• Title/Summary/Keyword: tropospheric ozone

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Inter-comparison of Total Ozone from the Ground-based and Satellite Measurements at Seoul (지상과 위성으로부터 측정된 서울시 대기 중 오존 전량의 상호 비교)

  • Hong, Hyunkee;Kim, Jhoon;Lee, Hanlim;Cho, Hi Ku
    • Atmosphere
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    • v.23 no.2
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    • pp.123-130
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    • 2013
  • Despite the extensive investigations to understand the difference between ground-based and space-borne measurements, there still exist differences in total ozone (TO) measured at those two different platforms. Comparisons were carried out for the first time between TO data obtaiend from the ground based Dobson and Brewer spectrophotometers, and the Ozone Monitoring Instrument (OMI) on board EOS-Aura satellite in a megacity site in Northeast Asia. The TO values retrieved by the OMI-DOAS (Differential optical absorption spectroscopy) algorithm tend to be lower than those measured by the ground based sensors in spring and summer as well as the low solar zenith angle condition. We found that such underestimation of the OMI-DOAS TO is caused by tropospheric ozone underestimated by the OMI-DOAS algorithm when tropospheric ozone are significantly enhanced.

Analysis of Tropospheric Carbon Monoxide and Ozone Production in East Asia

  • Lee S. H.;Choi G. H.;Lim H. S.;Lee J. H.;Seo D.C.;Jun J. N.;Jung J. H.;Kim I. S.;Kim J.
    • Proceedings of the KSRS Conference
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    • 2004.10a
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    • pp.182-183
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    • 2004
  • Atmospheric carbon monoxide (CO) and ozone $(O_3)$ play the important trace gases in tropospheric chemistry, through its concentration in the troposphere directly influences the concentrations of tropospheric hydroxyl (OH). Understanding the impact of CO and $O_3$ on the global tropospheric chemistry requires measurements of the global atmospheric CO and $O_3$ distributions. This study focuses on the identification of CO and O3 released in the East Asia between March 2000 and February 2004. During the period, the MOPITT instrument onboard the Earth Observing System (EOS)-Terra platform collected extensive measurement of CO. So we have used MOPITT data at 700hPa to analyze seasonal distribution of CO concentration. And the O3 measurements for this study were Total Ozone Mapping Spectrometer (TOMS) and Dobson spectrometer provided NASA/GSFC and Yonsei University, Korea. During springtime, the CO and O3 concentrations were increased over East Asia for April, May, and June. CO and O3 transport and chemistry in the springtime in East Asia are studied by use of the HYbrid Single Particle Lagrangian Integrated Trajectory (HYSPLIT) model.

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CRDS Study of Tropospheric Ozone Production Kinetics : Isoprene Oxidation by Hydroxyl Radical

  • Park, Ji-Ho
    • Journal of Environmental Health Sciences
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    • v.35 no.6
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    • pp.532-537
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    • 2009
  • The tropospheric ozone production mechanism for the gas phase additive oxidation reaction of hydroxyl radical (OH) with isoprene (2-methyl-1,3-butadiene) has been studied using cavity ring-down spectroscopy (CRDS) at total pressure of 50 Torr and 298 K. The applicability of CRDS was confirmed by monitoring the shorter (~4%) ringdown time in the presence of hydroxyl radical than the ring-down time without the photolysis of hydrogen peroxide. The reaction rate constant, $(9.8{\pm}0.1){\times}10^{-11}molecule^{-1}cm^3s^{-1}$, for the addition of OH to isoprene is in good agreement with previous studies. In the presence of $O_2$ and NO, hydroxyl radical cycling has been monitored and the simulation using the recommended elementary reaction rate constants as the basis to OH cycling curve gives reasonable fit to the data.

ANALYSIS OF TROPOSPHERIC $NO_2$ BASED ON SATELLITE MEASUREMENTS

  • Kwon Eun-Han;Lim Hyo-Suk
    • Proceedings of the KSRS Conference
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    • 2005.10a
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    • pp.374-377
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    • 2005
  • The distribution and changes of tropospheric nitrogen dioxide ($NO_2$) are analyzed using the satellite measurements data from GOME (Global Ozone Monitoring Experiment) and SCIMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY). We produced global maps of tropospheric $NO_2$ for 4 seasons using GOME measurements from January 1997 to June 2003. The global distribution shows high values in regions with dense population and high industrialization. Tropospheric $NO_2$ shows obvious seasonal changes depending on its emission and lifetime. Based on the good agreement between two instruments in the time period of overlapping measurements (January 2003-June2003), we linked SClAMACHY data to the GOME time series. The combined time series over the past decade indicate that $NO_2$ 1evels over China are rapidly increasing while those over Europe are decreasing. We also discussed potential application of spaceborne instruments in detecting and characterizing long-distance transport of $NO_2$.

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Study on the Characteristics of Surface Ozone Distributions and the Ozone Critical Levels to Vegetation in the South Korea (남한 지역의 지면 오존 농도 특성과 식생에 대한 임계값 적용 연구)

  • Koo, Hae-Jung;Park, Soon-Ung
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.3
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    • pp.310-320
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    • 2008
  • Concentration of tropospheric ozone ($O_3$) was investigated for the South Korea. And then the critical ozone levels, expressed as AOT40 (Accumulated exposure over a threshold of 40 ppb) to vegetation have been used in this region within the UNECE (United Nations Economic Commission for Europe) Convention on Long-Range Trans-boundary Air Pollution (CLRTAP). Hourly ozone concentration data from 1996 to 2001 at 26 air monitoring stations was used to estimate the exceedance of the critical levels. It was calculated for daylight hours for each station, and mapped using surface interpolation over the South Korea. The critical levels of ozone have shown the highly exceeded value in the Gyeonggi region, southern coastal region and central inland of the South Korea. It was some different from the typical ozone distribution which represented highly in the western inland and coastal regions. The area exceeding the critical level for crops was founded to be more than 40% of the whole South Korean territory. While that for trees was to be about 17% of the South Korea. The critical ozone critical level was based upon data from experiments on specific species, and thus may not be fully representative for all types of vegetation. Nevertheless, the critical level and its exceedance of the ozone concentration would be one of the useful tools for international agreements on abatement strategies to prevent ecosystem damage.