• Carbon letters
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• v.22
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• pp.14-24
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• 2017

Carboxylated multi-wall carbon nanotubes (MWCNTs-COOH) have been used as efficient adsorbents for the removal of picric acid from aqueous solutions under stirring and ultrasound conditions. Batch experiments were conducted to study the influence of the different parameters such as pH, amount of adsorbents, contact time and concentration of picric acid on the adsorption process. The kinetic data were fitted with pseudo-first order, pseudo-second-order, Elovich and intra-particle diffusion models. The kinetic studies were well described by the pseudo-second-order kinetic model for both methods. In addition, the adsorption isotherms of picric acid from aqueous solutions on the MWCNTs were investigated using six two-parameter models (Langmuir, Freundlich, Tempkin, Halsey, Harkins-Jura, Fowler-Guggenheim), four three-parameter models (Redlich-Peterson, Khan, Radke-Prausnitz, and Toth), two four-parameter equations (Fritz-Schlunder and Baudu) and one five-parameter equation (Fritz-Schlunder). Three error analysis methods, correlation coefficient, chi-square test and average relative errors, were applied to determine the best fit isotherm. The error analysis showed that the models with more than two parameters better described the picric acid sorption data compared to the two-parameter models. In particular, the Baudu equation provided the best model for the picric acid sorption data for both methods.

• Journal of Industrial Technology
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• v.22 no.B
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• pp.35-44
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• 2002

To find the optimal solution as rapidly and exactly as possible with Nelder-Mead simplex algorithm, the present values of the reflection, expansion, contraction and/or shrink parameters of this algorithm are needed to be changed at appropriate time during the search process. The reflection parameter is selected in this study in order to be changed because reflection, expansion and contraction process can be simultaneously effected by only this parameter. Two independent indices for determining whether the present value of the reflection parameter of this algorithm should be changed or not during the search process are suggested in this study. Those indices were made of the equations of Nelder-Mead simplex algorithm's convergence criterion and Dennis-Wood's convergence criterion, respectively. It is appeared that the optimal solution can be find with smaller numbers of objective function evaluation than the original Nelder-Mead's one with fixed parameter when the those indices are used during the search process. and the more remarkable reduction effect of the number of an objective function evaluation can be obtained when the latter index is used.

• 제어로봇시스템학회:학술대회논문집
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• 1999.10a
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• pp.153-156
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• 1999

The technique is reported of identifying parameters in off-line process. The technique demands that closed-loop system consists of a reference and two-degree-of-freedom controllers (TDFC) in real process. A model process is the same as the real process except their parameters. Deviations are differences between the reference and the output of the plant or the model. The technique is based on minimizing identification error between the two deviations. The parameter differences between the plant and the model are characterized of mean value and of variance which are derived from the identification error. Consequently, the algorithm which identifies the unknown plant parameters is shown by minimizing the mean value and the variance, respectively, within double convergence loops. The technique is applied to course change of a ship. The plant deviation at the first trial is shown to occur in replacing the nominal parameters by the default parameters. The plant deviation at the second trial is shown to not occur in replacing the nominal parameters by the identified parameters. Hence, the identification technique is confirmed to be feasible in the real field.

• Korean Journal of Chemical Engineering
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• v.36 no.3
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• pp.356-367
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• 2019

This work presents an advanced and systematic approach to analytically design the optimal parameters of a two parameter second-order internal model control (IMC) filter that satisfies operational constraints on the output process, the manipulated variable as well as rate of change of the manipulated variable, for a first-order plus dead time (FOPDT) process. The IMC parameters are designed to minimize a control objective function composed of the weighted sum of the error between the process variable and the set point, and the rate of change of the manipulated variable, and to satisfy the desired constraints. The feasible region of the constrained IMC control parameters was graphically analyzed, as the process parameters and the constraints varied. The resulting constrained IMC control parameters were also used to find the corresponding industrial proportional-integral controller parameters of a Smith predictor structure.

• Transactions of the Korean Society of Mechanical Engineers
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• v.12 no.4
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• pp.694-704
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• 1988

A recursive parameter estimation scheme utilizing the variance perturbation method is applied to the workpiece deflection model during CNC turning process, in order to improve the cylindricity of slender workpiece. It features that it is based on exponentially weighted recursive least squares method with post-process measurement of finish surfaces at two locations and it does not require a priori knowledge on the time varying deflection model parameter. The measurements of finish surfaces by using two proximity sensors mounted face to face enable one to identify the straightness, guide-way, run-out eccentricity errors. Preliminary cutting tests show that the straightness error of the finish surface due to workpiece deflection during cutting is most dominant. Identifying the errors and recursive updating the parameter, the off-line control is carried out to compensate the workpiece deflection error, through single pass cutting. Experimental results show that the proposed method is superior to the conventional multi-pass cutting and the direct compensation control in cutting accuracy and efficiency.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.37 no.1
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• pp.151-156
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• 2014

Control charts are generally used for process control, but the role of traditional control charts have been limited in case of a contaminated process. Traditional $\bar{x}$ control charts have not been activated well for such a problem because of trying to control processes as center line and control limits changed by the contaminated value. This paper is to propose robust $\bar{x}$ control charts which is considering a location parameter in order to respond to contaminated process. In this paper, we consider $\bar{x}_{\alpha}$, that is trimmed rate; typically ten percent rate is used. By comparing with p, ARL value, the responding results are decided. The comparison resultant results of proposed two control charts are shown and are well contrasted.

• 제어로봇시스템학회:학술대회논문집
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• 2003.10a
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• pp.84-89
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• 2003

Fuzzy controller is one of the succeed controller used in the process control in case of model uncertainties. But it my be difficult to fuzzy controller to articulate the accumulated knowledge to encompass all circumstance. Hence, it is essential to provide a tuning capability. There are many parameters in fuzzy controller can be adapted, scale factor tuning of normalized fuzzy controller is one of the adaptation parameter. Two adaptation methods are implemented in this work on an experimental thermal process, which simulate heating process in liquefied petroleum gases (LPG) recovery process in one of petrochemical industries: Gradient decent (GD) adaptation method; supervisory fuzzy controller. A comparison between the two methods is discussed.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1997.10a
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• pp.117-121
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• 1997

It is shown theoretically that uniform axial dopant concentration distribution can be made throughout the crystal by continuous Czochralski process. Numerical simulation are performed for the transient two-dimensional convection-diffusion model. A typical value of the growth and system parameters for Czochralski growth of p-type, 4 inches silicon crystal was used in the numerical calculations. Using this model with proper model parameter, the axial segregation in batchwise Czochralski growth can be described. It is studied by comparing with the experimental data. With this model parameter, the uniform axial concentration distribution of dopant is predicted in continuous Czochralski process.

• Journal of the Korean Statistical Society
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• v.28 no.1
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• pp.1-19
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• 1999

In this paper we establish some limit theorems for a two-parameter fractional Levy Brownian motion on rectangles in the Euclidean plane via estimating upper bounds of large deviation probabilities on suprema of the two-parameter fractional Levy Brownian motion.

• Journal of Welding and Joining
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• v.20 no.2
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• pp.102-108
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• 2002

Resistance spot welding of aluminum alloys is based upon Joule heating of the components by passing a large current in a short duration. Since aluminum alloys have the potential to replace steels fur automobile body assemblies, it is important to study the process robustness of aluminum spot welding process. In order to evaluate the effects of process parameters on the weld quality, major process variables and abnormal process conditions were selected and analyzed. A newly developed two-stage, sliding-level experiment was adopted fur effective parameter design and analysis. Suitable ranges of welding current and button diameters were obtained through the experiment. The effects of the factors and their levels on the variation of acceptable welding current were considered in terms of main effects. From the results, it is concluded that any abnormal process condition decreases the suitable current range in the weld lobe curve. Pareto analysis of variance was also introduced to estimate the significant factors on the signal-to-noise (S/N) ratio. Among the six factors studied, fit-up condition is found to be the most significant factor influencing the SM ratio. Using a Pareto diagram, the optimal condition is determined and the SM ratio is significantly improved using the optimal condition.