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Development of the Novel Dry and Wet Deposition Collector (새로운 건성 및 습성 침착 채취기의 개발)

  • 이병규;이채복
    • Journal of Korean Society for Atmospheric Environment
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    • v.16 no.6
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    • pp.675-684
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    • 2000
  • A novel dry and wet deposition collector, which can overcome the several problems such as water evaporation cartridge cracks and high costs founded in the previous collector systems, has been constructed. ENVI-18 SPE adsorption cartridge has been used to measure atmospheric deposition of polycylic aromatic hydrocarbons (PAHs). A surrogate surface, consisted of water and methanol, was filled in the dry deposition funnel to simulate dry deposition onto water surface. A water supply system in order to compensat evaporation of the surrogate surface was used and it was consisted of a piston pump, a tubing pump, a overflow tube and a chamber system. A novel water vaporizing system to supply water onto the wet SPE cartridge system with a constant flow rate was developed. The novel water vaporizing system, consisted of a vacuum pump, a water supply reserviour and tube and a mini space heater, could prevent the PAHs adsorption cartridge cracks occurred in the previous collector and effectively adsorb PAHs. The novel dry and wet deposition collector showed a good adsorption, desorption, and recovery rates of PAHs. By reducing the number of pumps used and employing polypyopylene (PP) instead of teflon as a material of collection funnel, the total construction costs were much reduced as compared with the previous dry and wet deposition collectors.

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Characteristics and Synergistic Effects of Coal/Waste Tire/Polypropylene Coliquefaction (석탄, 폐타이어, 폴리프로필렌의 공동액화 특성 및 상승효과)

  • Jeong, Tae-Jin;Jeong, Dae-Heui;Kim, Sung-Chul;Lim, Myung-Hoon;Na, Byung-Ki;Song, Hyung-Keun;Yoon, Do-Young;Kim, Dae-Heum;Han, Choon
    • Journal of Energy Engineering
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    • v.9 no.3
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    • pp.228-236
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    • 2000
  • 본 연구에서는 순간 고온식 tubing-bomb reactor를 사용하여 41$0^{\circ}C$에서 Alaska산 아역청탄, 폐타이어, 폴리프로필렌 혼합물의 공동액화 시 액화특성 및 상승효과를 연구하였다. 석탄, 폐타이어와, 폴리프로필렌의 조성을 변화시키고 수소공여용매인 tetralin의 양을 변화시켜가며 공동액화를 진행했을 경우 공동액화율을 살펴보면, 무촉매 반응의 경우 폴리프로필렌의 양이 많아지면 tetralin이 첨가되지 않았을 경우 액화율이 증가하였으나 tetralin이 첨가되었을 경우 공동액화율이 감소하였다. 촉매 반응의 경우에는 모든 반응조건에서 상승효과가 나타났으며 폴리프로필렌의 양이 증가할수록 공동액화율이 증가하여 석탄 : 폐타이어 : 폴리프로필렌의 조성이 1:1:3에서 tetralin 4$m\ell$, Co-naphthenate 촉매 사용하였을 때가 최적의 반응조건으로 83%의 공동액화율을 나타내었다.

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Improvement of Two-Stage Centrifugal Blood Pump for Cardiopulmonary Support System and Evaluation of Anti-Hemolysis Performance

  • Horiguchi, Hironori;Tsukiya, Tomonori;Takemika, Toratarou;Nomoto, Takeshi;Tsujimoto, Yoshinobu
    • International Journal of Fluid Machinery and Systems
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    • v.8 no.1
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    • pp.1-12
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    • 2015
  • In cardiopulmonary support systems with a membrane oxygenation such as a percutaneous cardiopulmonary support (PCPS) or an extracorporeal membrane oxygenation (ECMO), blood pumps need to generate the pressure rise of approximately 200mmHg or higher, due to the high hydraulic resistances of the membrane oxygenation and of the cannula tubing. In order to realize the blood pump with higher pressure rise, higher anti-hemolysis and thrombosis performances, the development of novel centrifugal blood pump composed of two-stage has been conducted by the authors. In the present paper, effective attempts to decrease the wall shear stress and to suppress the stagnation are introduced for the prevention of hemolysis and thrombosis in blood pumps. The hemolysis test was also carried out and it was clarified that the decrease of wall shear stress is effective as a guideline of design of blood pumps for improving the anti-hemolysis performance.

The Effect of Saponin Fraction of Panax ginseng C.A.Meyer on the Biosynthesis of Androgens in Rat Testis (인삼 사포닌이 쥐의 정소에서의 Androgen 생합성에 미치는 영향)

  • 홍성렬;주충노
    • Journal of Ginseng Research
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    • v.9 no.2
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    • pp.213-220
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    • 1985
  • It was attempted to observe the effects of ginseng saponin, one of the major components of the roots of Panax ginseng, on androgen biosynthesis from cholesterol in vitro as well as in vivo in rat testis. Ginseng saponin was administered by stomach tubing prior to intraperitoneal injection of cholesterol containing (4-14C)-cholesteroll into adult male rats and the liver, testis and blood serum were analyzed. The first high radioactivity of the liver and blood serum of test animal was observed at 6 hours after radioactive cholesterol injection, while that of control appeared at 12 hours after the injection. In the case of testis, the first high radioactivity of test group appeared between 4 and 6 hours after the radioactive cholesterol injection, while that of control appeared at 10-14 hours. Analysis of radioactivity distribution of cholesterol, androstenedione and testosterone in the testis of rats fed with/without ginseng saponin piror to (4-14C)-cholesterol injection showed that the saponin stmulated the synthesis of androgens from cholesterol. This was confirmed again by in vitro experiment using testis homogenate as an enzyme source. From the above experimental results, it was suggested that the ginseng saponin stimulates both cholesterol transport and the biosynthesis of androgens from cholesterol in rat testis.

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In-situ Calibration of the Hydroperoxyl Radical Using an Immobilized TiO2 Photocatalyst in the Atmosphere

  • Kwon, Bum-Gun
    • Bulletin of the Korean Chemical Society
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    • v.29 no.4
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    • pp.785-789
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    • 2008
  • The present study is the first report of utilizing $TiO_2$ photocatalyst to analytically calibrate the hydroperoxyl radical ($HO_2\;^{\cdot}$). An in-situ calibration method of $HO_2\;^{\cdot}$ is proposed for air monitoring by using an 2-methyl-6-(pmethoxyphenyl)- 3,7-dihydroimidazo-[1,2-a]pyrazin-3-one (MCLA)-chemiluminescence (CL) technique. In this method, $HO_2\;^{\cdot}$($pK_a$ = 4.80) is produced by the ultraviolet (UV) photolysis of immobilized $TiO_2$ using a constant flow rate of air equilibrated water, in which $HO_2\;^{\cdot}$ is controlled by using various lengths of knotted tubing reactor (KTR). The principle of the proposed calibration is based on the experimentally determined halflife ($t_{1/2}$) of $HO_2\;^{\cdot}$ and its empirically observed pH-dependent rate constant, $k_{obs}$, at a given pH. The concentration of $HO_2\;^{\cdot}$/$O_2\;^{\cdot}$− is increased as pH increases. This pH dependence is due to the different disproportionative reactivities between $HO_2\;^{\cdot}$/$O_2\;^{\cdot}$− and $HO_2\;^{\cdot}$/$O_2\;^{\cdot}$−. Experimental results indicate the practical feasibility of the approach, producing very promising method.

Elucidation of Corrosion and Failure of Stainless Steel Tubing buried in Soil for Potable Water (토양매설 스테인리스강 상수도 배관의 부식원인 규명)

  • Kim, Young Sik;Park, Soojin;Hwangbo, Deok;Shin, Mincheol
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.20-28
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    • 2012
  • Since buried pipes contact the soil directly, corrosion by the soil could be occurred. Recently, some stainless steel pipes after 8 years burial at G area were corroded and leaked. In order to elucidate highly corroded phenomena(its rate was about 0.175 mm/y) of these pipes, the investigation for corrosion environment, soil, stray current's effect, and chemical analysis on the pipes were performed. Most of investigated sites were close to traditional water-closet and showed high moisture and thus those areas could be highly corrosive. In the investigation by two kinds of soil evaluation methods, it was revealed that the soils at G areas were highly corrosive, and moreover the contents of sulfate reducing bacteria in the soils were high. Also, open circuit potentials of many pipes showed different values and its potentials were high positive. Therefore, it was considered that corrosion of buried pipes at G area could be affected by high corrosive soil's environment and stray current corrosion.

Dynamic characteristics and fatigue damage prediction of FRP strengthened marine riser

  • Islam, A.B.M. Saiful
    • Ocean Systems Engineering
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    • v.8 no.1
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    • pp.21-32
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    • 2018
  • Due to the escalation in hydrocarbon consumption, the offshore industry is now looking for advanced technology to be employed for deep sea exploration. Riser system is an integral part of floating structure used for such oil and gas extraction from deep water offering a system of drill twines and production tubing to spread the exploration well towards the ocean bed. Thus, the marine risers need to be precisely employed. The incorporation of the strengthening material, fiber reinforced polymer (FRP) for deep and ultra-deep water riser has drawn extensive curiosity in offshore engineering as it might offer potential weight savings and improved durability. The design for FRP strengthening involves the local design for critical loads along with the global analysis under all possible nonlinearities and imposed loadings such as platform motion, gravity, buoyancy, wave force, hydrostatic pressure, current etc. for computing and evaluating critical situations. Finite element package, ABAQUS/AQUA is the competent tool to analyze the static and dynamic responses under the offshore hydrodynamic loads. The necessities in design and operating conditions are studied. The study includes describing the methodology, procedure of analysis and the local design of composite riser. The responses and fatigue damage characteristics of the risers are explored for the effects of FRP strengthening. A detail assessment on the technical expansion of strengthening riser has been outlined comprising the inquiry on its behavior. The enquiry exemplifies the strengthening of riser as very potential idea and suitable in marine structures to explore oil and gas in deep sea.

EFFECTS OF IRRADIATION ON THERMAL CONDUCTIVITY OF ALLOY 690 AT LOW NEUTRON FLUENCE

  • Ryu, Woo Seog;Park, Dae Gyu;Song, Ung Sup;Park, Jin Seok;Ahn, Sang Bok
    • Nuclear Engineering and Technology
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    • v.45 no.2
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    • pp.219-222
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    • 2013
  • Alloy 690 has been selected as a steam generator tubing material for SMART owing to a near immunity to primary water stress corrosion cracking. The steam generators of SMART are faced with a neutron flux due to the integrated arrangement inside a reactor vessel, and thus it is important to know the irradiation effects of the thermal conductivity of Alloy 690. Alloy 690 was irradiated at HANARO to fluences of (0.7-28) ${\times}10^{19}n/cm^2$ (E>0.1MeV) at $250^{\circ}C$, and its thermal conductivity was measured using the laser-flash equipment in the IMEF. The thermal conductivity of Alloy 690 was dependent on temperature, and it was a good fit to the Smith-Palmer equation, which modified the Wiedemann-Franz law. The irradiation at $250^{\circ}C$ did not degrade the thermal conductivity of Alloy 690, and even showed a small increase (1%) at fluences of (0.7~28) ${\times}10^{19}n/cm^2$ (E>0.1MeV).

On-Line Measurement System for the Determination of Chemical Oxygen Demand (화학적 산소 요구량 측정을 위한 On-Line 측정 시스템에 관한 연구)

  • 정형근;차기철
    • Journal of Environmental Science International
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    • v.7 no.2
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    • pp.203-208
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    • 1998
  • A simple on-line measurement system consisting of a conventional peristaltic pump, a HPLC-type heater, and a flow-through spectrophotometer is introduced for the determination of chemical oxygen demand(CODI. The system was configured such that the reaction mixture in the highly concentrated surffuric acrid medium flowing through the PTFE reaction tubing was heated at 150℃ and the absorbance of dichromate was continuously moutored at 445 m. The same addation principle as in the standard procedure was employed akcept the use of CoSO4 as a new effective catalyst. To test the system, potassium hydrogen phthalate was selected as a COD standard material. With suitably optimized reaction condition, the applicable concentration range depends on the concentration of potassium dichromate in the oxidizing reagent. With 2.0×10-3 M and 5.0×10-4M dichromate, the linear dynamic range was observed up to 400 ppm and 100 ppm, respectively. The standards in the Unear ranges were shown to be completely oxidized, which was confirmed with sodium oxalate or Mohr's salt. In all cases, the typical reproduclbility for betweenruns was 2% or less. The proposed measurement system provides the valuable in- formation for the further development of automated analysis system based on the present standard procedure.

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A Study on the Characteristics of Inconel 625 for Casing and Tubing by FCAW Process (석유시추용 인코넬 625강의 FCAW용접 특성에 관한 연구)

  • Park, Keyung-Dong;Jin, Yonug-Beom;Park, Hyoung-Dong
    • Journal of the Korean Society of Safety
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    • v.20 no.3 s.71
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    • pp.9-13
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    • 2005
  • Inconel 625 is useful in variety of industrial applications because of the resistance to attack on various corrosive media at temperature from $200^{\circ}C$ to over $1090^{\circ}C$, in combination with good low and high temperature mechanical strength. Recently, this material is also used widely in offshore processing piping in order to extend the maintenance term and improvement the quality of anti-corrosion. In general, high quality weldments for this material are readily produced by commonly used processes. Not all processes are applicable to this material group, Ni-alloys. Metallurgical characteristics or the unavailability of matching, position or suitable welding process. Nowadays, the flux cored wire is developed and applied for the better productivity in several welding position including the vertical position. In this study, the weldability and weldment characteristics(mechanical properties) of inconel 625 are considered in FCAW(Flux Cored Arc Welding) associated with the severial shielding gases($80%Ar+20%CO_2,\;50%Ar+50%CO_2,\;100%CO_2$) in viewpoint of welding productivity.