• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2377-2381
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• 2007

Solvolyses of 3,4-dimethoxybenzenesulfonyl chloride (DSC) in water, D2O, CH3OD, and in aqueous binary mixtures of acetone, acetonitrile, 1,4-dioxane, ethanol, methanol, and 2,2,2-trifluoroethanol (TFE) have been investigated at 25.0 oC. Kinetic solvent isotope effects (KSIE) in water and in methanol and product selectivities in alcohol-water mixtures are also reported. The Grunwald-Winstein plot of first-order rate constants for the solvolyic reaction of DSC with YCl shows marked dispersions into separated lines for various aqueous mixtures. With use of the extended Grunwald-Winstein equation, the l and m values obtained are 1.12 and 0.58 respectively for the solvolyses of DSC. The relatively large magnitude of l is consistent with substantial nucleophilic solvent assistance. From Grunwald-Winstein plots the rate data are dissected approximately into contributions from two competing reaction channels. This interpretation is supported for alcohol-water mixtures by the trends of product selectivities, which show a maximum for ethanol-water mixtures. From the KSIE of 1.45 in methanol, it is proposed that the reaction channel favored in methanolwater mixtures and in all less polar media is general-base catalysed and/or is possibly (but less likely) an addition-elimination pathway. Also, the KISE value of 1.35 for DSC in water is expected for SN2-SN1 processes, with minimal general base catalysis, and this mechanism is proposed for solvolyses in the most polar media.

• Journal of the Korea Fashion and Costume Design Association
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• v.10 no.1
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• pp.69-78
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• 2008

A new coinage which calls a modern was appeared variously by values, taste, feature of lifestyle and the meaning of a new coinage has influence in the change of lifestyle. Particularly a popular star is a person who situates in the center of a new coinage, his role, behavior, and appearance have great influence in the birth of a new coinage. He is a fashion leader as well as the object of fashion imitation to the new generation being sensitive for fashion. As his fashion is appeared with important fashion icon in fashion market, fashion companies have developed actively star marketing marking him as an advertising model. Therefore, because the fashion trends of a popular star introduce season's fashion trends and can be important factor forecasting fashion behavior of consumer, this study aims at analysis for fashion trends of a popular star including a public entertainer. The dates of this study were collected by TV drama, internet, and magazines, etc. The fashion trends were divided into feminine fashion trend, sexy fashion trend, tomboy fashion trend, and retro fashion trend. Feminine fashion trend was based on feminity but it was classified in masculine look, simple look, chic look, and natural & romantic look according to the standard of a transformation of feminine image. Sexy fashion trend was divided into two sexy images according to the method wrapping oneself in a dress and the method exposing a specific body part. Tomboy fashion trend could be the immature boyish style which concealed bust or hip or pelvis symbolizing feminity. Retro fashion trend could be style being based on 1980's style and Y line. Fashion items as leggings, baby doll dress, tunic style, dot pattern, garsonne look were come into fashion.

• The KIPS Transactions:PartA
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• v.9A no.2
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• pp.147-162
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• 2002

Multi-processor system with fast I/O devices improves processing performance and reduces the bottleneck by I/O concentration. In the system, the Performance influenced by shared memory used for exchanging data between processors varies with configuration and utilization. This paper suggests a prediction model for buffer and shared memory optimization under interrupt recognition method using mailbox. Ethernet (IEEE 802.3) packets are used as the input of system and the amount of utilized memory is measured for different network bandwidth and burstiness. Some empirical studies show that the amount of buffer and shared memory varies with packet concentration rate as well as I/O bandwidth. And the studies also show the correlation between two memories.

• The Transactions of the Korea Information Processing Society
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• v.3 no.5
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• pp.1253-1261
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• 1996

The base station (BS) of CDMA mobile system (CMS) provides mobile call services by controlling call processing functions. The call Processing part of the BS is divided into two components; the base station transceiver subsystem (BTS) and the base station controller (BSC). In this paper, we present the call capacity estimation of the BS about control signals and traffic data of calls by the simulation, and find the bottleneck points and problems which may occur in the BS. In order to estimate the call capacity, first we extract the major parameters for the modeling the BS. Second, we suggest the simulation model for the BS. Third, we estimate the simulation results by finding major objective factors such that the call blocking probability, the utilization ratio and the delay time in the traffic channel elements (TCEs), the BTS interconnection network (BIN)-COMA interconnection network (CIN) trunks, the transcoding channels and the CIN packet router.

• The KIPS Transactions:PartB
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• v.8B no.5
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• pp.441-446
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• 2001

On global interconnectivity, the activation of real-time and worldwide contents will permeate and impact all aspects of day-to-day life well throughout this century. In managing contents and models, we too will see the impact of this rapidly changing environment. The real time availability of contents pertaining to a companys supply chain through means of the Internet and mobile networks(e.g., the IMT-2000) will necessitate a change in decision-making processes for effective management of contents and models. To increase the availability of many contents and models, a management system should have adaptive function in proving adequate content and model for companies. In the respect of management of contents and models, this paper discusses a production mechanism of meta-knowledge for effectively managing contents and models. Through two experimental analyses with the production mechanism, it is proven that the system enabling adaptive contents and models provision goes beyond existing ones in view of efficiency of management of contents and models in the wire and wireless networks.

• Journal of Environmental Science International
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• v.20 no.2
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• pp.275-289
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• 2011

In order to clarify the relation between sea breeze penetration and Planetary Boundary Layer development in southeastern part of the Korean Peninsula, several numerical assessments were carried out using atmospheric numerical model WRF(Weather Research and Forecasting). Compared with onset time of sea breeze at eastern coast area(Uljin), the time at southern coast region(Masan) with complex costal line tend to delay for several hours. The penetration patterns of sea breeze between two coastal regions are some different due to the shape of their coastal line and back ground topography. Intensified valley wind due to high topography of lee side of Uljin can help penetration of sea breeze at early time. So penetration of sea breeze at early time often prevent PBL to develop at Uljin and lower PBL height last for a day time. But because of late penetration of sea breeze at Masna, PBL Height dramatically decrease after 1500LST. The distribution of front genesis function based on the heat and momentum variation are explained obviously the sea breeze penetration patterns and agreed well with the PBL height distribution.

• The Bulletin of The Korean Astronomical Society
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• v.37 no.1
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• pp.82.2-82.2
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• 2012

We present Herschel-PACS observations of L1448-MM, a Class 0 protostar with a prominent outflow, part of the DIGIT Key Program (PI: N. Evans). We detect numerous emission lines including CO and $H_2O$ rotational transitions, OH transitions, and [OI] forbidden transitions at wavelengths from 55 to 210 ${\mu}m$. The $H_2O$, [OI], mid-J CO (J < 23), and OH emission distributes along the outflow direction although high-J CO and other OH emission peaks at the central spatial pixel. According to our simple excitation analysis, CO seems to have two temperature components of warm and hot, which might be attributed to the PDR and shock, respectively. After exploring a wide range of physical conditions with a non-LTE LVG code, RADEX, we found that either shock alone or the combination of PDR and shock can explain the observations. The relative fraction of observed line luminosities suggest that L1448-MM is shielded from the UV radiation because $H_2O$ and CO are the dominant coolants rather than OH and [OI]. In addition, our observed fluxes match better with C-shock models rather than J-shocks. The non-LTE LVG model supports that the IR pumping process is important for OH transitions because the OH line ratios are fitted much better when the dust thermal continuum is included.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.3
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• pp.537-547
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• 2001

The paper proposes the fuzzy logic global approximate optimization strategies in optimal sizing of automotive A-pillar trim with rib structures for occupant head protection. Two different strategies referred to as evolutionary fuzzy modeling (EFM) and neuro-fuzzy modeling (NFM) are implemented in the context of global approximate optimization. EFM and NFM are based on soft computing paradigms utilizing fuzzy systems, neural networks and evolutionary computing techniques. Such approximation methods may have their promising characteristics in a case where the inherent nonlinearity in analysis model should be accommodated over the entire design space and the training data is not sufficiently provided. The objective of structural design is to determine the dimensions of rib in A-pillar, minimizing the equivalent head injury criterion HIC(d). The paper describes the head-form modeling and head impact simulation using LS-DYNA3D, and the approximation procedures including fuzzy rule generation, membership function selection and inference process for EFM and NFM, and subsequently presents their generalization capabilities in terms of number of fuzzy rules and training data.

• Journal of Energy Engineering
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• v.5 no.1
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• pp.8-18
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• 1996

As a part of comprehensive IGCC process simulation, the thermal performance analysis was performed for coal gas firing combined power plant. The combined cycle analyzed consisted of il Texaco gasifier and a low temperature gas cleanup system for the gasification block and a GE 7FA gas turbine, a HRSG and steam turbine for the power block. A steady state simulator called ASPEN(Advanced System for Process Engineering) code was used to simulate IGCC processes. Composed IGCC configuration included air integration between ASU and gas turbine and steam integration between gasifier, gas clean up and steam turbine. The results showed 20% increase in terms of gas turbine power output(MWe) comparing with natural gas case based on same heat input. The results were compared with other study results which Bechtel Canada Inc. performed for Nova Scotia power plant in 1991 and the consistency was identified within two studies. As a result, the analysing method used in this study is verified as a sound tool for commercial IGCC process evaluation.

• Journal of the Korean Society for Precision Engineering
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• v.19 no.7
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• pp.71-79
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• 2002

A new rapid prototyping process, Variable Lamination Manufacturing using a 4-axis-controlled hotwire cutter and expandable polystyrene foam sheet as a laminating material of the part (VLM-S), has been developed to reduce building time and to improve the surface finish of parts. The objective of this study is to reconstruct the surface of the original 3D CAD model in order to generate mid-slice data using the advancing front technique. The generation of 3D layers by a 4 axis-controlled hot-wire cutter requires a completely different procedure to generate toolpath data unlike the conventional RP CAD systems. The cutting path data for VLM-S are created by VLM-Slicer, which is a special CAD/CAM software with automatic generation of 3D toolpath. For the conventional sheet type system like LOM, the STL file would be sliced into 2D data only. However, because of using the thick layers and a sloping edge with the firstorder approximation between the top and bottom layers, VLM-Slicer requires surface reconstruction, mid-slice, and the toolpath data generation as well as 2D slicing. Surface reconstruction demands the connection between the two neighboring cross-sectional contours using the triangular facets. VLM-S employs thick layers with finite thickness, so that surface reconstruction is necessary to obtain a sloping angle of a side surface and the point data at a half of the sheet thickness. In the process of the toolpath data generation the surface reconstruction algorithm is expected to minimize the error between the ruled surface and the original parts..