• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.884-889
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• 2018

In this study, polyaniline $(PANI)/WO_3$ electrode was prepared as an anode of a lithium ion capacitor, and its electrochemical characteristics were measured and analyzed. When PANI was electrochemically deposited on the surface of $WO_3$ electrode, the capacity of $PANI/WO_3$ was improved with increase of the deposited amounts of PANI. Furthermore, the effect of light irradiation on capacity and coulombic efficiency was examined by irradiating sunlight during charging and discharging. When the light was irradiated to the $WO_3$ electrode and the $PANI/WO_3$ electrode, those capacities and coulombic efficiencies were increased compared to that measured under the dark condition. It is attributed to the photocatalytic property of $WO_3$ that can generate photoelectrons by light irradiation. In $PANI/WO_3$ electrode, PANI also can be excited under the light irradiation with affecting the electrochemical property of electrode. The photoelectrons improve the capacity by participating in the intercalation of $Li^+$ ions, and also improve the coulombic efficiency by facilitating electrons' transport. Under the dark condition, the capacity of $PANI/WO_3$ was gradually reduced with increase of cycles due to a poor stability of PANI. However, the stability of PANI was significantly improved by the light irradiation, which is attributed to the oxidation-reduction reaction originated from the photogenerated electrons and holes in $PANI/WO_3$.

• The Korean Journal of Air & Space Law and Policy
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• v.35 no.2
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• pp.225-246
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• 2020

More than technical or academic matter, mitigation of height restriction around airports is about up-dating out-dated policies that have not kept up with rapidly developing aircraft and air traffic control technologies. Above all, instead of calling out 'flight safety' that the public do not comprehend, it is important to examine and carry out measures that can protect people's right of property. MOLIT(Ministry of Land, Infrastructure, and Transport) after reviewing ICAO's Obstacle Limitation Surface TF, made an announcement to provide further plans that would apply to contracting states from 2026. However, residents of redevelopment areas near Kimpo international airport asserted that MOLIT's policy overlooks the reality of the redevelopment zone. ICAO, UN's specialized agency for civilian aviation, recommends in Annex 14, 4.2.4 that contracting states conduct an aeronautical study to determine the flight safety of horizontal surface(45m), excluding approach surface, and to mitigate height restrictions if no threat is found. Numerous countries including the United States have been following this recommendation and have been able to effectively protect people's right of property, whereas the South Korean government have not following it so far. The number of height restriction mitigation cases in the recent three months (2019. 7. 15~10. 14.) FAA of the United States have allowed after conducting an aeronautical study reaches 14,706. Japan and Taiwan also reconstruct airspace around airports in metropolitan areas in order to protect people's right of property. Just as the United States is following, MLIT should follow ICAO's recommendation in Annex 14. 4.2.4(Vol. 1. Airport Construction / Operation) and protect people's right of property by first applying aeronautical studies to the horizontal surface(45m) of flight safety zones until the specifics of ICAO's 2026 TF materialize.

• Nuclear Engineering and Technology
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• v.41 no.5
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• pp.723-728
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• 2009

The response property of the CZT detector ($5{\times}5{\times}5\;mm^3$), widely used in photon spectroscopy, was evaluated by considering the charge collection efficiency, which depends on the interaction position of incident radiation, A quantitative analysis of the energy spectra obtained from the CZT detector was also performed to investigate the tail effect at the low energy side of the full energy peak. The collection efficiency of electrons and holes to the two electrodes (i.e., cathode and anode) was calculated from the Hecht equation, and radiation transport analysis was performed by two Monte Carlo codes, Geant4 and MCNPX. The radiation source was assumed to be 59.5 keV gamma rays emitted from a $^{241}Am$ source into the cathode surface of this detector, and the detector was assumed to be biased to 500 V between the two electrodes. Through the comparison of the results between the Geant4 calculation considering the charge collection efficiency and the ideal case from MCNPX, an pronounced difference of 4 keV was found in the full energy peak position. The tail effect at the low energy side of the full energy peak was confirmed to be caused by the collection efficiency of electrons and holes. In more detail, it was shown that the tail height caused by the charge collection efficiency went up to 1000 times the pulse height in the same energy bin at the calculation without considering the charge collection efficiency. It is, therefore, apparent that research considering the charge collection efficiency is necessary in order to properly analyze the characteristics of CZT detectors.

• Applied Chemistry for Engineering
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• v.21 no.6
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• pp.621-626
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• 2010

Anion exchange membranes can be used for reverse electrodialysis for electric energy generation, and capacitive deionization for water purification, as well as electrodialysis for desalination. In this study, anion exchange membranes of poly((vinylbenzyl) trimethylammonium chloride-2-hydroxyethyl methacrylate)/poly(vinyl alcohol) were prepared through the polymerization of (vinylbenzyl)trimethylammonium chloride and 2-hydroxyethyl methacrylate in aqueous poly(vinyl alcohol) solutions, esterification with glutaric acid, and cross-linking reaction with glutaraldehyde. We investigated electrochemical properties for the anion exchange membranes prepared according to experimental conditions. Ion exchange capacity and electrical resistance for the membranes were changed with a variation in the monomer ratio in polymerization. Water uptake and conductivity for the membranes decreased with an increase in the content of glutaric acid in esterification. The change in the time of crosslinking reaction with the formed film and glutaraldehyde affected electrochemical properties such as water uptake, conductivity, or transport number for the membranes. Chronopotentiometry and limiting current density for the anion exchange membranes prepared were measured.

• Journal of Korean Society of Transportation
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• v.33 no.3
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• pp.268-275
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• 2015

As Korea is predicted to be a super-aged society in the near future, transport policies that internalize the elderly have also drawn attentions. Even though some studies have examined the travel by the elderly with various motives, it is, however, difficult to find references that deal with the unique spatio-temporal characteristics of senior trips. For example, the models by time period have represented the temporal property while a set of independent variables associated with urban infrastructure have addressed the spatial feature. This study was conducted under a trip attraction model for transit. The result shows that transit facilities, commercial areas, and hospitals are the dominant factors to explain the travel by the elderly, particularly during 09:00-17:00.

• Transactions on Electrical and Electronic Materials
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• v.16 no.6
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• pp.342-345
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• 2015

The n -type Hf_0.25Zr_0.25Ti_0.5NiSn_0.998Sb_0.002 Half-Heusler (HH) alloy composition was prepared by using the induction melting method in addition to the mechanical grinding, annealing, and spark plasma sintering processes. Analysis of X-ray diffraction (XRD) results indicated the formation of a pure phase HH structured compound. The electrical and thermal properties at temperatures ranging from room temperature to 718 K were investigated. The electrical conductivity increased with increasing temperatures and demonstrated nondegenerate semiconducting behavior, and a large reduction in the thermal conductivity to the value of 2.5 W/mK at room temperature was observed. With the power factor and thermal conductivity, the dimensionless figure of merit was increased with temperature and measured at 0.94 at 718 K for the compound synthesized by the induction melting process.

• Proceedings of the Korean Vacuum Society Conference
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• 2015.08a
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• pp.148-148
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• 2015

Over the past several years, Colloidal core/shell type quantum dots lighting-emitting diodes (QDLEDs) have been developed for the future of optoelectronic applications. An inverted-type quantum-dot light-emitting-diode (QDLED), employing low work function organic material polyethylenimine ethoxylated(PEIE) (<10 nm)[1] modified ZnO nanoparticles (NPs) as electron injection and transport layer, was fabricated by all solution processing method, instead of electrode in the device. The PEIE surface modifier incorporated on the top of the ZnO NPs film, facilitates the enhancement of both electorn injection into the CdSe-ZnS QD emissive layer by lowering the workfunction of ZnO from 3.58eV to 2.87eV and charge balance on the QD emitter. In this inverted QDLEDs, blend of poly (9,9-di-n-octyl-fluorene-alt-benzothiadiazolo) and poly(N,N'-bis(4-butylphenyl)-N,N'-bis(phenyl)benzidine] are used as hole transporting layer (HTL) to improve hole transporting property. At the operating voltage of 7.5 V, the QDLED device emitted spectrally orange color lights with high luminance up to 11110 cd/m2, and showed current efficiency of 2.27 cd/A.[2]

• 한국정보디스플레이학회:학술대회논문집
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• 2004.08a
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• pp.1121-1124
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• 2004

Carbon Nitride exhibits high electrical resistivity and thermal conductivity that are similar to the properties shown by diamond-like carbon (DLC) films. These diamond-like transport properties in Carbon Nitride come in a material consisting of $sp^2$-bonded carbon versus the $sp^3$-carbon of DLC. The diamond-like properties and nondiamond-like bonding make NDLC an attractive candidate for applications. Liquid crystal (LC) alignment capabilities with ion beam exposure on carbon nitride thin films and Electro-Optical (EO) performances of the ion-beam aligned twisted nematic liquid crystal display (TN-LCD) with oblique ion beam exposure on the Carbon Nitride thin film surface were studied. An excellent uniform alignment of the nematic liquid crystal (NLC) alignment with the ion beam exposure on the Carbon Nitride thin films was observed. In addition, the good EO properties of the ion-beam-aligned TN-LCD were achieved. Finally, we achieved the residual DC property of the ion-beam- aligned TN-LCD on the Carbon Nitride thin film.

• Journal of the Korean Institute of Gas
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• v.15 no.3
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• pp.67-73
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• 2011

One of the important topics to prepare the up-coming era of so-called ‘hydrogen economy’ is hydrogen transmission. Pipeline is conceivably the most economic way to consistently and safely transport a large amount of hydrogen over a long distance, which may be strongly requested in hydrogen economy era. As a good starting point for the purpose, one might wonder whether conventional API pipeline steels as designed for natural gas transmission can be used as the hydrogen pipeline materials or not. To answer the question, here we performed a series of micro-/nano-indentations together with tensile tests on the hydrogen-charged API X65, X70 and X100 steels having different strength level. In this paper, from the results of tensile tests, the hydrogen effects on the mechanical behavior in the API steels are systematically evaluated.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.2
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• pp.449-454
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• 2010

In this paper, flow characteristics of R600a in an adiabatic capillary tube were investigated employing the homogeneous flow model. The model is based on fundamental equations of mass, energy and momentum which are solved simultaneously. Two friction factors(Churchill) and viscosity(McAdams) are comparatively used to investigate the flow characteristics. Thermodynamic and transport properties of R600a are calculated employing EES property code. Flow characteristics analysis of R600a in an adiabatic capillary tube is presented to offer the basic design data for the operating parameters. The operating parameters considered in this study include condensation temperature, evaporation temperature, subcooling degree and inner diameter tube of the adiabatic capillary tube. The main results were summarized as follows: condensation and evaporation temperature, inlet subcooling degree and inner diameter tube of an adiabatic capillary tube using R600a have an effect on length of an adiabatic capillary tube. The length of an adiabatic capillary tube using R600a is expressed to the correlation shown in Eq. (15).