• Title/Summary/Keyword: trichloroethylene

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Synthesis of Substituted Phenyltrichlorocyclopropene Derivatives Using Friedel-Crafts Reaction

  • Choi, Sam-Kwon;Suk ,Won-Kyung
    • Bulletin of the Korean Chemical Society
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    • v.2 no.3
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    • pp.83-85
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    • 1981
  • Tetrachlorocyclopropene has been prepared smoothly by the dehydrochlorination of pentachlorocyclopropane which could be obtained easily from sodium trichloroacetate and trichloroethylene in 1,2-dimethoxyethane. By the reaction of aromatic hydrocarbons with tetrachlorocyclopropene and aluminium chloride, new substituted phenyltrichlorocyclopropene derivatives have been prepared. The structures of these compounds were characterized by means of spectroscopic methods.

The Preparation of Polysiloxaneimide Membranes and their Pervaporation Properties (폴리실록산이미드 막의 제조와 투과증발특성)

  • Chang, Yeon-Hee;Kim, Jeong-Hoon;Lee, Soo-Bok;Rhee, Hee-Woo
    • Applied Chemistry for Engineering
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    • v.10 no.7
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    • pp.1041-1045
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    • 1999
  • Three polysiloxaneimide(PSI) as membrane material were prepared by polycondensation of three aromatic dianhydrides(6FDA, BTDA, PMDA) with one siloxane-containing diamine(SIDA, aver. MW. 800). The PSIs were rubbery polymers containing 30~40 wt % of flexible siloxane chains and exhibited low density, high fractional free volume and low surface energy. They were used for pervaporation experiments with 0.05 wt % of four organic aqueous solutions containing ethyl acetate, methylene chloride, trichloroethylene, and toluene, respectively. With increasing hydrophobicity of organic solvents, both pervaporation selectivity and pemeation flux increase.

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Development of Parallel Trickling Biofilter for the Treatment of Gas-phase Trichloroethylene

  • Lee, Eun-Yeol;Seol, Eun-Hee;Bae, Hyun-Chul;Kim, Hyun-suk;Ye, Byung-Dae;Park, Sung-Hoon
    • 한국생물공학회:학술대회논문집
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    • 2001.11a
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    • pp.537-540
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    • 2001
  • A parallel TBF system that is consisted of two TBFs was developed f ‘ or the long-term treatment of gas-phase trichloroethylene (TCE). Each TBF was operated for TCE degradation or reactivation in a parallel mode, and the effect of switching time and operation variables between the two reactors was investigated. Within 12 hr after switching from TCE degradation to reactivation mode, the MO activity increased up to the initial level. More than 50 % of TCE was degraded for feed concentrations ranging from 5 to 17 ppmv, and completely 100 % removed at concentration of less than 5 ppmv, while TCE removal decreased severely over 28 ppmv. In various empty bed retention times (EBRTs), ranging 상 om 5.2 to 10.7 min, the optimal EBRT was 10.7 min that TCE conversion achieved more than 50 %. For the inlet loading below 23.4 mg TCE/L/day, TCE was entirely removed. The maximal TCE elimination capacity in this system was about 66.63 mg TCE/L/day. During the continuous treatment of TCE over 3 months, TCE removal efficiency was maintained at the range of about 50 %. In these results, the parallel TBF system can be available for the continuously TCE biodegrading operation.

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Development of Two-stage CSTG/TBF System for the Cometabolic Degradation of Gas-phase TCE by Burkholderia cepacia G4 (Burkholdera cepacia G4를 이용한 기상의 트리클로로에틸렌의 공대사적분해를 위한 2단계 CSTR/TBF 시스템 개발)

  • 이은열;박성훈
    • KSBB Journal
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    • v.16 no.5
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    • pp.511-515
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    • 2001
  • In this paper, we development and operated a two-stage continuous stirred tank reactor (CSTR)/trickling biofilter(TBF)system for the long-term continuous treatment of trichloroethylene (TCE) using Burkholderia cepacia G4. In this reactor system. CDTR with cell recycle from TBF was coupled to the TBF for the reactivation of the cells deactivated during TCE degradation. The critical elimination capacity was determined to be 25.3 mg TCE/L day and the reactor has been stably operated for more than 1 months, which clearly represented that CSTR/TBF system can be used for long-term treatment of TCE.

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Swelling Properties of Poly(ethylene terephthalate) Fiber in Mixed Solvent(II) ―Equilibrium Swelling and Shrinkage― (혼합용매중에서의 Poly(ethylene terephthalate)섬유의 팽윤성(II) ―평형팽윤 및 수축거동―)

  • Lee, Mun Cheul;Pak, Pyong Ki;Cho, Hyun Hok
    • Textile Coloration and Finishing
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    • v.6 no.4
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    • pp.17-26
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    • 1994
  • Poly(ethylene terephthalate)(PET) filaments were treated in binary mixtures of organic solvents such as benzyl alcohol/perchloroethylene(BA/PER), benzyl alcohol/trichloroethylene(BA/TRI), benzyl alcohol/ethylene chloride(BA/EC), methanol/perchloroethylene (ME/PER), and methanol/trichloroethylene(ME/TRI). From the equilibrium swelling of PET, total and partial isotherms of PET for sorption of solvent mixtures and isotherms for distribution of the components between the phases were taken. Also the shrinkage and the crystallinity of PET treated with binary mixtures were investigated. The results obtained were summerized as follows: 1. All isotherms for distribution of the components between the phase deviated from the diagonal in system of PET-binary mixtures. Especially in the binary mixtures of ME/PER or ME/TRI, selectivo sorption of chlorinated hydrocarbon PER and TRI by PET occured. 2. The shrinkage of PET treated in binary mixrures was increased to compare with single solvent-treated, but the composition of binary mixtures corresponding to maximum values of shrinkage was not always agreed with the composition of binary mixtures corresponding to maximum values of shrinkage was not always agreed with the composition of binary mixtures exhibiting of the maximum swelling of PET. 3. The crystallinity of PET treated in binary mixtures generally increased than that of single solvent-treated.

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