model. Therefore, because the fashion trends of a popular star introduce season's fashion trends and can be important factor forecasting fashion behavior of consumer, this study aims at analysis for fashion trends of a popular star including a public entertainer. The dates of this study were collected by TV drama, internet, and magazines, etc. The fashion trends were divided into feminine fashion trend, sexy fashion trend, tomboy fashion trend, and retro fashion trend. Feminine fashion trend was based on feminity but it was classified in masculine look, simple look, chic look, and natural & romantic look according to the standard of a transformation of feminine image. Sexy fashion trend was divided into two sexy images according to the method wrapping oneself in a dress and the method exposing a specific body part. Tomboy fashion trend could be the immature boyish style which concealed bust or hip or pelvis symbolizing feminity. Retro fashion trend could be style being based on 1980's style and Y line. Fashion items as leggings, baby doll dress, tunic style, dot pattern, garsonne look were come into fashion.

• 정보처리학회논문지A
• /
• 제9A권2호
• /
• pp.147-162
• /
• 2002

고속 입출력 장치를 갖는 다중 프로세서 시스템은 데이터의 처리 성능 향상과 함께 입출력의 집중화에 따른 병목 현상을 줄여줄 수 있다. 이 때 프로세서간의 데이터 전송에 사용되는 공유 메모리는 그 구성과 이용 방법에 따라 시스템 성능에 많은 영향을 미치게 되는데, 본 논문에서는 공유 메모리의 사용방법을 비동기, 메일박스를 통한 인터럽트 전달인지 방식으로 설정한 후 버퍼 및 공유 메모리의 최적 사용량을 예측할 수 있는 모델에 대해 연구하였다. 시스템에 주어지는 입출력 데이터는 이더넷(IEEE 802.3) 망에 흐르는 패킷을 모델로 하며, 이의 대역폭과 burstiness(패킷의 집중화 정도)에 따른 메모리 사용 상황에 대해 살펴보았다. 고속 이더넷(Fast Ethernet) 환경 하에서 시뮬레이션 및 실험에 의해 시스템의 입출력 대역폭뿐만 아니라 패킷의 집중화 정도에 따라서도 버퍼 및 공유 메모리의 사용량이 달라지며, 두 메모리 사이의 사용량에 대한 상관관계가 성립될 수 있음을 알 수 있다.

• 한국정보처리학회논문지
• /
• 제3권5호
• /
• pp.1253-1261
• /
• 1996

CDMA mobile system (CMS)의 base station (BS)은 호 처리 프로토콜을 처리함 으로써 이동 가입자들에게 호 서비스를 제공한다. BS의 호 처리를 담당하는 시스템은 base station transceiver subsystem (BTS)과 base station controller (BSC)로 구성 된다. 이 논문에서는 호가 발생했을 경우, 제어 신호 및 트래픽 신호에 대해 성능 시뮬레이션을 수행하여 BS에서 발생 할 수도 있는 병목현상 (bottleneck) 및 문제점도 발견하고자 한다. BS의 호 처리 용량을 평가하기 위하여 첫째, BS의 모델에 필요한 주요 파라메터들을 추출한다. 둘째, BS의 시뮬레이션 모델을 제시한다. 셋째, traffic channel elements (TCEs), BTS interconnection network (BIN)-CDMA interconnection network (CIN)트렁크, 트랜스 코딩 채널(transcoding channel) 및 CIN 패킷 라우터 (packet router) 에 대한 호 손을(call blocking probability), 가용도(utilization ratio)및 지연 시간(delay time)등의 주요 요소들을 구하여 시뮬레이션 결과를 평가한다.

• 정보처리학회논문지B
• /
• 제8B권5호
• /
• pp.441-446
• /
• 2001

글로벌 네트워크 시대에는 전세계적으로 흩어져 있는 수많은 컨텐츠가 실시간으로 위한 생활의 스며들 것이며 그로 인해 많은 변화를 줄 것이다. 아울러 컨텐츠 및 다양한 모델 제공 업체들의 환경은 급속하게 변화 할 것이다. 인터넷이나 무선 인터넷으로 컨텐츠나 모델들을 적시에 활용할 수 있는 점은 기업측면에서 의사결정 프로세스를 변화시키며, 공급체인 상에서 많은 기업들이 자신들의 의사결정에 필요로 하는 정보나 모델을 짧은 시간에 탄력적으로 제공 받을 수 있어서 기업이 환경변화에 대한 높은 대응력을 갖출수 있게 한다. 이 논문은 컨텐츠와 모델을 필요로 하는 기업들에게 효과적이면서 효율적으로 제공하기 위한 메타지식의 생성 메커니즘을 제안하는 것이다. 그리고 본 논문에서 제안한 메커니즘을 통해서 실험결과를 얻었으며, 그 결과를 가지고 이 논문에서 제시한 탄력적인 컨텐츠나 모델 제공 이론이 인터넷이나 모바일 네트워크에서 요약된 모델 제공과 트래픽 감소 측면에서 매우 우수함을 보이고 있다.

• 한국환경과학회지
• /
• 제20권2호
• /
• pp.275-289
• /
• 2011

In order to clarify the relation between sea breeze penetration and Planetary Boundary Layer development in southeastern part of the Korean Peninsula, several numerical assessments were carried out using atmospheric numerical model WRF(Weather Research and Forecasting). Compared with onset time of sea breeze at eastern coast area(Uljin), the time at southern coast region(Masan) with complex costal line tend to delay for several hours. The penetration patterns of sea breeze between two coastal regions are some different due to the shape of their coastal line and back ground topography. Intensified valley wind due to high topography of lee side of Uljin can help penetration of sea breeze at early time. So penetration of sea breeze at early time often prevent PBL to develop at Uljin and lower PBL height last for a day time. But because of late penetration of sea breeze at Masna, PBL Height dramatically decrease after 1500LST. The distribution of front genesis function based on the heat and momentum variation are explained obviously the sea breeze penetration patterns and agreed well with the PBL height distribution.

• 천문학회보
• /
• 제37권1호
• /
• pp.82.2-82.2
• /
• 2012

We present Herschel-PACS observations of L1448-MM, a Class 0 protostar with a prominent outflow, part of the DIGIT Key Program (PI: N. Evans). We detect numerous emission lines including CO and $H_2O$ rotational transitions, OH transitions, and [OI] forbidden transitions at wavelengths from 55 to 210 ${\mu}m$. The $H_2O$, [OI], mid-J CO (J < 23), and OH emission distributes along the outflow direction although high-J CO and other OH emission peaks at the central spatial pixel. According to our simple excitation analysis, CO seems to have two temperature components of warm and hot, which might be attributed to the PDR and shock, respectively. After exploring a wide range of physical conditions with a non-LTE LVG code, RADEX, we found that either shock alone or the combination of PDR and shock can explain the observations. The relative fraction of observed line luminosities suggest that L1448-MM is shielded from the UV radiation because $H_2O$ and CO are the dominant coolants rather than OH and [OI]. In addition, our observed fluxes match better with C-shock models rather than J-shocks. The non-LTE LVG model supports that the IR pumping process is important for OH transitions because the OH line ratios are fitted much better when the dust thermal continuum is included.

• 대한기계학회논문집A
• /
• 제25권3호
• /
• pp.537-547
• /
• 2001

The paper proposes the fuzzy logic global approximate optimization strategies in optimal sizing of automotive A-pillar trim with rib structures for occupant head protection. Two different strategies referred to as evolutionary fuzzy modeling (EFM) and neuro-fuzzy modeling (NFM) are implemented in the context of global approximate optimization. EFM and NFM are based on soft computing paradigms utilizing fuzzy systems, neural networks and evolutionary computing techniques. Such approximation methods may have their promising characteristics in a case where the inherent nonlinearity in analysis model should be accommodated over the entire design space and the training data is not sufficiently provided. The objective of structural design is to determine the dimensions of rib in A-pillar, minimizing the equivalent head injury criterion HIC(d). The paper describes the head-form modeling and head impact simulation using LS-DYNA3D, and the approximation procedures including fuzzy rule generation, membership function selection and inference process for EFM and NFM, and subsequently presents their generalization capabilities in terms of number of fuzzy rules and training data.

• 에너지공학
• /
• 제5권1호
• /
• pp.8-18
• /
• 1996

석탄가스화 복합발전(IGCC) 시스템의 공정 시뮬레이션의 일환으로서 석탄가스용 복합발전 플랜트의 성능해석을 하였다. Texaco 가스화기와 저온가스 정제공정에서 생성된 가스를 연료로 하는 가스터빈/증기터빈/폐열회수보일러로 구성된 복합사이클발전시스템을 구성한 후, ASPEN(Advanced System for Process Engineering) Code를 이용하여 정상상태 성능해석을 수행하였다. 가스터빈 사이클(GE MS 7001FA)은 공기분리 공정과의 연계성(Integration)이 고려되었고, 증기사이클은 가스화공정과 가스정제 공정과의 연계성(Integration)을 고려하여 구성하였다. 공정해석결과 가스터빈출력(MWe)은 천연가스를 사용하는 경우에 비하여 동일 입열량(연소기 입구기준)기준으로 약 20%의 증가를 가져왔다. 본 연구의 결과를 Bechtel Canada Inc.에서 Nova Scotia 발전소를 대상으로 1991년에 수행한 연구결과와 비교하였을때 잘 일치하였으며, 이를 통하여 본 연구에서 사용된 해석방법이 상용화 공정의 시뮬레이션에 적정하게 이용될 수 있음을 확인하였다.

• 한국정밀공학회지
• /
• 제19권7호
• /
• pp.71-79
• /
• 2002

A new rapid prototyping process, Variable Lamination Manufacturing using a 4-axis-controlled hotwire cutter and expandable polystyrene foam sheet as a laminating material of the part (VLM-S), has been developed to reduce building time and to improve the surface finish of parts. The objective of this study is to reconstruct the surface of the original 3D CAD model in order to generate mid-slice data using the advancing front technique. The generation of 3D layers by a 4 axis-controlled hot-wire cutter requires a completely different procedure to generate toolpath data unlike the conventional RP CAD systems. The cutting path data for VLM-S are created by VLM-Slicer, which is a special CAD/CAM software with automatic generation of 3D toolpath. For the conventional sheet type system like LOM, the STL file would be sliced into 2D data only. However, because of using the thick layers and a sloping edge with the firstorder approximation between the top and bottom layers, VLM-Slicer requires surface reconstruction, mid-slice, and the toolpath data generation as well as 2D slicing. Surface reconstruction demands the connection between the two neighboring cross-sectional contours using the triangular facets. VLM-S employs thick layers with finite thickness, so that surface reconstruction is necessary to obtain a sloping angle of a side surface and the point data at a half of the sheet thickness. In the process of the toolpath data generation the surface reconstruction algorithm is expected to minimize the error between the ruled surface and the original parts..