• Title/Summary/Keyword: transport property

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Flow Characteristics in an Adiabatic Capillary Tube of Carbon Dioxide ($CO_2$ 단열 모세관내 유동 특성)

  • Roh, Geon-Sang;Son, Chang-Hyo
    • Journal of Hydrogen and New Energy
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    • v.19 no.6
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    • pp.537-544
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    • 2008
  • In this paper, flow characteristics of an adiabatic capillary tube in a transcritical $CO_2$ have been investigated employing the homogeneous model. The model is based on fundamental equations of mass, energy and momentum which are solved simultaneously. Two friction factors(Churchill) and viscosity(McAdams) are comparatively used to investigate the flow characteristics. Supercritical and subcritical thermodynamic and transport properties of $CO_2$ are calculated employing EES property code. Flow characteristics analysis of $CO_2$ adiabatic capillary tube is presented to offer the basic design data for the operating parameters. The operating parameters considered in this study include inlet temperature and pressure of an adiabatic capillary tube, evaporating temperature and inner diameter tube. The main results were summarized as follows : inlet temperature and pressure of an adiabatic capillary tube, evaporating temperature, mass flowrate and inner diameter of $CO_2$ adiabatic capillary tube have an effect on length of an adiabatic capillary tube.

Improvement on Enzyme Immobilization in Polypyrrole-Glucose Oxidase Enzyme Electrode using Organic Solvent Additive II. Electrochemical Analyses and Glucose Sensing (유기용매 첨가에 따른 Polypyrrole-Glucose Oxidase 효소전극의 효소고정화 향상 II. 전기화학적 분석 및 포도당 감지)

  • 김현철;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.7
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    • pp.621-626
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    • 2002
  • In the case of immobilizing of glucose oxidase (GOx) in polypyrrole (PPy) conducting polymer using electrosynthesis, the GOx obstructs charge transfer and mass transport during the film growth. This may lead to short chained polymer and/or make charge-coupling weak between the GOx and the backbone of the PPy. That is mainly due to insulating property and net chain of the GOx. Since being the case, it is useless to increase in amount of GOx mere than reasonable in the synthetic solution. We improved the amount of immobilized GOx into the PPy by adding a little ethanol in the synthetic solution without any more amount of GOx in the solution. We electrochemically analyzed an improvement in the immobilizing event. For the glucose sensing, when ethanol was added by 0.1 mol $dm^{-3}$ in the synthetic solution, the Michaelis constant of the resulting enzyme electrode was about 32 mmol $dm^{-3}$ and maximum current was about $146\mu A$.

Electro-mechanical properties in Bi-2223 superconducting composite tape due to axial fatigue loading (축방향 피로하중에 의한 Bi-2223 복합 초전도선재의 전기-기계적 특성)

  • Shin, Hyung-Seop;Dizon, John Ryan C.;Kim, Ki-Hyun;Oh, Sang-Soo;Ha, Dong-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.11a
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    • pp.345-348
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    • 2004
  • For practical applications, the evaluation of reliability or endurance of HTS conductors is necessary. The mechanical properties and the critical current, $I_c$, of multifilamentary Bi-2223 superconducting tapes, externally reinforced with stainless steel foils, subjected to high cycle fatigue loading in the longitudinal direction were investigated at 77K. The S-N curves were obtained and its transport property was evaluated with the increase of repeated cycles at different stress amplitudes. The effect of the stress ratio, R, on the $I_c$ degradation behavior under fatigue loading was also examined considering the practical application situation of HTS tapes. Microstructure observation was conducted in order to understand the L degradation mechanism in fatigued Bi-2223 tapes.

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Thickness and Angle Dependent Microcavity Properties in Top-Emission Organic Light-Emitting Diodes (상부 발광 유기 발광 소자에서 두께와 시야각에 따른 마이크로 캐비티 특성)

  • Lee, Won-Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.1
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    • pp.32-35
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    • 2011
  • Top-emission device has a merit of high aperture ratio and narrow emission spectrum compared to that of bottom-emission one. Emission spectra of top-emission organic light-emitting diodes depending on a layer thickness and view angle were analyzed using a theory of microcavity. Device structure was manufactured to be Al (100 nm)/TPD/$Alq_3$/LiF (0.5 nm)/Al (2 nm)/Ag (30 nm). N,N'-diphenyl-N,N'- di (m-tolyl)-benzidine (TPD) and tris (8-hydroxyquinoline) aluminium (Alq3) were used as a hole-transport layer and emission layer, respectively. And a thickness of TPD and Alq3 layer was varied in a range of 40 nm~70 nm and 60 nm~110 nm, respectively. Angle-dependent emission spectrum out of the device was measured with a device fixed on a rotating plate. Since the top-emission device has a property of microcavity, it was observed that the emission spectrum shift to a longer wavelength region as the organic layer thickness increases, and to a shorter wavelength region as the view angle increases. Layer thickness and view-angle dependent emission spectra of the device were analyzed in terms of microcavity theory. A reflectivity of semitransparent cathode and optical path length were deduced.

A Study on the Effects of Water Absorption on the Thermal Conductivity of Insulation Materials (수분 흡수가 단열재의 열전도계수에 미치는 영향에 관한 연구)

  • Yoo, Seong-Yeon;Kim, Tae-Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.3
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    • pp.119-125
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    • 2013
  • IInsulation material is generally used for preventing heat loss from heat transport fluids, and water absorption severely reduces the insulation property. The purpose of this study is to evaluate the amount of water absorption supplied by the pouring method and spraying method, to investigate the effects of water absorption on the thermal conductivity of an insulation material, and modeling the relation between water absorption and thermal conductivity. E-glass, a kind of glass fiber, and HYPERLITE, mainly composed of pearlite, are selected, to compare hygroscopic and insulation properties. E-glass is found to have much higher water absorptivity, compared to HYPERLITE. The thermal conductivity of the water-absorbed E-glass is increased by more than 150%, compared to that of no absorption, while variation of the thermal conductivity of HYPERLITE with water absorption is insignificant. A three-stage model of water absorption for thermal conductivity is developed, and the modeling results are found to be in good agreement with the experimental data.

Characteristic of Refrigerant for Heat-treatment Deformation Control of SM45C Steel (SM45G강의 열처리변형 제어를 위한 냉각매질의 특성)

  • Lyu, S.;Nam, T.;Ahn, M.;Park, J.
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.5
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    • pp.330-336
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    • 2000
  • This study deals with the characteristic of refrigerant for heat-treatment deformation control of SM45C steel. The control of heat-treatment deformation must need the progress of production parts for a landing gear. Most of the deformation is occurred on unequal cooling. The unequal cooling is occurred by a property of quenching refrigeration. When a heated metal is deposited in the refrigeration, the cooling speed is so slow in early period of cooling because of occurring a steam-curtain. After more cooling, the steam-curtain is destroyed. In this progress, the cooling speed is very fast. The object of this study is to control the deformation of heat-treatment for landing gear by improving the conditions of quenching. The cooling curves and cooling rates of water, oil and polymer solution are obtained and illustrated. From the characteristics of the quenching refrigerant, the effects of heat-treatments on thermal deformation and fatigue strength are also investigated.

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Fractal Scaling of Permeability in Unsaturated Fractured Tuff: Wavelet-Based Approach

  • Hyun, Yunjung
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.140-143
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    • 2003
  • Air permeabilities in unsaturated fractured tuff at the Apache Leap Research Site (ALRS) near Superior, Arizona, exhibit a self-affine behavior, thus renders a field random fractal. Based up fractal scaling, the observed scale effect has been interpreted [Hyun et al., 2002]. Recently, Frantziskonis and Hansen [2000] presented that fractal scaling can be represented based on wavelets. This study deals with the way of using wavelets for fractal scaling. A numerical study is presented to examine the applicability of wavelet-based approach to determining upscaled air permeability values on various data supports at the site. To characterize the scaling property of self-affine fields generated based upon wavelets, Hurst coefficient, H. was inferred by applying the average wavelet coefficient (AWC) method. The result yielded H = 0.24, which is very close to the result of geostatistical analysis using a power variogram (H = 0.22). The study concludes that wavelet-based scaling is a useful way of determining parameter values on different data supports, which is an essential task for modeling of subsurface flow and mass transport in a numeric grid with different resolutions (grid size).

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Application of Generalized Transmission Line Models to Mixed Ionic-Electronic Transport Phenomena

  • Ahn, Pyung-An;Shin, Eui-Chol;Kim, Gye-Rok;Lee, Jong-Sook
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.549-558
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    • 2011
  • Application of a generalized equivalent circuit including the electrode condition for the Hebb-Wagner polarization in the frequency domain proposed by Jamnik and Maier can provide a consistent set of material parameters, such as the geometric capacitance, partial conductivities, chemical capacitance or diffusivity, as well as electrode characteristics. Generalization of the shunt capacitors for the chemical capacitance by the constant phase elements (CPEs) was applied to a model mixed conducting system, $Ag_2S$, with electron-blocking AgI electrodes and ion-blocking Pt electrodes. While little difference resulted for the electron-blocking cell with almost ideal Warburg behavior, severely non-ideal behavior in the case of Pt electrodes not only necessitates a generalized transmission line model with shunt CPEs but also requires modelling of the leakage in the cell approximately proportional to the cell conductance, which then leads to partial conductivity values consistent with the electron-blocking case. Chemical capacitance was found to be closer to the true material property in the electron-blocking cell while excessively high chemical capacitance without expected silver activity dependence resulted in the electron-blocking cell. A chemical storage effect at internal boundaries is suggested to explain the anomalies in the respective blocking configurations.

Monitoring and Forecasting the Eyjafjallajökull Volcanic Ash using Combination of Satellite and Trajectory Analysis (인공위성 관측자료와 궤적분석을 이용한 Eyjafjallajökull 화산재 감시와 예측)

  • Lee, Kwon Ho
    • Journal of Korean Society for Atmospheric Environment
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    • v.30 no.2
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    • pp.139-149
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    • 2014
  • A new technique, namely the combination of satellite and trajectory analysis (CSTA), for exploring the spatio-temporal distribution information of volcanic ash plume (VAP) from volcanic eruption. CSTA uses the satellite derived ash property data and a matching forward-trajectories, which can generate airmass history pattern for specific VAP. In detail, VAP properties such as ash mask, aerosol optical thickness at 11 ${\mu}m$ ($AOT_{11}$), ash layer height, and effective radius from the Moderate Resolution Imaging Spectro-radiometer (MODIS) satellite were retrieved, and used to estimate the possibility of the ash forecasting in local atmosphere near volcano. The use of CSTA for Iceland's Eyjafjallaj$\ddot{o}$kull volcano erupted in May 2010 reveals remarkable spatial coherence for some VAP source-transport pattern. The CSTA forecasted points of VAP are consistent with the area of MODIS retrieved VAP. The success rate of the 24 hour VAP forecast result was about 77.8% in this study. Finally, the use of CSTA could provide promising results for VAP monitoring and forecasting by satellite observation data and verification with long term measurement dataset.

Development of polypropylene-clay nanocomposite with supercritical $CO_2$ assisted twin screw extrusion

  • Hwang, Tae-Yong;Lee, Sang-Myung;Ahn, Young-Joon;Lee, Jae-Wook
    • Korea-Australia Rheology Journal
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    • v.20 no.4
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    • pp.235-243
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    • 2008
  • The aim of this study is to explore the possibility of incorporating supercritical carbon dioxide ($scCO_2$) into twin screw extrusion process for the production of polypropylene-clay nanocomposite (PPCN). The $CO_2$ is used as a reversible plasticizer which is expected to rapidly transport polymeric chains into the galleries of clay layers in its supercritical condition inside the extruder barrel and to expand the gallery spacings in its sub-critical state upon emerging from die. The structure and properties of the resulting PPCNs are characterized using wide-angle X-ray diffraction (WAXD), transmission electron microscopy (TEM), rheometry, thermogravimetry and mechanical testing. In the processing of the PPCNs with $scCO_2$, optimum $scCO_2$ concentration and screw speed which maximized the degree of intercalation of clay layers were observed. The WAXD result reveals that the PP/PP-g-MA/clay system treated with $scCO_2$ has more exfoliated structure than that without $scCO_2$ treatment, which is supported by TEM result. $scCO_2$ processing enhanced the thermal stability of PPCN hybrids. From the measurement of linear viscoelastic property, a solid-like behavior at low frequency was observed for the PPCNs with high concentration of PP-g-MA. The use of $scCO_2$ generally increased Young's modulus and tensile strength of PPCN hybrids.