• Title/Summary/Keyword: triethanolamine

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Decolorization of Wastewater and Collecting of Sludge from Hanji Production (한지 생산공정에서 발생하는 폐수의 탈색 및 슬러지 회수)

  • Choi, Hee-Seon;Kim, Tai-Jin
    • Analytical Science and Technology
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    • v.13 no.3
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    • pp.351-356
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    • 2000
  • The decolorization of wastewater and the collecting conditions of final sludge from hanji production were investigated. Black wastewater (50 mL) from the process cooking with NaOH could be effectively decolorized by 2.0 g of $Ca(OCl)_2$ So, if excess bleach $Ca(OCl)_2$ used in bleaching process were recycled, the decolorization of wastewater by adding less $Ca(OCl)_2$ would be successfully realized. However, the decolorization by electrolyzed oxidation was ineffective. The final sludge could be effectively collected by polymer coagulator, but the addition of $Al_2(SO_4)_3$ was required, and the pure fibrous sludge could not be collected. Therefore, surfactants such as triethanolamine and Triton X-100 were used instead of polymer coagulator. The collecting yield was obtained about 85% as good as those by polymer coagulator. When mixed surfactants were used in collecting the final sludge, $Al_2(SO_4)_3$ was not required. In addition, as the pure fibrous sludge could be collected, the effective recycling of sludges would be done.

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Analysis on Chemical Ingredients with Anti-microbial Activity in Water-based Metalworking Fluids

  • Park, Dong-Uk;Kim, Bok-Hwan;Lee, Kwon-Sup
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.06a
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    • pp.217-222
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    • 2004
  • This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) ‘A’ can cause anti-microbial activity and health effect. Three water-based MWF products (‘A’, ‘B’, and ‘C’) were studied every week for two months. Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF ‘A’ was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF ‘A’ were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF ‘A’ are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically. To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

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Analysis on Chemical Ingredients with Anti-microbial Activity in Water-based Metalworking Fluids

  • Park, Donguk;Lee, Jonghang;Lee, Kwonsup
    • KSTLE International Journal
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    • v.4 no.2
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    • pp.52-55
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    • 2003
  • This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) "A" can cause anti-microbial activity and health effect. Three water-based MWF products ("A", "B", and "C") were studied every week for two months (from June 1, 2002 to July 30, 2002). Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF "A" was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF "A" were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF "A" are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically. To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

The Study on Synthesis and Application of Polymer Dispersion for Cement Modifier (II) - The Waterproofing Effect of Cement Mortar using Acrylic Copolymer - (시멘트 혼화용 폴리머 합성과 그 응용에 관한 연구(II) - 아크릴공중합체를 이용한 시멘트 모르터의 방수성 -)

  • Kim, Hong-Dai;Kim, Young-Geun;Kim, Seung-Jin;Park, Hong-Soo
    • Applied Chemistry for Engineering
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    • v.7 no.4
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    • pp.679-690
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    • 1996
  • Acrylic copolymer was synthesized from 2-dimethylaminoethyl methacrylate and alkylmethacrylate containing long chain hydrocarbon group. To facilitate emulsification in water, acrylic copolymer was treated with acetic acid, and therefore acetated acrylic copolymer was produced. Acetated acrylic copolymer was perfectly emulsified in water and showed increased emulsion stability. Polymer as a cement dispersion agent(PDCM-PSD) was prepared by blending the newly synthesized acetates acrylic copolymer with sodium gluconate, oleic acid, and triethanolamine. The applicability of the blended polymer was examined, and it was found that the effects of dispersion and water-proof(0.3~0.5) were excellent.

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Chemical Absorption of Carbon Dioxide into Non-Newtonian Polyacrylamide Solution (Polyacrylamide 비뉴튼액체에서의 이산화탄소의 화학흡수)

  • Hwang, Byung-Jin;Park, Sang-Wook
    • Clean Technology
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    • v.14 no.4
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    • pp.281-286
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    • 2008
  • Absorption rate of carbon dioxide was measured in the aqueous polyacrylamide (PAA) solution containing triethanolamine (TEA) of $0{\sim}2.0\;kg\;mol/m^3$ in a flat-stirred vessel with an impeller of 0.05 m and agitation speed of 50 rpm at $25^{\circ}C$ and 101.3 kPa. The chemical absorption rate of $CO_2$ was estimated by mass transfer mechanism based on the film theory using the physicochemical properties containing the liquid-side mass transfer coefficient of $CO_2$ and the kinetics of reaction between $CO_2$ and TEA to compare with the measured rate. The aqueous PAA solution acted as a reducing agent by viscoelastic property of non-Newtonian liquid based on the same viscosity of the solution.

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Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine (Hexachlorocyclophosphazene과 Triethanolamine을 이용한 면섬유의 포름알데히드-프리 내구성 방염가공)

  • Kim, Jeong-Hwan;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.150-157
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    • 2020
  • Hexachloro-cyclophosphazene(HCCP), a formaldehyde-free flame retardant (FR), was steam-cured with triethanol amine(TEA) to impart durable flame-retardancy to cotton fabrics. While the HCCP treatment alone showed very limited resistance to repeated laundering cycles, the addition of TEA substantially improved the laundering durability of the FR cotton up to twenty laundering cycles. The extended washing resistance was accomplished by the increased nucleophilic substitution of unreacted P-Cl groups in HCCP by the TEA resulting in the more densely crosslinked FR networks. With increasing molar ratio of TEA to the HCCP up to 2, the flame retarding effectivity and the synergistic effectiveness improved to 2.8 and 1.8 respectively. TGA and microscale combustion calorimetry verified the pyrolysis and combustion behaviors of the FR-cotton, which showed lower maximum pyrolysis and combustion temperatures together with substantially decreased peak pyrolysis and heat release rate, synergistically yielding larger amounts of carbonaceous chars. The formaldehyde-free HCCP and TEA can be a durable FR finishing agents for cotton fabrics acting through a solid-phase flame-retarding mechanism.

Utilization of Kota stone slurry powder and accelerators in concrete

  • Devi, Kiran;Saini, Babita;Aggarwal, Paratibha
    • Computers and Concrete
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    • v.23 no.3
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    • pp.189-201
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    • 2019
  • Recent advances in the concrete technology are aiding in minimizing the use of conventional materials by substituting by-products of various industries and energy sources. A large amount of stone waste i.e., dust and slurry form both are being originated during natural stone processing and causing deadily effects on the environment. The disposal problem of stone waste can be resolved effectively by using waste in construction industries. In present work, Kota stone slurry powder, as a substitution of cement was used along with accelerators namely calcium nitrate and triethanolamine as additives, to study their impact on various properties of the concrete mixtures. Kota stone slurry powder (7.5%), calcium nitrate (1%) and triethanolamine (0.05%) were used separately as well in combination in different concrete mixtures. Mechanical Strength, modulus of elasticity and electrical resistivity of concrete specimens of different mix proportions under water curing were studied experimentally. The durability properties in terms of strength and electrical resistivity against sulphate and chloride solution attack at various curing ages were also studied experimentally. Results showed that accelerators and Kota stone slurry powder separately enhanced the mechanical strength and electrical resistivity; but, their combination decreased strength at all curing ages. The durability of concrete specimens was also affected under the exposure to chemical attack too. Kota stone slurry powder found to be the most effective material among all materials. Material characterization was also done to study the microstructural properties.

A Study on the Inhibiting Corrosion of Triethanolamine for the SCM440 Steel (CM440 강에 대한 트리에탄올아민의 부식억제에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.56-61
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    • 2015
  • In this study, the current-voltage curves for the SCM440 steel by the addition of an organic corrosion inhibitor triethanolamine(TEA) was measured using the conventional three electrodes of cyclic voltammetry. As a result, the C-V characteristics of SCM440 steel were to be for an irreversible process due to the oxidation current from the cyclic voltammetry. Diffusion coefficient according to the twice increasing the concentration of TEA in the corrosion inhibitor from $2.5{\times}10^{-4}M$ to $5.0{\times}10^{-4}M$, the diffusion coefficient was found to be a good corrosion-inhibiting effect is reduced by 1.5 times, so for each $2.561{\times}10^{-6}cm^2s^{-1}$ to $1.707{\times}10^{-6}cm^2s^{-1}$. When according to the electrolyte concentration and the effect is to increase the electrolyte concentration to 1.0 N at 0.5 N, the diffusion coefficient is $2.56{\times}10^{-6}cm^2s^{-1}$ to $5.12{\times}10^{-6}cm^2s^{-1}$, each 2 times decrease in the use of the electrolyte of 1.0 N, because this was more appropriate.

Determination of Sulfur Dioxide in Pickles by Acid Distillation-HPLC Method and Monnier Williams Modified Method (산증류-HPLC법과 모니어윌리암스변법을 이용한 절임류중의 이산화황 함량 분석)

  • Jung, So-Young;Kim, Il-Young;Kim, Sung-Dan;Jang, Mi-Ra;Chang, Min-Su;Han, Ki-Young
    • Korean Journal of Food Science and Technology
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    • v.35 no.6
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    • pp.1028-1032
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    • 2003
  • To assess accurate methods for measuring sulfur dioxide residue in pickles, the acid distillation HPLC-UV method and Monnier Willams modified method were examined. By the acid distillation HPLC-UV method, sulfites released from pickles by acid distillation were absorbed in 1% triethanolamine solution and detected as sulfite ion by HPLC with UV monitoring at 240nm. An anion exchange column was employed with 1.8mM $Ma_2CO_3-1.7mM\;NaHCO_3$ solution as a mobile phase, $84.0{\sim}91.7%$ of sulfite added to pickled radish were recovered. Total sulfite levels from 48 kinds of pickles analyzed by acid distillation HPLC-UV was compared with those analyzed by the Monnier Williams modified method. The Monnier Williams modified method showed higher levels of sulfur dioxide than the acid distillation HPLC-UV method due to the presence of volatile acids in pickles. The concentration of sulfur dioxide was in the range of $N.D{\sim}173.05ppm$ in pickled radish and over 30ppm of sulfur dioxide from 3 samples by the acid distillation-HPLC-UV method.

Fabrication of Tin(IV) Oxide Film by Sol-gel Method (졸겔법을 이용한 산화주석 박막의 제조에 관한 연구)

  • Lee Seung-Chul;Lee Jae-Ho;Kim Young-Hwan
    • Journal of the Korean Electrochemical Society
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    • v.3 no.1
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    • pp.15-18
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    • 2000
  • Transparent conducting tin (IV) oxide thin films have been studied and developed for the electrode materials of solar cell substrate. Fabrication of tin oxide thin films by sol-gel method is process development of lower cost photovoltaic solar cell system. The research is focused on the establishment of process conditions and development of precursor. The precursor solution was made of tin isopropoxide dissolved in isopropyl alcohol. The hydrolysis rate was controlled by addition of triethanolamine. Dip and spin coating technique were applied to coat tin oxide on borosilicate glass. The resistivity of the thin film was lower than 0.01-cm and the transmittance is higher than $90\%$ in a visible range.